CN104946103B - Resin paint brushing method - Google Patents
Resin paint brushing method Download PDFInfo
- Publication number
- CN104946103B CN104946103B CN201510455036.3A CN201510455036A CN104946103B CN 104946103 B CN104946103 B CN 104946103B CN 201510455036 A CN201510455036 A CN 201510455036A CN 104946103 B CN104946103 B CN 104946103B
- Authority
- CN
- China
- Prior art keywords
- wall
- parts
- whitewashing
- lifting support
- cold coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a resin paint brushing method, and provides an automatic wall brushing machine which comprises a moving device, a material carrying box arranged on the moving device, a lifting device arranged on one side of the material carrying box and used for lifting, and a wall brushing device arranged on the lifting device and used for brushing wall, wherein a cavity used for holding paint and a power device are arranged in the material carrying box; a display control system is also arranged on one side of the box body of the material carrying box; the lifting device comprises a first lifting bracket and a second lifting bracket which are symmetrically arranged on side of the material carrying box and used for lifting the wall brushing device. The resin paint comprises the following raw component materials in parts by weight: 10-200 parts of alkyd resin, 5-100 parts of filling material, 1-30 parts of paint, 0.5-10 parts of a catalyst, 4-80 parts of ammonia water, 3-7 parts of a solid additive and 1.5-6 parts of a second solid additive. The automatic wall brushing machine is low in manufacturing cost, excellent in wall brushing effect, and suitable for being pushed into market for wide use.
Description
Technical field
The present invention relates to paint field, more particularly to a kind of brushing method of cold coating.
Background technology
With the improvement of people's living standards, the environmental requirements such as house are also increasingly increased, this is just brought to environment, rent
Room constantly improves, and also just produces thereupon and whitewashes a wall this technique, and traditional whitewashing a wall all be that by being accomplished manually, common whitewashes a wall
Work is whitewashed a wall often to exist and smears inequality, and the phenomenon of drippage is wanted to look for a skilled work of whitewashing a wall to waste time and energy again, and now artificial
Expense rises steadily, and to whitewashing a wall, this procedure increased many costs, also has many wall painting machines to be invented in recent years, such as publication number
For CN202500453U（2012-10-24）The automatic plastering apparatus of the wheeled uniform feeding of disclosed a kind of even tooth pushing, although reduce
Manpower, but in use, wall painting machine can not be automatically performed one complete coating work, it is desired nonetheless to manually aside enter
Row is constantly debugged, loaded down with trivial details again without improvement for what is whitewashed a wall.
The content of the invention
Present invention aim to address the problems referred to above, there is provided a kind of brushing method of cold coating, it is only necessary to artificial
Area of whitewashing a wall is input into, wall painting machine is put in into specified location and just can be completed to whitewash a wall, whole procedure is simple and convenient.
The present invention above-mentioned technical purpose technical scheme is that：
A kind of brushing method cold coating of cold coating includes the component materials of following weight portion：
Alkyd resin：10-200, filler：5-100,
Pigment：1-30, catalyst： 0.5-10；
Ammonia：4-80,
First solid additive 3-7；Second solid additive 1.5-6；
Wherein alkyd resin includes the raw material of following weight portion：
Trimethylolpropane：5-100, ethylene glycol：1-50,
Glycerol：5-150, phthalic anhydride：5-110,
Maleic acid：5-90, vegetable oil：0.05-1,
Butyl glycol ether：4-50, styrene：6-140, polymerization inhibitor： 0.05-1；
The cold coating brushes metope automatically by automatic plastering apparatus；
The automatic plastering apparatus include mobile device, the tote box being arranged in the mobile device, are arranged at the load
The lowering or hoisting gear for lifting of side in thing case, and be arranged on the lowering or hoisting gear for the device of whitewashing a wall whitewashed a wall,
The cavity volume and power set for holding paint vehicle is provided with the tote box, and the loading box body side is additionally provided with display control system
System；The lowering or hoisting gear includes being arranged at symmetrically arranged first liter for lifting the device of whitewashing a wall in the tote box side
Descending branch frame and the second lifting support；The device of whitewashing a wall includes material passing tube, connects first lifting support with described second liter
3rd support of descending branch frame, the sensing device being arranged on first lifting support, and it is arranged at second liter of descending branch
Cylinder of whitewashing a wall on frame.
This programme is, by manually switching on power, the required area whitewashed a wall, height, width to be input into display control program,
Power set are opened again, and coating is pressed into material passing tube by power set, and coating is sent to brush rifle cylinder, display control system by material passing tube
The movement of the height of system control lowering or hoisting gear and mobile device so that cylinder of whitewashing a wall can be carried out according to the movement of mobile device
The function of whitewashing a wall.
It has been investigated that, trimethylolpropane, glycerol can improve the water solublity of alkyd resin, but be single use this two
The less stable of the alkyd resin water solublity, dry rate and resin that prepare is planted, the use of ethylene glycol in use can keep away
Exempt from this defect, so that the hydrolytic stability of the resin for being formed, water solublity, dry rate (curing rate) are all significantly improved.
The price of the phthalic anhydride is cheap compared with other polyprotic acid, and esterification reaction temperature is low, and reacting balance is convenient to be controlled, but
It is that phthalic anhydride easily forms half ester and causes resin relative molecular weight relatively low, so as to the time lengthening that coating can be affected to be dried, hardness drop
It is low, replace part phthalic anhydride that the defect of phthalic anhydride can then made up using maleic acid.
The use of ammonia can improve the yellowing of the water solublity of alkyd resin, stability, viscosity, curing rate and film
Property.The effect of butyl glycol ether is to increase dissolubility of the alkyd resin in water, adjusts the viscosity of resin, improves stablizing for resin
Property, improve levelability and the outward appearance of resin paint film.
Styrene is the organic compound formed with a hydrogen atom of benzene substituted ethylene, and the electronics of vinyl is with phenyl ring altogether
Yoke, it is water insoluble, it is dissolved in ethanol, ether, polymerization gradually occurs in being exposed to air and aoxidizes, cinnamic addition can make
The increase of alkyd resin bonding force is obtained, water-tolerant, rate of drying are accelerated.
Preferably, the particle size range of first solid additive is 0.8-5 microns;Wherein, 0.8-1 microns
Grain accounts for the 20-40% of the solid additive gross weight;The granule of 1-2 microns accounts for the 10-30% of the solid additive gross weight；It is remaining
Measure the granule for 3-5 microns；
Regulation of second solid additive for the molybdenum disulfide nano ball and particle diameter 6-9 microns of particle diameter 10-20 nanometers
Grain is according to mass ratio 1:The mixture of 2-5 compositions.
First solid additive and the second solid additive of different-grain diameter and species is increasing corrosion resistance of coating, durable
Property, while weatherability, moreover it is possible to give coating with water repelling property and abrasion resistance.
Preferably, described filler includes Calcium Carbonate, talcous any one or two kinds of any ratios are mixed, selected
Color stuffing requires the heavy metallic pigments such as not leaded, hydrargyrum, meets the requirement of nontoxic industry, has again good in paint film
Closure and Corrosion Protection, make coating have certain rheological characteristic, reduce the cost of coating, therefore, through multiple orthogonal examination
Test, this patent selects Calcium Carbonate, Pulvis Talci is main stuffing.
Preferably, the pigment be dark green, titanium dioxide, chrome yellow any one or more be mixed by any ratio and
Into selected color stuffing requires the heavy metallic pigments such as not leaded, hydrargyrum, meets the requirement of nontoxic industry, has in paint film again
There are good closure and Corrosion Protection, make coating that there is certain rheological characteristic, reduce the cost of coating, therefore, Jing Guoduo
Secondary orthogonal test, this patent select dark green, titanium white, and chrome yellow is main pigments.
Preferably, the catalyst includes the one kind or two in bipyridyl compound and novel polymeric type catalyst
Kind, it is undesirable that the use of catalyst is primarily due to many coating drying effect in film forming, the bipyridyl compound and
Novel polymeric type catalyst can be water-soluble, can solve the problems, such as that coating film forming is undesirable well.
Preferably, the vegetable oil includes Oleum Ricini, castor oil hydrogenated, one or more in Oleum Cocois, Jing researchs
It was found that, preferably, Oleum Cocois take second place the alkyd resin water solublity of Oleum Ricini and castor oil hydrogenated synthesis, and Oleum Glycines are compared more poor.
Preferably, the polymerization inhibitor is quinones polymerization inhibitor or phenolic inhibitor, the use of polymerization inhibitor is to prevent alcohol
The self-polymeric reaction of acid resin, adds polymerization inhibitor improve alkyd resin and obtains stability.
Preferably, the preparation method is as follows：
（1）By the trimethylolpropane：5-100 parts, ethylene glycol：1-50 parts, glycerol：5-150 parts, phthalic anhydride：5-110
Part, maleic acid：5-90 parts, add in reactor by weight, and intensification makes alcohol acid reaction completely, obtains reactant；
（2）By step（1）In reactant be cooled to 180-190 DEG C, add vegetable oil by weight：0.05-1 parts, resistance
Poly- agent：0.05-1 parts, obtain mixture；
（3）By step（2）In mixture be cooled to 120-130 DEG C, add styrene by weight：6-140 parts, obtain dilute
Release thing；
（4）By the butyl glycol ether：4-50 parts, are added to step by weight（3）In dilution in, stir
Obtain alkyd resin；
（5）By step（4）In alkyd resin and described filler, pigment, catalyst, ammonia 10-200 by weight：5-
100：1-30：0.5-10：4-80 mixes, and stirs, obtains final product coating.
Preferably, the step（1）In intensification include that rising for the first time gentle second heats up, the first time heats up
Temperature maximum is controlled at 160-170 DEG C, second warming temperature peak control between 230-240 DEG C, for the first time
The span of control of temperature is because maleic acid in this temperature range, can be transformed into cis reaction structure more stable
Transconfiguration, is more beneficial for sold resin, and depending on the setting of the scope of second temperature is then the property according to acid alcohol, in this model
In enclosing, alkyd sufficiently can be reacted.
Preferably, the step（4）In dilution temperature between 60-70 DEG C, the selection for diluting temperature is basis
What numerous experimental datas was determined, temperature is too high, and autohemagglutination easily occurs in the alkyd resin of formation, and temperature is too low, it is not easy to carry out
Dilution.
Preferably, first lifting support includes the first short column of one or more hollow different inner diameters, it is described
First short column of different inner diameters is formed by connecting inside and outside gear, is additionally provided with sensing device on the first short column top, different
The setting of internal diameter can be embedded between two neighboring first short column to allow, and connected with gear between adjacent two first short columns
Connect, facilitate display control program to control the flexible of the first lifting support, the setting of the sensing device can scan the wall brushed
The smoothness in face and flatness, discovery smear the situation of inequality, can send information to display control program, display control program
Feedback being made to information, promoting mobile device to return to and do not smear uniform position, the position for smearing inequality is entered again
Row is smeared.
Preferably, second lifting support includes the second short column of one or more hollow different inner diameters, it is described
Second short column of different inner diameters is formed by connecting inside and outside gear, is additionally provided with cylinder of whitewashing a wall on the second short column top, different
The setting of internal diameter can be embedded between two neighboring second short column to allow, and connected with gear between adjacent two second short columns
Connect, facilitate display control program to control the flexible of the second lifting support, the cylinder of whitewashing a wall is arranged on the second short column top is
For the function that convenient realization is whitewashed a wall.
Preferably, the 3rd support is hollow structure, being disposed to of hollow structure is set in the 3rd internal stent
Put material passing tube so that the material passing tube inside first lifting support is connected with the material passing tube inside second lifting support
Connect.
Preferably, the corresponding top second in the corresponding inside of horizontal direction between cylinder upper and lower side of whitewashing a wall is short
Post is provided with symmetrical opening, and being disposed to of the second short column upper shed allows coating to flow out to cylinder of whitewashing a wall, so as to realize brush
The function that wall cylinder is whitewashed a wall.
Preferably, the material passing tube insertion is arranged on first lifting support, second lifting support and institute
State the 3rd internal stent, being circularly set for material passing tube can make full use of, and material passing tube is arranged at so that coating is not wasted
First lifting support, second lifting support and the 3rd internal stent, can avoid whitewashing a wall cylinder in operation
During coating is dripped into problem on the ground.
Preferably, the material passing tube is provided with discharging opening positioned at the opening portion, being disposed to of discharging opening allows painting
Material from material passing tube be ejected into it is described whitewash a wall on cylinder so that the cylinder of whitewashing a wall can realize the function of whitewashing a wall.
Preferably, being provided with stirring paddle in the cavity volume, and lead to the inlet and outlet of material, institute for the material passing tube
State being disposed to prevent the uneven of coating so that the metope for brushing out is rough smooth for stirring paddle, the import and institute
That states outlet is disposed to allow coating from import into the material passing tube, then the coating being not used in the material passing tube is led to
Cross the outlet to return in the cavity volume, then be circulated use.
Preferably, the power set include promoting whitewashing a wall, device realizes the charging pump of function, and promotes described stirring
The motor of oar operation is mixed, the function of the charging pump is that the coating in the cavity volume is pressed into material passing tube and is formed by increase pressure
Pressure, can allow coating through discharging opening be ejected into it is described whitewash a wall on cylinder, the effect of the motor is to promote described
Stirring paddle in cavity volume is rotated, so that coating mix homogeneously.
Preferably, be provided with the cylinder of whitewashing a wall whitewash a wall be stained with material cloth and bar pit, bar on the cylinder of whitewashing a wall
Being disposed to of pit allows the coating of ejection to reach through the brush rifle cylinder to be stained with material cloth, so as to realize the function of whitewashing a wall.
In sum, the invention has the advantages that：
1. a kind of automatic plastering apparatus of the present invention only need to the input on the display control program of wall painting machine needs what is whitewashed a wall
Area parameters, then place wall painting machine and can just complete work of whitewashing a wall in specified location, and are not in apply during whitewashing a wall
Smear irregular, drippage etc. manifests, whole operation process is simple and convenient efficiently；
2. a kind of water-soluble resin coating of the present invention has complied with environmental requirement, and with good thermostability, it is water-fast
Property, weatherability, durability, corrosion resistance, by force, solidification effect is excellent for bonding force, and production prepares routine, cheap, is adapted to many
Regional, multi-field use；
3. the cold coating of the present invention is brushed automatically using wall painting machine of the present invention, with durability and good weatherability, intelligence
Automatic plurality of advantages.
Description of the drawings
Fig. 1 is the structural representation of the present invention；
Fig. 2 is the lowering or hoisting gear sectional view of the present invention；
Fig. 3 is the tote box sectional view of the present invention；
1- mobile devices in figure, 2- tote boxs, 3- lowering or hoisting gears, 4- are whitewashed a wall device, 21- cavity volumes, 22- power set, 23-
Display control program, the first lifting supports of 31-, the second lifting supports of 32-, the 3rd supports of 41-, 42- sensing devices, 43- are whitewashed a wall
Cylinder, 44- openings, 45- material passing tubes, 431- are stained with material cloth, 451- discharging openings.
Specific embodiment
The present invention is described in further detail below in conjunction with accompanying drawing.
This specific embodiment is only explanation of the invention, and which is not limitation of the present invention, people in the art
Member can make the modification for not having creative contribution after this specification is read as needed to the present embodiment, but as long as at this
All protected by Patent Law in the right of invention.
As shown in Figure 1, Figure 2, Figure 3 shows, a kind of brushing method of cold coating, it includes mobile device 1, is arranged at mobile dress
The tote box 2 on 1 is put, the lowering or hoisting gear 3 for lifting of side in tote box 2 is arranged at, and is arranged on lowering or hoisting gear 3
For the device 4 of whitewashing a wall whitewashed a wall, is provided with the cavity volume 21 and power set 22 for holding paint vehicle, 2 casing of tote box in tote box 2
Side is additionally provided with display control program 23；Lowering or hoisting gear 3 includes being arranged at that 2 side of tote box is symmetrically arranged whitewashes a wall for lifting
First lifting support 31 and the second lifting support 32 of device 4；Device 4 of whitewashing a wall includes material passing tube 45, connects the first lifting support
31 and second lifting support 32 the 3rd support 41, the sensing device 42 being arranged on the first lifting support 31, and being arranged at
Cylinder 43 of whitewashing a wall on second lifting support 32；Whitewash a wall can be provided with cylinder 43 whitewash a wall be stained with material cloth 431.
This programme is by manually switching on power, by the required area whitewashed a wall, height, width input display control program
23, then power set 22 are opened, coating is pressed into material passing tube 45 by power set 22, and coating is sent to brush rifle cylinder by material passing tube 45
43, the movement of the height of the control lowering or hoisting gear 3 of display control program 23 and mobile device 1 so that cylinder 43 of whitewashing a wall can be with root
According to the function whitewashed a wall by the movement of mobile device 1.
First lifting support 31 includes the first short column of two hollow different inner diameters, and the first short column of different inner diameters is passed through
It is formed by connecting inside and outside gear, on the first short column top, is additionally provided with sensing device 42, the setting of different inner diameters is two neighboring in order to allow
Can be embedded between first short column, between adjacent two first short columns, then facilitate display control program 23 to control with gear connection
The flexible of the first lifting support 31 is made, the setting of sensing device 42 can scan smoothness and the flatness of the metope brushed, sent out
The situation of inequality is now smeared, display control program 23 can be sent information to, display control program 23 can make feedback to information,
Promote mobile device 1 to return to and do not smear uniform position, the position for smearing inequality is re-started and is smeared.Second liter of descending branch
Frame 32 includes the second short column of two hollow different inner diameters, and the second short column of different inner diameters is formed by connecting inside and outside gear,
Cylinder 43 of whitewashing a wall is additionally provided with second short column top, and the setting of different inner diameters can be entered between two neighboring second short column to allow
Row is embedded, then facilitates display control program 23 to control the second lifting support 32 with gear connection between adjacent two second short columns
Flexible, it is the function of whitewashing a wall for convenient realization that cylinder 43 of whitewashing a wall is arranged on the second short column top.3rd support 41
For hollow structure, being disposed to of hollow structure arranges material passing tube 45 inside the 3rd support 41 so that the first lifting support
Material passing tube 45 inside 31 is connected with the material passing tube 45 inside the second lifting support 32.
The corresponding second short column top in the corresponding inside of horizontal direction between 43 upper and lower side of cylinder of whitewashing a wall is provided with symmetrical
Opening 44, being disposed to of the second short column upper shed 44 allow coating to flow out to cylinder 43 of whitewashing a wall, so as to realize cylinder 43 of whitewashing a wall
The function of whitewashing a wall.45 insertion of material passing tube is arranged on the first lifting support 31, inside the second lifting support 32 and the 3rd support 41,
Being circularly set for material passing tube 45 can make full use of, and material passing tube 45 is arranged at first liter of descending branch so that coating is not wasted
Frame 31, inside the second lifting support 32 and the 3rd support 41, the cylinder 43 that can avoid whitewashing a wall will apply gob during operation
The problem for falling on the ground.Material passing tube 45 is provided with discharging opening 451 positioned at 44 part of opening, and being disposed to of discharging opening 451 allows
Coating is ejected into from material passing tube 45 and whitewashes a wall on cylinder 43, so that cylinder 43 of whitewashing a wall can realize the function of whitewashing a wall.
Stirring paddle is provided with cavity volume 21, and for the inlet and outlet of the logical material of material passing tube 45, the setting of stirring paddle is
In order to prevent the uneven of coating so that the metope for brushing out is rough smooth, being disposed to of import and outlet allows coating
Material passing tube 45 is entered from import, then the coating being not used in material passing tube 45 is returned in cavity volume 21 by outlet, then carried out
Recycle.The device 4 that includes promoting whitewashing a wall of power set 22 realizes the charging pump of function, and promotes the horse that stirring paddle runs
Reach, the function of charging pump is that the coating in cavity volume 21 is pressed into material passing tube and forms pressure by increase pressure, can cause coating
Can be ejected into through discharging opening 451 and whitewash a wall on cylinder 45, the effect of motor is to promote the stirring paddle in cavity volume 21 to rotate, so as to
Make coating mix homogeneously.Whitewash a wall be provided with cylinder 43 whitewash a wall be stained with material cloth 431 and bar pit, bar pit on cylinder 43 of whitewashing a wall
Be disposed to allow ejection coating through brush rifle cylinder 43 reach be stained with material cloth 431, so as to realize the function of whitewashing a wall.
A kind of automatic plastering apparatus of the present invention need to only switch on power when function is realized, by the required area whitewashed a wall, height,
Width is input into display control program 23, then opens power set 22, and motor starting drives the rotation of stirring paddle, feed pump startup to promote
Coating is made to enter in material passing tube 45 from import, material passing tube 45 coating is ejected into being stained with cylinder 43 of whitewashing a wall and expects cloth 431, shows control
The movement of the height of the control lowering or hoisting gear 3 of system processed 23 and mobile device 1, the mobile drive of mobile device 1 are whitewashed a wall cylinder 43
Whitewashed a wall, sensing device 42 is detected to swiped through metope, swiped through metope detection is unqualified, sensing device 42 is by signal
Display control program 23 is sent to, display control program 23 makes feedback, the control lowering or hoisting gear 3 of display control program 23 to information
And mobile device 1 is repaired to unqualified place, so circulate, until brush facade wall, wall painting machine of the invention is being used
During do not need artificial supervision, time saving and energy saving function can be reached.
Embodiment 1
Alkyd resin includes the raw material of following weight portion：Trimethylolpropane：5 parts, ethylene glycol：1 part, glycerol：5 parts,
Phthalic anhydride：5 parts, maleic acid：5 parts, Oleum Ricini：0.05 part, butyl glycol ether：4 parts, styrene：6 parts, quinones polymerization inhibitor：0.05
Part；
Alkyd resin preparation method is as follows：
（1）By trimethylolpropane：5 parts, ethylene glycol：1 part, glycerol：5 parts, phthalic anhydride：5 parts, maleic acid：5 parts, add
In reactor, intensification makes alcohol acid reaction completely, obtains reactant；
（2）By step（1）In reactant be cooled to 190 DEG C, add Oleum Ricini：0.05 part, quinones polymerization inhibitor：0.05
Part, obtain mixture；
（3）By step（2）In mixture be cooled to 120 DEG C, add styrene：6 parts, obtain dilution；
（4）By butyl glycol ether：4 parts, it is added to step（3）In dilution in, stir to obtain alkyd resin；
The preparation of cold coating：
By alkyd resin and Pulvis Talci, dark green, bipyridyl compound, ammonia, the first solid additive；Second solid
Additive by weight 10：5：1：0.5：4：3:6, mixing stirs, obtains final product coating.
Wherein, the particle size range of the first solid additive is 0.8-5 microns;Wherein, the granule of 0.8-1 microns accounts for solid
The 20% of additive gross weight;The granule of 1-2 microns accounts for the 10% of solid additive gross weight；Balance of 3 microns of granule；
Second solid additive for molybdenum disulfide nano ball and the particle diameter 6-9 microns of 10 nanometers of particle diameter tungsten disulfide according to
Mass ratio 1:The mixture of 2 compositions.
Embodiment 2
Alkyd resin includes the raw material of following weight portion：Trimethylolpropane：100 parts, ethylene glycol：50 parts, glycerol：
150 parts, phthalic anhydride：110 parts, maleic acid：90 parts, castor oil hydrogenated：1 part, butyl glycol ether：50 parts, styrene：140 parts, phenols
Polymerization inhibitor：1 part；
Alkyd resin preparation method is as follows：
（1）By trimethylolpropane：100 parts, ethylene glycol：50 parts, glycerol：150 parts, phthalic anhydride：110 parts, maleic acid：90
Part, adding in reactor, intensification makes alcohol acid reaction completely, obtains reactant；
（2）By step（1）In reactant be cooled to 180 DEG C, add castor oil hydrogenated：1 part, phenolic inhibitor：1 part,
Obtain mixture；
（3）By step（2）In mixture be cooled to 130 DEG C, add styrene：140 parts, obtain dilution；
（4）By butyl glycol ether：50 parts, it is added to step（3）In dilution in, stir to obtain alkyd resin；
The preparation of cold coating：
By alkyd resin and Calcium Carbonate, chrome yellow, novel polymeric type catalyst, ammonia, the first solid additive；Second solid
Additive by weight 200：100：30：10：80：7:1.5, mixing stirs, obtains final product coating.
Wherein, the particle size range of the first solid additive is 0.8-5 microns;Wherein, the granule of 0.8-1 microns accounts for solid
The 40% of additive gross weight;The granule of 1-2 microns accounts for the 30% of solid additive gross weight；Balance of 5 microns of granule；
Second solid additive is the molybdenum disulfide nano ball of 20 nanometers of particle diameter and the micro powder graphite of 9 microns of particle diameter according to matter
Amount compares 1:The mixture of 5 compositions.
Embodiment 3
Alkyd resin includes the raw material of following weight portion：Trimethylolpropane：50 parts, ethylene glycol：25 parts, glycerol：100
Part, phthalic anhydride：90 parts, maleic acid：60 parts, Oleum Cocois：0.5 part, butyl glycol ether：25 parts, styrene：70 parts, phenolic inhibitor：
0.5 part；
Alkyd resin preparation method is as follows：
（1）By trimethylolpropane：50 parts, ethylene glycol：25 parts, glycerol：100 parts, phthalic anhydride：90 parts, maleic acid：60
Part, adding in reactor, intensification makes alcohol acid reaction completely, obtains reactant；
（2）By step（1）In reactant be cooled to 185 DEG C, add Oleum Cocois：0.5 part, phenolic inhibitor：0.5 part,
Obtain mixture；
（3）By step（2）In mixture be cooled to 123 DEG C, add styrene：70 parts, obtain dilution；
（4）By butyl glycol ether：25 parts, it is added to step（3）In dilution in, stir to obtain alkyd resin；
The preparation of cold coating：
By alkyd resin and Calcium Carbonate, Pulvis Talci, titanium dioxide, bipyridyl compound, ammonia, the first solid additive；
Second solid additive by weight 100：25:25：15：5：40:4:5, mixing stirs, obtains final product coating.
Wherein, the particle size range of the first solid additive is 0.8-5 microns;Wherein, the granule of 0.8-1 microns accounts for solid
The 30% of additive gross weight;The granule of 1-2 microns accounts for the 20% of solid additive gross weight；The granule of balance of 3-5 microns；
Second solid additive is the molybdenum disulfide nano ball of 15 nanometers of particle diameter and the Calcium Carbonate of 8 microns of particle diameter according to quality
Than 1:The mixture of 3 compositions.
Comparative example 1
Cold coating includes the component materials of following weight portion：Alkyd resin：500 parts, Calcium Carbonate：200 parts, dark green：
50 parts, bipyridyl compound：2 parts；
Wherein alkyd resin includes the raw material of following weight portion：Trimethylolpropane：110 parts, glycerol：200 parts, benzene
Acid anhydride：120 parts, maleic acid：100 parts, Oleum Ricini：0.01 part, styrene：260 parts, phenolic inhibitor：0.01 part；
Alkyd resin preparation method is as follows：
（1）By trimethylolpropane：110 parts, glycerol：200 parts, phthalic anhydride：120 parts, maleic acid：100 parts, add reaction
In kettle, intensification makes alcohol acid reaction completely, obtains reactant；
（2）By step（1）In reactant be cooled to 180 DEG C, add Oleum Ricini：0.01 part, phenolic inhibitor：0.01
Part, obtain mixture；
（3）By step（2）In mixture be cooled to 120 DEG C, add styrene：260 parts, obtain alkyd resin；
The preparation of cold coating：
By alkyd resin and Calcium Carbonate, dark green, bipyridyl compound, ammonia by weight 500：200：50：2, mix
Close, stir, obtain final product coating.
Comparative example 2
Cold coating includes the component materials of following weight portion：Alkyd resin：9 parts, Pulvis Talci：4 parts, novel polymeric type is urged
Agent：0.4 part；
Wherein alkyd resin includes the raw material of following weight portion：Trimethylolpropane：110 parts, glycerol：160 parts, benzene
Acid anhydride：120 parts, maleic acid：100 parts, butyl glycol ether：60 parts, styrene：150 parts, quinones polymerization inhibitor：1 part；
Alkyd resin preparation method is as follows：
（1）By trimethylolpropane：110 parts, glycerol：160 parts, phthalic anhydride：120 parts, maleic acid：100 parts, add reaction
In kettle, intensification makes alcohol acid reaction completely, obtains reactant；
（2）By step（1）In reactant be cooled to 170 DEG C, add quinones polymerization inhibitor：1 part, obtain mixture；
（3）By step（2）In mixture be cooled to 140 DEG C, add styrene：160 parts, obtain dilution；
（4）By butyl glycol ether：60 parts, it is added to step（3）In dilution in, stir to obtain alkyd resin；
The preparation of cold coating：
By alkyd resin and Pulvis Talci, novel polymeric type catalyst, ammonia by weight 9：4：0.4, mixing, stirring are equal
It is even, obtain final product coating.
Experimental data
5 kinds of coating are obtained respectively by above-mentioned preparation method, 5 kinds of coating are applied on a face body of wall respectively, control coating
Consumption so that the area that 5 kinds of coating is applied to metope is identical, and the phenomenon observed during coating use simultaneously records observed and recorded knot
Fruit is as follows：
From above experimental result, the coating of embodiment 1-3 has a good performance, and the painting of embodiment 1 or 2
Material using effect is undesirable, from embodiment 1 or 2 it can also be seen that wanting to prepare good coating, the manufacturing process of alkyd resin
The ratio of middle acid alcohol also needs to coordinate appropriate, and adjuvant need to be coordinated just to show good performance, and not so coating is overall
Using effect can decline because of the impact of alkyd resin.
Claims (10)
1. a kind of brushing method of cold coating, it is characterised in that：
Cold coating includes the component materials of following weight portion：
Alkyd resin：10-200, filler：5-100,
Pigment：1-30, catalyst： 0.5-10；
Ammonia：4-80,
First solid additive 3-7；Second solid additive 1.5-6；
Wherein alkyd resin includes the raw material of following weight portion：
Trimethylolpropane：5-100, ethylene glycol：1-50,
Glycerol：5-150, phthalic anhydride：5-110,
Maleic acid：5-90, vegetable oil：0.05-1,
Butyl glycol ether：4-50, styrene：6-140, polymerization inhibitor： 0.05-1；
The cold coating brushes metope automatically by automatic plastering apparatus；
The automatic plastering apparatus include mobile device（1）, it is arranged at the mobile device（1）On tote box（2）, it is arranged at institute
State tote box（2）The lowering or hoisting gear for lifting of interior side（3）, and it is arranged on the lowering or hoisting gear（3）On for brushing
The device of whitewashing a wall of wall（4）, the tote box（2）The cavity volume for holding paint vehicle is provided with inside（21）And power set（22）, the load
Thing case（2）Casing side is additionally provided with display control program（23）；
The lowering or hoisting gear（3）Including being arranged at the tote box（2）Side for lifting the device of whitewashing a wall（4）First
Lifting support（31）With the second lifting support（32）；
The device of whitewashing a wall（4）Including material passing tube（45）, connect first lifting support（31）With second lifting support
（32）The 3rd support（41）, it is arranged at first lifting support（31）On sensing device（42）, and be arranged at described
Second lifting support（32）On cylinder of whitewashing a wall（43）.
2. the brushing method of a kind of cold coating according to claim 1, it is characterised in that：First lifting support
（31）Including the first short column of one or more hollow different inner diameters, the first short column of the different inner diameters is inside and outside gear
It is formed by connecting, the first short column top is provided with sensing device（42）.
3. the brushing method of a kind of cold coating according to claim 2, it is characterised in that：Second lifting support
（32）Including the second short column of one or more hollow different inner diameters, the second short column of the different inner diameters is inside and outside gear
It is formed by connecting, the second short column top is provided with cylinder of whitewashing a wall（43）.
4. the brushing method of a kind of cold coating according to claim 3, it is characterised in that：3rd support（41）For
Hollow structure.
5. the brushing method of a kind of cold coating according to claim 4, it is characterised in that：The cylinder of whitewashing a wall（43）On
Between lower end, the corresponding inside of horizontal direction second short column is provided with symmetrical opening（44）.
6. the brushing method of a kind of cold coating according to claim 5, it is characterised in that：The material passing tube（45）Insertion
It is arranged on first lifting support（31）, second lifting support（32）And the 3rd support（41）It is internal.
7. the brushing method of a kind of cold coating according to claim 6, it is characterised in that：The material passing tube（45）It is located at
The opening（44）Part is provided with discharging opening（451）.
8. the brushing method of a kind of cold coating according to claim 7, it is characterised in that：The cavity volume（21）Interior setting
There is stirring paddle, and be used for the material passing tube（45）The inlet and outlet of logical material.
9. the brushing method of a kind of cold coating according to claim 8, it is characterised in that：The power set（22）Bag
Include and promote device of whitewashing a wall（4）Realize the charging pump of function, and the motor for promoting the stirring paddle operation.
10. the brushing method of a kind of cold coating according to claim 1, it is characterised in that：
The particle size range of first solid additive is 0.8-5 microns;Wherein, the granule of 0.8-1 microns accounts for the solid and adds
Plus the 20-40% of agent gross weight;The granule of 1-2 microns accounts for the 10-30% of the solid additive gross weight；Balance of 3-5 microns
Grain；
Second solid additive is pressed with the regulation grain of particle diameter 6-9 microns for the molybdenum disulfide nano ball of particle diameter 10-20 nanometers
According to mass ratio 1:The mixture of 2-5 compositions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455036.3A CN104946103B (en) | 2015-07-30 | 2015-07-30 | Resin paint brushing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455036.3A CN104946103B (en) | 2015-07-30 | 2015-07-30 | Resin paint brushing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104946103A CN104946103A (en) | 2015-09-30 |
| CN104946103B true CN104946103B (en) | 2017-03-22 |
Family
ID=54161185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510455036.3A Active CN104946103B (en) | 2015-07-30 | 2015-07-30 | Resin paint brushing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104946103B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105885662A (en) * | 2016-06-22 | 2016-08-24 | 广德瑞邦涂料有限公司 | Environment-friendly compound cathode electrophoretic paint |
| CN105885639A (en) * | 2016-06-22 | 2016-08-24 | 广德瑞邦涂料有限公司 | Method for producing environment-friendly efficient electrophoretic paint |
| CN109776745A (en) * | 2018-12-19 | 2019-05-21 | 浙江新华新材料科技有限责任公司 | A kind of preparation method of butyl glycol ether modifying moieties Amino resin |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3140801A (en) * | 1961-07-21 | 1964-07-14 | Raymond A Delligatti | Automatic plastering machine |
| JPH06226156A (en) * | 1993-02-08 | 1994-08-16 | Kajima Corp | Automatic coating device |
| CN101307137A (en) * | 2007-05-17 | 2008-11-19 | 上海涂料有限公司技术中心 | Water dispersion of self-drying acrylic modified alkyd resin industrial topcoat using the water dispersion as base |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN104086761A (en) * | 2014-06-05 | 2014-10-08 | 华南理工大学 | Aqueous organosilicone-modified alkyd resin and preparing method thereof |
| CN204126223U (en) * | 2014-10-11 | 2015-01-28 | 陕西科技大学 | A kind of new type auto wall painting machine |
-
2015
- 2015-07-30 CN CN201510455036.3A patent/CN104946103B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3140801A (en) * | 1961-07-21 | 1964-07-14 | Raymond A Delligatti | Automatic plastering machine |
| JPH06226156A (en) * | 1993-02-08 | 1994-08-16 | Kajima Corp | Automatic coating device |
| CN101307137A (en) * | 2007-05-17 | 2008-11-19 | 上海涂料有限公司技术中心 | Water dispersion of self-drying acrylic modified alkyd resin industrial topcoat using the water dispersion as base |
| CN103937391A (en) * | 2014-03-21 | 2014-07-23 | 安徽蓝柯复合材料有限公司 | Antibacterial self-dry paint and preparation method thereof |
| CN104086761A (en) * | 2014-06-05 | 2014-10-08 | 华南理工大学 | Aqueous organosilicone-modified alkyd resin and preparing method thereof |
| CN204126223U (en) * | 2014-10-11 | 2015-01-28 | 陕西科技大学 | A kind of new type auto wall painting machine |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104946103A (en) | 2015-09-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104962183A (en) | Brushing method of functional environment-friendly paint | |
| CN1247716C (en) | Colorant, dispersor, dispersant and printing ink | |
| CN104946103B (en) | Resin paint brushing method | |
| CN103788328B (en) | Self-crosslinked oxidation type Aqueous acrylic urethane dispersion and preparation method thereof | |
| CN101245219B (en) | Alkyd paint with low content of VOC and manufacture method thereof | |
| CN102464938B (en) | Plastic cement list is coated with painted UV radiation curable coating and production thereof, using method | |
| CN1121462C (en) | Method for providing waterborne coating composition with improved color acceptance | |
| CN107429100A (en) | Dispersible pigment dispersion | |
| CA2790620A1 (en) | Composition of pigments soluble in water and/or in organic solvents | |
| CN1373166A (en) | Method for improving viscosity stability by adding water-based coloring composition | |
| CN1262608C (en) | Low-viscosity polymeric colorants exhibiting high color strength characteristics | |
| CN104725588A (en) | Method for preparing solvent-free negative/non-ionic water-based polyurethane-acrylate grafted copolymer with IPN structure | |
| CN101412864B (en) | Self-drying glass ink and preparation thereof | |
| CN105400254B (en) | A kind of weatherable polyether powder coating and preparation method thereof | |
| CN104629605A (en) | Single-component water-based metal flashing paint and preparation method thereof | |
| CN109153774A (en) | Polymer, method, composition and purposes | |
| CN203990376U (en) | A kind of alkyd paint mixing arrangement | |
| CN110256905A (en) | A kind of filled-type UV colorant and preparation method thereof | |
| CN102702958B (en) | Water-based paint compositions, preparation method and its usage | |
| CN114790346A (en) | Preparation process of modified polyamide wax for coating and formed coating | |
| CN1057526C (en) | Novel crystal modification of diketopyrrolopyrrole pigment | |
| JP5294707B2 (en) | Granular gel production apparatus and multicolor pattern paint production method | |
| KR101270276B1 (en) | Paint composition for fiber reinforced plastic base | |
| ITMI981190A1 (en) | UNIVERSAL WATERPROOF PIGMENTARY PASTES ZERO V.O.C. | |
| CN208878444U (en) | A kind of paint mixing device that mixing efficiency is high |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |