CN104961372A - Setting time-adjustable waterproof foam stabilizer and preparation method thereof - Google Patents
Setting time-adjustable waterproof foam stabilizer and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a setting time-adjustable waterproof foam stabilizer and a preparation method thereof. The waterproof foam stabilizer comprises, by weight, 40-60 parts of stearic acid, 8-10 parts of potassium hydroxide, 2-4 parts of soda ash, 25-38 parts of ammonia water, 0.06 parts of sodium fluoride, 6-9 parts of triethanolamine, 10-50 parts of sodium chloride, 5-15 parts of lithium carbonate and 814-904 parts of water. The waterproof foam stabilizer prepared in the invention can be applied in foamed cement in order to effectively control the setting rate of the foamed cement at different production environment temperatures, has a far lower formwork collapsing rate than a same type of common ammonium stearate emulsion stabilizers, can shorten the demolding and cutting time, shortens the construction period, and is suitable for popularization use.
Description
Technical field
The invention belongs to wall heat insulation material technical field, be specifically related to adjustable waterproof suds-stabilizing agent a kind of time of coagulation and preparation method thereof.
Background technology
China has a large amount of newly constructed house every year, only within 2013, just has 20.1 hundred million square metres of newly constructed houses, and annual newly constructed house area is also in increase.Along with the needs of the construction of national development " resource-conserving, environmentally friendly " society, building energy conservation is subject to increasing attention.Present stage building energy conservation enforcement, mainly reduce the energy loss of refrigeration and heating in house use procedure, this not only relates to the improvement of heating refrigeration equipment, the more important thing is and strengthens house building enclosure energy-efficient treatment, reduces Discussion on architecture thermal convection thus realizes building energy conservation.No matter the energy-efficient treatment to the building enclosure that newly finishes a house, or the reducing energy consumption to old house building enclosure, all need to use a large amount of heat insulating wall materials.Wherein, cement based foamed products, as cement foaming insulation board, aerated blocks etc., has the advantages such as cost is low, performance good, environment friendly and pollution-free, is widely used gradually.
In the production of China's cement insulation board, remain in some technological deficiencies, the sedimentation wherein comparatively seriously occurred in cement foaming insulation board production process, mould situation of collapsing, had a strong impact on the quality of production efficiency and product; The problem that the not enough water-intake rate caused of the compactness of cement foaming insulation board air vent wall is higher in addition, easily causes product heat-insulating property to decline and weather resistance declines.Cause sedimentation, mould phenomenon of collapsing occur reason be: add in the cement slurry good to mixing whipping agent formed porous foaming idiosome after, because suds-stabilizing agent surely steeps limited time, and cement setting formation intensity needs the regular hour, to support its deadweight, the even overall sedimentation of subsiding of local will be there is, collapse mould in the foaming idiosome undercapacity of porous.
In addition, when producing at different ambient temperatures, the surface hardening time of cement foaming insulation board and envrionment temperature are obvious negative correlation, and when winter environment temperature is not less than 5 DEG C, its surface hardening time is not less than 135min; And when summer environment temperature is not less than 25 DEG C, its surface hardening time is not less than 75min.When only using ammonium stearate as suds-stabilizing agent, the foaming idiosome surface hardening time is not better higher than foam stabilizing effect during 60min, and mould rate of collapsing is very low; There is certain sedimentation phenomenon and along with the increase of mould rate of collapsing in foaming idiosome surface hardening time 60 ~ 90min; The foaming idiosome surface hardening time, mould rate of collapsing was higher when more than 120min.
For solving the problem, the steady bubble time of suds-stabilizing agent need be extended and accelerate the rate of setting of cement.Comparatively general way uses the rapid hardening cement Substitute For Partials such as aluminosulfate cement or whole silicate cement at present, thus shorten the time of coagulation of gelling material.But do like this along with series of side effects: 1) rapid hardening cement longterm strength causes product strength to decline lower than ordinary Portland cement; 2) rapid hardening cement aquation condensation post-shrinkage ratio is comparatively large, easily causes the decline of product compactness thus causes ftractureing and the increase of water-intake rate; 3) when using part or all of rapid hardening cement to substitute ordinary Portland cement, the Costco Wholesale of production is added, the complexity of production technique also increased.
Summary of the invention
The object of this invention is to provide adjustable waterproof suds-stabilizing agent a kind of time of coagulation, this waterproof suds-stabilizing agent can promote the condensation of gelling material in foam cement product, reduces sedimentation and mould phenomenon of collapsing, and shortens its production cycle.
For achieving the above object, the technical solution used in the present invention is: the waterproof suds-stabilizing agent that a kind of time of coagulation is adjustable, shared by each component, weight proportion is: stearic acid 40 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 25 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 9 parts, 10 ~ 50 parts, sodium-chlor, Quilonum Retard 5 ~ 15 parts, 814 ~ 904 parts, water.
In such scheme, described ammoniacal liquor is industrial ammoniacal liquor, and described ammoniacal liquor is industrial ammoniacal liquor, and mass concentration is 19 ~ 21%.
Preferably, when construction environment temperature is higher than 25 DEG C, in described waterproof suds-stabilizing agent, shared by each component, weight proportion is: stearic acid 40 ~ 50 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 25 ~ 32 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 7 parts, 10 ~ 20 parts, sodium-chlor, Quilonum Retard 5 ~ 10 parts, 867 ~ 904 parts, water.
Preferably, when construction environment temperature is at 15 ~ 25 DEG C, in described waterproof suds-stabilizing agent, shared by each component, weight proportion is: stearic acid 50 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 32 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 7 parts, 15 ~ 35 parts, sodium-chlor, Quilonum Retard 5 ~ 15 parts, 831 ~ 882 parts, water.
Preferably, when construction environment temperature is at 5 ~ 15 DEG C, in described waterproof suds-stabilizing agent, shared by each component, weight proportion is: stearic acid 50 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 32 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 7 ~ 9 parts, 25 ~ 50 parts, sodium-chlor, Quilonum Retard 10 ~ 15 parts, 814 ~ 866 parts, water.
The preparation method of the waterproof suds-stabilizing agent that above-mentioned a kind of time of coagulation is adjustable, comprises the following steps:
1) each raw material is taken by following weight proportion: stearic acid 40 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 25 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 9 parts, 10 ~ 50 parts, sodium-chlor, Quilonum Retard 5 ~ 15 parts, 814 ~ 904 parts, water;
2) water accounting for water total mass 1/3 ~ 2/5 is placed in stirred vessel, be heated to 60 ~ 65 DEG C, then potassium hydroxide, soda ash, Sodium Fluoride, sodium-chlor and Quilonum Retard is added, be stirred to after dissolving completely, add stearic acid rapidly, be stirred to stearic acid to dissolve completely, obtain ammonium stearate emulsion (surely steeping component); Then add the water of residuals weight, add trolamine when temperature is down to 20 ~ 25 DEG C, after stirring, add ammoniacal liquor, continue to be stirred to forming homogeneous emulsion, obtain adjustable waterproof suds-stabilizing agent described time of coagulation.
For achieving the above object, principle of design of the present invention is: only using the ammonium stearate with good foam stabilizing effect as surely steeping component, making full use of its water-proof function, and optimizing the production technique of ammonium stearate emulsion; But when adopting separately ammonium stearate as steady bubble component, usually need to add other suds-stabilizing agents such as rosin based suds-stabilizing agent, protein-based suds-stabilizing agent, the stability of guarantee foaming idiosome, avoid mould phenomenon of collapsing, the present invention uses the steady foam system adapted with cement foamed product further, balance hydrated cementitious time and suds-stabilizing agent surely steep the time, reduce the generation of collapse mould and sedimentation, and shorten the production cycle.
Stearic acid is dissolved in the alkaline solution of heat by the present invention, alkaline solution comprises potassium hydroxide and soda ash, and regulate alkali and stearic stoichiometric ratio by Reasonable Regulation And Control proportioning, make stearic acid and alkali that sufficient chemical reaction can occur, and avoid base excess to waste, obtained ammonium stearate emulsion is as surely steeping component; Prepare in the process of ammonium stearate emulsion and only need once to heat, make full use of hydration heat when alkali and water react, technique is simple, save energy.
The present invention adopts trolamine, sodium-chlor, Quilonum Retard to form ternary early strong system.When trolamine is more than 20 DEG C, early strong Be very effective, and when temperature 5 DEG C its early potent fruit can not play very well, simultaneously because trolamine volume is lower, the extremely bad control of its volume, too highly can affect later strength, too lowly can not play its early strength function again, trolamine and sodium-chlor are mixed again, its low-temperature high-early strength effect can not only be recovered, and trolamine can be made when concentration is lower well to play its early potent fruit.When sodium-chlor is separately as hardening accelerator, needs larger volume could obtain early potent fruit, itself and Quilonum Retard are mixed again, can significantly reduce its consumption.Quilonum Retard morning extensive chemical mechanism from trolamine and sodium-chlor all different, the synergistic effect of early potent fruit can be produced when mixing further, and contribute to the longterm strength improving cement products.Therefore, use trolamine, sodium-chlor, Quilonum Retard composition ternary early strong system, overcome the shortcoming that when single hardening accelerator uses, low, the required volume of low-temperature high-early strength usefulness is large, longterm strength is not enough, and play the synergy between different hardening accelerator.By regulating the time of coagulation of the adjustable cement cementitious material of consumption of accelerating component.And strong system can be good at being adapted to the alkaline environment in cement foaming insulation board foaming process this morning.
When trolamine, sodium-chlor, Quilonum Retard ternary strong system morning and ammonium stearate steady foam system compound use, because ammonium stearate has very strong surfactivity, gelling material particles can be made better to be scattered in water, trolamine better can be attached to cement particle surface, it is made to strengthen the effect that hydrated cementitious promotes, trolamine and ammonium stearate, sodium-chlor, Quilonum Retard and the steady metallic cation steeping potassium and sodium etc. in emulsion form complex compound simultaneously, better can destroy cement particle surface hydrated product wall, increase hydrated cementitious speed.Through rational volume proportioning test, by the adjustment to steady bubble component and ternary accelerating component volume, can ensure that the time of coagulation of cement foamed idiosome is lower than 60min, effectively reduce the generation of collapse mould and sedimentation, ensured quality product; And greatly shorten the demoulding and curing time, thus shorten the production cycle, increase production efficiency; Meanwhile, waterproof suds-stabilizing agent of the present invention can be used as admixture unique in cement foamed goods and uses, and simplifies production process.
Beneficial effect of the present invention is:
1) waterproof suds-stabilizing agent of the present invention effectively can regulate the time of coagulation of gelling material in the cement foamed article manufacturing process such as foaming insulation board, and reduces it and occur sedimentation and the phenomenons such as mould of collapsing, and is applicable to promoting the use of.
2) waterproof suds-stabilizing agent of the present invention can be used as the production of unique admixture for cement foamed goods, can effectively enhance productivity, and reduces production cost, simplifies production process.
Embodiment
For a better understanding of the present invention, illustrate content of the present invention further below in conjunction with specific embodiment, but content of the present invention is not only confined to the following examples.
In following examples, as no specific instructions, the reagent of employing is commercially available chemical reagent.
In following examples, thermal conductivity is tested according to GB/T 10295-2008 " the mensuration heat flowmeter method of Technology of Steady State Thermal Resistance of Thermal Insulating Material and related characteristics "; Apparent density is tested according to GB/T 5486-2008 " inorganic hard insulating product test method ", and baking oven for heating temperature is 65 ± 2 DEG C; Ultimate compression strength is tested according to after GB/T 5486-2008 " inorganic hard insulating product test method " in laboratory conditions maintenance 3d; Water-intake rate measures according to GB/T 5486 " inorganic hard insulating product test method "; Mould rate of collapsing and surface hardening time are obtained by observation.
Embodiment 1
When the production environment temperature of cement foaming insulation board is 30 DEG C:
The waterproof suds-stabilizing agent that a kind of time of coagulation is adjustable, the addition of each raw material is: stearic acid 45kg, potassium hydroxide 8kg part, soda ash 3kg, ammoniacal liquor 28kg (mass concentration is 20%), Sodium Fluoride 60g, trolamine 7kg, sodium-chlor 15kg, Quilonum Retard 8kg, water 886kg, its preparation method comprises the following steps:
300kg water is placed in stirred vessel, is heated to 60 DEG C, add potassium hydroxide, soda ash, Sodium Fluoride, sodium-chlor and Quilonum Retard, stir 1min to dissolving completely, add stearic acid rapidly, continue to stir 10min and dissolve completely to stearic acid, obtain ammonium stearate emulsion (surely steeping component); Then add 586kg water, when solution is cooled to 20 DEG C, add trolamine, stir 5min, then add ammoniacal liquor, continue to stir 15min and form homogeneous latex emulsion, obtain adjustable waterproof suds-stabilizing agent described time of coagulation.
The waterproof suds-stabilizing agent that the time of coagulation obtained by the present embodiment is adjustable is applied to prepares cement foaming insulation board, and the addition of each component is: normal silicate 42.5 cement 55kg, flyash 35kg, polypropylene fibre 0.3kg, water 38kg, waterproof suds-stabilizing agent 5kg, hydrogen peroxide (mass concentration 27.5%) 5.4kg that time of coagulation is adjustable; Its preparation method comprises the following steps: first water, waterproof suds-stabilizing agent that time of coagulation is adjustable and polypropylene fibre are placed in whipping device and stir 10s; Then add ordinary Portland cement and stir 3min, obtain homogeneous slurry; Then add hydrogen peroxide, after stirring 10s rapidly, pour slurry into mould foaming immediately, under natural condition, form removal after maintenance 12h, cuts after 1d, obtains described cement foaming insulation board.
The cement foaming insulation board that the present embodiment is obtained carries out performance test, the results are shown in Table 1.
The performance test results of the cement foaming insulation board that table 1 embodiment 1 is obtained
Embodiment 2
When the production environment temperature of cement foaming insulation board is 20 DEG C:
The foam cement waterproof suds-stabilizing agent that a kind of time of coagulation is adjustable, the addition of each raw material is: stearic acid 50kg, potassium hydroxide 9kg, soda ash 3kg, ammoniacal liquor 32kg (mass concentration is 20%), Sodium Fluoride 60g, trolamine 7kg, sodium-chlor 20kg, Quilonum Retard 10kg, water 869kg, its preparation method comprises the following steps:
300kg water is placed in stirred vessel, is heated to 60 DEG C, add potassium hydroxide, soda ash, Sodium Fluoride, sodium-chlor and Quilonum Retard, stir 1min to dissolving completely, add stearic acid rapidly, continue to stir 10min and dissolve completely to stearic acid, obtain ammonium stearate emulsion (surely steeping component); Then add 569kg water, when solution is cooled to 20 DEG C, add trolamine, stir 5min, then add ammoniacal liquor, continue to stir 15min and form homogeneous latex emulsion, obtain adjustable waterproof suds-stabilizing agent described time of coagulation.
Be applied to by foam cement waterproof suds-stabilizing agent obtained for the present embodiment and prepare cement foaming insulation board, the addition of each component is: normal silicate 42.5 cement 55kg, flyash 35kg, polypropylene fibre 0.3kg, water 38kg, waterproof suds-stabilizing agent 5kg, hydrogen peroxide (mass concentration 27.5%) 5.8kg that time of coagulation is adjustable; Its preparation method comprises the following steps: first water, waterproof suds-stabilizing agent that time of coagulation is adjustable and polypropylene fibre are placed in whipping device and stir 10s; Then add ordinary Portland cement and stir 3min, obtain homogeneous slurry; Then add hydrogen peroxide, after stirring 10s rapidly, pour slurry into mould foaming immediately, under natural condition, form removal after maintenance 12h, cuts after 1d, obtains described cement foaming insulation board.
The cement foaming insulation board that the present embodiment is obtained carries out performance test, the results are shown in Table 2.
The performance test results of the cement foaming insulation board that table 2 embodiment 2 is obtained
Embodiment 3
When the production environment temperature of cement foaming insulation board is 10 DEG C:
The waterproof suds-stabilizing agent that a kind of time of coagulation is adjustable, the addition of each raw material is: stearic acid 55kg, potassium hydroxide 10kg, soda ash 3.5kg, ammoniacal liquor 38kg (mass concentration is 20%), Sodium Fluoride 60g, trolamine 9kg, sodium-chlor 40kg, Quilonum Retard 15kg, water 830kg, its preparation method comprises the following steps:
300kg water is placed in stirred vessel, is heated to 60 DEG C, add potassium hydroxide, soda ash, Sodium Fluoride, sodium-chlor and Quilonum Retard, stir 1min to dissolving completely, add stearic acid rapidly, continue to stir 10min and dissolve completely to stearic acid, obtain ammonium stearate emulsion (surely steeping component); Then add 530kg water, when solution is cooled to 20 DEG C, add trolamine, stir 5min, then add ammoniacal liquor, continue to stir 15min and form homogeneous latex emulsion, obtain adjustable waterproof suds-stabilizing agent described time of coagulation.
The waterproof suds-stabilizing agent that the time of coagulation obtained by the present embodiment is adjustable is applied to prepares cement foaming insulation board, and the addition of each component is: normal silicate 42.5 cement 55kg, flyash 35kg, polypropylene fibre 0.3kg, water 38kg, waterproof suds-stabilizing agent 5kg, hydrogen peroxide (mass concentration 27.5%) 6.5kg that time of coagulation is adjustable; Its preparation method comprises the following steps: first water, waterproof suds-stabilizing agent that time of coagulation is adjustable and polypropylene fibre are placed in whipping device and stir 10s; Then add ordinary Portland cement and stir 3min, obtain homogeneous slurry; Then add hydrogen peroxide, after stirring 10s rapidly, pour slurry into mould foaming immediately, under natural condition, form removal after maintenance 1d, cuts after 2d, obtains described cement foaming insulation board.
The cement foaming insulation board that the present embodiment is obtained carries out performance test, the results are shown in Table 3.
The performance test results of the cement foaming insulation board that table 3 embodiment 3 is obtained
Comparative example 1
When the production environment temperature of cement foaming insulation board is 10 DEG C:
A kind of cement foaming insulation board, the addition of each raw material is: normal silicate 42.5 cement 55kg, flyash 35kg, polypropylene fibre 0.3kg, water 38kg, ammonium stearate emulsion (mass concentration is 5.8%) 6.5kg, hydrogen peroxide (mass concentration is 27.5%) 5.8kg, and its preparation method comprises the following steps:
First water, ammonium stearate emulsion and polypropylene fibre are placed in whipping device and stir 10s, then add ordinary Portland cement and stir 3min, obtain homogeneous slurry; Then add hydrogen peroxide, after stirring 10s rapidly, pour slurry into mould foaming immediately, under natural condition, form removal after maintenance 1d, cuts after 3d, obtains cement foaming insulation board.
Obtained cement foaming insulation board is carried out performance test, the results are shown in Table 4.
The performance test results (construction temperature is 10 DEG C) of the cement foaming insulation board that table 4 comparative example 1 is obtained
Comparative example 2
When the production environment temperature of cement foaming insulation board is 10 DEG C:
A kind of cement foaming insulation board, the addition of each raw material is: normal silicate 42.5 cement 55kg, flyash 35kg, polypropylene fibre 0.3kg, water 38kg, ammonium stearate emulsion (mass concentration is 5.8%) 6.5kg, trolamine 9kg, hydrogen peroxide (mass concentration is 27.5%) 5.8kg, and its preparation method comprises the following steps:
First water, ammonium stearate emulsion, trolamine and polypropylene fibre are placed in whipping device and stir 10s, then add ordinary Portland cement and stir 3min, obtain homogeneous slurry; Then add hydrogen peroxide, after stirring 10s rapidly, pour slurry into mould foaming immediately, under natural condition, form removal after maintenance 1d, cuts after 3d, obtains cement foaming insulation board.
Obtained cement foaming insulation board is carried out performance test, the results are shown in Table 5.
The performance test results (construction temperature is 10 DEG C) of the cement foaming insulation board that table 5 comparative example 2 is obtained
Comparative example 3
When the production environment temperature of cement foaming insulation board is 10 DEG C:
A kind of cement foaming insulation board, the addition of each raw material is: normal silicate 42.5 cement 55kg, flyash 35kg, polypropylene fibre 0.3kg, water 38kg, ammonium stearate emulsion (mass concentration is 5.8%) 6.5kg, sodium-chlor 40kg, hydrogen peroxide (mass concentration is 27.5%) 5.8kg, and its preparation method comprises the following steps:
First water, ammonium stearate emulsion and polypropylene fibre are placed in whipping device and stir 10s, then add ordinary Portland cement and sodium-chlor stirring 3min, obtain homogeneous slurry; Then add hydrogen peroxide, after stirring 10s rapidly, pour slurry into mould foaming immediately, under natural condition, form removal after maintenance 1d, cuts after 3d, obtains cement foaming insulation board.
Obtained cement foaming insulation board is carried out performance test, the results are shown in Table 6.
The performance test results (construction temperature is 10 DEG C) of the cement foaming insulation board that table 6 comparative example 3 is obtained
Comparative example 4
When the production environment temperature of cement foaming insulation board is 10 DEG C:
A kind of cement foaming insulation board, the addition of each raw material is: normal silicate 42.5 cement 55kg, flyash 35kg, polypropylene fibre 0.3kg, water 38kg, ammonium stearate emulsion (mass concentration is 5.8%) 6.5kg, Quilonum Retard 15kg, hydrogen peroxide (mass concentration is 27.5%) 5.8kg, and its preparation method comprises the following steps:
First water, ammonium stearate emulsion and polypropylene fibre are placed in whipping device and stir 10s, then add ordinary Portland cement and sodium-chlor stirring 3min, obtain homogeneous slurry; Then add hydrogen peroxide, after stirring 10s rapidly, pour slurry into mould foaming immediately, under natural condition, form removal after maintenance 1d, cuts after 3d, obtains cement foaming insulation board.
Obtained cement foaming insulation board is carried out performance test, the results are shown in Table 7.
The performance test results (construction temperature is 10 DEG C) of the cement foaming insulation board that table 7 comparative example 4 is obtained
In embodiment 1 ~ 3, performance table with test results is bright: at different production environment temperature, by the change to proportioning raw materials of the present invention, can control cement setting speed to control the surface hardening time in cement foaming insulation board production process.
The performance test results in embodiment 3 and comparative example 1 shows: waterproof suds-stabilizing agent the present invention obtained is applied in foam cement, its mould rate of collapsing is well below common ammonium stearate emulsion suds-stabilizing agent of the same type, and decrease the time of the demoulding and cutting, shorten the duration, Be very effective.
The performance test results in embodiment 3 and comparative example 2 ~ 4 shows: ternary accelerating component (trolamine, sodium-chlor, Quilonum Retard) can promote that the time of coagulation of cement foaming insulation board and steady bubble time reach equilibrium relationship, and the accelerating component of single component cannot meet the Production requirement under cement foaming insulation board low temperature environment.
The foregoing is only the preferred embodiment of the present invention, it should be pointed out that for the person of ordinary skill of the art, without departing from the concept of the premise of the invention, make some improvement and conversion, these all belong to protection scope of the present invention.
Claims (6)
1. the waterproof suds-stabilizing agent that time of coagulation is adjustable, it is characterized in that, shared by each component, weight proportion is: stearic acid 40 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 25 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 9 parts, 10 ~ 50 parts, sodium-chlor, Quilonum Retard 5 ~ 15 parts, 814 ~ 904 parts, water.
2. waterproof suds-stabilizing agent according to claim 1, is characterized in that, described ammoniacal liquor is industrial ammoniacal liquor, and mass concentration is 19 ~ 21%.
3. waterproof suds-stabilizing agent according to claim 1, it is characterized in that, shared by each component, weight proportion is: stearic acid 40 ~ 50 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 25 ~ 32 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 7 parts, 10 ~ 20 parts, sodium-chlor, Quilonum Retard 5 ~ 10 parts, 867 ~ 904 parts, water.
4. waterproof suds-stabilizing agent according to claim 1, it is characterized in that, shared by each component, weight proportion is: stearic acid 50 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 32 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 7 parts, 15 ~ 35 parts, sodium-chlor, Quilonum Retard 5 ~ 15 parts, 831 ~ 882 parts, water.
5. waterproof suds-stabilizing agent according to claim 1, it is characterized in that, shared by each component, weight proportion is: stearic acid 50 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 32 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 7 ~ 9 parts, 25 ~ 50 parts, sodium-chlor, Quilonum Retard 10 ~ 15 parts, 814 ~ 866 parts, water.
6. the preparation method of the waterproof suds-stabilizing agent that the time of coagulation described in any one of Claims 1 to 5 is adjustable, is characterized in that, comprise the following steps:
1) each raw material is taken by following weight proportion: stearic acid 40 ~ 60 parts, 8 ~ 10 parts, potassium hydroxide, soda ash 2 ~ 4 parts, ammoniacal liquor 25 ~ 38 parts, Sodium Fluoride 0.06 part, trolamine 6 ~ 9 parts, 10 ~ 50 parts, sodium-chlor, Quilonum Retard 5 ~ 15 parts, 814 ~ 904 parts, water;
2) water accounting for water total mass 1/3 ~ 2/5 is placed in stirred vessel, is heated to 60 ~ 65 DEG C, then add potassium hydroxide, soda ash, Sodium Fluoride, sodium-chlor and Quilonum Retard, be stirred to after dissolving completely, add stearic acid, be stirred to stearic acid and dissolve completely; Then add the water of residuals weight, add trolamine when temperature is down to 20 ~ 25 DEG C, after stirring, add ammoniacal liquor, continue to be stirred to forming homogeneous emulsion, obtain adjustable waterproof suds-stabilizing agent described time of coagulation.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019099444A (en) * | 2017-12-08 | 2019-06-24 | 太平洋セメント株式会社 | Construction method of mortar or concrete using ultra rapid hardening cement |
| CN110255962A (en) * | 2019-04-30 | 2019-09-20 | 武汉理工大学 | A kind of hydrophobicity chemical combination hole bolt object lotion and preparation method thereof |
| CN110357478A (en) * | 2019-08-21 | 2019-10-22 | 黑龙江恒昌新型建筑材料有限公司 | A kind of rigid waterproofing agent and preparation method thereof |
| CN110950609A (en) * | 2019-12-20 | 2020-04-03 | 汝州市东江建筑工业科技有限公司 | Ultra-light heat-preservation aerated concrete for prefabricated parts and preparation method thereof |
| CN111763029A (en) * | 2020-06-09 | 2020-10-13 | 广东首诚建设科技有限公司 | Foaming agent capable of reducing water absorption of foam mixed light soil |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6244343B1 (en) * | 2000-03-09 | 2001-06-12 | Halliburton Energy Services, Inc. | Cementing in deep water offshore wells |
| CN101519287A (en) * | 2009-02-17 | 2009-09-02 | 河南省绿韵建材有限公司 | Multifunctional waterproof anti-leakage liquid for cement mortar and a preparation method thereof |
| CN102701780A (en) * | 2012-05-18 | 2012-10-03 | 江苏沃因思建筑节能科技有限公司 | Preparation method of polymer foamed cement heat-insulation board |
| CN102795800A (en) * | 2012-09-06 | 2012-11-28 | 吴江市晴亿纺织有限公司 | Soluble metallic soap waterproofing agent |
| CN103183487A (en) * | 2013-04-24 | 2013-07-03 | 重庆思贝肯节能技术开发有限公司 | Preparation method of modified common silicate cement based foam insulating plate and special assistant |
| CN104628420A (en) * | 2015-01-16 | 2015-05-20 | 济南大学 | Production method of waterproofing agent |
-
2015
- 2015-06-10 CN CN201510316175.8A patent/CN104961372B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6244343B1 (en) * | 2000-03-09 | 2001-06-12 | Halliburton Energy Services, Inc. | Cementing in deep water offshore wells |
| CN101519287A (en) * | 2009-02-17 | 2009-09-02 | 河南省绿韵建材有限公司 | Multifunctional waterproof anti-leakage liquid for cement mortar and a preparation method thereof |
| CN102701780A (en) * | 2012-05-18 | 2012-10-03 | 江苏沃因思建筑节能科技有限公司 | Preparation method of polymer foamed cement heat-insulation board |
| CN102795800A (en) * | 2012-09-06 | 2012-11-28 | 吴江市晴亿纺织有限公司 | Soluble metallic soap waterproofing agent |
| CN103183487A (en) * | 2013-04-24 | 2013-07-03 | 重庆思贝肯节能技术开发有限公司 | Preparation method of modified common silicate cement based foam insulating plate and special assistant |
| CN104628420A (en) * | 2015-01-16 | 2015-05-20 | 济南大学 | Production method of waterproofing agent |
Non-Patent Citations (2)
| Title |
|---|
| 刘其城等: "《混凝土外加剂》", 31 January 2009 * |
| 黄玉媛等: "《小化工产品配方》", 30 June 2008 * |
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| CN110255962B (en) * | 2019-04-30 | 2021-08-10 | 武汉理工大学 | Hydrophobic compound pore plug emulsion and preparation method thereof |
| CN110357478A (en) * | 2019-08-21 | 2019-10-22 | 黑龙江恒昌新型建筑材料有限公司 | A kind of rigid waterproofing agent and preparation method thereof |
| CN110950609A (en) * | 2019-12-20 | 2020-04-03 | 汝州市东江建筑工业科技有限公司 | Ultra-light heat-preservation aerated concrete for prefabricated parts and preparation method thereof |
| CN111763029A (en) * | 2020-06-09 | 2020-10-13 | 广东首诚建设科技有限公司 | Foaming agent capable of reducing water absorption of foam mixed light soil |
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