CN104943302A - Advertisement consumable without cold laminating film and production method thereof - Google Patents

Advertisement consumable without cold laminating film and production method thereof Download PDF

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Publication number
CN104943302A
CN104943302A CN201510406570.5A CN201510406570A CN104943302A CN 104943302 A CN104943302 A CN 104943302A CN 201510406570 A CN201510406570 A CN 201510406570A CN 104943302 A CN104943302 A CN 104943302A
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CN
China
Prior art keywords
layer
ink
adhesive
advertisement
basic unit
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Granted
Application number
CN201510406570.5A
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Chinese (zh)
Other versions
CN104943302B (en
Inventor
江叔福
杨晓明
代树祥
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Zhejiang Ouren New Material Co Ltd
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Zhejiang Ouren New Material Co Ltd
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Priority to CN201510406570.5A priority Critical patent/CN104943302B/en
Publication of CN104943302A publication Critical patent/CN104943302A/en
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Publication of CN104943302B publication Critical patent/CN104943302B/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/08Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • B32B38/164Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207Heat-activated adhesive
    • B32B2037/1215Hot-melt adhesive

Abstract

The invention discloses an advertisement consumable without a cold laminating film. The advertisement consumable comprises a base layer, a viscose layer and an ink absorption material layer. The upper portion of the ink absorption material layer is subjected to printing or spray painting to form an image layer. The viscose layer comprises three functional layers including a viscose protective layer, a viscose permeable layer and a bonding layer from top to bottom in sequence. The viscose protective layer is located on the image layer. The viscose permeable layer permeates into a porous structure of the ink absorption material layer. The bonding layer is bonded to the portion between the ink absorption material layer and the base layer. The viscose protective layer, the viscose permeable layer and the bonding layer are connected into a whole. The base layer is made of PET materials. The viscose layer is mainly formed by hot melt adhesives. The main ingredient of the hot melt adhesives is a thermoplastic high-polymer material with the Tg not lower than 80 DEG C. A production method of the advertisement consumable mainly comprises three steps of coating, printing/spray painting and hot pressing. The advertisement consumable and the production method thereof have the advantages of being convenient to use, high in production efficiency and low in cost, not requiring the cold laminating film, and the like.

Description

A kind of advertisement consumptive material without the need to cold lamination film and production method thereof
Technical field
The present invention relates to a kind of advertisement consumptive material and production method thereof, more specifically to a kind of advertisement consumptive material without the need to cold lamination film and production method thereof.
Background technology
In prior art, the printing of advertisement or the preparation method of air brushing consumptive material, usually by basic unit's consumptive material and cold lamination film two completely independently product form, as shown in Figure 1.The ink-absorbing material bed of material 3 that basic unit's consumptive material generally includes polymer basic unit 4 and is positioned in polymer basic unit, during use, first prints or air brushing formation image layer 2 on the ink-absorbing material bed of material 3, after completing required image, re-uses cold lamination film 1 and carries out mounting film protection.
The cold lamination film adopted in said process, it is also lamination layer structure, as shown in Figure 2, usually by release liners 11, non-drying glue layer 12 and polymer basic unit 13 is bonding forms; During use, release liners is torn off, then non-drying glue layer and polymer basic unit are mounted and apply on the advertisement poster needing protection or photograph, the surface protection of advertisement consumptive material can be completed.Release liners is also known as silicone oil paper, separate paper, body paper is typically used or recycled paper is processed into through film due to release liners, surface is comparatively coarse, even if the silicone oil on the surface when film, still do not reach the requirement of high aloof from politics and material pursuits degree, cold lamination film is made often to there is the comparatively significantly defect such as snowflake and cloudy surface, finally the display effect of meeting effect diagram picture.
Because above-mentioned basic unit consumptive material and cold lamination film are two completely independently products, need to carry out production and processing respectively, operation is various, makes production efficiency lower; And cold lamination film needs the materials such as the release liners of use, non-drying glue layer and polymer basic unit to make the production cost of advertisement consumptive material also cannot reduce always.
Summary of the invention
In order to make up the deficiencies in the prior art, the object of the invention be to provide a kind of easy to use, production efficiency is higher, cost is lower, without the need to using advertisement consumptive material and the production method thereof of cold lamination film.
The technical scheme that technical solution problem of the present invention adopts is: a kind of advertisement consumptive material without the need to cold lamination film, described consumptive material comprises basic unit, adhesive-layer and the ink-absorbing material bed of material, the described ink-absorbing material bed of material is positioned at the top of described basic unit, carries out printing or forming image layer after air brushing above the described ink-absorbing material bed of material; Described adhesive-layer is also positioned at the top of described basic unit, and described adhesive-layer comprises three functional layers, is followed successively by viscose glue protective layer, viscose glue permeable formation and adhesive linkage from top to bottom; Described viscose glue protective layer is positioned at the top of described image layer, and described viscose glue permeable formation oozes in the loose structure of the described ink-absorbing material bed of material, and described adhesive linkage is adhered between the described ink-absorbing material bed of material and described basic unit; Described viscose glue protective layer, viscose glue permeable formation and adhesive linkage hold together; The thickness of described adhesive-layer is greater than the thickness of the described ink-absorbing material bed of material; Described basic unit is PET material, and described adhesive-layer is formed primarily of PUR, and the main component of described PUR is the thermoplastic macromolecule material that Tg is not less than 80 DEG C.
Further, the thickness range of described PET basic unit is 25 ~ 200 μm.
Further, the thickness range of the described ink-absorbing material bed of material is 10 ~ 50 μm.
Further, the thickness range of described adhesive-layer is 10 ~ 80 μm.
Further, the composition of described blotting material and the percentage by weight of each component as follows: water soluble glue 1.5 ~ 10%, pounce 2 ~ 30%, color-fixing agent 1.5 ~ 10%, brightening agent 0.5 ~ 2%, surfactant 0.5 ~ 2%, surplus is deionized water.
Further, described water soluble glue is the wherein one in polyvinyl alcohol, cellulose acetate, polyethylene glycol oxide.
Further, described pounce is SiO 2, CaCO 3, TiO 2, Al 2o 3in wherein one or more mixing.
Further, described color-fixing agent is the wherein one in quaternary ammonium salt, halogenated phosphates, bromide sixteen alkyls pyridine.
Without the need to a production method for the advertisement consumptive material of cold lamination film, described method mainly comprises the following steps:
(1) be coated with: at wherein even spread one deck PUR of PET basic unit, adhesive-layer is formed after PUR cooling curing, above described adhesive-layer, continue even spread one deck ink-absorbing material bed of material, above-mentioned coated composite material is put into baking oven and dries, then solidify, cool; Described coating speed is 10 ~ 80 ms/min;
(2) printing, air brushing: the ink-absorbing material bed of material of the composite material obtained in above-mentioned steps 1 carries out print or air brushing operation, the ink-absorbing material bed of material forms image layer;
(3) hot pressing: by the product hot pressing a period of time under certain temperature and pressure obtained in above-mentioned steps 2, form viscous state after the PUR in adhesive-layer is heated, form adhesive linkage in PET basic unit between the ink-absorbing material bed of material; The PUR of flowing upwards spreads gradually, penetrates in the loose structure of the ink-absorbing material bed of material, forms viscose glue permeable formation; Finally above described image layer, Uniform Flow forms one deck viscose glue protective layer; Just finished product can be obtained after cooling, solidification.
Further, in described hot pressing process, the hot pressing temperature of employing is 100 ~ 140 DEG C, and the hot pressing pressure of employing is 1 ~ 4kg, and the time that described hot pressing needs is 10 ~ 40s.
The invention has the beneficial effects as follows: compared with prior art; advertisement consumptive material provided by the invention and production method thereof; it mainly adopts hot pressing mode; PUR is made to flow to blotting material surface; image layer that printing (or air brushing) is good forms fish tail and waterproof layer; avoid the use of cold lamination film, while reducing production cost, also substantially increase production efficiency.
Accompanying drawing explanation
Fig. 1 is the structural representation of advertisement consumptive material of the prior art.
Fig. 2 is the structural representation of cold lamination film of the prior art.
Fig. 3 is the schematic flow sheet of the production method of advertisement consumptive material provided by the invention.
Fig. 4 is the structural representation of the advertisement consumptive material without the need to cold lamination film provided by the invention.
Wherein, 1-cold lamination film; 11-release liners; 12-adhesive sticker; 13-polymer basic unit; 2-image layer; The 3-ink-absorbing material bed of material; 4-polymer basic unit; 31-PET basic unit; 32-adhesive-layer; 321-viscose glue protective layer; 322-viscose glue permeable formation; 323-adhesive linkage; The 33-ink-absorbing material bed of material; 34-image layer.
Detailed description of the invention
Below in conjunction with the drawings and specific embodiments, illustrate the present invention further, following detailed description of the invention should be understood and be only not used in for illustration of the present invention and limit the scope of the invention.
Embodiment
A kind of advertisement consumptive material without the need to cold lamination film, described consumptive material comprises PET basic unit 31, adhesive-layer 32 and the ink-absorbing material bed of material 33, the described ink-absorbing material bed of material 33 is positioned at the top of described PET basic unit 31, carries out printing or forming image layer 34 after air brushing above the described ink-absorbing material bed of material 33; Described adhesive-layer 32 is also positioned at the top of described PET basic unit 31, and described adhesive-layer 32 comprises three functional layers, is followed successively by viscose glue protective layer 321, viscose glue permeable formation 322 and adhesive linkage 323 from top to bottom; Described viscose glue protective layer 321 is positioned at the top of described image layer 34, and described viscose glue permeable formation 322 oozes in the loose structure of the described ink-absorbing material bed of material 33, and described adhesive linkage 323 is adhered between the described ink-absorbing material bed of material 33 and described PET basic unit 31; Described viscose glue protective layer 321, viscose glue permeable formation 322 and adhesive linkage 323 hold together; The thickness of described adhesive-layer 32 is greater than the thickness of the described ink-absorbing material bed of material 33; Described adhesive-layer 32 is formed primarily of PUR, and the main component of described PUR is the thermoplastic macromolecule material that Tg is not less than 80 DEG C.
In above-mentioned advertisement consumptive material, the thickness of described PET basic unit 31 is 100 μm, and the thickness of the described ink-absorbing material bed of material 33 is 20 μm; The thickness of described adhesive-layer 32 is 30 μm.
In the above-mentioned ink-absorbing material bed of material 33, the composition of described blotting material and the percentage by weight of each component as follows: water soluble glue 1.5 ~ 10%, pounce 2 ~ 30%, color-fixing agent 1.5 ~ 10%, brightening agent 0.5 ~ 2%, surfactant 0.5 ~ 2%, surplus is deionized water.Wherein, described water soluble glue is polyvinyl alcohol, and described pounce is SiO 2, described color-fixing agent is halogenated phosphates.
Without the need to a production method for the advertisement consumptive material of cold lamination film, described method mainly comprises the following steps:
(1) be coated with: at wherein even spread one deck PUR of PET basic unit 31, adhesive-layer 32 is formed after PUR cooling curing, even spread one deck ink-absorbing material bed of material 33 is continued above described adhesive-layer 32, above-mentioned coated composite material is put into baking oven dry, then solidify, cool; Described coating speed is 10 ~ 80 ms/min;
(2) printing, air brushing: the ink-absorbing material bed of material 33 of the composite material obtained in above-mentioned steps 1 carries out print or air brushing operation, the ink-absorbing material bed of material 33 is formed image layer 34;
(3) hot pressing: by the product hot pressing a period of time under certain temperature and pressure obtained in above-mentioned steps 2, form viscous state after the PUR in adhesive-layer 32 is heated, form adhesive linkage 323 in PET basic unit 31 between the ink-absorbing material bed of material 33; The PUR of flowing upwards spreads gradually, penetrates in the loose structure of the ink-absorbing material bed of material 33, forms viscose glue permeable formation 322; Finally above described image layer 34, Uniform Flow forms one deck viscose glue protective layer 321; Just finished product can be obtained after cooling, solidification.
In aforementioned production method, the embodiment of different hot pressing condition is as following table:
Embodiment 1 Embodiment 2 Embodiment 3
Temperature, DEG C 100 120 140
Pressure, kg 4 2 1
Time, s 30 20 10
Above embodiment is only for illustration of the present invention; and be not limitation of the present invention; the those of ordinary skill of relevant technical field; without departing from the spirit and scope of the present invention; can also make a variety of changes and modification; therefore all equivalent technical schemes also belong to category of the present invention, and scope of patent protection of the present invention should be defined by the claims.

Claims (10)

1. without the need to an advertisement consumptive material for cold lamination film, described consumptive material comprises basic unit, adhesive-layer and the ink-absorbing material bed of material, it is characterized in that: the described ink-absorbing material bed of material is positioned at the top of described basic unit, carries out printing or forming image layer after air brushing above the described ink-absorbing material bed of material; Described adhesive-layer is also positioned at the top of described basic unit, and described adhesive-layer comprises three functional layers, is followed successively by viscose glue protective layer, viscose glue permeable formation and adhesive linkage from top to bottom; Described viscose glue protective layer is positioned at the top of described image layer, and described viscose glue permeable formation oozes in the loose structure of the described ink-absorbing material bed of material, and described adhesive linkage is adhered between the described ink-absorbing material bed of material and described basic unit; Described viscose glue protective layer, viscose glue permeable formation and adhesive linkage hold together; The thickness of described adhesive-layer is greater than the thickness of the described ink-absorbing material bed of material; Described basic unit is PET material, and described adhesive-layer is formed primarily of PUR, and the main component of described PUR is the thermoplastic macromolecule material that Tg is not less than 80 DEG C.
2. a kind of advertisement consumptive material without the need to cold lamination film according to claim 1, is characterized in that: the thickness range of described PET basic unit is 25 ~ 200 μm.
3. a kind of advertisement consumptive material without the need to cold lamination film according to claim 1, is characterized in that: the thickness range of the described ink-absorbing material bed of material is 10 ~ 50 μm.
4. a kind of advertisement consumptive material without the need to cold lamination film according to claim 1, is characterized in that: the thickness range of described adhesive-layer is 10 ~ 80 μm.
5. a kind of advertisement consumptive material without the need to cold lamination film according to claim 1, it is characterized in that, the composition of described blotting material and the percentage by weight of each component as follows: water soluble glue 1.5 ~ 10%, pounce 2 ~ 30%, color-fixing agent 1.5 ~ 10%, brightening agent 0.5 ~ 2%, surfactant 0.5 ~ 2%, surplus is deionized water.
6. a kind of advertisement consumptive material without the need to cold lamination film according to claim 5, is characterized in that: described water soluble glue is the wherein one in polyvinyl alcohol, cellulose acetate, polyethylene glycol oxide.
7. a kind of advertisement consumptive material without the need to cold lamination film according to claim 5, is characterized in that: described pounce is SiO 2, CaCO 3, TiO 2, Al 2o 3in wherein one or more mixing.
8. a kind of advertisement consumptive material without the need to cold lamination film according to claim 5, is characterized in that: described color-fixing agent is the wherein one in quaternary ammonium salt, halogenated phosphates, bromide sixteen alkyls pyridine.
9. a production method for the advertisement consumptive material without the need to cold lamination film according to claim 1, it is characterized in that, described method mainly comprises the following steps:
(1) be coated with: at wherein even spread one deck PUR of PET basic unit, adhesive-layer is formed after PUR cooling curing, above described adhesive-layer, continue even spread one deck ink-absorbing material bed of material, above-mentioned coated composite material is put into baking oven and dries, then solidify, cool; Described coating speed is 10 ~ 80 ms/min;
(2) printing/air brushing: the ink-absorbing material bed of material of the composite material obtained in above-mentioned steps 1 carries out print or air brushing operation, the ink-absorbing material bed of material forms image layer;
(3) hot pressing: by the product hot pressing a period of time under certain temperature and pressure obtained in above-mentioned steps 2, form viscous state after the PUR in adhesive-layer is heated, form adhesive linkage in PET basic unit between the ink-absorbing material bed of material; The PUR of flowing upwards spreads gradually, penetrates in the loose structure of the ink-absorbing material bed of material, forms viscose glue permeable formation; Finally above described image layer, Uniform Flow forms one deck viscose glue protective layer; Just finished product can be obtained after cooling, solidification.
10. the production method of a kind of advertisement consumptive material without the need to cold lamination film according to claim 9, it is characterized in that: in described hot pressing process, the hot pressing temperature adopted is 100 ~ 140 DEG C, and the hot pressing pressure of employing is 1 ~ 4kg, and the time that described hot pressing needs is 10 ~ 40s.
CN201510406570.5A 2015-07-10 2015-07-10 A kind of production method of the advertisement consumptive material without the need for cold lamination film Expired - Fee Related CN104943302B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9799240B2 (en) 2016-02-29 2017-10-24 Dong Guan Zhong Shi Tuo Enterprise Ltd. Low tack bubble free advertisement film
CN115450066A (en) * 2022-10-28 2022-12-09 江苏万宝瑞达高新技术有限公司 Ink-jet synthetic paper and manufacturing method thereof

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CN103009860A (en) * 2012-12-27 2013-04-03 天津海华科技发展有限公司 Printing paper coated with gold-loaded resin for ink-jet printing
EP2708370A1 (en) * 2012-09-07 2014-03-19 Kabushiki Kaisha Toshiba Indirect transfer medium and forgery prevention medium producing apparatus
CN103709973A (en) * 2013-12-04 2014-04-09 浙江固特热熔胶有限公司 Cross-interface penetration adhesive

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US20060156940A1 (en) * 2004-12-24 2006-07-20 Canon Kabushiki Kaisha Laminate film and image protection method using the same
CN101249768A (en) * 2008-03-17 2008-08-27 汕头市新协特种纸科技有限公司 Thermal transfer printing paper capable of ink-jet printing and preparation method thereof
CN201702996U (en) * 2010-05-24 2011-01-12 张家港保税区康得菲尔实业有限公司 Bidirectional stretching polypropylene coextrusion pre-coated film
CN102501674A (en) * 2011-10-14 2012-06-20 江苏格美高科技发展有限公司 Glossy waterproof polypropylene photo paper applicable for aqueous ink and its preparation method
EP2708370A1 (en) * 2012-09-07 2014-03-19 Kabushiki Kaisha Toshiba Indirect transfer medium and forgery prevention medium producing apparatus
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CN103709973A (en) * 2013-12-04 2014-04-09 浙江固特热熔胶有限公司 Cross-interface penetration adhesive

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9799240B2 (en) 2016-02-29 2017-10-24 Dong Guan Zhong Shi Tuo Enterprise Ltd. Low tack bubble free advertisement film
CN115450066A (en) * 2022-10-28 2022-12-09 江苏万宝瑞达高新技术有限公司 Ink-jet synthetic paper and manufacturing method thereof

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