CN104991194A - Method for detecting dry-state zinc-silver battery in non-activated state - Google Patents

Method for detecting dry-state zinc-silver battery in non-activated state Download PDF

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Publication number
CN104991194A
CN104991194A CN201510357504.3A CN201510357504A CN104991194A CN 104991194 A CN104991194 A CN 104991194A CN 201510357504 A CN201510357504 A CN 201510357504A CN 104991194 A CN104991194 A CN 104991194A
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China
Prior art keywords
zinc
silver oxide
dry
oxide cell
dry state
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CN201510357504.3A
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Chinese (zh)
Inventor
刘孟峰
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CETC 18 Research Institute
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CETC 18 Research Institute
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Priority to CN201510357504.3A priority Critical patent/CN104991194A/en
Publication of CN104991194A publication Critical patent/CN104991194A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a method for detecting a dry-state zinc-silver battery in a non-activated state. The method includes the steps of: 101. selecting a ZM2353 LCR tester; adjusting the LCR tester to an ESR(ohm) gear, adjusting output frequency to 100kHz, and adjusting voltage to 1V; 102. connecting N dry-state zinc-silver battery cells in series to form a dry-sate zinc-silver battery group, and leading out a positive pole wiring terminal and a negative pole wiring terminal of the dry-state zinc-silver battery group; 103. electrically connecting the abovementioned positive pole wiring terminal and negative pole wiring terminal with two meter pens of the LCR tester; and 104. turning on the LCR tester, and obtaining an alternating current impedance value of the dry-state zinc-silver battery group. By adoption of the abovementioned technical scheme, the electrical performance condition of the battery can be judged without the need of activation and discharge in advance.

Description

The nonactivated detection method of a kind of dry state zinc-silver oxide cell
Technical field
The present invention relates to dry state zinc-silver oxide cell technical field, particularly relate to the nonactivated detection method of a kind of dry state zinc-silver oxide cell.
Background technology
The features such as to have specific energy high due to zinc-silver oxide cell, and specific power is large, can heavy-current discharge, discharging voltage balance, and voltage accuracy is high, and reliability, security are good, are widely used in each field.Zinc-silver oxide cell is generally in series by multiple cell, it is completely isolated for using between front electrolytic solution and battery pole plates group, when needing to use, the electrolytic solution separately deposited is injected pole plate group (activation), make it activate and set up electromotive force, can outside output voltage.
Zinc-silver oxide cell, due to its characteristic, judges that its electrical property situation often needs to adopt the detection method activating electric discharge.Therefore, in the dry storage process before its un-activation uses, cannot judge its electrical property.Adopt this method, battery electrical property situation can be detected before battery un-activation.
Summary of the invention
The technical problem to be solved in the present invention is: provide a kind of dry state zinc-silver oxide cell nonactivated detection method; This experimental technique makes zinc-silver oxide cell not need, through to activate in advance and discharge, can judge the electrical property situation of its battery.
The technical scheme that the present invention takes for the technical matters existed in solution known technology is:
The nonactivated detection method of a kind of dry state zinc-silver oxide cell, comprises the steps:
Step 101, choose the LCR tester that model is ZM2353; Described LCR tester is adjusted to ESR (Ω) shelves, output frequency is adjusted to 100kHz, Voltage Cortrol to 1V;
Step 102, by monomer series-connected for N number of dry state zinc-silver oxide cell rear composition dry state zinc-silver oxide cell group, and draw positive terminal and the negative terminal of dry state zinc-silver oxide cell group;
Step 103, above-mentioned positive terminal and negative terminal to be electrically connected with two root table pens of LCR tester respectively;
Step 104, unlatching LCR tester, obtain the AC impedance of dry state zinc-silver oxide cell group.
The advantage that the present invention has and good effect are:
1, method provided by the invention does not need activated batteries to test
2, method of testing of the present invention uses simple LCR tester to test, and test is simple, quick.
3, method of testing of the present invention can be assessed zinc-silver reserve battery and desiccates and deposit the situation of change of electrical property after a period of time.
Accompanying drawing illustrates:
Fig. 1 is test circuit figure of the present invention.
Fig. 2 is discharge capacity and the AC impedance comparison diagram of the different period of storage of certain zinc-silver oxide cell monomer.
Wherein: 1, dry state zinc-silver oxide cell group; 2, LCR tester.
Embodiment
For summary of the invention of the present invention, Characteristic can be understood further, hereby exemplify following examples, and coordinate accompanying drawing to be described in detail as follows:
Refer to Fig. 1 and Fig. 2, the nonactivated detection method of a kind of dry state zinc-silver oxide cell, comprises the steps:
Step 101, choose the LCR tester 2 that model is ZM2353; Described LCR tester 2 is adjusted to ESR (Ω) shelves, output frequency is adjusted to 100kHz, Voltage Cortrol to 1V;
Step 102, by monomer series-connected for N number of dry state zinc-silver oxide cell rear composition dry state zinc-silver oxide cell group 1, and draw positive terminal and the negative terminal of dry state zinc-silver oxide cell group 1;
Step 103, above-mentioned positive terminal and negative terminal to be electrically connected with two root table pens of LCR tester 2 respectively; Annexation as shown in Figure 1;
Step 104, unlatching LCR tester 2, obtain AC impedance and the discharge capacity value of dry state zinc-silver oxide cell group 1.
Principle of work of the present invention is:
According to capacitance principle, any two insulated from each other and all form a capacitor between the conductor (comprising wire) of being separated by very near.As shown in Figure 1, positive and negative pole plate is metallic conductor to the structural representation of dry state pole plate group, and barrier film is good insulating body, and therefore pole plate group has the characteristic of electric capacity.
According to the architectural characteristic of zinc-silver oxide cell dry state pole plate group, the AC impedance of dry state pole plate group includes Ohmage and electric capacity capacitive reactance two parts.The Ohmage of zinc-silver oxide cell dry state pole plate group can be ignored relative to electric capacity capacitive reactance.Therefore, according to the principle of electric capacity, zinc-silver oxide cell dry state pole plate group can be similar to regards plane-parallel capacitor as, and AC impedance is electric capacity capacitor value.The capacitor value of capacitor amasss with the right opposite at capacitor the two poles of the earth, insulating medium between two die openings and pole plate is relevant.Zinc-silver oxide cell is with longer storage duration, and positive/negative plate and barrier film composition all can change a lot, and therefore between pole plate, insulating medium there occurs change, and therefore capacitor value also can change thereupon, thus cause AC impedance to change.Therefore by ac impedance measurement, can qualitative reflection battery with longer storage duration, the situation of change of electrical property.
For checking the method validity, select certain zinc-silver oxide cell monomers some, store 2 years, 4 years, 6 years, 8 years and 10 years respectively and carry out AC impedance test and the test of monomer discharge capacity, test result as shown in Figure 2.As can be seen from the figure, this zinc-silver oxide cell monomer discharge capacity constantly reduce with period of storage and AC impedance then constantly increase, thus zinc-silver oxide cell monomer electrical property situation can be inferred by ac impedance measurement value.
Above embodiments of the invention have been described in detail, but described content being only preferred embodiment of the present invention, can not being considered to for limiting practical range of the present invention.All equalizations done according to the present patent application scope change and improve, and all should still belong within patent covering scope of the present invention.

Claims (1)

1. the nonactivated detection method of dry state zinc-silver oxide cell, is characterized in that: comprise the steps:
Step 101, choose the LCR tester that model is ZM2353; Described LCR tester is adjusted to ESR (Ω) shelves, output frequency is adjusted to 100kHz, Voltage Cortrol to 1V;
Step 102, by monomer series-connected for N number of dry state zinc-silver oxide cell rear composition dry state zinc-silver oxide cell group, and draw positive terminal and the negative terminal of dry state zinc-silver oxide cell group;
Step 103, above-mentioned positive terminal and negative terminal to be electrically connected with two root table pens of LCR tester respectively;
Step 104, unlatching LCR tester, obtain the AC impedance of dry state zinc-silver oxide cell group.
CN201510357504.3A 2015-06-25 2015-06-25 Method for detecting dry-state zinc-silver battery in non-activated state Pending CN104991194A (en)

Priority Applications (1)

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CN201510357504.3A CN104991194A (en) 2015-06-25 2015-06-25 Method for detecting dry-state zinc-silver battery in non-activated state

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Application Number Priority Date Filing Date Title
CN201510357504.3A CN104991194A (en) 2015-06-25 2015-06-25 Method for detecting dry-state zinc-silver battery in non-activated state

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR980012774A (en) * 1996-07-16 1998-04-30 이데이 노부유키 Charging device
US20060197498A1 (en) * 2005-03-07 2006-09-07 Constantin Bucur Battery state monitoring circuitry with low power consumption during a stand-by-state of a battery pack
CN101855761A (en) * 2007-11-08 2010-10-06 丰田自动车株式会社 Fuel cell system
CN104198949A (en) * 2014-09-09 2014-12-10 上虞安卡拖车配件有限公司 Battery health state detection method
CN104502844A (en) * 2014-11-18 2015-04-08 国家电网公司 Power lithium battery deterioration degree diagnosis method based on AC impedance

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR980012774A (en) * 1996-07-16 1998-04-30 이데이 노부유키 Charging device
US20060197498A1 (en) * 2005-03-07 2006-09-07 Constantin Bucur Battery state monitoring circuitry with low power consumption during a stand-by-state of a battery pack
CN101855761A (en) * 2007-11-08 2010-10-06 丰田自动车株式会社 Fuel cell system
CN104198949A (en) * 2014-09-09 2014-12-10 上虞安卡拖车配件有限公司 Battery health state detection method
CN104502844A (en) * 2014-11-18 2015-04-08 国家电网公司 Power lithium battery deterioration degree diagnosis method based on AC impedance

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
张永光: "贮备式锌-银电池氧化银电极的电化学性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅱ辑》 *
徐瑞云 等: "电化学测量分析仪", 《物理化学实验》 *
杨德才: "交流阻抗谱图的解析", 《锂离子电池安全性》 *

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