CN104945149A - Production method of water-soluble fertilizer with effects of changing color and preventing counterfeiting - Google Patents
Production method of water-soluble fertilizer with effects of changing color and preventing counterfeiting Download PDFInfo
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- CN104945149A CN104945149A CN201510381394.4A CN201510381394A CN104945149A CN 104945149 A CN104945149 A CN 104945149A CN 201510381394 A CN201510381394 A CN 201510381394A CN 104945149 A CN104945149 A CN 104945149A
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Abstract
The invention relates to a production method of a water-soluble fertilizer with the effects of changing color and preventing counterfeiting. The water-soluble fertilizer is obtained by mixing macroelement-containing fertilizers, trace elements, medium elements, acid-base regulators and color-changing agents in a closed environment. The production method has the beneficial technical effects that by utilizing the principle that the color-changing agents change color in the presence of acid and base, the water-soluble fertilizer changes color after being put into water and dissolved to achieve the aim of preventing counterfeiting and does not have the problem of fading. The product does not have the problem of non-uniformity in dyeing.
Description
Technical field
The present invention relates to a kind of preparation method with the macroelement Water soluble fertilizer of color-changing anti-counterfeit effect.
Background technology
In order to make fertilizer have false proof effect, fertilizer is made to have become the Main of Production of manure industry with particular color.Current macroelement Water soluble fertilizer mainly dyes by adding dyestuff, because dyestuff add-on is subject to strict restriction, is difficult to accomplish even dyeing, situation about fading after also having a lot of dyeing, and it is all color that hand one grabs full hand, allows people feel dislike.
Summary of the invention
Technical problem to be solved by this invention is, provides a kind of Water soluble fertilizer production method with color-changing anti-counterfeit effect, utilizes soda acid to make the principle of colour-changing agent variable color, drops into variable color after dissolving in water.
In order to solve the problems of the technologies described above, present invention employs following technical scheme:
There is the Water soluble fertilizer production method of color-changing anti-counterfeit effect, it is characterized in that being prepared from according to following steps:
Using the urea as macroelement fertilizer, ammonium sulfate, PHOSPHORIC ACID TECH.GRADE potassium dihydrogen, one or more in PHOSPHORIC ACID TECH.GRADE ammonium dihydrogen and saltpetre, as the ethylenediamine tetraacetic acid disodium zinc salt of trace element fertilizer, disodium ethylene diamine tetraacetate is ferrous, disodium ethylene diamine tetraacetate copper, disodium ethylene diamine tetraacetate manganese, one or several in boric acid and borax, as the magnesium sulfate of secondary nutrients, nitrocalcite, ethylenediamine tetraacetic acid disodium magnesium salt, one or more in Sormetal and magnesium nitrate, as the citric acid of acid-base modifier, oxalic acid, oxysuccinic acid, in salt of wormwood and sodium carbonate one or more and as the phenolphthalein of colour-changing agent, one or more in purple cabbage and reindeer moss mix under airtight environment,
Described macroelement fertilizer, trace element fertilizer, secondary nutrients, mass ratio between acid-base modifier and colour-changing agent are 50 ~ 99.999:0 ~ 40:0 ~ 40:0 ~ 10:0.001 ~ 10.
The present invention has following Advantageous Effects: the present invention, when not affecting product true qualities, utilizes soda acid to make the principle of colour-changing agent variable color, drops into variable color after dissolving in water, to reach false proof object, there is not the problem faded.There is not the uneven problem of dyeing in product of the present invention yet.
Embodiment
The present invention is further illustrated below in conjunction with specific examples.
embodiment one
By urea, ethylenediamine tetraacetic acid disodium zinc salt, magnesium sulfate and phenolphthalein according to mass ratio 80:9.92:10:0.08, mix in closed environment, obtain product of the present invention.
embodiment two
By PHOSPHORIC ACID TECH.GRADE ammonium dihydrogen and purple cabbage according to mass ratio 99.99:0.01, mix in closed environment, obtain product of the present invention.
embodiment three
By ammonium sulfate, disodium ethylene diamine tetraacetate ferrous iron and reindeer moss according to mass ratio 90:9.96:0.04, mix in closed environment, obtain product of the present invention.
embodiment four
By saltpetre, ethylenediamine tetraacetic acid disodium magnesium salt, citric acid and purple cabbage according to mass ratio 80:19:0.92:0.08, mix in closed environment, obtain product of the present invention.
Closed environment described in above-described embodiment refers to dry environment, to avoid the material moisture absorption.
Beneficial effect of the present invention is further illustrated below in conjunction with experimental data:
1, experimental water: get use for laboratory tap water.
2, experiment is for examination material
Product of the present invention 1 kilogram, 1500 kilograms, water.
3, experimental design
Setup Experiments divides 2 process, is respectively: 800 kg of water dilute product of the present invention, 1500 kg of water dilute product of the present invention.
4, experiment is implemented
First use eye observation product of the present invention, then grab product of the present invention with hand, then dilute 1 kilogram of product of the present invention by 800 kg of water, then add remaining 700 kg of water in the product of dilution.
5, results and analysis
| Outward appearance | Uniform color, non-variegation |
| Hand is grabbed | There are not the phenomenons such as decolouring |
| Dilute 800 times of colour-change | Within latter 5 minutes of whole dissolving, product becomes pink or other colors from colourless |
| Dilute 1500 times of colour-change | Mix product within latter 5 minutes and become bluish voilet or other colors from pink |
As can be seen from the above results, product color of the present invention is even, and without decolouring phenomenon, variable color exists change along with the difference of extension rate, and mainly along with extension rate varying ph is also along with change, therefore color also exists change.
6, discuss: because the colour developing of this product is relevant with pH, the multiple that may dilute because user is different and color is slightly different, belongs to normal phenomenon, does not affect fertilizer efficiency.
Claims (1)
1. there is the Water soluble fertilizer production method of color-changing anti-counterfeit effect, it is characterized in that being prepared from according to following steps:
Using the urea as macroelement fertilizer, ammonium sulfate, PHOSPHORIC ACID TECH.GRADE potassium dihydrogen, one or more in PHOSPHORIC ACID TECH.GRADE ammonium dihydrogen and saltpetre, as the ethylenediamine tetraacetic acid disodium zinc salt of trace element fertilizer, disodium ethylene diamine tetraacetate is ferrous, disodium ethylene diamine tetraacetate copper, disodium ethylene diamine tetraacetate manganese, one or several in boric acid and borax, as the magnesium sulfate of secondary nutrients, nitrocalcite, ethylenediamine tetraacetic acid disodium magnesium salt, one or more in Sormetal and magnesium nitrate, as the citric acid of acid-base modifier, oxalic acid, oxysuccinic acid, in salt of wormwood and sodium carbonate one or more and as the phenolphthalein of colour-changing agent, one or more in purple cabbage and reindeer moss mix under airtight environment,
Described macroelement fertilizer, trace element fertilizer, secondary nutrients, mass ratio between acid-base modifier and colour-changing agent are 50 ~ 99.999:0 ~ 40:0 ~ 40:0 ~ 10:0.001 ~ 10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510381394.4A CN104945149A (en) | 2015-07-03 | 2015-07-03 | Production method of water-soluble fertilizer with effects of changing color and preventing counterfeiting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510381394.4A CN104945149A (en) | 2015-07-03 | 2015-07-03 | Production method of water-soluble fertilizer with effects of changing color and preventing counterfeiting |
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| CN104945149A true CN104945149A (en) | 2015-09-30 |
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| CN201510381394.4A Pending CN104945149A (en) | 2015-07-03 | 2015-07-03 | Production method of water-soluble fertilizer with effects of changing color and preventing counterfeiting |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105777390A (en) * | 2016-04-25 | 2016-07-20 | 纪新强 | Macroelement-mid-element type water-soluble color-changing liquid fertilizer and dilution control method of same |
| CN105777392A (en) * | 2016-04-25 | 2016-07-20 | 纪新强 | Macroelement-microelement type water-soluble color-changing fertilizer and dilution control method of same |
| CN105777391A (en) * | 2016-04-25 | 2016-07-20 | 纪新强 | Macroelement-mid-element type water-soluble color-changing fertilizer and dilution control method of same |
| CN105884532A (en) * | 2016-04-25 | 2016-08-24 | 纪新强 | Macro and trace elements type liquid water-soluble discoloring fertilizer and dilution control method thereof |
| CN106380298A (en) * | 2016-08-30 | 2017-02-08 | 安徽辉隆集团五禾生态肥业有限公司 | Water soluble fertilizer with color self-change anti-counterfeiting function |
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| RO103624B1 (en) * | 1988-11-01 | 1993-08-16 | Inst De Cercetari Pentru Pedol | Complex foliar fertilizer |
| CN101234926A (en) * | 2008-02-26 | 2008-08-06 | 云南云天化国际化工股份有限公司 | Method for dyeing phosphorus complex fertilizer |
| CN101486616A (en) * | 2009-03-05 | 2009-07-22 | 安徽农业大学 | Colorful slow release drought resisting compound fertilizer and preparation thereof |
| CN102925135A (en) * | 2012-10-18 | 2013-02-13 | 金红叶纸业集团有限公司 | Color-change powder and color-change liquid applying same |
| CN104446853A (en) * | 2013-09-21 | 2015-03-25 | 山东恩宝生物科技有限公司 | Coating organic efficient granule fertilizer |
| CN104725101A (en) * | 2013-12-20 | 2015-06-24 | 刘玲 | Potted flower granular fertilizer and preparation method thereof |
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2015
- 2015-07-03 CN CN201510381394.4A patent/CN104945149A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RO103624B1 (en) * | 1988-11-01 | 1993-08-16 | Inst De Cercetari Pentru Pedol | Complex foliar fertilizer |
| CN101234926A (en) * | 2008-02-26 | 2008-08-06 | 云南云天化国际化工股份有限公司 | Method for dyeing phosphorus complex fertilizer |
| CN101486616A (en) * | 2009-03-05 | 2009-07-22 | 安徽农业大学 | Colorful slow release drought resisting compound fertilizer and preparation thereof |
| CN102925135A (en) * | 2012-10-18 | 2013-02-13 | 金红叶纸业集团有限公司 | Color-change powder and color-change liquid applying same |
| CN104446853A (en) * | 2013-09-21 | 2015-03-25 | 山东恩宝生物科技有限公司 | Coating organic efficient granule fertilizer |
| CN104725101A (en) * | 2013-12-20 | 2015-06-24 | 刘玲 | Potted flower granular fertilizer and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105777390A (en) * | 2016-04-25 | 2016-07-20 | 纪新强 | Macroelement-mid-element type water-soluble color-changing liquid fertilizer and dilution control method of same |
| CN105777392A (en) * | 2016-04-25 | 2016-07-20 | 纪新强 | Macroelement-microelement type water-soluble color-changing fertilizer and dilution control method of same |
| CN105777391A (en) * | 2016-04-25 | 2016-07-20 | 纪新强 | Macroelement-mid-element type water-soluble color-changing fertilizer and dilution control method of same |
| CN105884532A (en) * | 2016-04-25 | 2016-08-24 | 纪新强 | Macro and trace elements type liquid water-soluble discoloring fertilizer and dilution control method thereof |
| CN106380298A (en) * | 2016-08-30 | 2017-02-08 | 安徽辉隆集团五禾生态肥业有限公司 | Water soluble fertilizer with color self-change anti-counterfeiting function |
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Application publication date: 20150930 |
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