CN104947900A - Ultra-thin stone glass fiber composite decoration plate and manufacturing method thereof - Google Patents
Ultra-thin stone glass fiber composite decoration plate and manufacturing method thereof Download PDFInfo
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- CN104947900A CN104947900A CN201510283251.XA CN201510283251A CN104947900A CN 104947900 A CN104947900 A CN 104947900A CN 201510283251 A CN201510283251 A CN 201510283251A CN 104947900 A CN104947900 A CN 104947900A
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Abstract
The invention relates to an ultra-thin stone glass fiber composite decoration plate and a manufacturing method thereof. The ultra-thin stone glass fiber composite decoration plate comprises a stone face layer and a middle glass fiber cloth layer which are bonded through epoxy adhesive. The adhesive includes a component A comprising, by weight, 20-30 parts of bisphenol A epoxy resin E-51, 10-15 parts of mixture of 2:1 of HELOXY84 and HELOXY505, 10-15 parts of 40 baume degree sodium silicate and 25-30 parts of quartz fine powder and a component B comprising, by weight, 15-20 parts of 793 curing agent, 10-15 parts of tri ethylene glycol and 2-4 parts of organosiloxane KH-550. The component A and the component B are mixed and used according to the mass ratio of 6-9:1-2 during using. According to the ultra-thin stone glass fiber composite decoration plate, the stone face layer and the middle glass fiber layer are bonded through the adhesive, the large composite decoration plate is manufactured, the bonding strength between stone and glass fiber is obviously improved, the anti-impact strength is good, and constructability is high.
Description
Technical field
The present invention relates to building material field, especially a kind of superthin stone glass composite decorating board and manufacture method thereof.
Background technology
In recent years, in order to save lithotome, stone material is bonded with other materials or makes a kind of new composite stone material goods or dalle together with splicing, this composite board can reach the decoration function the same with former marble, and have that price is lower, weight is lighter, install the advantages such as easy, architectural decoration composite stone material consumption increases substantially.But at present, it is low that stone material and glass composite decorating board have adhesion strength, the easily aging shortcoming such as to come unstuck.
Summary of the invention
The object of the invention is to provide a kind of superthin stone glass composite decorating board and manufacture method thereof, to solve prior art Problems existing.
Technical scheme of the present invention is:
A kind of superthin stone glass composite decorating board, comprise with the stone material surface layer of epoxy adhesive bonding and middle glass layer of cloth, wherein adhesive component composition with parts by weight is: first group: bisphenol-A epoxy resin E-51 20-30, HELOXY84 and HELOXY505 are mixture 10-15,40 Baume degrees silicate of soda 10-15, the quartzy trickle powder 25-30 of 2:1; Second group: 793 curing compound 15-20, triethylene-glycol 10-15, organosiloxane KH-550 2-4; 6-9:1-2 is used in combination in mass ratio in use for the first and second two components.
Above-mentioned stone material glass composite decorating board, wherein stone material surface layer, thickness in monolayer is 4-8mm, and two-layer gross thickness is 8-16mm; Middle glass layer of cloth, thickness in monolayer is 2-4mm, and gross thickness is 4-8mm.
Preferably, above-mentioned stone material glass composite decorating board, wherein glass-fiber-fabric is low alkali glass fiber cloth, and stone material is marble.
The manufacture method of above-mentioned superthin stone glass composite decorating board, comprises the following steps:
1) bisphenol-A epoxy resin E-51 is added in the reactor, under stirring, add mixture, 40 Baume degrees silicate of soda that HELOXY84 and HELOXY505 is 2:1 successively, be warming up to 60 DEG C, insulation reaction 4 hours, stop heating, then add quartzy trickle powder, continue stirring 1 hour afterwards, grind three roads through grinder, discharging obtains first component; Add triethylene-glycol in the reactor, under stirring, add 793 curing compound, organosiloxane KH-550 successively, be warming up to 40 DEG C, insulated and stirred 2 hours, stop heating, grind three roads through grinder, discharging obtains component B; Under normal temperature, first and second groups mix in mass ratio, obtain bonding adhesive, for subsequent use;
2), at normal temperatures, under air humidity is less than the condition of 50%, bonding adhesive for subsequent use is coated on uniformly on each to be bonded, each face that connects bond and applies the pressure of 15-25kg/cm2, keeps pressure 3-4 hour, maintenance temperature 30-35 DEG C;
3), at normal temperatures, under air humidity is less than the condition of 50%, 10-12 hour is left standstill;
4) cutting sizing.
The superthin stone glass composite decorating board produced as stated above, thickness is 12-25mm.
Advantage of the present invention is: superthin stone glass composite decorating board of the present invention, with adhesive bonds stone material surface layer and middle glass layer of cloth, the composite decorating board greatly produced, the adhesion strength between stone material and glass significantly improves, impact strength is good, can application property strong.
Detailed description of the invention
Below in conjunction with example, the present invention is described further, but application claims protection domain is not limited to the scope represented by embodiment.
In following embodiment, the preparation method of bonding adhesive is as follows:
Wherein adhesive component composition with parts by weight is: first group: bisphenol-A epoxy resin E-51 20, HELOXY84 and HELOXY505 are mixture 12, the 40 Baume degrees silicate of soda 13 of 2:1, quartzy trickle powder 25;
Second group: 793 curing compound 20, triethylene-glycol 10, organosiloxane KH-550 3;
Preparation method is as follows for above-mentioned stone material-glass compound epoxy adhesive:
1) bisphenol-A epoxy resin E-51 is added in the reactor, under stirring, add mixture, 40 Baume degrees silicate of soda that HELOXY84 and HELOXY505 is 2:1 successively, be warming up to 60 DEG C, insulation reaction 4 hours, stop heating, then add quartzy trickle powder, continue stirring 1 hour afterwards, grind three roads through grinder, discharging obtains first component;
2) add triethylene-glycol in the reactor, under stirring, add 793 curing compound, organosiloxane KH-550 successively, be warming up to 40 DEG C, insulated and stirred 2 hours, stop heating, grind three roads through grinder, discharging obtains component B;
8:1 is used in combination in mass ratio in use for the first and second two components.
In enforcement, glass-fiber-fabric is low alkali glass fiber cloth, and stone material surface layer is marble.
Embodiment 1
In the present embodiment, low alkali glass fiber cloth gross thickness is 4mm, and marble is the one side layer that two 4mm are thick.
Embodiment 2
In the present embodiment, low alkali glass fiber cloth gross thickness is 4mm, and marble is the one side layer that two 5mm are thick.
Embodiment 3
In the present embodiment, low alkali glass fiber cloth gross thickness is 4mm, and marble is the one side layer that two 8mm are thick.
Embodiment 4
In the present embodiment, low alkali glass fiber cloth gross thickness is 6mm, and marble is the one side layer that two 4mm are thick.
Embodiment 5
In the present embodiment, low alkali glass fiber cloth gross thickness is 6mm, and marble is the one side layer that two 5mm are thick.
Embodiment 6
In the present embodiment, low alkali glass fiber cloth gross thickness is 6mm, and marble is the one side layer that two 8mm are thick.
Embodiment 7
In the present embodiment, low alkali glass fiber cloth gross thickness is 8mm, and marble is the one side layer that two 4mm are thick.
Embodiment 8
In the present embodiment, low alkali glass fiber cloth gross thickness is 8mm, and marble is the one side layer that two 5mm are thick.
Embodiment 9
In the present embodiment, low alkali glass fiber cloth gross thickness is 8mm, and marble is the one side layer that two 8mm are thick.
In above-described embodiment, superthin stone glass composite decoration board fabrication method is as follows:
1), at normal temperatures, under air humidity is less than the condition of 50%, bonding adhesive for subsequent use is coated on uniformly on each to be bonded, each face that connects bond and applies the pressure of 20kg/cm2, keeps pressure 3 hours, maintenance temperature 30-35 DEG C; 2), at normal temperatures, under air humidity is less than the condition of 50%, 10 hours are left standstill; 3) cutting sizing.
According to GBT 29059-2012 ultra-thin stone composite board, Performance Detection is carried out to the superthin stone glass composite decorating board that above-described embodiment produces, wherein Frozen-thawed cycled 200 times in this test, Falling ball impact strength record be occur crackle depression arrisdefect time steel ball free falling bodies height, other test conditions are all undertaken by standard, and result is as following table:
Other performances of above-described embodiment all meet this standard.
Claims (5)
1. a superthin stone glass composite decorating board, it is characterized in that, comprise with the stone material surface layer of epoxy adhesive bonding and middle glass layer of cloth, wherein adhesive component composition, with parts by weight is: first group: bisphenol-A epoxy resin E-51 20-30, HELOXY84 and HELOXY505 are mixture 10-15,40 Baume degrees silicate of soda 10-15, the quartzy trickle powder 25-30 of 2:1; Second group: 793 curing compound 15-20, triethylene-glycol 10-15, organosiloxane KH-550 2-4; 6-9:1-2 is used in combination in mass ratio in use for the first and second two components.
2. stone material glass composite decorating board according to claim 1, is characterized in that, described stone material surface layer, and thickness in monolayer is 4-8mm, and two-layer gross thickness is 8-16mm; Middle glass layer of cloth, thickness in monolayer is 2-4mm, and gross thickness is 4-8mm.
3. stone material glass composite decorating board according to claim 1, is characterized in that, described glass-fiber-fabric is low alkali glass fiber cloth, and stone material is marble.
4. a manufacture method for the superthin stone glass composite decorating board described in any one of claim 1-3, is characterized in that, comprise the following steps:
1) bisphenol-A epoxy resin E-51 is added in the reactor, under stirring, add mixture, 40 Baume degrees silicate of soda that HELOXY84 and HELOXY505 is 2:1 successively, be warming up to 60 DEG C, insulation reaction 4 hours, stop heating, then add quartzy trickle powder, continue stirring 1 hour afterwards, grind three roads through grinder, discharging obtains first component; Add triethylene-glycol in the reactor, under stirring, add 793 curing compound, organosiloxane KH-550 successively, be warming up to 40 DEG C, insulated and stirred 2 hours, stop heating, grind three roads through grinder, discharging obtains component B; Under normal temperature, first and second groups mix in mass ratio, obtain epoxy adhesive, for subsequent use;
2), at normal temperatures, under air humidity is less than the condition of 50%, epoxy adhesive for subsequent use is coated on uniformly on each to be bonded, each face that connects bond and applies the pressure of 15-25kg/cm2, keeps pressure 3-4 hour, maintenance temperature 30-35 DEG C;
3), at normal temperatures, under air humidity is less than the condition of 50%, 10-12 hour is left standstill;
4) cutting sizing.
5. the superthin stone glass composite decorating board that produces of method according to claim 4, thickness is 12-25mm.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112411009A (en) * | 2020-10-26 | 2021-02-26 | 安徽岩棉建材科技有限公司 | Rock wool felt and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112411009A (en) * | 2020-10-26 | 2021-02-26 | 安徽岩棉建材科技有限公司 | Rock wool felt and preparation method thereof |
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Application publication date: 20150930 |
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| WD01 | Invention patent application deemed withdrawn after publication |