CN104962039A - Anti-static electricity modified plastic composition - Google Patents
Anti-static electricity modified plastic composition Download PDFInfo
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- CN104962039A CN104962039A CN201510362119.8A CN201510362119A CN104962039A CN 104962039 A CN104962039 A CN 104962039A CN 201510362119 A CN201510362119 A CN 201510362119A CN 104962039 A CN104962039 A CN 104962039A
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Abstract
The invention discloses an anti-static electricity modified plastic composition. Aiming at the defects of existing modified plastics, the anti-static electricity modified plastic composition is made of preparation raw materials such as inorganic salt, carboxylic acids, olefine acids, anti-static electricity epoxy resin, cellulose acetate fiber, hydroxyethyl cellulose sodium polyacrylate, nanometer Zinc oxide, polyethylene, an interface modifying agent, a plasticizer, a dispersed lubricant, solubilizer and a curing agent. The anti-static electricity modified plastic composition is non-poisonous and harmless, good in weather resistance, good in stability, remarkable in antistatic effect and long in service life, the defects of traditional modified plastics are broken, and the practical value is high.
Description
Technical field
The present invention relates to a kind of macromolecule modified plastics, especially relate to a kind of anti-electrostatic modified plastic composition.
Background technology
Along with the development of industry, plastics obtain applying more and more widely.Polyethylene, polypropylene, PTT polyester, ABS etc. are used in the industries such as water saving irrigation, building, indoor decoration, furniture, electric power, transport in a large number.Nowadays, plastics are employed in increasing field, plastics widespread use in our life, have become indispensable integral part in our life.
But now nearly all plastics are all isolators, easily produce electrostatic, the static voltage of thousands of even tens thousand of volt can produced in some cases.This physical property just because of plastics brings much problem hidden danger, loss or even disaster to people in the process using plastic prod, the electromagnetic field that such as electrostatic produces makes plastics very easily attract dust just as suction cleaner, impact is normal produces, and causes product appearance defect; For another example, in numerous industry such as petrochemical complex, mining, static sparking can bring blast, if process not in time and control, with the plastics of electrostatic just as a stealthy bomb, may ignite at any time, therefore all can need to use effective antistatic plastic in a lot of field now.
Summary of the invention
Goal of the invention: in order to solve in prior art existing problem, the present invention proposes that antistatic effect is good, the anti-electrostatic modified plastic composition of long service life.
Technical scheme: to achieve these objectives, the present invention takes following technical scheme: a kind of anti-electrostatic modified plastic composition, the raw materials of following component is comprised: inorganic salt 9-12 part according to weighing scale, carboxylic-acid 6-15 part, olefin(e) acid class 5-8 part, antistatic epoxide resin 12-14 part, cellulose acetate 6-12 part, Natvosol 8-16 part, sodium polyacrylate 5-10 part, nano zine oxide 6-10 part, polyethylene 6-12 part, interface modifier 6-8 part, softening agent 10-12 part, dispersed lubricant 3-10 part, solubilizing agent 5-12 part, solidifying agent 6-10 part, wherein solidifying agent is calcium nitrite, glacial acetic acid and water reducer are mixed, its each material mass adding proportion is followed successively by 3:1:1.
Further, described inorganic salt are calcium salt or silicate.
Further, described carboxylic-acid and olefin(e) acid class carbon atom number are 6-12.
Further, described interface modifier is macromolecule interfacial modifier.
Further, described dispersion agent is the polymkeric substance of the oh group be connected with side direction containing linear main chain.
Further, described softening agent is ester plasticizer.
Further, described solubilizing agent is sorbyl alcohol and the amino acid whose mixture of lard type.
Further, sorbyl alcohol and the amino acid whose mixture of lard type of described solubilizing agent to be mass ratio be 3:2.
Further, described water reducer is powdery water-reducing agent.
Beneficial effect: a kind of anti-electrostatic modified plastic composition provided by the invention, for the defect that existing modified plastics exists, by inorganic salt, carboxylic-acid, olefin(e) acid class, antistatic epoxide resin, cellulose acetate, Natvosol sodium polyacrylate, nano zine oxide, polyethylene, interface modifier, softening agent, dispersed lubricant, solubilizing agent, the raw materials such as solidifying agent are formed, anti-electrostatic modified plastic composition of the present invention, not only nontoxic, good weatherability, there is good stability, and antistatic effect is remarkable, long service life, breach the defect of traditional modified plastics, there is very strong practical value.
Embodiment
Embodiment 1:
A kind of anti-electrostatic modified plastic composition, the raw materials of following component is comprised: 9 parts, inorganic salt, carboxylic-acid 6 parts, olefin(e) acid class 5 parts, antistatic epoxide resin 12 parts, cellulose acetate 6 parts, Natvosol 8 parts, sodium polyacrylate 5 parts, nano zine oxide 6 parts, polyethylene 6 parts, interface modifier 6 parts, 10 parts, softening agent, dispersed lubricant 3 parts, solubilizing agent 5 parts, 6 parts, solidifying agent according to weighing scale, wherein solidifying agent is that calcium nitrite, glacial acetic acid and water reducer are mixed, and its each material mass adding proportion is followed successively by 3:1:1.
Wherein, above-mentioned inorganic salt are calcium salt or silicate; Carboxylic-acid and olefin(e) acid class carbon atom number are 6-12; Interface modifier is macromolecule interfacial modifier; Described dispersion agent is the polymkeric substance of the oh group be connected with side direction containing linear main chain; Described softening agent is ester plasticizer; Sorbyl alcohol and the amino acid whose mixture of lard type of described solubilizing agent to be mass ratio be 3:2; Described water reducer is powdery water-reducing agent.
Embodiment 2:
A kind of anti-electrostatic modified plastic composition, the raw materials of following component is comprised: 12 parts, inorganic salt, carboxylic-acid 15 parts, olefin(e) acid class 8 parts, antistatic epoxide resin 14 parts, cellulose acetate 12 parts, Natvosol 16 parts, sodium polyacrylate 10 parts, nano zine oxide 10 parts, polyethylene 12 parts, interface modifier 8 parts, 12 parts, softening agent, dispersed lubricant 10 parts, solubilizing agent 12 parts, 10 parts, solidifying agent according to weighing scale, wherein solidifying agent is that calcium nitrite, glacial acetic acid and water reducer are mixed, and its each material mass adding proportion is followed successively by 3:1:1.
Wherein, above-mentioned inorganic salt are calcium salt or silicate; Carboxylic-acid and olefin(e) acid class carbon atom number are 6-12; Interface modifier is macromolecule interfacial modifier; Described dispersion agent is the polymkeric substance of the oh group be connected with side direction containing linear main chain; Described softening agent is ester plasticizer; Sorbyl alcohol and the amino acid whose mixture of lard type of described solubilizing agent to be mass ratio be 3:2; Described water reducer is powdery water-reducing agent.
Embodiment 3:
A kind of anti-electrostatic modified plastic composition, the raw materials of following component is comprised: 11 parts, inorganic salt, carboxylic-acid 10 parts, olefin(e) acid class 5-8 part, antistatic epoxide resin 13 parts, cellulose acetate 9 parts, Natvosol 12 parts, sodium polyacrylate 8 parts, nano zine oxide 8 parts, polyethylene 9 parts, interface modifier 7 parts, 11 parts, softening agent, dispersed lubricant 6 parts, solubilizing agent 7 parts, 8 parts, solidifying agent according to weighing scale, wherein solidifying agent is that calcium nitrite, glacial acetic acid and water reducer are mixed, and its each material mass adding proportion is followed successively by 3:1:1.
Wherein, above-mentioned inorganic salt are calcium salt or silicate; Carboxylic-acid and olefin(e) acid class carbon atom number are 6-12; Interface modifier is macromolecule interfacial modifier; Described dispersion agent is the polymkeric substance of the oh group be connected with side direction containing linear main chain; Described softening agent is ester plasticizer; Sorbyl alcohol and the amino acid whose mixture of lard type of described solubilizing agent to be mass ratio be 3:2; Described water reducer is powdery water-reducing agent.
Get according to above-described embodiment 1-3 composition traditionally plastics preparation method be prepared into modified plastic composition, according to GB/T 15738-2008 " Test method of resistivity for fibre reinforced conducting and antistatic plastics ", its antistatic property is measured, its surface resistivity and volume specific resistance all meet use standard, and are better than traditional anti-static plastic.
Use a kind of anti-electrostatic modified plastic composition of above-described embodiment 1-3, more traditional anti-static plastic, not only nontoxic, good weatherability, there is good stability and antistatic effect is remarkable, long service life, breaches the defect of traditional modified plastics, has very strong practical value.
It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvement, these improvement also should be considered as protection scope of the present invention.
Claims (9)
1. an anti-electrostatic modified plastic composition, it is characterized in that the raw materials comprising following component according to weighing scale: inorganic salt 9-12 part, carboxylic-acid 6-15 part, olefin(e) acid class 5-8 part, antistatic epoxide resin 12-14 part, cellulose acetate 6-12 part, Natvosol 8-16 part, sodium polyacrylate 5-10 part, nano zine oxide 6-10 part, polyethylene 6-12 part, interface modifier 6-8 part, softening agent 10-12 part, dispersed lubricant 3-10 part, solubilizing agent 5-12 part, solidifying agent 6-10 part, wherein solidifying agent is calcium nitrite, glacial acetic acid and water reducer are mixed, its each material mass adding proportion is followed successively by 3:1:1.
2. anti-electrostatic modified plastic composition according to claim 1, is characterized in that: described inorganic salt are calcium salt or silicate.
3. anti-electrostatic modified plastic composition according to claim 1, is characterized in that: described carboxylic-acid and olefin(e) acid class carbon atom number are 6-12.
4. anti-electrostatic modified plastic composition according to claim 1, is characterized in that: described interface modifier is macromolecule interfacial modifier.
5. anti-electrostatic modified plastic according to claim 1, is characterized in that: described dispersion agent is the polymkeric substance of the oh group be connected with side direction containing linear main chain.
6. anti-electrostatic modified plastic composition according to claim 1, is characterized in that: described softening agent is ester plasticizer.
7. anti-electrostatic modified plastic composition according to claim 1, is characterized in that: described solubilizing agent is sorbyl alcohol and the amino acid whose mixture of lard type.
8. anti-electrostatic modified plastic composition according to claim 7, is characterized in that: sorbyl alcohol and the amino acid whose mixture of lard type of described solubilizing agent to be mass ratio be 3:2.
9. anti-electrostatic modified plastic composition according to claim 1, is characterized in that: described water reducer is powdery water-reducing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510362119.8A CN104962039A (en) | 2015-06-26 | 2015-06-26 | Anti-static electricity modified plastic composition |
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| CN201510362119.8A CN104962039A (en) | 2015-06-26 | 2015-06-26 | Anti-static electricity modified plastic composition |
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| CN104962039A true CN104962039A (en) | 2015-10-07 |
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| CN201510362119.8A Pending CN104962039A (en) | 2015-06-26 | 2015-06-26 | Anti-static electricity modified plastic composition |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106750557A (en) * | 2016-12-08 | 2017-05-31 | 滁州麦迪尔塑胶有限公司 | A kind of antistatic heat resist modification plastics composite |
| CN110177842A (en) * | 2017-01-23 | 2019-08-27 | 株式会社资生堂 | Containing powder composition and its manufacturing method and cosmetics |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4448911A (en) * | 1983-04-12 | 1984-05-15 | Owens-Corning Fiberglas Corporation | Aqueous epoxy sizing composition for glass fibers and fibers sized therewith |
| CN1333315A (en) * | 2000-07-11 | 2002-01-30 | 上海惠邦特种涂料有限公司 | Elastic building paint |
| CN1792961A (en) * | 2005-11-28 | 2006-06-28 | 乌鲁木齐汇源新科技开发有限公司 | Engineering material synthesized by mica |
| CN103205068A (en) * | 2013-01-27 | 2013-07-17 | 甘春丽 | Antistatic soaked-plastic product and preparation method thereof |
-
2015
- 2015-06-26 CN CN201510362119.8A patent/CN104962039A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4448911A (en) * | 1983-04-12 | 1984-05-15 | Owens-Corning Fiberglas Corporation | Aqueous epoxy sizing composition for glass fibers and fibers sized therewith |
| CN1333315A (en) * | 2000-07-11 | 2002-01-30 | 上海惠邦特种涂料有限公司 | Elastic building paint |
| CN1792961A (en) * | 2005-11-28 | 2006-06-28 | 乌鲁木齐汇源新科技开发有限公司 | Engineering material synthesized by mica |
| CN103205068A (en) * | 2013-01-27 | 2013-07-17 | 甘春丽 | Antistatic soaked-plastic product and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106750557A (en) * | 2016-12-08 | 2017-05-31 | 滁州麦迪尔塑胶有限公司 | A kind of antistatic heat resist modification plastics composite |
| CN110177842A (en) * | 2017-01-23 | 2019-08-27 | 株式会社资生堂 | Containing powder composition and its manufacturing method and cosmetics |
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Application publication date: 20151007 |
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