CN104962949A - Method for removing copper in nickel electrolysis anode solution for purification - Google Patents
Method for removing copper in nickel electrolysis anode solution for purification Download PDFInfo
- Publication number
- CN104962949A CN104962949A CN201510310800.8A CN201510310800A CN104962949A CN 104962949 A CN104962949 A CN 104962949A CN 201510310800 A CN201510310800 A CN 201510310800A CN 104962949 A CN104962949 A CN 104962949A
- Authority
- CN
- China
- Prior art keywords
- solution
- nickel
- copper
- purity
- anolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims abstract description 88
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 30
- 239000010949 copper Substances 0.000 title claims abstract description 30
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 14
- 229910052759 nickel Inorganic materials 0.000 title abstract description 41
- 238000000746 purification Methods 0.000 title abstract description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 20
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000000706 filtrate Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 9
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 11
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 claims description 8
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical group OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 6
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- JNVCSEDACVAATK-UHFFFAOYSA-L [Ca+2].[S-]SSS[S-] Chemical compound [Ca+2].[S-]SSS[S-] JNVCSEDACVAATK-UHFFFAOYSA-L 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 230000002829 reductive effect Effects 0.000 claims 2
- 229940051851 sulfurated lime Drugs 0.000 claims 2
- 235000011149 sulphuric acid Nutrition 0.000 claims 2
- 239000001117 sulphuric acid Substances 0.000 claims 2
- 239000003638 chemical reducing agent Substances 0.000 abstract description 4
- 230000033116 oxidation-reduction process Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 229910001431 copper ion Inorganic materials 0.000 description 10
- 239000000463 material Substances 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011825 aerospace material Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Electrolytic Production Of Metals (AREA)
Abstract
本发明公开了一种镍电解阳极液中净化除铜的方法，该方法为：在镍电解阳极液中加入还原剂调整镍电解阳极液的氧化还原电位，再用稀硫酸调整至溶液pH=1.3~4.0，溶液温度控制在50~70℃；在调整好的溶液中加入硫化钡粉末，50~70℃下搅拌反应20~50分钟，热过滤，收集滤液测定溶液中的铜含量。本发明具有净化效果显著、操作简单、运行成本低、绿色无毒等优点。The invention discloses a method for purifying and removing copper in the nickel electrolysis anolyte. The method comprises: adding a reducing agent to the nickel electrolysis anolyte to adjust the oxidation-reduction potential of the nickel electrolysis anolyte, and then using dilute sulfuric acid to adjust the pH of the solution to 1.3 ~4.0, the solution temperature is controlled at 50~70°C; add barium sulfide powder to the adjusted solution, stir and react at 50~70°C for 20~50 minutes, heat filter, collect the filtrate to measure the copper content in the solution. The invention has the advantages of remarkable purification effect, simple operation, low operating cost, green and non-toxic, and the like.
Description
技术领域 technical field
本发明涉及一种镍电解阳极液中净化除铜的方法。 The invention relates to a method for purifying and removing copper in nickel electrolysis anolyte.
背景技术 Background technique
金属镍在国民经济中占重要地位，是重要的战略性资源和用途非常广泛的金属单质材料。实际应用中，镍主要是以合金元素的形式用于特殊用途的零部件、精密仪器和军事装备材料中，是军事、机械、钢铁和航空材料中必不可少的添加剂。镍能够与其它金属材料按比例形成用途各异的金属合金材料，如镍基耐热材料、镍基耐蚀材料、镍基耐磨材料和镍基精密记忆材料。镍基合金材料被广泛的应用于航空、生物、化工等领域。广阔的镍市场对镍的纯度和质量都提出了严格要求。在镍的电解过程中，镍电解阳极液中的铜离子一旦流入阴极会先于镍在阴极析出，影响电镍质量，因此镍电解阳极液净化除铜成为保证电镍质量的关键。本发明主要针对镍电解阳极液的净化除铜，可作为一种除铜方法在电解镍生产或类似情况下使用，降低液体铜离子含量，保证电解镍的产品质量，具有实际的应用价值和很大的市场潜力。 Nickel metal plays an important role in the national economy, and is an important strategic resource and a metal element material with a wide range of uses. In practical applications, nickel is mainly used in the form of alloying elements in special-purpose parts, precision instruments and military equipment materials, and is an essential additive in military, machinery, steel and aerospace materials. Nickel can form metal alloy materials with different uses in proportion with other metal materials, such as nickel-based heat-resistant materials, nickel-based corrosion-resistant materials, nickel-based wear-resistant materials and nickel-based precision memory materials. Nickel-based alloy materials are widely used in aviation, biology, chemical and other fields. The vast nickel market imposes strict requirements on the purity and quality of nickel. In the process of nickel electrolysis, once the copper ions in the nickel electrolysis anolyte flow into the cathode, they will be precipitated at the cathode before the nickel, which affects the quality of the electrolytic nickel. Therefore, the purification and removal of copper from the nickel electrolytic anolyte becomes the key to ensure the quality of the electrolytic nickel. The present invention is mainly aimed at the purification and copper removal of nickel electrolytic anolyte, and can be used as a copper removal method in electrolytic nickel production or similar situations to reduce the liquid copper ion content and ensure the product quality of electrolytic nickel, which has practical application value and great Great market potential.
发明内容 Contents of the invention
本发明的目的在于提供一种除铜效果好、操作简便的镍电解阳极液中净化除铜的方法。 The object of the present invention is to provide a method for purifying and removing copper in nickel electrolysis anolyte with good copper removal effect and easy operation.
为了实现以上目的，本发明所采用的技术方案是： In order to achieve the above object, the technical solution adopted in the present invention is:
在镍电解阳极液中加入还原剂调整镍电解阳极液的氧化还原电位至50~200mV，再用稀硫酸调整至溶液pH=1.3~4.0，溶液温度控制在50~70℃；在调整好的溶液中加入硫化钡粉末，50~70℃下搅拌反应20~50分钟，热过滤，收集滤液测定溶液中的铜含量。 Add a reducing agent to the nickel electrolysis anolyte to adjust the oxidation-reduction potential of the nickel electrolysis anolyte to 50~200mV, then adjust the solution pH to 1.3~4.0 with dilute sulfuric acid, and control the solution temperature at 50~70°C; Add barium sulfide powder to the solution, stir and react at 50~70°C for 20~50 minutes, heat filter, collect the filtrate to measure the copper content in the solution.
所述还原剂为水合肼溶液、镍粉、硫化钙、盐酸羟胺。 The reducing agent is hydrazine hydrate solution, nickel powder, calcium sulfide, hydroxylamine hydrochloride.
所述水合肼溶液的质量浓度为10%；所述镍粉的纯度为99.5%，粒径小于50μm；所述硫化钙的纯度为97%，粒径小于50μm；所述盐酸羟胺的纯度为99%。 The mass concentration of the hydrazine hydrate solution is 10%; the purity of the nickel powder is 99.5%, and the particle size is less than 50 μm; the purity of the calcium sulfide is 97%, and the particle size is less than 50 μm; the purity of the hydroxylamine hydrochloride is 99% %.
所述稀硫酸的质量浓度为10%。 The mass concentration of the dilute sulfuric acid is 10%.
所述硫化钡的纯度为80%，粒径小于50μm，其加入的摩尔量为铜离子摩尔量的1~5倍。 The purity of the barium sulfide is 80%, the particle size is less than 50 μm, and the molar amount added is 1 to 5 times the molar amount of copper ions.
本发明的除铜原理是：硫化钡水解，缓慢释放硫化氢，硫化氢与溶液中的铜离子反应生成难溶的硫化铜，经过滤除去沉淀即可达到净化除铜的目的。由于镍电解阳极液具有较强的氧化性，为防止除铜的有效成分硫化氢与溶液中的氧化剂发生反应而失去除铜活性，因此除铜前需要先加入还原剂改善镍电解阳极液的氧化还原状态。 The copper removal principle of the present invention is: barium sulfide is hydrolyzed, slowly releases hydrogen sulfide, hydrogen sulfide reacts with copper ions in the solution to form insoluble copper sulfide, and the purpose of purifying and removing copper can be achieved by removing precipitates by filtration. Since the nickel electrolytic anolyte has strong oxidizing properties, in order to prevent the effective component of copper removal, hydrogen sulfide, from reacting with the oxidizing agent in the solution and lose the copper removal activity, it is necessary to add a reducing agent before removing copper to improve the oxidation of the nickel electrolytic anolyte. restore state.
除铜反应方程如下： The copper removal reaction equation is as follows:
具体实施方式 Detailed ways
实施例1： Example 1:
取镍电解阳极液（铜含量为800mg/L）1升，加入水合肼溶液调整镍电解阳极液的氧化还原电位至150mV，用稀硫酸调整至溶液pH=1.3，溶液温度控制为55℃。在调整好的1升溶液中加入硫化钡粉末，硫化钡摩尔量为铜离子摩尔量的1倍，70℃下搅拌反应20分钟，热过滤，收集滤液测定溶液中的铜含量，结果为0.46mg/L。 Take 1 liter of nickel electrolysis anolyte (copper content is 800mg/L), add hydrazine hydrate solution to adjust the redox potential of the nickel electrolysis anolyte to 150mV, adjust the pH of the solution to 1.3 with dilute sulfuric acid, and control the solution temperature to 55°C. Add barium sulfide powder to 1 liter of the adjusted solution, the molar weight of barium sulfide is 1 times the molar weight of copper ions, stir and react at 70°C for 20 minutes, heat filter, collect the filtrate to measure the copper content in the solution, the result is 0.46mg /L.
实施例2： Example 2:
取镍电解阳极液（铜含量为800mg/L）1升，加入水合肼溶液调整镍电解阳极液的氧化还原电位至150mV，用稀硫酸调整至溶液pH=4.0，溶液温度控制为70℃。在调整好的1升溶液中加入硫化钡粉末，硫化钡摩尔量为铜离子摩尔量的5倍，70℃下搅拌反应30分钟，热过滤，收集滤液测定溶液中的铜含量，结果为0.094mg/L。 Take 1 liter of nickel electrolysis anolyte (copper content is 800mg/L), add hydrazine hydrate solution to adjust the redox potential of nickel electrolysis anolyte to 150mV, adjust the solution pH to 4.0 with dilute sulfuric acid, and control the solution temperature to 70°C. Add barium sulfide powder into 1 liter of the adjusted solution, the molar weight of barium sulfide is 5 times of the molar weight of copper ions, stir and react at 70°C for 30 minutes, heat filter, collect the filtrate to measure the copper content in the solution, the result is 0.094mg /L.
实施例3： Example 3:
取镍电解阳极液（铜含量为800mg/L）1升，加入镍粉调整镍电解阳极液的氧化还原电位至50mV，用稀硫酸调整至溶液pH=1.5，溶液温度控制为65℃。在调整好的1升溶液中加入硫化钡粉末，硫化钡摩尔量为铜离子摩尔量的3倍，65℃下搅拌反应50分钟，热过滤，收集滤液测定溶液中的铜含量，结果为0.92mg/L。 Take 1 liter of nickel electrolysis anolyte (with a copper content of 800mg/L), add nickel powder to adjust the redox potential of the nickel electrolysis anolyte to 50mV, adjust the solution pH to 1.5 with dilute sulfuric acid, and control the solution temperature to 65°C. Add barium sulfide powder to 1 liter of the adjusted solution, the molar weight of barium sulfide is 3 times of the molar weight of copper ions, stir and react at 65°C for 50 minutes, heat filter, collect the filtrate to measure the copper content in the solution, the result is 0.92mg /L.
实施例4： Example 4:
取镍电解阳极液（铜含量为800mg/L）1升，加入镍粉调整镍电解阳极液的氧化还原电位至100mV，用稀硫酸调整至溶液pH=1.5，溶液温度控制为65℃。在调整好的1升溶液中加入硫化钡粉末，硫化钡摩尔量为铜离子摩尔量的5倍，65℃下搅拌反应50分钟，热过滤，收集滤液测定溶液中的铜含量，结果为0.80mg/L。 Take 1 liter of nickel electrolysis anolyte (copper content is 800mg/L), add nickel powder to adjust the oxidation-reduction potential of the nickel electrolysis anolyte to 100mV, adjust the pH of the solution to 1.5 with dilute sulfuric acid, and control the solution temperature to 65°C. Add barium sulfide powder into 1 liter of the adjusted solution, the molar weight of barium sulfide is 5 times of the molar weight of copper ions, stir and react at 65°C for 50 minutes, heat filter, collect the filtrate to measure the copper content in the solution, the result is 0.80mg /L.
实施例5： Example 5:
取镍电解阳极液（铜含量为800mg/L）1升，加入硫化钙粉末调整镍电解阳极液的氧化还原电位至100mV，用稀硫酸调整至溶液pH=1.5，溶液温度控制为65℃。在调整好的1升溶液中加入硫化钡粉末，硫化钡摩尔量为铜离子摩尔量的5倍，65℃下搅拌反应20分钟，热过滤，收集滤液测定溶液中的铜含量，结果为0.90mg/L。 Take 1 liter of nickel electrolysis anolyte (copper content is 800mg/L), add calcium sulfide powder to adjust the oxidation-reduction potential of the nickel electrolysis anolyte to 100mV, adjust the pH of the solution to 1.5 with dilute sulfuric acid, and control the solution temperature to 65°C. Add barium sulfide powder into 1 liter of the adjusted solution, the molar weight of barium sulfide is 5 times the molar weight of copper ions, stir and react at 65°C for 20 minutes, heat filter, collect the filtrate to measure the copper content in the solution, the result is 0.90mg /L.
实施例6： Embodiment 6:
取镍电解阳极液（铜含量为800mg/L）1升，加入盐酸羟胺调整镍电解阳极液的氧化还原电位至200mV，用稀硫酸调整至溶液pH=1.5，溶液温度控制为65℃。在调整好的1升溶液中加入硫化钡粉末，硫化钡摩尔量为铜离子摩尔量的5倍，65℃下搅拌反应20分钟，热过滤，收集滤液测定溶液中的铜含量，结果为0.25mg/L。 Take 1 liter of nickel electrolysis anolyte (copper content is 800mg/L), add hydroxylamine hydrochloride to adjust the redox potential of the nickel electrolysis anolyte to 200mV, adjust the solution pH to 1.5 with dilute sulfuric acid, and control the solution temperature to 65°C. Add barium sulfide powder into 1 liter of the adjusted solution, the molar weight of barium sulfide is 5 times of the copper ion molar weight, stir and react at 65°C for 20 minutes, heat filter, collect the filtrate to measure the copper content in the solution, the result is 0.25mg /L.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510310800.8A CN104962949A (en) | 2015-06-09 | 2015-06-09 | Method for removing copper in nickel electrolysis anode solution for purification |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510310800.8A CN104962949A (en) | 2015-06-09 | 2015-06-09 | Method for removing copper in nickel electrolysis anode solution for purification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104962949A true CN104962949A (en) | 2015-10-07 |
Family
ID=54217028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510310800.8A Pending CN104962949A (en) | 2015-06-09 | 2015-06-09 | Method for removing copper in nickel electrolysis anode solution for purification |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104962949A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111411229A (en) * | 2020-04-29 | 2020-07-14 | 长沙华时捷环保科技发展股份有限公司 | Process for efficiently separating nickel and copper in nickel electrolyte |
| CN112981458A (en) * | 2021-02-04 | 2021-06-18 | 中国科学院兰州化学物理研究所 | Method for regulating and controlling brightness of appearance of nickel button |
| CN115233257A (en) * | 2022-04-27 | 2022-10-25 | 金川集团股份有限公司 | A kind of control method of nickel electrolytic purification to remove copper depth |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB528112A (en) * | 1939-03-21 | 1940-10-23 | Frederick William Atack | Improvements in the electrolytic production of manganese |
| US5783057A (en) * | 1996-09-19 | 1998-07-21 | Nippon Mining & Metals Co., Ltd. | Method of purifying copper electrolytic solution |
| US6214238B1 (en) * | 1998-07-27 | 2001-04-10 | Tosco Corporation | Method for removing selenocyanate ions from waste water |
| JP2004169158A (en) * | 2002-11-22 | 2004-06-17 | Nippon Mining & Metals Co Ltd | Copper electrolyte cleaning method |
| CN1765764A (en) * | 2004-10-25 | 2006-05-03 | 郭胜 | Copper-containing waste acid water treatment method |
| JP2007270291A (en) * | 2006-03-31 | 2007-10-18 | Nikko Kinzoku Kk | Method of producing metallic nickel from crude nickel sulfate |
| CN102964015A (en) * | 2012-12-11 | 2013-03-13 | 湖南大学 | Method for removing heavy metals Zn and Cu in dredged river sediment |
| JP2013067841A (en) * | 2011-09-22 | 2013-04-18 | Sumitomo Metal Mining Co Ltd | Method for removing copper ion in nickel chloride aqueous solution and method for producing electrolytic nickel |
| EP2584055A1 (en) * | 2010-06-21 | 2013-04-24 | Sumitomo Metal Mining Co., Ltd. | Method for removal of copper ions from copper-containing nickel chloride solution, and process for production of electrolytic nickel |
| CN103320811A (en) * | 2013-06-05 | 2013-09-25 | 中南大学 | Method for removing impurities from nickel electrolysis anolyte |
| CN103820809A (en) * | 2014-02-28 | 2014-05-28 | 金川集团股份有限公司 | Copper removal method |
-
2015
- 2015-06-09 CN CN201510310800.8A patent/CN104962949A/en active Pending
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB528112A (en) * | 1939-03-21 | 1940-10-23 | Frederick William Atack | Improvements in the electrolytic production of manganese |
| US5783057A (en) * | 1996-09-19 | 1998-07-21 | Nippon Mining & Metals Co., Ltd. | Method of purifying copper electrolytic solution |
| US6214238B1 (en) * | 1998-07-27 | 2001-04-10 | Tosco Corporation | Method for removing selenocyanate ions from waste water |
| JP2004169158A (en) * | 2002-11-22 | 2004-06-17 | Nippon Mining & Metals Co Ltd | Copper electrolyte cleaning method |
| CN1765764A (en) * | 2004-10-25 | 2006-05-03 | 郭胜 | Copper-containing waste acid water treatment method |
| JP2007270291A (en) * | 2006-03-31 | 2007-10-18 | Nikko Kinzoku Kk | Method of producing metallic nickel from crude nickel sulfate |
| EP2584055A1 (en) * | 2010-06-21 | 2013-04-24 | Sumitomo Metal Mining Co., Ltd. | Method for removal of copper ions from copper-containing nickel chloride solution, and process for production of electrolytic nickel |
| JP2013067841A (en) * | 2011-09-22 | 2013-04-18 | Sumitomo Metal Mining Co Ltd | Method for removing copper ion in nickel chloride aqueous solution and method for producing electrolytic nickel |
| CN102964015A (en) * | 2012-12-11 | 2013-03-13 | 湖南大学 | Method for removing heavy metals Zn and Cu in dredged river sediment |
| CN103320811A (en) * | 2013-06-05 | 2013-09-25 | 中南大学 | Method for removing impurities from nickel electrolysis anolyte |
| CN103820809A (en) * | 2014-02-28 | 2014-05-28 | 金川集团股份有限公司 | Copper removal method |
Non-Patent Citations (4)
| Title |
|---|
| LIN LI等: "Removal of Cu from the nickel electrolysis anolyte using amorphous MnS", 《HYDROMETALLURGY》 * |
| 卢建波 等: "基于铜离子活化的非晶态硫化镍净化除铜研究", 《现代化工》 * |
| 王得祥 等: "基于硫化镍除铜反应的化学添加剂对电解镍质量影响研究", 《材料导报》 * |
| 赵思佳: "镍电解液除铜技术研究进展", 《湖南有色金属》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111411229A (en) * | 2020-04-29 | 2020-07-14 | 长沙华时捷环保科技发展股份有限公司 | Process for efficiently separating nickel and copper in nickel electrolyte |
| CN111411229B (en) * | 2020-04-29 | 2021-04-09 | 长沙华时捷环保科技发展股份有限公司 | Process for efficiently separating nickel and copper in nickel electrolyte |
| CN112981458A (en) * | 2021-02-04 | 2021-06-18 | 中国科学院兰州化学物理研究所 | Method for regulating and controlling brightness of appearance of nickel button |
| CN112981458B (en) * | 2021-02-04 | 2022-05-17 | 中国科学院兰州化学物理研究所 | Method for regulating and controlling brightness of appearance of nickel button |
| CN115233257A (en) * | 2022-04-27 | 2022-10-25 | 金川集团股份有限公司 | A kind of control method of nickel electrolytic purification to remove copper depth |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6299620B2 (en) | Method for producing nickel sulfate | |
| CN103320811A (en) | Method for removing impurities from nickel electrolysis anolyte | |
| CN104357671A (en) | Method for separating and recovering vanadium and chromium from vanadium-chromium slag | |
| PH12016501636B1 (en) | Method for producing seed crystals used for producing hydrogen-reduced nickel powder | |
| CN104962949A (en) | Method for removing copper in nickel electrolysis anode solution for purification | |
| CN110510659A (en) | A method for comprehensively treating waste copper-nickel skin | |
| CN103820809B (en) | A kind of copper-removing method | |
| CN107779599B (en) | A kind of preparation and its application method of rare precious metal complex reducing agent | |
| CN103510106B (en) | A kind of copper electrolysis additive and using method thereof | |
| JP6218121B2 (en) | Purification method of aqueous cobalt chloride solution | |
| CN102010007B (en) | Method for producing industrial-grade ammonium dimolybdate by combination method | |
| CN114517263A (en) | Method for extracting and recovering nickel from nickel-containing waste capacitor material and preparing nickel product | |
| JP2016210648A (en) | Method of producing nickel sulfate | |
| CN102251120B (en) | Desulfurization method for acid leaching process of manganese-rich slag | |
| CN104561579B (en) | A kind of method of composite reduction high efficiente callback rare precious metal | |
| CN104805285B (en) | Method for leaching gold by virtue of thiosulfate utilizing ammonium alcohol polyvinyl phosphate as additive | |
| CN106853999B (en) | A kind of method using ABS plating metal charge production high pure nitric acid nickel and copper powder | |
| WO2016194658A1 (en) | Aqueous cobalt chloride solution purification method | |
| JP2009126759A (en) | Method of preparing high-purity solution containing nickel sulfate and cobalt sulfate, and method of producing high-purity nickel with use of the same solution | |
| CN110724837B (en) | Method for selectively separating iron and chromium in hydrochloric acid system solution | |
| CN104928540A (en) | Al-Nb-Si-Ti intermediate alloy and preparation method thereof | |
| CN102560562A (en) | Manufacturing method and application method of nickel-based intermetallic compound inert anode | |
| CN103864157B (en) | A kind of preparation method of amorphous state nickel sulfide | |
| JP2016222976A5 (en) | ||
| CN102730759A (en) | A preparing method for an ultra-pure ammonium tungstate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151007 |