CN104960296B - A kind of PP delustrings are without glue composite membrane and preparation method thereof - Google Patents

A kind of PP delustrings are without glue composite membrane and preparation method thereof Download PDF

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Publication number
CN104960296B
CN104960296B CN201510448621.0A CN201510448621A CN104960296B CN 104960296 B CN104960296 B CN 104960296B CN 201510448621 A CN201510448621 A CN 201510448621A CN 104960296 B CN104960296 B CN 104960296B
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China
Prior art keywords
temperature
top layer
composite membrane
raw material
percetage
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CN104960296A (en
Inventor
丁伟
单利英
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Furong New Materials Jiangsu Co ltd
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FURONGHUI INDUSTRY (FUJIAN) Co Ltd
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/408Matt, dull surface

Abstract

The invention discloses a kind of PP delustrings without glue composite membrane and preparation method thereof, belong to polymeric material field.Composite membrane is made up of top layer 1, top layer 2 and sandwich layer;The raw material components and percetage by weight on top layer 1 are:Delustring material 100%;The raw material components and percetage by weight on top layer 2 are:Heat-sealing material 96.50 97.50%, antiblocking agent 2.50 3.50%;The raw material components and percetage by weight of sandwich layer are:PP 98.00 98.20%, antistatic additive 1.10 1.30%, slipping agent 0.70%.The thickness of obtained composite membrane is 10 15 microns, and extinction performance is excellent, and strong without the compound fastness of glue, preparation method is simple, is conducive to popularization and application.

Description

A kind of PP delustrings are without glue composite membrane and preparation method thereof
Technical field
The invention belongs to polymeric material field, and in particular to a kind of PP delustrings are without glue composite membrane and preparation method thereof.
Background technology
As the change of people's aesthetic standards, the requirement to package packing supplies are constantly updated, it is in package material surface feature Existing diversity requirements, from many-sided reaction article such as aesthetics, restocking effect, advertising and show manufacturer and stimulate consumer sense The special-effect of official's vision.Matt film is a kind of film for packaging of low gloss haze into diffusing reflection extinction effect, film surface Similar paper, the gloss with height, its surface reflection is weak and soft, and surface gloss is less than 15%, mist degree 70% with On, with comfortable feel, the quiet elegance of outward appearance, during printing color can reproduction true to nature many advantages, such as, ordinary packing film is nothing What method reached.The top layer that present invention control easily occurs during heated compounded is shunk and causes the situation of film fold, is realized With other solvent-free direct combinations of plastics soft material, by force, compound fastness fully meets use requirement to the compound fastness of storeroom, and There is no organic solvent to volatilize in production process and pollute environment.
The content of the invention
It is an object of the invention to provide a kind of PP delustrings without glue composite membrane and preparation method thereof, the thickness of obtained composite membrane It is 10-15 microns to spend, and extinction performance is excellent, and strong without the compound fastness of glue, preparation method is simple, is conducive to popularization and application.
To achieve the above object, the present invention is adopted the following technical scheme that:
A kind of PP delustrings are made up of without glue composite membrane top layer 1, top layer 2 and sandwich layer;The raw material components and weight hundred on top layer 1 Fraction is:Delustring material 100%;The raw material components and percetage by weight on top layer 2 are:Heat-sealing material 96.50-97.50%, antiblocking agent 2.50-3.50%;The raw material components and percetage by weight of sandwich layer are:It is PP 98.00-98.20%, antistatic additive 1.10-1.30%, refreshing Lubrication prescription 0.70%.The thickness of obtained composite membrane is 10-15 microns.
It is molded using biaxial tension after three-decker co-extrusion.Process parameter control is as follows:Main extruder temperature 240-250 DEG C, 240-260 DEG C of skin temperature, 28-30 DEG C of tank temperature, 30-37 DEG C of chilling roller temperature, 240-250 DEG C of die head temperature, vertical draw temperature 115-129 DEG C of degree, longitudinal stretching than 4.78, it is horizontal draw 165-179 DEG C of temperature, cross directional stretch ratio 9-9.4, horizontal drawing wind speed 85-95%, Corona 27-31.
Remarkable advantage of the invention is:The thickness of obtained composite membrane is 10-15 microns, and extinction performance is excellent, without glue Compound fastness is strong, and preparation method is simple, is conducive to popularization and application.
Specific embodiment
Embodiment 1
A kind of PP delustrings are made up of without glue composite membrane top layer 1, top layer 2 and sandwich layer;The raw material components and weight hundred on top layer 1 Fraction is:Delustring material 100%;The raw material components and percetage by weight on top layer 2 are:Heat-sealing material 96.50%, antiblocking agent 3.50%;Core Layer raw material components and percetage by weight be:PP 98.00%, antistatic additive 1.30%, slipping agent 0.70%.Obtained composite membrane Thickness is 10 microns.
It is molded using biaxial tension after three-decker co-extrusion.Process parameter control is as follows:240 DEG C of main extruder temperature, 240 DEG C of skin temperature, 28 DEG C of tank temperature, 30 DEG C of chilling roller temperature, 240 DEG C of die head temperature, vertical 115 DEG C of temperature of drawing, longitudinal stretching Than 4.78, horizontal 165 DEG C of temperature of drawing, cross directional stretch ratio 9, horizontal drawing wind speed 85%, corona 27.
Embodiment 2
A kind of PP delustrings are made up of without glue composite membrane top layer 1, top layer 2 and sandwich layer;The raw material components and weight hundred on top layer 1 Fraction is:Delustring material 100%;The raw material components and percetage by weight on top layer 2 are:Heat-sealing material 97.50%, antiblocking agent 2.50%;Core Layer raw material components and percetage by weight be:PP 98.20%, antistatic additive 1.10%, slipping agent 0.70%.Obtained composite membrane Thickness is 15 microns.
It is molded using biaxial tension after three-decker co-extrusion.Process parameter control is as follows:250 DEG C of main extruder temperature, 260 DEG C of skin temperature, 30 DEG C of tank temperature, 37 DEG C of chilling roller temperature, 250 DEG C of die head temperature, vertical 129 DEG C of temperature of drawing, longitudinal stretching Than 4.78, horizontal 179 DEG C of temperature of drawing, cross directional stretch ratio 9.4, horizontal drawing wind speed 95%, corona 31.
Embodiment 3
A kind of PP delustrings are made up of without glue composite membrane top layer 1, top layer 2 and sandwich layer;The raw material components and weight hundred on top layer 1 Fraction is:Delustring material 100%;The raw material components and percetage by weight on top layer 2 are:Heat-sealing material 97.00%, antiblocking agent 3.00%;Core Layer raw material components and percetage by weight be:PP 98.10%, antistatic additive 1.20%, slipping agent 0.70%.Obtained composite membrane Thickness is 12 microns.
It is molded using biaxial tension after three-decker co-extrusion.Process parameter control is as follows:245 DEG C of main extruder temperature, 250 DEG C of skin temperature, 29 DEG C of tank temperature, 33 DEG C of chilling roller temperature, 245 DEG C of die head temperature, vertical 120 DEG C of temperature of drawing, longitudinal stretching Than 4.78, horizontal 170 DEG C of temperature of drawing, cross directional stretch ratio 9.2, horizontal drawing wind speed 90%, corona 29.
The foregoing is only presently preferred embodiments of the present invention, all impartial changes done according to scope of the present invention patent with Modification, should all belong to covering scope of the invention.

Claims (1)

1. a kind of PP delustrings are without glue composite membrane, it is characterised in that:It is made up of top layer 1, top layer 2 and sandwich layer;The raw material group on top layer 1 Divide and percetage by weight is:Delustring material 100%;The raw material components and percetage by weight on top layer 2 are:Heat-sealing material 97.00%, resist blocking and that Agent 3.00%;The raw material components and percetage by weight of sandwich layer are:PP 98.10%, antistatic additive 1.20%, slipping agent 0.70%;It is obtained Composite membrane thickness be 12 microns;It is molded using biaxial tension after three-decker co-extrusion, process parameter control is as follows:It is main to squeeze 245 DEG C of out-of-machine temperature, 250 DEG C of skin temperature, 29 DEG C of tank temperature, 33 DEG C of chilling roller temperature, 245 DEG C of die head temperature, vertical drawing temperature 120 DEG C, longitudinal stretching than 4.78, horizontal 170 DEG C of temperature of drawing, cross directional stretch ratio 9.2, horizontal drawing wind speed 90%, corona 29.
CN201510448621.0A 2015-07-28 2015-07-28 A kind of PP delustrings are without glue composite membrane and preparation method thereof Active CN104960296B (en)

Priority Applications (1)

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CN201510448621.0A CN104960296B (en) 2015-07-28 2015-07-28 A kind of PP delustrings are without glue composite membrane and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201510448621.0A CN104960296B (en) 2015-07-28 2015-07-28 A kind of PP delustrings are without glue composite membrane and preparation method thereof

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CN104960296B true CN104960296B (en) 2017-06-16

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108515761A (en) * 2018-04-09 2018-09-11 福融辉实业(福建)有限公司 Film and preparation method thereof is compiled in a kind of BOPP delustrings modeling

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101531078A (en) * 2009-03-10 2009-09-16 安徽国风塑业股份有限公司 BOPP extinction film without anti-adhesion agent and production method thereof
CN103709517A (en) * 2013-12-31 2014-04-09 浙江凯利新材料股份有限公司 Matte BOPP (Biaxially-oriented Polypropylene) film for leather transferring and preparation method thereof
CN104070757A (en) * 2014-06-19 2014-10-01 晋江市新合发塑胶印刷有限公司 CPP (casting polypropylene) matt film and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10309789A (en) * 1997-05-13 1998-11-24 Sekisui Chem Co Ltd Inflation film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101531078A (en) * 2009-03-10 2009-09-16 安徽国风塑业股份有限公司 BOPP extinction film without anti-adhesion agent and production method thereof
CN103709517A (en) * 2013-12-31 2014-04-09 浙江凯利新材料股份有限公司 Matte BOPP (Biaxially-oriented Polypropylene) film for leather transferring and preparation method thereof
CN104070757A (en) * 2014-06-19 2014-10-01 晋江市新合发塑胶印刷有限公司 CPP (casting polypropylene) matt film and preparation method thereof

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Effective date of registration: 20180522

Address after: 350300 Fuqing City, Fuzhou, Fujian, the reunification of overseas Chinese economic and Technological Development Zone

Co-patentee after: GUANGZHOU RONGSHENG PACKAGING MATERIALS CO.,LTD.

Patentee after: FURONGHUI INDUSTRIAL (FUJIAN) Co.,Ltd.

Address before: 350300 Fuqing City, Fuzhou, Fujian, the reunification of overseas Chinese economic and Technological Development Zone

Patentee before: FURONGHUI INDUSTRIAL (FUJIAN) Co.,Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20221026

Address after: 226010 No. 18, Changxing East Road, Nantong Economic and Technological Development Zone, Nantong City, Jiangsu Province

Patentee after: Furong new materials (Jiangsu) Co.,Ltd.

Address before: 350300 Fuqing City, Fuzhou, Fujian, the reunification of overseas Chinese economic and Technological Development Zone

Patentee before: FURONGHUI INDUSTRIAL (FUJIAN) Co.,Ltd.

Patentee before: GUANGZHOU RONGSHENG PACKAGING MATERIALS CO.,LTD.