CN104961213A - Water treating agent for removing organo-chlorine pesticides in water - Google Patents
Water treating agent for removing organo-chlorine pesticides in water Download PDFInfo
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- CN104961213A CN104961213A CN201510355907.4A CN201510355907A CN104961213A CN 104961213 A CN104961213 A CN 104961213A CN 201510355907 A CN201510355907 A CN 201510355907A CN 104961213 A CN104961213 A CN 104961213A
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Abstract
The invention relates to a water treating agent for removing organo-chlorine pesticides in water. The water treating agent is formed in a composite mode by the raw materials of 3, 7-dimethyl-6-octenal, 3-amino-2-hydracrylic acid, 4-nitro-2-phenoxy methane sulfonyl aniline, aluminum sulfate, trans, trans-2, 4-nonadienal, 5, 4'-dyhydroxy-7-methoxy group isoflavone, alpha-amino isocaproicacid, sodium alginate, arborinone, Arurasperone D, isoimperatorin, sodium polyacrylate, 3, 7, 11-trimethyl-1, 6, 10-dodecatriene-3-alcohol, D-acridine-2-carboxylic acid and 2-ethyl-2, 5-dimethyl caproic acid. The complexing power of the water treating agent and the organo-chlorine pesticides is high, the formed complex is high in sediment speed, the removing rate can reach 99%, toxicity is low, using amount is low, a water body is not damaged, and processing cost is low.
Description
Technical field
The present invention relates to a kind of water conditioner removing organochlorine pesticide in water, belong to environmental protection technical field.
Background technology
China brings into use organochlorine pesticide from the 40's of 20th century, and because their controls are wide, drug effect is better than other agricultural chemicals at that time and acute toxicity is low, does not find its residual toxicity at that time, is thus widely used in the insect pest of control crop, forest and livestock.The 60's of 20th century, the production of organochlorine pesticide and usage quantity accounted for the over half of China's agricultural chemicals ultimate production always to the beginning of the eighties.Within 1970, China uses HCHs altogether, DDTs, the organochlorine insecticides such as toxaphene 19.17 × 10
4ton, accounts for 80.1% of agricultural chemicals ultimate production, peaks, stopped organochlorine pesticide HCHs thereafter in 1983, the production of DDTs and use in the 70's of 20th century.Current China also exist multiple pesticide-like POPs production, use and discarded stock, be faced with relevant POPs pollute severe situation.
The main source that environment water Pesticides pollutes has: the discharge of wastewater of (l) pesticide producing factory; (2) the plants and soil remained on surface agricultural chemicals rainwater shower after applying pesticides and infiltration; (3) loss of pesticide producing, the course of processing, as the volatilization of agricultural chemicals finished product, the discharge etc. of waste gas, smog, dust.Remains of pesticide in air floating or adsorb by the floating dust in air, or to be suspended in air with gas or aerocolloidal state.Agricultural chemicals residual in air, the motion with air spread, the scope of topsoil is constantly expanded, the organochlorine pesticide with high stable can enter in atmosphere convection layer, thus propagates into far place, and Polluted area is constantly expanded.The agricultural chemicals part entered in air enters soil and water due to vapor condenses.The organochlorine pesticide existed in environment all causes serious threat to the mankind and other biology, this is mainly because organochlorine pesticide is not easy degraded at environment, by the inrichment of biology, and then by food chain enter in human body or organism cause accumulation and have an effect.Because organochlorine pesticide has very high fat-soluble, not easily excreted by metabolic degradation in vivo, be therefore easy to enrichment in vivo, the enrichment times particularly in hydrobiont (as fish) body is just higher.Just accumulate in vivo after the mankind are edible again thus harm is produced to the health of the mankind.
Although the degradation technique of existing organochlorine pesticide achieves certain progress, be mostly in the laboratory study stage.High-level oxidation technology, because condition is harsh, it is high to invest, reactor manufactures the shortcomings such as complicated, is difficult to scale process chlorobenzene class waste water, is only suitable for pre-treatment or aftertreatment.Microbiological deterioration CBs is utilized to be very promising environment clearance technique, but the reaction mechanism of microbiological deterioration chlorobenzene still imperfectly understands, and the impact of outside atmosphere on microorganism growth and chlorobenzene degraded is very large, the impact how overcoming environment is the difficult point of practical application.Although reduction method process chlorobenzene has some superiority, along with a large amount of metal ion for the treatment of processes enters waste water, cause new pollution, the high flow rate of zero-valent metal also result in the difficulty of practical application.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of water conditioner removing organochlorine pesticide in water, it can with the organochlorine pesticide effect in water, form complex compound sediment, remove by filtering, there is low toxicity, non-environmental-pollution, clearance is high, the advantage that cost is low.
Technology contents of the present invention is: a kind of water conditioner removing organochlorine pesticide in water, comprises the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 10-20 part,
3-amino-2 hydroxy propanoic acid 6-10 part,
Nimesulide 0.4-1.0 part,
Tai-Ace S 150 15-20 part,
Instead, trans-2,4-nonadienal 10-20 parts,
Prunetin 0.7-1.5 part,
Alpha-amino group isocaproic acid 6-14 part,
Sodium Alginate 10-15 part,
Chinese lime sub-terpene alcohol 3-8 part,
Ou Nansipi ketone D 2-6 part,
Isoimperatorin 2-5 part,
Sodium polyacrylate 5-10 part,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 15-30 part,
D-acridine-2-carboxylic acid 5-8 part,
2-ethyl-2,5-dimethylhexanoic acid 4-6 part.
Preferably, the raw material of the following meter of mark is by weight comprised:
3,7-dimethyl-6-octenal 15 parts,
3-amino-2 hydroxy propanoic acid 8 parts,
Nimesulide 0.7 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 15 parts,
Prunetin 1.1 parts,
Alpha-amino group isocaproic acid 10 parts,
Sodium Alginate 12 parts,
The sub-terpene alcohol of Chinese lime 5 parts,
Ou Nansipi ketone D 4 parts,
Isoimperatorin 3 parts,
Sodium polyacrylate 7 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,
D-acridine-2-carboxylic acid 6 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
The present invention has following beneficial effect:
(1) 3,7-dimethyl-6-octenal, 3-amino-2 hydroxy propanoic acid, nimesulide, Tai-Ace S 150 four kinds of materials produce synergy, can with quintozene effect, form complex compound sediment; Instead, trans-2,4-nonadienals, Prunetin, alpha-amino group isocaproic acid, Sodium Alginate, the sub-terpene alcohol of Chinese lime, these six kinds of materials of Ou Nansipi ketone D produce synergy, can with orthodichlorobenzene and santochlor effect, formed complex compound sediment; Isoimperatorin, sodium polyacrylate, 3,7,11-trimethylammoniums-1,6,10-12 carbon triolefin-3-alcohol, D-acridine-2-carboxylic acid, 2-ethyl-2,5-dimethylhexanoic acid five kinds of materials produce synergy, can with the effect of heptachlor benzene, form complex compound sediment;
(2) strong with the complex ability of organochlorine pesticide, form complex compound sediment speed fast, clearance can reach 99%;
(3) hypotoxicity, consumption is few, does not produce harm to water body;
(4) only need dosing and filtering separation device, low for equipment requirements, processing cost is low.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but the present invention's scope required for protection is not limited to the described scope of embodiment.
Embodiment 1
Remove a water conditioner for organochlorine pesticide in water, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 11 parts,
3-amino-2 hydroxy propanoic acid 7 parts,
Nimesulide 0.5 part,
16 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 12 parts,
Prunetin 0.8 part,
Alpha-amino group isocaproic acid 13 parts,
Sodium Alginate 12 parts,
The sub-terpene alcohol of Chinese lime 4 parts,
Ou Nansipi ketone D 3 parts,
Isoimperatorin 4 parts,
Sodium polyacrylate 8 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 23 parts,
D-acridine-2-carboxylic acid 7 parts,
2-ethyl-2,5-dimethylhexanoic acid 6 parts.
Before process: containing chlorobenzene 10mg, orthodichlorobenzene 10mg, santochlor 10mg in 1L water sample, add this water conditioner 50mg;
After process: containing chlorobenzene 0.01mg, orthodichlorobenzene 0.01 mg in 1L water sample, santochlor does not detect.
Embodiment 2
Remove a water conditioner for organochlorine pesticide in water, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 16 parts,
3-amino-2 hydroxy propanoic acid 7 parts,
Nimesulide 0.8 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 17 parts,
Prunetin 1.2 parts,
Alpha-amino group isocaproic acid 11 parts,
Sodium Alginate 13 parts,
The sub-terpene alcohol of Chinese lime 6 parts,
Ou Nansipi ketone D 5 parts,
Isoimperatorin 4 parts,
Sodium polyacrylate 8 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 25 parts,
D-acridine-2-carboxylic acid 7 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
Before process: containing chlorobenzene 10mg, orthodichlorobenzene 10mg, Perchlorobenzene 10mg in 1L water sample, add this water conditioner 50mg;
After process: all do not detect containing chlorobenzene, orthodichlorobenzene and Perchlorobenzene in 1L water sample.
Embodiment 3
Remove a water conditioner for organochlorine pesticide in water, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 15 parts,
3-amino-2 hydroxy propanoic acid 8 parts,
Nimesulide 0.7 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 15 parts,
Prunetin 1.1 parts,
Alpha-amino group isocaproic acid 10 parts,
Sodium Alginate 12 parts,
The sub-terpene alcohol of Chinese lime 5 parts,
Ou Nansipi ketone D 4 parts,
Isoimperatorin 3 parts,
Sodium polyacrylate 7 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,
D-acridine-2-carboxylic acid 6 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
Before process: in 1L water sample containing chlorobenzene 15mg, santochlor 15mg, Perchlorobenzene 15mg, add this water conditioner 50mg;
After process: in 1L water sample, chlorobenzene, santochlor and Perchlorobenzene all do not detect.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (2)
1. remove a water conditioner for organochlorine pesticide in water, it is characterized in that, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 10-20 part,
3-amino-2 hydroxy propanoic acid 6-10 part,
Nimesulide 0.4-1.0 part,
Tai-Ace S 150 15-20 part,
Instead, trans-2,4-nonadienal 10-20 parts,
Prunetin 0.7-1.5 part,
Alpha-amino group isocaproic acid 6-14 part,
Sodium Alginate 10-15 part,
Chinese lime sub-terpene alcohol 3-8 part,
Ou Nansipi ketone D 2-6 part,
Isoimperatorin 2-5 part,
Sodium polyacrylate 5-10 part,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 15-30 part,
D-acridine-2-carboxylic acid 5-8 part,
2-ethyl-2,5-dimethylhexanoic acid is about 4-6 part.
2. the water conditioner of organochlorine pesticide in removal water according to claim 1, is characterized in that, comprise the raw material of the following meter of mark by weight:
3,7-dimethyl-6-octenal 15 parts,
3-amino-2 hydroxy propanoic acid 8 parts,
Nimesulide 0.7 part,
17 parts, Tai-Ace S 150,
Instead, trans-2,4-nonadienal 15 parts,
Prunetin 1.1 parts,
Alpha-amino group isocaproic acid 10 parts,
Sodium Alginate 12 parts,
The sub-terpene alcohol of Chinese lime 5 parts,
Ou Nansipi ketone D 4 parts,
Isoimperatorin 3 parts,
Sodium polyacrylate 7 parts,
3,7,11-trimethylammonium-1,6,10-12 carbon triolefin-3-alcohol 22 parts,
D-acridine-2-carboxylic acid 6 parts,
2-ethyl-2,5-dimethylhexanoic acid 5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510355907.4A CN104961213B (en) | 2015-06-25 | 2015-06-25 | A kind of remove the water treatment agent of organochlorine pesticide in water |
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| CN201510355907.4A CN104961213B (en) | 2015-06-25 | 2015-06-25 | A kind of remove the water treatment agent of organochlorine pesticide in water |
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| CN104961213A true CN104961213A (en) | 2015-10-07 |
| CN104961213B CN104961213B (en) | 2016-10-05 |
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| CN201510355907.4A Expired - Fee Related CN104961213B (en) | 2015-06-25 | 2015-06-25 | A kind of remove the water treatment agent of organochlorine pesticide in water |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105600987A (en) * | 2015-12-31 | 2016-05-25 | 杨俊锋 | Water treatment agent for removing organic pesticide in wastewater |
| CN106745411A (en) * | 2017-02-16 | 2017-05-31 | 华北水利水电大学 | A kind of water treatment agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101591074A (en) * | 2009-07-20 | 2009-12-02 | 浙江亚星源环保科技有限公司 | Phosphate-free water treatment agent and preparation method |
| CN103204560A (en) * | 2013-01-08 | 2013-07-17 | 大唐国际发电股份有限公司高铝煤炭资源开发利用研发中心 | Preparation of waste water treating agent by using active calcium silicate and treatment method for papermaking waste water |
| CN103641182A (en) * | 2013-11-28 | 2014-03-19 | 大连创达技术交易市场有限公司 | Sewage treatment drug |
-
2015
- 2015-06-25 CN CN201510355907.4A patent/CN104961213B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101591074A (en) * | 2009-07-20 | 2009-12-02 | 浙江亚星源环保科技有限公司 | Phosphate-free water treatment agent and preparation method |
| CN103204560A (en) * | 2013-01-08 | 2013-07-17 | 大唐国际发电股份有限公司高铝煤炭资源开发利用研发中心 | Preparation of waste water treating agent by using active calcium silicate and treatment method for papermaking waste water |
| CN103641182A (en) * | 2013-11-28 | 2014-03-19 | 大连创达技术交易市场有限公司 | Sewage treatment drug |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105600987A (en) * | 2015-12-31 | 2016-05-25 | 杨俊锋 | Water treatment agent for removing organic pesticide in wastewater |
| CN106745411A (en) * | 2017-02-16 | 2017-05-31 | 华北水利水电大学 | A kind of water treatment agent and preparation method thereof |
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| Publication number | Publication date |
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| CN104961213B (en) | 2016-10-05 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160901 Address after: 325055 Wenzhou, Longwan District, Haicheng Street prosperous road, No. 55, No. Applicant after: Zhang Jun Address before: 312000 Zhejiang city of Shaoxing province Zhuji city Jiyang street Jin Jin Road No. 9 Applicant before: Jin Shuanglei |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Huang Zhaobin Inventor before: Jin Shuanglei |
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| TR01 | Transfer of patent right |
Effective date of registration: 20170531 Address after: 528300 Guangdong Province, Foshan city Shunde District Leliu Leliu Street office community neighborhood committee Longsheng Road (exhibition hall of Quanxing Aquatic Feed Co. Ltd.) Patentee after: Shunde Foshan times Biotechnology Co., Ltd. Address before: 325055 Wenzhou, Longwan District, Haicheng Street prosperous road, No. 55, No. Patentee before: Zhang Jun |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20161005 Termination date: 20190625 |
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| CF01 | Termination of patent right due to non-payment of annual fee |