CN104939959B - Rehabilitation therapy and movement protection tool based on shape memory polymer - Google Patents
Rehabilitation therapy and movement protection tool based on shape memory polymer Download PDFInfo
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- CN104939959B CN104939959B CN201510309932.9A CN201510309932A CN104939959B CN 104939959 B CN104939959 B CN 104939959B CN 201510309932 A CN201510309932 A CN 201510309932A CN 104939959 B CN104939959 B CN 104939959B
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Abstract
The invention relates to a rehabilitation therapy and movement protection tool based on a shape memory polymer. The rehabilitation therapy and movement protection tool comprises wrist bands, kneecaps, elbow pads, shoulder pads, a neck guard and the like, wherein the wrist bands, the kneecaps and the elbow pads are used for movement protection, and the shoulder pads, the neck guard and the like are used for rehabilitation therapy. The rehabilitation therapy and movement protection tool includes a tubular body which is opened or closed, and the tubular body is made of a shape memory polymer material which is elastic or rigid at a normal temperature. The pre-deformation temperature of the tubular body is 30-80 DEG C, and the tubular body can be in the deformed shape matched with the shapes of the wearing positions of a human body at the pre-deformation temperature and can keep the pre-deformed shape after being cooled. According to the rehabilitation therapy and movement protection tool based on the shape memory polymer, the body of the therapy and protection tool is made of the shape memory polymer material, and the wearing positions can be limited and removed through the change between the pre-deformation shape and the recovery shape. Due to the fact that there is no need for the pre-deformation shape in the limited state to consider the follow-up disengaging means, the pre-deformed shape can be completely matched with the wearing positions, and therefore the wearing comfort and convenience are improved.
Description
Technical field
The present invention relates to a kind of rehabilitation and athletic protective apparatus based on shape-memory polymer, including for moving
The wrister of protection, knee cap, knee cap, elbow support, and the shoulder protector for rehabilitation, rib etc..
Background technology
Existing wrister for athletic protective, knee cap, knee cap, elbow support and the shoulder protector for rehabilitation, rib etc.
Apparatus, generally existing following defect:1 and the shape bad adaptability master at wearing position, affect the comfort level that uses;2nd, it is guarantor
Card is reliably fitted with wearing position, frequently with the stronger material cladding wearing position of elasticity, causes human body stress excessive, comfortableness
Difference;3rd, affected by the organization of human body at wearing position, the difficulty of wearing is larger, affected the convenience for using.
The content of the invention
It is comfortably poly- based on shape memory that the technical problem to be solved is to provide a kind of easy to wear, use
The rehabilitation of compound and athletic protective apparatus.
Rehabilitation and athletic protective apparatus of the present invention based on shape-memory polymer includes an opening or remains silent
Cylindrical body, the cylindrical body be under room temperature elasticity or rigid shape memory polymer material;Cylindrical body it is pre-
Deformation temperature is 30 DEG C -80 DEG C, and cylindrical body can be formed at a temperature of predeformation dresses what position form was adapted with human body
Deformation simultaneously keeps after the cooling period the shape after predeformation.Cylindrical body after predeformation can at normal temperatures repeat de- wearing or heated
After remove;Cylindrical body can repeatedly set predeformation.
The cylindrical body can be made up by under room temperature of rigid shape memory polymer material;Cylindrical body can
The deformation adaptable with the shape that human body dresses position is formed at a temperature of predeformation and the shape after predeformation is kept after the cooling period
Shape, and the rigid cylindrical body with predeformation can depart from limited wearing position after softening of being heated.
The cylindrical body is extensible opening shape, and cylindrical body is by being that the memory of rigid rigid shape is poly- under room temperature
Compound material is made;Cylindrical body can form the deformation adaptable with the shape at human body wearing position simultaneously at a temperature of predeformation
The shape after predeformation, and the rigid cylindrical body with predeformation is kept to strut by the elasticity of opening after the cooling period
And depart from limited human body wearing position.
The cylindrical body can also be made by having resilient shape memory polymer material under room temperature;Cylindrical body
The deformation adaptable with the shape that human body dresses position can be formed at a temperature of predeformation and is kept after the cooling period after predeformation
Shape, and the cylindrical body with predeformation can disengage it from limited human body wearing portion by the elasticity of itself
Position.
The cylindrical body can be connected as entirety, rigid limit part and shape-memory polymer material with a rigid limit part
The cylindrical body of material surrounds opening or the cylindrical cavity remained silent jointly.
The cylindrical body of the elastic shape memory polymer material and a rigid limit part are connected as entirety, described firm
Property locating part be rigid limit part and elastic shape memory polymer material for rigid shape memory polymer material under room temperature
Cylindrical body surround opening or the cylindrical cavity remained silent jointly;Rigid limit part can be formed and human body at a temperature of predeformation
What the shape at wearing position was adapted deforms and keeps after the cooling period the shape after predeformation, and the rigidity limit with predeformation
Position part can depart from limited wearing position after softening of being heated.
The cylindrical body of the elastic shape memory polymer material and a rigid limit part are connected as entirety, described firm
Property locating part be that for rigid shape memory polymer material, rigid limit part covers elastic shape memory polymer material under room temperature
The part or all of surface of the cylindrical body periphery of material;Rigid limit part can be formed and human body wearing portion at a temperature of predeformation
What the shape of position was adapted deforms and keeps after the cooling period the shape after predeformation, and the rigid limit part energy with predeformation
It is enough to depart from limited wearing position after softening of being heated.
The elastic shape memory polymer material of the cylindrical body is ethylene-vinyl acetate copolymer(EVA), poly- ammonia
One or more combination in ester, silica gel, silica gel-ethylene-vinyl acetate copolymer mixture.
The rigid shape memory polymer material of the cylindrical body for crosslinking or noncrosslinking pla-pcl, polyurethane,
Styrene, epoxy, cyanate, polyethylene, polypropylene, Merlon, acrylonitrile-butadiene-styrene copolymer(ABS)Tree
One or more combination in fat, polymethyl methacrylate.
The rehabilitation based on shape-memory polymer of the present invention and another technical scheme of athletic protective apparatus, bag
Include one and the cylindrical body that human body dresses position is made up and can be enclosed within of elastomeric material, cylindrical body is connected with by rigid shape
Rigid limit part made by shape memory polymer material;The rigid limit part can be formed at a temperature of predeformation and worn with human body
Wear position shape be adapted deformation and after the cooling period holding predeformation after shape;And the rigid limit with predeformation
Part departs from limited wearing position after can softening after being heated;The predeformation temperature of rigid limit part is 30 DEG C -80 DEG C.
The rehabilitation based on shape-memory polymer of the present invention and another technical scheme of athletic protective apparatus, bag
Including a rigidity can be enclosed within the cylindrical body that human body dresses position, and cylindrical body is connected with to be made up of elastic shape memory material
Elastic spacing one;The elastic spacing one has the predeformation that the shape for dressing position with human body is adapted, and can borrow
The elasticity of itself is helped to disengage it from limited human body wearing position.
The present invention is using shape memory polymer material as treatment and the main body of safety device, it is possible to use its predeformation
Shape and the change recovered between shape are realized to dressing the spacing of position and removing.Due to the spacing state of pre-deformed shape
Without the need for considering follow-up disengaging means, the shape after predeformation can accomplish to be matched completely with wearing position, wear so as to improve shape
The comfortableness worn and convenience.Above-mentioned spacing and remove can be with Reusability.
Description of the drawings
Fig. 1 is the schematic shapes before and after the wrister wearing of the embodiment of the present invention one;
Fig. 2 is the schematic shapes before and after the elbow support wearing of the embodiment of the present invention two and embodiment three;
Fig. 3 is the schematic shapes before and after the elbow support wearing of the embodiment of the present invention four;
Fig. 4 is the schematic shapes before and after the knee cap wearing of the embodiment of the present invention five;
Fig. 5 is the schematic shapes before and after the leg guard wearing of the embodiment of the present invention six;
Fig. 6 is the schematic shapes of the rib of the embodiment of the present invention seven;
Fig. 7 is the cross-sectional view of the rib of the embodiment of the present invention seven.
Specific embodiment
Embodiment one:Elastic wrister.
The wrister of the present embodiment is the cylindrical body 1 of an elastic shape memory silica gel-EVA mixture.Cylindrical body adds
Heat expands its diameter to after 45 DEG C, keeps this shape and is cooled to after room temperature, and the cylindrical body under free state keeps expanding
Shape afterwards, such as Fig. 1(a)It is shown.Cylindrical body after will be enlarged by is enclosed within wrist and is again heated to 45 DEG C, cylindrical body contraction
Wrap wrist, such as Fig. 1(b)It is shown.After cooling, shape and the wrist shape of cylindrical body are adapted.Using material at normal temperatures
Elasticity departed from after, cylindrical body keeps Fig. 1(b)The shape matched with unique individual's wrist for being formed.This has
The elastic wrister of matching unique individual's wrist shape can also can be heated to 45 DEG C by same unique individual's Reusability, make cylinder
The deformation matched with unique individual's wrist of shape body is wholly absent.Repeat what above-mentioned heating enlarged diameter was cooled down again afterwards
Process makes wrister have Fig. 1 again(a)Shown shape.Reheat that to shrink setting new with unique individual's wrist phase after wearing
The shape matched somebody with somebody.
Embodiment two:Elastic elbow support.
The elbow support of the present embodiment has the cylindrical body 1 of an elastic cellular shape memory EVA material.Before the elbow support wearing
With such as Fig. 2(a)Shown cylindrical shape original shape.After 50 DEG C are heated to it, using its resilient sleeve after ancon, curved elbow
Portion is to the angle being comfortable on and keeps this angle until cylindrical body cools back room temperature.Since then, the spontaneous holding of cylindrical body
The shape being adapted with ancon(Such as Fig. 2(b)It is shown).The elasticity being heated to after 50 DEG C using cylindrical body can be departed from.Under
It is secondary to be again heated to 50 DEG C when using, and repeat above procedure.
Embodiment three:Elastic elbow support.
The elbow support of the present embodiment has the cylindrical body 1 of an elastic cellular shape memory polyurethane material.The elbow support is worn
There is such as Fig. 2 before wearing(a)Shown cylindrical shape original shape.At room temperature, using its elasticity be easily sleeved on ancon it
Afterwards, heating cylinder is to 50oAfter C, bend elbow is to the angle being comfortable on and keeps this angle until cylindrical body is cooled back
Room temperature.Since then, cylindrical body keeps the shape matched with ancon.Cylindrical body can be departed from using its elasticity.After coming off
Cylinder keep with ancon be adapted shape(Such as Fig. 2(b)It is shown), and can dress repeatedly.It is heated to 50oC, cylindrical body is extensive
Multiple its original shape(Such as Fig. 2(a)It is shown), and predeformation can be reset by above-mentioned steps.
Example IV:Rigid elbow support.
The elbow support cylindrical body 1 of the present embodiment is opening shape, and its middle part has the rigid limit part 2 of a solid shape
Used as support section, the standing part at two ends is rigid shape memory polyurethane material, such as Fig. 3 before being not used(a)It is shown.When two
The standing part at end is heated to 50oAfter C, polyurethane softens with good bendability.Now by intermediate support portions and human body
Ancon bends again the polyurethane portion at two ends and is allowed to be fixed on the upper lower arms in comfortable case of bending after matching.It is to be cooled
To room temperature, rigid elbow support is fixed on arm by the polyurethane for bending, such as Fig. 3(b)It is shown.It is available when needing to remove
The elasticity of bending polyurethane material is departed from.Afterwards this elbow support can be dressed repeatedly.Plus thermal polyurethane is to 50oC, polyurethane is solid
It is fixed partly to recover its original shape, such as Fig. 3(a)It is shown.Afterwards flexural deformation can be reset by above-mentioned steps.
Embodiment five:Knee cap.
The knee cap of the present embodiment has the cylindrical body 1 of an elastic cellular shape memory polyurethane, the local in the middle part of it
The upper rigid limit part 2 with microprotrusion.When using, this cylindrical body is heated to50Expand its diameter after DEG C, keep this
Shape is simultaneously cooled to after room temperature, and the cylindrical body under free state keeps the shape after expanding, such as Fig. 4(a)It is shown.After will be enlarged by
Cylindrical body be enclosed within human knee and be adapted dimpling position and knee, then bend knee to the angle being comfortable on and protect
This angle is held until cylindrical body is cooled to room temperature.Afterwards cylindrical body is fitted with thigh and calf and plays good fixed knee cap
Effect, such as Fig. 4(b)It is shown.Using the elasticity of cellular polyurethane, knee cap can elasticity disengaging.The cylinder of the free state for separating
Shape body keeps Fig. 4(b)The shape matched with knee for being formed.This has the knee cap of deformation can be with Reusability.Will be disengaged from
The cylindrical body for getting off is heated to50After DEG C, predeformation disappears.Cooling after above-mentioned heating enlarged diameter is repeated afterwards, dressed again
The step of heat shrink, resets predeformation.
Embodiment six:Leg guard.
The leg guard of the present embodiment has the cylindrical body of an elastic cellular shape memory EVA as liner 1, in its cylinder
Wall side is a shape memory PCL rigid limits part 2, such as Fig. 5(a)It is shown.After leg guard is integrally heated to into 70 DEG C PCL and
EVA softens, to be cooled to after 50 DEG C, and cylindrical body is enclosed within into human calf's desired area, cylindrical body deform and with
Shank is fitted.After cooling, the deformation of cylindrical body is fixed.Remember the elasticity of EVA using porous shape, leg guard can be taken off.It is de-
Leg guard after lower keeps the shape after deformation, such as Fig. 5(b)It is shown, and can put on again.Cylindrical body is again heated to70
After DEG C, cylindrical body returns to original shape, and can retighten deformation.
Embodiment seven:Rib.Its stereochemical structure is as shown in fig. 6, cross-section structure is as shown in Figure 7
The rib of the present embodiment is initially double-deck ribbon.Internal layer is the porous shape memory polyurethane of elasticity
(The cylindrical body 1 of elasticity).And outer layer is rigid shape memory polyurethane(Rigid limit part 2).
When using, 45 DEG C are first to heat to, rib softens.Cervical region is wound on so as to form the change being adapted with neck shaped
Shape.After being cooled to room temperature, deformation is fixed.When removing, 45 DEG C are heated to, rib softens to rewind removes disengaging neck
Portion.Rib after removing can be reused by above-mentioned steps.
Claims (8)
1. a kind of rehabilitation and athletic protective apparatus based on shape-memory polymer, is characterized in that:It includes one and opens
Mouth or the cylindrical body remained silent, the cylindrical body is made by having resilient elastic shape memory polymer material under room temperature;
Cylindrical body can form the deformation adaptable with the shape at human body wearing position at a temperature of predeformation and keep after the cooling period
Shape after predeformation, and the cylindrical body with predeformation can disengage it from limited human body by the elasticity of itself
Wearing position;The predeformation temperature of cylindrical body is 30 DEG C -80 DEG C;
The cylindrical body and a rigid limit part are connected as entirety, the rigid limit part be by be under room temperature it is rigid just
Property shape memory polymer material is made, and rigid limit part is total to the cylindrical body by made by elastic shape memory polymer material
With the cylindrical cavity for surrounding opening or remain silent;Rigid limit part can be formed at a temperature of predeformation dresses the shape at position with human body
What shape was adapted deforms and keeps the shape after predeformation, and the rigid limit part with predeformation to receive after the cooling period
Heat departs from limited wearing position after softening.
2. the rehabilitation and athletic protective apparatus based on shape-memory polymer according to claim 1, is characterized in that:
The elastic shape memory polymer material of the cylindrical body is silica gel and ethylene-vinyl acetate copolymer mixture, ethylene-vinegar
One or more combination in sour ethylene copolymer and polyurethane.
3. the rehabilitation and athletic protective apparatus based on shape-memory polymer according to claim 1, is characterized in that:
The elastic shape memory polymer material of the cylindrical body is the one kind or many in the porous material of the material of act set forth below
Plant combination:Silica gel and ethylene-vinyl acetate copolymer mixture, ethylene-vinyl acetate copolymer and polyurethane.
4. a kind of rehabilitation and athletic protective apparatus based on shape-memory polymer, is characterized in that:It includes one and opens
Mouth or the cylindrical body remained silent, the cylindrical body is made by having resilient elastic shape memory polymer material under room temperature;
Cylindrical body can form the deformation adaptable with the shape at human body wearing position at a temperature of predeformation and keep after the cooling period
Shape after predeformation, and the cylindrical body with predeformation can disengage it from limited human body by the elasticity of itself
Wearing position;The predeformation temperature of cylindrical body is 30 DEG C -80 DEG C;
The cylindrical body and a rigid limit part are connected as entirety, the rigid limit part be by be under room temperature it is rigid just
Property shape memory polymer material make, rigid limit part cover by made by elastic shape memory polymer material cylindrical body
The part or all of surface of periphery;Rigid limit part can form the shape for dressing position with human body at a temperature of predeformation and mutually fit
That what is answered deforms and keeps the shape after predeformation after the cooling period, and the rigid limit part with predeformation can be in softening of being heated
Depart from limited wearing position afterwards.
5. the rehabilitation and athletic protective apparatus based on shape-memory polymer according to claim 4, is characterized in that:
The elastic shape memory polymer material of the cylindrical body is silica gel and ethylene-vinyl acetate copolymer mixture, ethylene-vinegar
One or more combination in sour ethylene copolymer and polyurethane.
6. the rehabilitation and athletic protective apparatus based on shape-memory polymer according to claim 4, is characterized in that:
The elastic shape memory polymer material of the cylindrical body is the one kind or many in the porous material of the material of act set forth below
Plant combination:Silica gel and ethylene-vinyl acetate copolymer mixture, ethylene-vinyl acetate copolymer and polyurethane.
7. a kind of rehabilitation and athletic protective apparatus based on shape-memory polymer, is characterized in that:One is included by bullet
Property material make and can be enclosed within the cylindrical body that human body dresses position, cylindrical body is connected with by rigid shape memory polymer material
Rigid limit part made by material;The rigid limit part can be formed at a temperature of predeformation dresses the shape phase at position with human body
The deformation of adaptation simultaneously keeps after the cooling period the shape after predeformation;And the rigid limit part with predeformation can be in change of being heated
Depart from limited wearing position after soft;The predeformation temperature of rigid limit part is 30 DEG C -80 DEG C.
8. a kind of rehabilitation and athletic protective apparatus based on shape-memory polymer, is characterized in that:Include a rigidity
Be enclosed within human body dress the cylindrical body at position, cylindrical body is connected with the elastic spacing by made by elastic shape memory material
Part;The elastic spacing one has the predeformation that the shape for dressing position with human body is adapted, and can be by the bullet of itself
Property disengage it from limited human body wearing position.
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Families Citing this family (5)
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CN105936747B (en) * | 2016-05-13 | 2019-01-29 | 哈尔滨工业大学 | The method for preparing triple shape-memory polymers and its application in 3D printing is blended in shape memory polyurethane and ABS resin |
CN211097440U (en) * | 2018-07-18 | 2020-07-28 | 北京化工大学 | Protective tool for four limbs |
CN111623226A (en) * | 2020-05-19 | 2020-09-04 | 苏州佑行健康科技有限公司 | Wearable equipment and system of wearable equipment |
CN111803263B (en) * | 2020-07-07 | 2022-02-15 | 冉建英 | Orthopedic nursing support |
CN112190390B (en) * | 2020-10-09 | 2022-05-27 | 哈尔滨工业大学 | Shape memory low-temperature treatment neck sleeve and using method thereof |
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CN1502313A (en) * | 2002-11-26 | 2004-06-09 | 上海第二医科大学附属仁济医院 | Shape memory bone fixing splint |
GB2482298A (en) * | 2010-07-27 | 2012-02-01 | Univ Bolton | Shape memory cast |
CN202198704U (en) * | 2011-07-25 | 2012-04-25 | 高峰 | Shape memory alloy super-elastic limbs scar contracture deformity corrector |
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US8100843B2 (en) * | 2009-03-24 | 2012-01-24 | GM Global Technology Operations LLC | Shape memory polymer medical cast |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1502313A (en) * | 2002-11-26 | 2004-06-09 | 上海第二医科大学附属仁济医院 | Shape memory bone fixing splint |
GB2482298A (en) * | 2010-07-27 | 2012-02-01 | Univ Bolton | Shape memory cast |
CN202198704U (en) * | 2011-07-25 | 2012-04-25 | 高峰 | Shape memory alloy super-elastic limbs scar contracture deformity corrector |
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