CN104960293B - A kind of solvent-free composite membrane of localized fluorescence - Google Patents
A kind of solvent-free composite membrane of localized fluorescence Download PDFInfo
- Publication number
- CN104960293B CN104960293B CN201510353509.9A CN201510353509A CN104960293B CN 104960293 B CN104960293 B CN 104960293B CN 201510353509 A CN201510353509 A CN 201510353509A CN 104960293 B CN104960293 B CN 104960293B
- Authority
- CN
- China
- Prior art keywords
- microcapsules
- solvent
- silicone resin
- fluorescence
- impressing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000002131 composite material Substances 0.000 title claims abstract description 14
- 239000012528 membrane Substances 0.000 title claims abstract description 14
- 239000003094 microcapsule Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000003292 glue Substances 0.000 claims abstract description 20
- 229920002050 silicone resin Polymers 0.000 claims abstract description 17
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 15
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 15
- 239000000758 substrate Substances 0.000 claims abstract description 12
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims description 3
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 3
- 229940043267 rhodamine b Drugs 0.000 claims description 3
- 229920006268 silicone film Polymers 0.000 claims 1
- 230000000149 penetrating effect Effects 0.000 abstract description 5
- 239000005022 packaging material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/14—Layered products comprising a layer of synthetic resin next to a particulate layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/025—Particulate layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
- B32B2264/02—Synthetic macromolecular particles
- B32B2264/0214—Particles made of materials belonging to B32B27/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/54—Filled microcapsules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/406—Bright, glossy, shiny surface
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses a kind of solvent-free composite membrane of localized fluorescence, including film substrate, microcapsules fixing glue bottom, microcapsules, organic fluorescence materials, solvent-free glue, silicone resin and thermoplastic shape localized fluorescence colour developing impressing, the microcapsules fixing glue primary coat is distributed in film substrate surface, the microcapsules are fixed in microcapsules fixing glue bottom, the organic fluorescence materials are arranged inside microcapsules, the solvent-free glue coats silicone resin surface, the silicone resin is combined with film substrate Jing rolls, the thermoplastic shape localized fluorescence colour developing impressing is arranged at silicone resin surface.By the way, the problems such as present invention can be pungent for existing fluorescent film smell, fluorescer is easily leaked, increase the microcapsules containing organic fluorescence materials and thermoplastic shape localized fluorescence colour developing impressing, effectively lock organic fluorescence materials, greatly reduces the penetrating odor of film.
Description
Technical field
The present invention relates to packaging material manufacture field, more particularly to a kind of solvent-free composite membrane of localized fluorescence.
Background technology
With the continuous progress of packaging material manufacturing technology, the composite membrane containing solvent can cause various use problems,
Such as penetrating odor etc., this cannot adapt to present packaging material demand.In addition, fluorescent material is easily let out in localized fluorescence film
Leakage problem generally existing, using effect cannot be ensured.
The content of the invention
The invention mainly solves the technical problem of providing a kind of localized fluorescence solvent-free composite membrane, can be directed to existing glimmering
The problems such as light film smell is pungent, fluorescer is easily leaked, increases the microcapsules containing organic fluorescence materials and thermoplastic shape localized fluorescence
Colour developing impressing, effectively lock organic fluorescence materials, greatly reduces the penetrating odor of film.
To solve above-mentioned technical problem, one aspect of the present invention is：There is provided a kind of localized fluorescence solvent-free
Composite membrane, including film substrate, microcapsules fixing glue bottom, microcapsules, organic fluorescence materials, solvent-free glue, organic siliconresin
Film and thermoplastic shape localized fluorescence colour developing impressing, the microcapsules fixing glue primary coat are distributed in film substrate surface, the microcapsules
It is fixed in microcapsules fixing glue bottom, the organic fluorescence materials are arranged inside microcapsules, the solvent-free glue is coated
Silicone resin surface, the silicone resin are combined with film substrate Jing rolls, the thermoplastic shape localized fluorescence colour developing
Impressing is arranged at silicone resin surface.
In a preferred embodiment of the present invention, the organic fluorescence materials for 20% ~ 30% rhodamine B, 50% ~ 60%
Thio-flavin and 15% ~ 25% fluorescein.
In a preferred embodiment of the present invention, the upper surface of the thermoplastic shape localized fluorescence colour developing impressing is apart from organosilicon
The height of surface resin film differs at least 0.5 millimeter.
The invention has the beneficial effects as follows：The solvent-free composite membrane of a kind of localized fluorescence that the present invention is provided, can be directed to existing
The problems such as fluorescent film smell is pungent, fluorescer is easily leaked, increases the microcapsules containing organic fluorescence materials and thermoplastic shape local is glimmering
Light colour developing impressing, effectively lock organic fluorescence materials, greatly reduces the penetrating odor of film.
Description of the drawings
For the technical scheme being illustrated more clearly that in the embodiment of the present invention, below will be to making needed for embodiment description
Accompanying drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present invention, for
For those of ordinary skill in the art, on the premise of not paying creative work, can be obtaining other according to these accompanying drawings
Accompanying drawing, wherein：
Fig. 1 is a kind of structure chart of a preferred embodiment of the solvent-free composite membrane of localized fluorescence of the invention.
Specific embodiment
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement
Example is only a part of embodiment of the present invention, rather than the embodiment of whole.Based on the embodiment in the present invention, this area is common
All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection
Enclose.
As shown in figure 1, the embodiment of the present invention includes：
A kind of solvent-free composite membrane of localized fluorescence, including it is film substrate 1, microcapsules fixing glue bottom 2, microcapsules 3, organic glimmering
Luminescent material 4, solvent-free glue 5, silicone resin 6 and thermoplastic shape localized fluorescence colour developing impressing 7, the microcapsules 3 are fixed
1 surface of film substrate is coated at glue bottom 2, and the microcapsules 3 are fixed in 3 fixing glue bottom 2 of microcapsules, the organic fluorescence materials
4 are arranged inside microcapsules 3, and the solvent-free glue 5 coats 6 surface of silicone resin, the silicone resin 6 with
1 Jing rolls of film substrate are combined, and the thermoplastic shape localized fluorescence colour developing impressing 7 is arranged at 6 surface of silicone resin.
Wherein, the organic fluorescence materials 4 are 20% ~ 30% rhodamine B, 50% ~ 60% thio-flavin and 15% ~ 25%
Fluorescein.By the way, can be film in daylight and night lighting environment and meanwhile produce fluorescent effect.
Further, height of the upper surface of the thermoplastic shape localized fluorescence colour developing impressing 7 apart from 6 surface of silicone resin
At least 0.5 millimeter of degree difference.By the way, it is prevented effectively from organic fluorescence materials 4 to leak.
In sum, the invention provides a kind of solvent-free composite membrane of localized fluorescence, can be directed to existing fluorescent film smell
The problems such as pungent, fluorescer is easily leaked, increases the microcapsules 3 containing organic fluorescence materials 4 and thermoplastic shape localized fluorescence colour developing pressure
Print 7, effectively locking organic fluorescence materials 4, greatly reduce the penetrating odor of film.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (3)
1. the solvent-free composite membrane of a kind of localized fluorescence, it is characterised in that including film substrate, microcapsules fixing glue bottom, microcapsules,
Organic fluorescence materials, solvent-free glue, silicone resin and thermoplastic shape localized fluorescence colour developing impressing, the microcapsules are fixed
Glue primary coat is distributed in film substrate surface, and the microcapsules are fixed in microcapsules fixing glue bottom, and the organic fluorescence materials are arranged
Inside microcapsules, the solvent-free glue coats silicone resin surface, the silicone resin and film substrate
Jing rolls are combined, and the thermoplastic shape localized fluorescence colour developing impressing is arranged at silicone resin surface.
2. the solvent-free composite membrane of localized fluorescence according to claim 1, it is characterised in that the organic fluorescence materials are
20% ~ 30% rhodamine B, 50% ~ 60% thio-flavin and 15% ~ 25% fluorescein.
3. the solvent-free composite membrane of localized fluorescence according to claim 2, it is characterised in that the thermoplastic shape localized fluorescence shows
Height of the upper surface of color impressing apart from silicone resin surface differs at least 0.5 millimeter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510353509.9A CN104960293B (en) | 2015-06-25 | 2015-06-25 | A kind of solvent-free composite membrane of localized fluorescence |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510353509.9A CN104960293B (en) | 2015-06-25 | 2015-06-25 | A kind of solvent-free composite membrane of localized fluorescence |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104960293A CN104960293A (en) | 2015-10-07 |
| CN104960293B true CN104960293B (en) | 2017-04-05 |
Family
ID=54214454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510353509.9A Active CN104960293B (en) | 2015-06-25 | 2015-06-25 | A kind of solvent-free composite membrane of localized fluorescence |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104960293B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN204129247U (en) * | 2014-10-22 | 2015-01-28 | 苏州百诚精密科技有限公司 | Long-acting highlighted type reflecting piece |
| CN104330846A (en) * | 2014-10-22 | 2015-02-04 | 苏州百诚精密科技有限公司 | Long-acting high-brightness light-reflection sheet and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060024487A1 (en) * | 2004-07-27 | 2006-02-02 | Eastman Kodak Company | Creating stencils using microencapsulated material |
| US20070116910A1 (en) * | 2005-11-23 | 2007-05-24 | Polykarpov Alexander Y | Multilayer laminated structures |
-
2015
- 2015-06-25 CN CN201510353509.9A patent/CN104960293B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN204129247U (en) * | 2014-10-22 | 2015-01-28 | 苏州百诚精密科技有限公司 | Long-acting highlighted type reflecting piece |
| CN104330846A (en) * | 2014-10-22 | 2015-02-04 | 苏州百诚精密科技有限公司 | Long-acting high-brightness light-reflection sheet and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104960293A (en) | 2015-10-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Huang Zhenxiong Inventor before: Yang Weishuai |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170621 Address after: 528415, No. 103, No. two, Jiuzhou base, Xiaolan Town, Zhongshan City, Guangdong Province, Jianshe Road Patentee after: Packaging products Co., Ltd. Zhongshan Connaught Connaught Address before: High tech Zone Suzhou city Jiangsu province 215011 Chuk Yuen Road No. 209 Patentee before: Suzhou Rui Qili new material Co., Ltd |
|
| TR01 | Transfer of patent right |