It is a kind of to utilize soil conditioner of marine animal and plant residuum production and preparation method thereof
Technical field
The present invention relates to a kind of using soil conditioner of marine animal and plant residuum production and preparation method thereof, belong to ocean
Waste's reclamation technical field.
Background technology
Soil conditioner was agriculturally progressively starting to apply in recent years, and the change of soil aciditiy refers to hydrogen ion in soil
The change of concentration, from the early stage eighties in last century so far, the pH value of all soil types almost found in China all have dropped
0.13-0.80, the continuous acidifying of soil also have the trend developed.That is, due to the influence of the unreasonable production activity of the mankind,
China's soil acidification is greatly accelerated, it will great harm is caused to ecological environment and human survival.
The area of China's acid soil is about 200,000 km2, account for 21% of national total area or so.The big portion of these acid soils
PH value is divided to be less than 5.5, wherein more pH value is less than 5.0, even as low as 4.5.These soil irrational land use, plough
Manage down, acidizing degree is increasingly serious, as agricultural production obstruction factor.Current National soil acidity or alkalinity (pH) 30 years
0.6 unit is averagely have dropped, acid cultivated area (pH < 5.5) rises to current 18% from 7% before 30 years.South
Ratio of 14 provinces (the area, city) soil pH value less than 6.5 is expanded to 65% by 52% before 30 years, pH value less than 5.5 by 20%
40% is expanded to, pH value is expanded to 4% less than 4.5 by 1%.The ground pH value such as the Guangdong, Guangxi, Sichuan of most serious are acidified to be less than
4.5 arable soil ratio is respectively 13%, 7%, 4%.Soil (the 0-20cm layers of In Yujiang County, jiangxi Province Red Sandstone parent material development
It is secondary), determined through 1980, wild grass ground pH value 4.84, low yield paddy field pH value 5.90;And 1996 sample survey with the sample point
Fixed, wild grass ground pH value is 4.67, have dropped 0.17, low yield paddy field pH is 4.89, have dropped 1.01.
In recent years, the report on the nonacid soil acidification of northern China also gradually increases.According to investigations, Area in Yantai Region apple
Different degrees of acidifying occurred for Orchard Soil, the proportion of soil pH≤5.5, is arranged as in order:Zhaoyuan 32.03%, Peng Lai
29.88%th, Qixia 27.7%, Longkou 15.73%, significantly lower than the pH value of overall survey of soil the 1980s.
Statistics shows, Shandong Province's year pure chemical fertilizer dose up to 472.7 ten thousand tons, utilization rate of nitrogen fertilizer is 30% or so,
Only the 1/2 of developed country's level, remaining is all residued in soil.Average 27.2 kilograms of the fertilizer amount of mu is broadcast, it is more flat than the whole nation
Equal dosage is high 6 kilograms, higher than world average dose 19.2 kilograms.
The consequence of Use out of range chemical fertilizer is soil acidification, secondary salinization exacerbation.Soil acidification speed in Shandong adds in recent years
It hurry up, Jiaodong Areas is especially prominent, and acidifying area of the pH value less than 5.5 is up to more than 980 ten thousand mu.13,000,000 mu of layout plannings of the whole province
In, there are 2,600,000 mu of generation secondary salinizations.
Soil acidification causes soil nutrient out of proportion, and crop incidence of disease rise, quality of agricultural product declines.PH value is less than
4.5 plot, it can typically cause crop failure more than 30%.After layout planning is planted 4 years, soil salinization phenomenon increases year by year
Add, have a strong impact on crop yield and quality.
Some vegetables flakes in Shandong, due to Use out of range chemical fertilizer for years, land quality degradation,
It also result in " chemical fertilizer dependence ".Some places have to carry out soil displacement from the Northeast's drawing come black earth with train.And replace
The soil gone out, even if not using chemical fertilizer, also difficulty grows fine in several years of crops.
The soil conditioner of domestic improvement acidified soil is mostly traditional calcium hydroxide (dolomite ash), calcium carbonate at present
Based on (magnesium), calcium silicates (magnesium, potassium) etc., different administration limitations all be present.
Calcium hydroxide, this is acidic soil conditioner the most remote, and chemical property is highly basic, and the reaction with soil is neutralization
Reaction, neutralization reaction is violent exothermic reaction, can injure edaphon, and the plain toxic agent of generally making to disappear uses, and excess or is applied
Local soil may be caused to cross alkali or caused soil hardening with uneven.Single calcium nutrition can be provided, but without other battalion
Support effect.
Lime stone, dolomite, causticity legal system alkali residue, main component is all calcium carbonate, and some contain magnesium carbonate.Calcium carbonate
Reaction with soil is metathesis reaction, due to the fixation of sulfate radical and the precipitation of carbon dioxide, weakens soil acidity, pH is carried
Height, but to faintly acid soil, because when soil pH reaches 5.8, just can not separate out, so opsonic action has certain limitations.
Silicate containing elements such as calcium, magnesium, after activation process, can with soil acid reaction, it is micro in contained
Plant nutrient has plant absorption active, still, simply with industrial slags class silicate such as blast furnace water quenching slag, cinder etc.
Directly make acidic soil conditioner, easily cause Heavy Metal Pollution, various mine tailings also can not necessarily be used for manufacturing soil conditioning
Agent, perhaps can also secondary hazards be caused to soil.
In recent years as seashells cultivate the expansion of scale, a large amount of shellfishes remained in seashells process of manufacture
Discarded object, by taking oyster shell as an example, the oyster shell of the only annual output in city of Weihai in Shandong province is about ten thousand tons of 30-40, and an only small part obtains
Reasonable utilization has been arrived, it is most of not to be utilized effectively and deal carefully with, rural environments are seriously polluted, directly affects town and country
The improvement of human settlement and new countryside construction.And the material composition of oyster shell is divided into inanimate matter and organic matter two parts, inanimate matter
Based on calcium carbonate, account for more than the 90% of oyster shell quality, wherein calcium constituent accounts for 39.78%-40.23%, additionally containing copper,
The various trace elements of zinc, manganese, strontium etc. 20, the organic principle of oyster shell account for the 3-5% of oyster shell quality, contain glycine, Guang
17 kinds of amino acid such as propylhomoserin, methionine, can be absorbed and used by plants after activation process.
Sea shells tradition and conventional processing mode directly utilize after simply simply crushing, and active ingredient therein needs
To pass through the long-term conversion of soil can just be absorbed and used by plants, and effect is slow, and this is also that peasant is unwilling to adjust using such soil
The main reason for managing agent.
The A of Chinese patent literature CN 102321484 (application number 201110154187.7) disclose a kind of improvement acidifying or
The organic environment-friendly soil conditioner of acid soil.This patent using biogas residue, oyster shell whiting, calcium magnesium phosphate, plant ash, chitosan,
Zeolite powder, bentonite are as soil conditioner.The A of Chinese patent literature CN 1502672 (application number 02135914.8) are disclosed
Soil conditioner based on oyster shell.It is characterized in that by oyster shell powder, polyaspartic acid salts, chitosan or derivatives thereof, life
The all or part of powder of thing or fermentate are formed.
Above-mentioned two patents are to improved soil shape, increasing soil fertility has certain effect, but the nutrition that raw material provides
Components utilising is insufficient, limited to the effect of improvement crop quality.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides it is a kind of using marine animal and plant residuum production soil conditioner and
Its preparation method.
Term explanation:
Sea-plant residuum:Remaining marine alga root, corner etc. in alga food industrial processes.
Marine animal residuum:Remaining shell, such as oyster shell, various mussel shells etc. after sea mollusk processing.
Technical scheme is as follows:
It is a kind of using marine animal and plant residuum produce soil conditioner, including pre-processed, crushed, being calcined, dispensing,
Mixture and granulation, raw material components are as follows, are parts by weight:
10~15 parts of seawood meal, 62~76 parts of oyster shell whiting, 2~5 parts of biochemical fulvic acid, 0.8~1.0 part of zinc sulfate, sulfuric acid
It is ferrous 1.0~1.5 parts, 0.2~0.5 part of boron, 10~15 parts of magnesium powder.
According to currently preferred, raw material components are as follows, are parts by weight:
10~12 parts of seawood meal, 69~72 parts of oyster shell whiting, 4~5 parts of biochemical fulvic acid, 0.8~0.9 part of zinc sulfate, sulfuric acid
It is ferrous 1.0~1.3 parts, 0.2~0.3 part of boron, 11~12.5 parts of magnesium powder.
The preparation method of the above-mentioned soil conditioner using the production of marine animal and plant residuum, comprises the following steps:
(1) impurity in sea-plant residuum is rejected, the moisture through drying or being dried to material is less than 35%, through powder
It is broken, seawood meal is made;
(2) air storage of marine animal residuum is subjected to nature curing in 2~3 years, then rejects impurity, dried, Ran Hou
Under conditions of 800~1200 DEG C, 30~40min is calcined, screening disintegration is broken for the material that length is not more than 5cm, through crushing, system
Obtain oyster shell whiting;Material of the length more than 5cm repeats calcining step after screening;
(3) in proportion by oyster shell whiting made from seawood meal made from step (1), step (2), biochemical fulvic acid, zinc sulfate,
Ferrous sulfate, boron, magnesium powder mixing, stir, soil conditioner are made.
According to currently preferred, the crushing in the step (1) is to be crushed to more than 90% fineness of materials to reach 60
Mesh.
It is as follows according to currently preferred, the drying in the step (1), condition:100~130 DEG C of drying 10~
20min。
According to currently preferred, the crushing in the step (2), fineness is 80~100 mesh.
According to currently preferred, the calcining in the step (2), calcined using electrical heating or heated by natural gas formula
Stove.
According to the present invention it is further preferred that the calcining furnace moves drum-type calcining furnace using chain, 0.8~1.5m of diameter,
10~12m of length, 8~10r/min of drum rotation speed.
After being stirred according to currently preferred, described step (3), in addition to granulation step.
Beneficial effect
1st, the present invention is carrying out nature curing activation process by way of calcining is combined to marine animal residuum, greatly
The release of the nutritional ingredient in marine animal residuum is improved, is laid to improve the application effect of the soil conditioner finally prepared
Basis.
2nd, material composition reasonable mixture ratio of the invention, not only contributes to making full use of for marine animal residuum, and each group
Divide and mutually promote, the utilizing status of nutritional ingredient can be improved, it is slow, not notable to overcome soil conditioner effect in the prior art
The drawbacks of.
3rd, the present invention using nature curing process, can largely remove the sodium chloride that contains in marine animal residuum from
Son, be advantageous to the raising of subsequent calcination effect and application effect.
4th, soil conditioner produced by the present invention is in that the moisture content in alkalescent, and soil forms a kind of weak base body, can be disappeared
Except the various germs in soil, the acid ion in sweetening of the soil, promote nitrate nitrogen conversion, improve the utilization rate of chemical fertilizer.
Promote absorption of the crop to available nutrient in soil, improved soil physical behavior, chesson, abolish hardened, promotion crop life
It is long, improve crop anti-adversity and diseases and insect pests resistance, particularly to plant growth caused by lacking calcium constituent fruit tree root rot,
Bitter pit, bitter rot, citrus, grape, the shedding of lichee, dehiscent fruit, decayed fruit, canker, anthracnose, the navel of tomato of apple are rotten
The preventing and treating of the physiological disturbances such as disease, gray mold of cucumber has special efficacy, improves quality of agricultural product, and the effect of increasing income is obvious.
Embodiment
Technical scheme is described further with reference to embodiment, but institute's protection domain of the present invention is not limited to
This.
Sea-plant residuum described in embodiment derives from marine products processing factory, predominantly after marine alga root and marine alga processing
Waste material;
Marine animal residuum described in embodiment derives from marine products processing factory, predominantly oyster shell;
Biochemical fulvic acid is purchased from Pingxiang City Le Le humic acids factory of Jiangxi Province, biochemical fulvic acid be using plant source, weathered coal,
The raw materials such as turf, after special bacteria biofermentation and chemical treatment, obtain high-purity, the similar fulvic acid and richness of high activity
In acid substance, the aromatic carboxylic acids containing small molecule.Its Main Ingredients and Appearance contains fulvic acid (butt) >=90, amino acid >=3%,
Also contain the biochemical activity material such as trace element, nucleic acid, salicylic acid, carbohydrate, indoles acids, collagen and plant endogenous simultaneously
Hormone.
Embodiment 1
It is a kind of using marine animal and plant residuum produce soil conditioner, including pre-processed, crushed, being calcined, dispensing,
Mixture and granulation, raw material components are as follows, are parts by weight:
10 parts of seawood meal, 72 parts of oyster shell whiting, 5 parts of biochemical fulvic acid, 0.8 part of zinc sulfate, 1.0 parts of ferrous sulfate, boron 0.2
Part, 11 parts of magnesium powder.
The preparation method of the above-mentioned soil conditioner using the production of marine animal and plant residuum, comprises the following steps:
(1) impurity such as the plastic ties of the sand adulterated in sea-plant residuum and cultivation are rejected, through 120 DEG C of drying
15min, the moisture of material reach 30%, and ground crushing, obtained more than 90% fineness of materials reaches the seawood meal of 60 mesh;
(2) air storage of marine animal residuum is subjected to nature curing in 3 years, then rejects impurity, dried, then moved in chain
Calcining 30min, calcining furnace diameter 1.1m, length 10m, drum rotation speed 8r/min are carried out in drum-type electro heating and calcining stove, is calcined
At 1200 degree, outlet temperature controls at 800 degree the control of stove inlet temperature, and screening disintegration is broken for the material that length is not more than 5cm,
Through crushing, it is 90 mesh oyster shell whitings that fineness, which is made,;Material of the length more than 5cm is as raw material and the sea after curing, drying after screening
Foreign animal residue together enters calcining furnace and carries out calcining step;
(3) in proportion by oyster shell whiting made from seawood meal made from step (1), step (2), biochemical fulvic acid, zinc sulfate,
Ferrous sulfate, boron, magnesium powder mixing, stir 20min, are granulated, soil conditioner is made.
Embodiment 2
It is a kind of using marine animal and plant residuum produce soil conditioner, including pre-processed, crushed, being calcined, dispensing,
Mixture and granulation, raw material components are as follows, are parts by weight:
15 parts of seawood meal, 69 parts of oyster shell whiting, 2 parts of biochemical fulvic acid, 0.8 part of zinc sulfate, 1.0 parts of ferrous sulfate, boron 0.2
Part, 12 parts of magnesium powder.
The preparation method of the above-mentioned soil conditioner using the production of marine animal and plant residuum, comprises the following steps:
(1) impurity such as the plastic ties of the sand adulterated in sea-plant residuum and cultivation are rejected, through 130 DEG C of drying
10min, the moisture of material reach 30%, and ground crushing, obtained more than 90% fineness of materials reaches the seawood meal of 60 mesh;
(2) air storage of marine animal residuum is subjected to nature curing in 2 years, then rejects impurity, dried, then moved in chain
Calcining 40min, calcining furnace diameter 1.5m, length 11m, drum rotation speed 10r/min are carried out in drum-type electro heating and calcining stove, is calcined
At 1200 degree, outlet temperature controls at 800 degree the control of stove inlet temperature, and screening disintegration is broken for the material that length is not more than 5cm,
Through crushing, it is 100 mesh oyster shell whitings that fineness, which is made,;Material of the length more than 5cm is as raw material and the sea after curing, drying after screening
Foreign animal residue together enters calcining furnace and carries out calcining step;
(3) in proportion by oyster shell whiting made from seawood meal made from step (1), step (2), biochemical fulvic acid, zinc sulfate,
Ferrous sulfate, boron, magnesium powder mixing, stir 20min, are granulated, soil conditioner is made.
Embodiment 3
It is a kind of using marine animal and plant residuum produce soil conditioner, including pre-processed, crushed, being calcined, dispensing,
Mixture and granulation, raw material components are as follows, are parts by weight:
13 parts of seawood meal, 76 parts of oyster shell whiting, 3 parts of biochemical fulvic acid, 1.0 parts of zinc sulfate, 1.5 parts of ferrous sulfate, boron 0.5
Part, 15 parts of magnesium powder.
The preparation method of the above-mentioned soil conditioner using the production of marine animal and plant residuum, comprises the following steps:
(1) impurity such as the plastic ties of the sand adulterated in sea-plant residuum and cultivation are rejected, through 100 DEG C of drying
20min, the moisture of material reach 30%, and ground crushing, obtained more than 90% fineness of materials reaches the seawood meal of 60 mesh;
(2) air storage of marine animal residuum is subjected to nature curing in 3 years, then rejects impurity, dried, then moved in chain
Calcining 35min, calcining furnace diameter 0.8m, length 12m, drum rotation speed 9r/min are carried out in drum-type electro heating and calcining stove, is calcined
At 1200 degree, outlet temperature controls at 800 degree the control of stove inlet temperature, and screening disintegration is broken for the material that length is not more than 5cm,
Through crushing, it is 80 mesh oyster shell whitings that fineness, which is made,;Material of the length more than 5cm is as raw material and the sea after curing, drying after screening
Foreign animal residue together enters calcining furnace and carries out calcining step;
(3) in proportion by oyster shell whiting made from seawood meal made from step (1), step (2), biochemical fulvic acid, zinc sulfate,
Ferrous sulfate, boron, magnesium powder mixing, stir 20min, are granulated, soil conditioner is made.
Embodiment 4
It is a kind of using marine animal and plant residuum produce soil conditioner, including pre-processed, crushed, being calcined, dispensing,
Mixture and granulation, raw material components are as follows, are parts by weight:
12 parts of seawood meal, 69 parts of oyster shell whiting, 4 parts of biochemical fulvic acid, 0.9 part of zinc sulfate, 1.3 parts of ferrous sulfate, boron 0.3
Part, 12.5 parts of magnesium powder.
The preparation method of the above-mentioned soil conditioner using the production of marine animal and plant residuum, comprises the following steps:
(1) impurity such as the plastic ties of the sand adulterated in sea-plant residuum and cultivation are rejected, through 130 DEG C of drying
10min, the moisture of material reach 30%, and ground crushing, obtained more than 90% fineness of materials reaches the seawood meal of 60 mesh;
(2) air storage of marine animal residuum is subjected to nature curing in 2 years, then rejects impurity, dried, then moved in chain
Calcining 35min, calcining furnace diameter 1.5m, length 11m, drum rotation speed 10r/min are carried out in drum-type electro heating and calcining stove, is calcined
At 1200 degree, outlet temperature controls at 800 degree the control of stove inlet temperature, and screening disintegration is broken for the material that length is not more than 5cm,
Through crushing, it is 100 mesh oyster shell whitings that fineness, which is made,;Material of the length more than 5cm is as raw material and the sea after curing, drying after screening
Foreign animal residue together enters calcining furnace and carries out calcining step;
(3) in proportion by oyster shell whiting made from seawood meal made from step (1), step (2), biochemical fulvic acid, zinc sulfate,
Ferrous sulfate, boron, magnesium powder mixing, stir 20min, are granulated, soil conditioner is made.
Comparative example 1
It is as described in Example 1 using the soil conditioner of marine animal and plant residuum production, difference, raw material group
It is point as follows, it is parts by weight:
10 parts of seawood meal, 30 parts of oyster shell whiting, 5 parts of biochemical fulvic acid, 0.8 part of zinc sulfate, 1.0 parts of ferrous sulfate, boron 0.2
Part, 11 parts of magnesium powder.
Preparation method is the same as embodiment 1.
Comparative example 2
As described in Example 1 using the soil conditioner of marine animal and plant residuum production, difference is, using such as
It is prepared by lower section method:
(1) impurity such as the plastic ties of the sand adulterated in sea-plant residuum and cultivation are rejected, through 120 DEG C of drying
15min, the moisture of material reach 30%, and ground crushing, obtained more than 90% fineness of materials reaches the seawood meal of 60 mesh;
(2) by marine animal residuum fresh water flush, impurity is then rejected, is dried, then moves drum-type electro heating in chain
Calcining 30min, calcining furnace diameter 1.1m, length 10m, drum rotation speed 8r/min, calcining furnace inlet temperature control are carried out in calcining furnace
At 1200 degree, outlet temperature controls at 800 degree system, and screening disintegration is broken for the material that length is not more than 5cm, through crushing, is made
Fineness is 90 mesh oyster shell whitings;Material of the length more than 5cm is as raw material and the marine animal residuum one after curing, drying after screening
Calcining step is carried out with calcining furnace is entered;
(3) in proportion by oyster shell whiting made from seawood meal made from step (1), step (2), biochemical fulvic acid, zinc sulfate,
Ferrous sulfate, boron, magnesium powder mixing, stir 20min, are granulated, soil conditioner is made.
Comparative example 3
Method according to embodiment 1 in patent document CN102321484A (application number 201110154187.7) prepares
Soil conditioner.
Comparative example 4
The soil prepared according to the method described in patent document CN1502672A (application number 02135914.8) is adjusted
Manage agent.
Test example:
Using randomized blocks, plot area 100m2If 3 repetitions, with the soil in embodiment 1-4 and comparative example 1-4
Conditioner is as base fertilizer, amount of application 100kg/ mus;It is respectively labeled as treatment group 1-8.Not apply fertilizer area as a control group.
Plantation instruction crop is cucumber, and kind is the miscellaneous No.1 in Tianjin.
Before soil conditioner, soil sample measure soil physical and chemical property is first gathered, collection soil sample is surveyed per cell for off-test
Determine soil physical and chemical property.Using soil weight application core cutter method (referring to NY/T 1121.4-2006 standards), pH value application current potential
Method (referring to NY/T 1121.2-2006 standards), organic matter application potassium bichromate titrimetric method measure (refer to NY/T 1121.6-
2006 standards).
Above-mentioned group, except applied fertilizer to the subsoil difference, manuring late and management all same.
Testing result:
Influence of the different disposal of table 1 to cucumber yield
Processing |
Control group |
Treatment group 1 |
Treatment group 2 |
Treatment group 3 |
Treatment group 4 |
Treatment group 5 |
Treatment group 6 |
Treatment group 7 |
Treatment group 8 |
Average product (kg/ mus) |
4896.6 |
5584.3 |
5567.4 |
5545.2 |
5599.2 |
5378.4 |
5342.6 |
5301.2 |
5329.3 |
Increase production (%) |
|
14.0 |
13.7 |
13.2 |
14.3 |
9.8 |
9.1 |
8.3 |
8.8 |
Influence of the different disposal group of table 2 to soil physical properties
Processing |
Control group |
Treatment group 1 |
Treatment group 2 |
Treatment group 3 |
Treatment group 4 |
Treatment group 5 |
Treatment group 6 |
Treatment group 7 |
Treatment group 8 |
pH |
6.32 |
6.52 |
6.49 |
6.50 |
6.51 |
6.41 |
6.43 |
6.42 |
6.40 |
Unit weight (g/cm3) |
1.32 |
1.26 |
1.27 |
1.28 |
1.27 |
1.30 |
1.30 |
1.29 |
1.30 |
Organic matter (%) |
1.73 |
1.83 |
1.81 |
1.82 |
1.83 |
1.77 |
1.76 |
1.77 |
1.79 |
Interpretation of result:
As can be seen from Table 1, it is respectively 14.0%, 13.7%, 13.2%, 14.3% to handle cucumber production promoting in 1-4,
Higher than the rate of growth 9.8% of cucumber in processing 5, illustrate the reasonable raw material proportioning of soil conditioner of the present invention, can be obvious
Improve crop yield.Cucumber production promoting rate is above the rate of growth of cucumber in processing 6 in processing 1-4, illustrates the shell through overcuring
Powder is more conducive to the growth of crop, improves the yield of crop.Cucumber yield is above the yield of cucumber in processing 7,8 in processing 1-4,
Illustrate soil conditioner effect of increasing production of the present invention better than soil conditioner described in the A of CN 102321484A and CN 1502672.
As can be seen from Table 2, the pH of soil in 1-4 is handled to significantly improve, the soil weight reduces by 4.5% respectively,
3.8%th, 3.0%, 3.8%.It is above the reduced rate 1.5% of the soil weight in processing 5.The content of organic matter is respectively increased 5.8%,
4.6%th, 5.2%, 5.8%.It is above the increase rate 2.3% of the soil organism in processing 5.It can thus be seen that institute of the present invention
The reasonable raw material proportioning of soil conditioner is stated, there is good effect to improved soil.The indices for handling soil in 1-4 are equal
Better than the indices of soil in processing 6, illustrate that the oyster shell whiting through overcuring is more conducive to the improvement of soil.Handle soil in 1-4
Indices be superior to processing 7, the indices of 8 soil.Illustrate that soil conditioner reclamation result of the present invention is better than
Soil conditioner described in the CN102321484A and A of CN 1502672.