CN104946110A - Anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating and preparation method thereof - Google Patents
Anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating and preparation method thereof Download PDFInfo
- Publication number
- CN104946110A CN104946110A CN201510334268.3A CN201510334268A CN104946110A CN 104946110 A CN104946110 A CN 104946110A CN 201510334268 A CN201510334268 A CN 201510334268A CN 104946110 A CN104946110 A CN 104946110A
- Authority
- CN
- China
- Prior art keywords
- parts
- coating
- component
- graffiti
- high durable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to the field of coatings, in particular to an anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating and a preparation method thereof. The anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating comprises an A component and a B component, wherein the A component comprises the following components in parts by weight: 20-50 parts of modified hydroxy acrylic resin, 10-40 parts of FEVE fluorocarbon resin, 1-5 parts of organopolysiloxane and 2-10 parts of organosilicone modified acrylate; and the B component comprises the following components in parts by weight: 70-80 parts of curing agent and 20-30 parts of solvent. The anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating has very excellent hydrophobic and oleophobic properties and anti-doodling and anti-sticking functions, reduces water percolation, and can prolong the service life of a paint film; and mould growth is not easy.
Description
Technical field
The present invention relates to paint field, be specifically related to coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil and preparation method thereof.
Background technology
Along with modern industry expanding economy, in urban life, no matter be public transport, as on subway, train, light rail, bus, or communal facility, as on public transport stop board, waiting booth, electric pole, wall, the scribble of the various coating and drawing at random that is all seen everywhere and the small advertisement arbitrarily puted up, have a strong impact on city appearance, and remove the manpower and materials that these scribbles want at substantial.Found by research, the surface of low surface energy effectively can prevent scribble attachment and pollute, use high-performance anti-doodling paint, the direct effective means tackling scribble, especially long-acting lasting anti-doodling paint, its surface is hard, smooth, and scribble material is difficult to stain on it, and very easily removes.Polysiloxane has excellent hydrophobic and lyophobic property and oilness, is applied in coating, significantly can reduces the surface energy of film, obtain splendid low surface energy effect.
Scientific research personnel have also been made a few thing in the research and development of anti-doodling and anti-affixing coating, and patent CN101585995B reports the oil-based anti-graffiti adhesion resistant paint prepared for main raw material with Hydroxylated acrylic resin, fluorocarbon resin, hydroxyl polydimethylsiloxaneresins resins, hexamethylene diisocyanate biuret.Patent CN101781519A reports the anti-doodling and anti-affixing coating prepared for main raw material with Hydroxylated acrylic resin, fluorine richness Hydroxylated acrylic resin, organic-silicon-modified Hydroxylated acrylic resin, polyisocyanate prepolymers.Although above-mentioned antigraffiti effect and the ageing resistance that significantly improve paint film about anti-doodling and anti-affixing coating in the application, after Multi-time graffiti and physical abrasion, its surface energy can raise, and polluting proofing property can decline.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of coating of anti-graffiti, the anti-stick subsides high durable of anti-soil.
Another object of the present invention is to provide the preparation method of above-mentioned coating.
Technical problem to be solved by this invention is achieved by the following technical programs:
A coating for the anti-stick subsides high durable of anti-graffiti, anti-soil, described coating is made up of A, B two kinds of components, and wherein component A comprises the component of following parts by weight:
Modified hydroxyl acrylic resin 20 ~ 50 parts; FEVE fluorocarbon resin 10 ~ 40 parts; Organopolysiloxane 1 ~ 5 part; Organosilicon-modified acrylate 2 ~ 10 parts;
Wherein B component comprises the component of following parts by weight:
70 ~ 80 parts, solidifying agent, solvent 20 ~ 30 parts.
Further, the hydroxyl value of described modified hydroxyl acrylic resin is 80-150 mgKOH/g, and number-average molecular weight is 2000-20000 g/mol.
Further, described FEVE fluorocarbon resin hydroxyl value is 10-100 mgKOH/g, and number-average molecular weight is 15000-20000 g/mol, and Oil repellent is 20% ~ 25%, and water contact angle is greater than 95 °, and surface tension is less than 24 dyne.
Further, described organopolysiloxane is organosilicon microsphere powder, and its particle diameter is 2 ~ 5 μm, the preferential organopolysiloxane used containing one or more groups in epoxy group(ing), amino, methacryloxy, sulfydryl isoreactivity group.
Further, described solidifying agent is hexamethylene diisocyanate.
Further, the weight ratio of described component A and B component is 5 ~ 10:2 ~ 4.
Further, according to parts by weight, component A also comprises functional agent 0.1 ~ 5 part.
Further, described functional agent is at least one in defoamer, flow agent, siccative, protective agent.
Preferred further, described component A is made up of the component of following parts by weight:
Modified hydroxyl acrylic resin 20 ~ 50 parts; FEVE fluorocarbon resin 10 ~ 30 parts; Organopolysiloxane 1 ~ 5 part; Organosilicon-modified acrylate 2 ~ 10 parts; Defoamer 0.1 ~ 0.5 part; Flow agent 0.2 ~ 1 part; Siccative 0.1 ~ 0.2 part; Protective agent 0.5 ~ 3 part; Solvent 10 ~ 35 parts.
A kind of preparation method of coating of anti-graffiti, the anti-stick subsides high durable of anti-soil:
The preparation method of described component A comprises the following steps:
Modified hydroxyl acrylic resin, FEVE low surface energy fluoro-resin are added in stirred pot, agitator stirs with the speed of 600-700 rev/min, then organopolysiloxane is added, continue to stir at least 10 minutes with 800-850 rev/min, add solvent, functional agent and organosilicon-modified acrylate respectively again, continue to stir at least 10 minutes with 500-600 rev/min, by remainder solvent adjustment viscosity, after the assay was approved, filter and package;
The preparation method of described B component comprises the following steps:
First in stirred pot, add solvent, then add solidifying agent, 500-600 rev/min is stirred under an inert gas, then filters and packages.
During use, A, B two kinds of components fully mixed by certain weight ratio and stir, namely obtaining transparent anti-graffiti anti-stick dirty coatings with high weatherability of the present invention.
Defoamer, flow agent, siccative, protective agent adopt the conventional material of the art all can realize the present invention.Those skilled in the art can select corresponding defoamer, flow agent, siccative, protective agent as required voluntarily.
Solvent adopts the conventional solvent of the art all can realize the present invention, such as ester class and ketones solvent, is preferably 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE in the present invention.
Hydrophobic oleophobic and the good silicone-modified polyacrylate of hydrophobic nature and organopolysiloxane is added in system of the present invention, so the paint film hydrophobic oleophobic, the solvent resistant that are formed, acid and alkali-resistance salt fog performance is given prominence to, define the condition of anti-graffiti anti-stick dirt, oiliness, free ink pen are difficult to retain at coating surface, and a small amount of retention is also easy to be eliminated, various non-setting adhesive, glue is difficult to paste, and this is the most important characteristic of anti-graffiti anti-contamination.
The present invention has following beneficial effect:
Coating that is anti-graffiti, the anti-stick subsides high durable of anti-soil of the present invention has the following advantages:
1, there is very excellent hydrophobic and oleophobic property and anti-doodling and anti-affixing function, reduce water permeation, not easily grow mold, the work-ing life of paint film can be improved.
2, excellent scrub resistance, easy to clean, easy construction.
3, coating surface is smooth, smooth, and can be made into high light or the unglazed paint film of dumb light, weathering resistance is good.
4, paint film flexibility is good, 1mm flawless, and sticking power reaches one-level, and Mitsubishi's pencil hardness reaches H.
5, acid and alkali-resistance salt medium, solvent resistance is good, alcohol, gasoline, acetone wipe 100 times not show-through.
6, adhibit quality is good repeatedly, more than 50 times glue-free residues.
7, anti-graffiti property is good, all can clean, paint film not damaged after oil pen, free ink pen, ink, the scribble that sprays paint with cleaner special.
8, environmentally friendly paint, nuisance quality reaches Standard.
Embodiment
In the middle of embodiments of the invention, if no special instructions, the hydroxyl value of the modified hydroxyl acrylic resin that the present invention is used is 80-150 mgKOH/g, and number-average molecular weight is 2000-20000 g/mol; FEVE fluorocarbon resin hydroxyl value used is 10-100 mgKOH/g, and number-average molecular weight is 15000-20000 g/mol, and Oil repellent is 20% ~ 25%, and water contact angle is greater than 95 °, and surface tension is less than 24 dyne.The particle diameter of organopolysiloxane used is 2 ~ 5 μm.
Its preparation method is as described below:
The preparation method of described component A comprises the following steps:
Modified hydroxyl acrylic resin, FEVE low surface energy fluoro-resin are added in stirred pot, agitator stirs with the speed of 600-700 rev/min, then organopolysiloxane is added, continue to stir at least 10 minutes with 800-850 rev/min, add solvent, functional agent and organosilicon-modified acrylate respectively again, continue to stir at least 10 minutes with 500-600 rev/min, by remainder solvent adjustment viscosity, after the assay was approved, filter and package;
The preparation method of described B component comprises the following steps:
First in stirred pot, add solvent, then add solidifying agent, 500-600 rev/min is stirred under an inert atmosphere, then filters and packages.
A, B two kinds of components fully mixed by certain weight ratio during use and stir, adjusting to suitable viscosity can construct, and obtains the paint film solidified.
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, is not limitation of the invention.
embodiment 1
A coating for the anti-stick subsides high durable of anti-graffiti, anti-soil, comprise A, B two kinds of components, wherein component A comprises the material of following parts by weight:
Modified hydroxyl acrylic resin 50 parts, FEVE low surface energy fluoro-resin 25 parts, organopolysiloxane 1 part, organosilicon-modified acrylate 3 parts, defoamer 0.2 part, flow agent 0.3 part, siccative 0.2 part, protective agent 1.6 parts, N-BUTYL ACETATE 12 parts, 1-Methoxy-2-propyl acetate 6.7 parts.
B component comprises the material of following parts by weight:
Hexamethylene diisocyanate 75 parts, N-BUTYL ACETATE 15 parts, 1-Methoxy-2-propyl acetate 10 parts.
embodiment 2
A coating for the anti-stick subsides high durable of anti-graffiti, anti-soil, comprise A, B two kinds of components, wherein component A comprises the material of following parts by weight:
Modified hydroxyl acrylic resin 50 parts, FEVE low surface energy fluoro-resin 25 parts, organopolysiloxane 5 parts, organosilicon-modified acrylate 3 parts, defoamer 0.2 part, flow agent 0.3 part, siccative 0.2 part, protective agent 1.6 parts, N-BUTYL ACETATE 12 parts, 1-Methoxy-2-propyl acetate 2.7 parts.
B component comprises the material of following parts by weight:
Hexamethylene diisocyanate 75 parts, N-BUTYL ACETATE 15 parts, 1-Methoxy-2-propyl acetate 10 parts.
embodiment 3
A coating for the anti-stick subsides high durable of anti-graffiti, anti-soil, comprise A, B two kinds of components, wherein component A comprises the material of following parts by weight:
Modified hydroxyl acrylic resin 50 parts, FEVE low surface energy fluoro-resin 25 parts, organopolysiloxane 3 parts, organosilicon-modified acrylate 7 parts, defoamer 0.2 part, flow agent 0.6 part, siccative 0.2 part, protective agent 3 parts, N-BUTYL ACETATE 10 parts, 1-Methoxy-2-propyl acetate 1 part.
B component comprises the material of following parts by weight:
Hexamethylene diisocyanate 70 parts, N-BUTYL ACETATE 20 parts, 1-Methoxy-2-propyl acetate 10 parts.
comparative example 1
A kind of coating, comprise A, B two kinds of components, wherein component A comprises the material of following parts by weight:
Modified hydroxyl acrylic resin 50 parts, FEVE low surface energy fluoro-resin 25 parts, organosilicon-modified acrylate 3 parts, defoamer 0.2 part, flow agent 0.3 part, siccative 0.2 part, protective agent 1.6 parts, N-BUTYL ACETATE 12 parts, 1-Methoxy-2-propyl acetate 7.7 parts.
B component comprises the material of following parts by weight:
Hexamethylene diisocyanate 75 parts, N-BUTYL ACETATE 15 parts, 1-Methoxy-2-propyl acetate 10 parts.
comparative example 2
The particle diameter of the organopolysiloxane used in this comparative example is 8 μm.
A kind of coating, comprise A, B two kinds of components, wherein component A comprises the material of following parts by weight:
Modified hydroxyl acrylic resin 50 parts, FEVE low surface energy fluoro-resin 25 parts, organopolysiloxane 5 parts, organosilicon-modified acrylate 3 parts, defoamer 0.2 part, flow agent 0.3 part, siccative 0.2 part, protective agent 1.6 parts, N-BUTYL ACETATE 12 parts, 1-Methoxy-2-propyl acetate 2.7 parts.
B component comprises the material of following parts by weight:
Hexamethylene diisocyanate 75 parts, N-BUTYL ACETATE 15 parts, 1-Methoxy-2-propyl acetate 10 parts.
comparative example 3
The Hydroxylated acrylic resin used in this comparative example, fluorocarbon resin, organosilicon-modified acrylate are market usual products, and strictly control hydroxyl value, molecular weight, the Oil repellent of being correlated with unlike the present invention.
A kind of coating, comprise A, B two kinds of components, wherein component A comprises the material of following parts by weight:
Hydroxylated acrylic resin 50 parts, fluorocarbon resin 25 parts, organopolysiloxane 3 parts, organosilicon-modified acrylate 7 parts, defoamer 0.2 part, flow agent 0.6 part, siccative 0.2 part, protective agent 3 parts, N-BUTYL ACETATE 10 parts, 1-Methoxy-2-propyl acetate 1 part.
B component comprises the material of following parts by weight:
Hexamethylene diisocyanate 75 parts, N-BUTYL ACETATE 15 parts, 1-Methoxy-2-propyl acetate 10 parts.
By the paint spay-coating of above-described embodiment and comparative example on the various base materials specified, after paint film solidifies completely on base material, properties test is carried out in requirement according to technical performance index, comprise: outward appearance, hardness, sticking power, wear resistance, salt fog resistance, artificial ageing resistance, acid resistance, resistant to liquid medium, solvent resistant wiping, anti-graffiti property, anti-adhibit quality etc., concrete test performance the results are shown in following table:
The above embodiment only have expressed embodiments of the present invention; it describes comparatively concrete and detailed; but therefore can not be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme adopting the form of equivalent replacement or equivalent transformation to obtain, all should drop within protection scope of the present invention.
Claims (10)
1. a coating for the anti-stick subsides high durable of anti-graffiti, anti-soil, is characterized in that, described coating is made up of A, B two kinds of components, and wherein component A comprises the component of following parts by weight:
Modified hydroxyl acrylic resin 20 ~ 50 parts;
FEVE fluorocarbon resin 10 ~ 40 parts;
Organopolysiloxane 1 ~ 5 part;
Organosilicon-modified acrylate 2 ~ 10 parts;
Wherein B component comprises the component of following parts by weight:
70 ~ 80 parts, solidifying agent, solvent 20 ~ 30 parts.
2. the coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil according to claim 1, it is characterized in that, the hydroxyl value of described modified hydroxyl acrylic resin is 80-150 mgKOH/g, and number-average molecular weight is 2000-20000 g/mol.
3. the coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil according to claim 1, it is characterized in that, described FEVE fluorocarbon resin hydroxyl value is 10-100 mgKOH/g, number-average molecular weight is 15000-20000 g/mol, Oil repellent is 20% ~ 25%, water contact angle is greater than 95 °, and surface tension is less than 24 dyne.
4. the coating of a kind of anti-graffiti, the anti-stick subsides high durable of anti-soil according to claim 1 ~ 3 any one, it is characterized in that, the particle diameter of described organopolysiloxane is 2 ~ 5 μm.
5. the coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil according to claim 1, it is characterized in that, described solidifying agent is hexamethylene diisocyanate.
6. the coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil according to claim 1, it is characterized in that, the weight ratio of described component A and B component is 5 ~ 10:2 ~ 4.
7. the coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil according to claim 1, it is characterized in that, according to parts by weight, component A also comprises functional agent 0.1 ~ 5 part.
8. the coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil according to claim 7, it is characterized in that, described functional agent is at least one in defoamer, flow agent, siccative, protective agent.
9. the coating of a kind of anti-graffiti, anti-stick subsides high durable of anti-soil according to claim 8, it is characterized in that, described component A is made up of the component of following parts by weight:
Modified hydroxyl acrylic resin 20 ~ 50 parts;
FEVE fluorocarbon resin 10 ~ 40 parts;
Organopolysiloxane 1 ~ 5 part;
Organosilicon-modified acrylate 2 ~ 10 parts;
Defoamer 0.1 ~ 0.5 part;
Flow agent 0.2 ~ 1 part;
Siccative 0.1 ~ 0.2 part;
Protective agent 0.5 ~ 3 part;
Solvent 10 ~ 35 parts.
10. a preparation method for the coating of a kind of anti-graffiti, the anti-stick subsides high durable of anti-soil described in claim 1 ~ 9 any one, is characterized in that:
The preparation method of described component A comprises the following steps:
Modified hydroxyl acrylic resin, FEVE fluoro-resin are added in stirred pot, agitator stirs with the speed of 600-700 rev/min, then organopolysiloxane is added, continue to stir at least 10 minutes with 800-850 rev/min, add solvent, functional agent and organosilicon-modified acrylate respectively again, continue to stir at least 10 minutes with 500-600 rev/min, by remainder solvent adjustment viscosity, after the assay was approved, filter and package;
The preparation method of described B component comprises the following steps:
First in stirred pot, add solvent, then add solidifying agent, 500-600 rev/min is stirred under an inert gas, then filters and packages.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510334268.3A CN104946110A (en) | 2015-06-17 | 2015-06-17 | Anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510334268.3A CN104946110A (en) | 2015-06-17 | 2015-06-17 | Anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104946110A true CN104946110A (en) | 2015-09-30 |
Family
ID=54161190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510334268.3A Pending CN104946110A (en) | 2015-06-17 | 2015-06-17 | Anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104946110A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105385347A (en) * | 2015-12-29 | 2016-03-09 | 湖南自洁材料研究院有限公司 | Anti-sticking and anti-scrawling coating for urban management |
| CN105802363A (en) * | 2016-03-29 | 2016-07-27 | 苏州嘉乐威企业发展有限公司 | Novel scrawl-preventing self-cleaning polytetrafluoroethylene vanish for aluminum-plastic composite panel and preparing method of novel scrawl-preventing self-cleaning polytetrafluoroethylene vanish |
| CN107974186A (en) * | 2017-12-12 | 2018-05-01 | 启智书写墙科技（杭州）有限公司 | The environmental protection wall surface coating and preparation method of a kind of resistance to writing |
| CN109207041A (en) * | 2018-08-20 | 2019-01-15 | 安徽嘉智信诺化工股份有限公司 | A kind of aqueous anti-graffiti adhesion resistant paint |
| CN111320922A (en) * | 2018-12-14 | 2020-06-23 | 天津中航百慕新材料技术有限公司 | High weather-proof anti-sticking coating and preparation method thereof |
| CN113683927A (en) * | 2021-08-23 | 2021-11-23 | 宁波宇明工程防腐材料有限公司 | Special long-acting anti-doodling anti-sticking coating and preparation method thereof |
| CN114163885A (en) * | 2021-12-23 | 2022-03-11 | 深圳邦荣汽车用品有限公司 | Electrosilvering paint, preparation method and application |
| CN114395321A (en) * | 2021-12-24 | 2022-04-26 | 广东粤港澳大湾区黄埔材料研究院 | Anti-fouling coating and preparation and application thereof |
| CN115846167A (en) * | 2022-10-21 | 2023-03-28 | 天津欧派集成家居有限公司 | Coating method of easy-to-clean baking finish |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275056A (en) * | 2008-05-16 | 2008-10-01 | 哈尔滨金士源科技有限公司 | Anti-sticking anti-scribbling paint composition |
| CN101585995A (en) * | 2009-07-08 | 2009-11-25 | 兰州迅美漆业科技有限公司 | Oil-based anti-graffiti adhesion resistant paint and preparation method thereof |
| CN101781519A (en) * | 2009-12-22 | 2010-07-21 | 北京航材百慕新材料技术工程股份有限公司 | Transparent anti-graffiti dirt-resistant anti-weathering coating |
| CN102876150A (en) * | 2011-07-14 | 2013-01-16 | 上海大通高科技材料有限责任公司 | High weather resistant anti-pasting and doodling-proof water-based paint and preparing method thereof |
| CN102911584A (en) * | 2012-11-21 | 2013-02-06 | 戚城 | Anti-graffiti anti-sticking nano coating and preparation method thereof |
-
2015
- 2015-06-17 CN CN201510334268.3A patent/CN104946110A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275056A (en) * | 2008-05-16 | 2008-10-01 | 哈尔滨金士源科技有限公司 | Anti-sticking anti-scribbling paint composition |
| CN101585995A (en) * | 2009-07-08 | 2009-11-25 | 兰州迅美漆业科技有限公司 | Oil-based anti-graffiti adhesion resistant paint and preparation method thereof |
| CN101781519A (en) * | 2009-12-22 | 2010-07-21 | 北京航材百慕新材料技术工程股份有限公司 | Transparent anti-graffiti dirt-resistant anti-weathering coating |
| CN102876150A (en) * | 2011-07-14 | 2013-01-16 | 上海大通高科技材料有限责任公司 | High weather resistant anti-pasting and doodling-proof water-based paint and preparing method thereof |
| CN102911584A (en) * | 2012-11-21 | 2013-02-06 | 戚城 | Anti-graffiti anti-sticking nano coating and preparation method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105385347A (en) * | 2015-12-29 | 2016-03-09 | 湖南自洁材料研究院有限公司 | Anti-sticking and anti-scrawling coating for urban management |
| CN105802363A (en) * | 2016-03-29 | 2016-07-27 | 苏州嘉乐威企业发展有限公司 | Novel scrawl-preventing self-cleaning polytetrafluoroethylene vanish for aluminum-plastic composite panel and preparing method of novel scrawl-preventing self-cleaning polytetrafluoroethylene vanish |
| CN107974186A (en) * | 2017-12-12 | 2018-05-01 | 启智书写墙科技（杭州）有限公司 | The environmental protection wall surface coating and preparation method of a kind of resistance to writing |
| CN109207041A (en) * | 2018-08-20 | 2019-01-15 | 安徽嘉智信诺化工股份有限公司 | A kind of aqueous anti-graffiti adhesion resistant paint |
| CN111320922A (en) * | 2018-12-14 | 2020-06-23 | 天津中航百慕新材料技术有限公司 | High weather-proof anti-sticking coating and preparation method thereof |
| CN113683927A (en) * | 2021-08-23 | 2021-11-23 | 宁波宇明工程防腐材料有限公司 | Special long-acting anti-doodling anti-sticking coating and preparation method thereof |
| CN114163885A (en) * | 2021-12-23 | 2022-03-11 | 深圳邦荣汽车用品有限公司 | Electrosilvering paint, preparation method and application |
| CN114395321A (en) * | 2021-12-24 | 2022-04-26 | 广东粤港澳大湾区黄埔材料研究院 | Anti-fouling coating and preparation and application thereof |
| CN115846167A (en) * | 2022-10-21 | 2023-03-28 | 天津欧派集成家居有限公司 | Coating method of easy-to-clean baking finish |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104946110A (en) | Anti-doodling, anti-fouling, anti-sticking and high weather-resistant coating and preparation method thereof | |
| CN101712842B (en) | Adhesion and doodling prevention coating | |
| CN101585995B (en) | Oil-based anti-graffiti adhesion resistant paint and preparation method thereof | |
| CN101781519B (en) | Transparent anti-graffiti dirt-resistant anti-weathering coating | |
| CN103555156B (en) | Ultraviolet light curing fingerprint resistant, antistatic coating composition | |
| CN102516859B (en) | Anti-doodling and anti-affixing paint and its preparation method | |
| JP2015534601A (en) | Hydrophobic and oleophobic coating composition | |
| CN102120913A (en) | Water-based polyurethane paint for protecting windmill generator blade | |
| CN112210293A (en) | Hydrophobic and oleophobic coating composition and preparation method thereof | |
| CN102559008A (en) | Protective coating and preparation method thereof | |
| CN102993946B (en) | Waterborne fluorine silicone resin modified acrylic acid concrete protective coating | |
| CN102477249A (en) | Aqueous anti-doodling and anti-affixing paint and its preparation method | |
| CN104263208A (en) | UV (Ultraviolet) laminated topcoat gloss coating with performances of smell removal, stain resistance and yellowing resistance as well as preparation method and construction process thereof | |
| CN108003693A (en) | A kind of anti-pollution wear-resistant paint for stainless steel sink and preparation method thereof | |
| CN102277048A (en) | Self-cleaning polytetrafluoroethylene FEVE (fluoralkene alkyl vinyl ether or ester) coating and preparation method thereof | |
| CN105694646A (en) | Fluorine-containing composition for surface treatment of porous base material | |
| CN101565579B (en) | Anti-doodling and anti-affixing coating and preparation method thereof | |
| CN102660199A (en) | Automobile care product | |
| KR20220000908U (en) | Glass film coating composition for automotive surface protection and the method of | |
| CN107686691B (en) | Water-based acrylic release silicone oil and preparation method and application thereof | |
| CN106047129B (en) | A kind of bullet train high resiliency anti-blown sand wear-resisting weather-proof finishing coat and preparation method | |
| CN105440938B (en) | Antisticking coating and anti-sticking patch | |
| CN109251612A (en) | A kind of organosilicon water paint and preparation method thereof | |
| CN112662294A (en) | Water-based anti-doodling paint | |
| CN115851099B (en) | Water-based two-component coating for plastic and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150930 |