CN104926000B - A kind of continuous method of quick removing floating green alga water - Google Patents

A kind of continuous method of quick removing floating green alga water Download PDF

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CN104926000B
CN104926000B CN201510396034.1A CN201510396034A CN104926000B CN 104926000 B CN104926000 B CN 104926000B CN 201510396034 A CN201510396034 A CN 201510396034A CN 104926000 B CN104926000 B CN 104926000B
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water
continuous
silk floss
sedimentation agent
floating
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CN104926000A (en
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吴振斌
易科浪
刘碧云
代志刚
张义
贺锋
周巧红
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Institute of Hydrobiology of CAS
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Abstract

The continuous method of floating green alga water, its step are removed the invention discloses a kind of:1)Regional choice:The region of the selection water silk floss vigorous floating in blocks of growing power;2)The preparation of algicide:Hydrogen peroxide is diluted with distilled water;3)The preparation of sedimentation agent:Clay and bentonite are configured to sedimentation agent in mass ratio;4)The consumption and spraying condition of algicide:The hydrogen peroxide of preparation is sprayed at selected region reclaimed water silk floss surface;5) addition of sedimentation agent:After algicide treatment water silk floss, according to the area of Experimental Area, sedimentation agent is uniformly sprinkled into water body, water silk floss sinks to water bottom therewith, after standing, water body clarification, the anhydrous continuous floating of the water surface.The method is simple, easy to operate, with low cost, non-secondary pollution, the water to water body is continuous with fairly obvious removal effect, while having the effect for improving to high organic substrate, for the recovery of lake submerged vegetation creates precondition, the method has environment very high, economic and social benefit.

Description

A kind of continuous method of quick removing floating green alga water
Technical field
The present invention relates to the removal of silkweed algal tufa in eutrophic lake and lake high organic substrate improving environment Field, is more particularly to a kind of continuous method of the quick removing floating green alga water of ecological, environmental protective, is suitable in eutrophic lake The serious high organic substrate water body of the continuous outburst of water, such as pond, lake.
Background technology
In season the end of spring and the beginning of summer, in the current ratio such as landscape water body, culture of Chinese mitten crab water body, aqiuculrue water body, rice field, lake Relatively slow, water transparency is high, and it is continuous that water often occurs in the few region of water plant(Spirogyrasp.)Amount reproduction is simultaneously floated on The water surface, it is a class silkweed of Chlorophyta Zygnemataceae Spirogyra that water is continuous, and light water such as common in fresh water is continuous(S. communis), special-shaped water silk floss(S. varians), single water silk floss(S. sigularis)Deng, its filamentous not branch, chloroplaset In the shape of a spiral.Water is continuous usually to be nourished and generated with the algal filament being broken;Zoogamy is carried out with trapezoidal engagement, engagement sides;With Quiet wall spore, azygospore etc. carry out asexual reproduction;Due to continuous with the extremely strong reproductive capacity and again fecundity of water, water is continuous suitable Suitable environment usually abnormality proliferation, serious harm is caused to water body:In landscape water body, water body scape is not only influenceed during water silk floss outburst See, rot also produce peculiar smell, surrounding environment is impacted;In breeding water body, water nutrition, or even death of rotting are consumed Algae toxins are produced, the growth to other animals and plants brings threat;In rice field, the continuous winding seedling of water influences the growth of seedling Deng;In the recovery of lake submerged vegetation, the continuous presence of water is usually wound to submerged plant, shading, nutrient competition, even Allelopathy is produced, the effect of recovery is largely affected.
Mainly there are three class methods to thread alga eruption prophylactico-therapeutic measures both at home and abroad at present:(1)Physical method:Manually salvaging is Most common method, its most rapid, most safe, but laborious, somewhat expensive that operates that takes effect, salvages and carrys out inappropriate treatment Method easily makes thread algae rot, and produces niff, and easily environment is polluted;Algal filament easily breaks when salvaging simultaneously Split, the algal filament of fracture can quickly grow up to filamentous by cell division, it is impossible to tackle the problem at its root;(2)Chemical method:It is main If destroying alga cells so as to realize killing the purpose of algae control algae using chemical reagent, this method has efficient, quick, method It is easy.Conventional medicine is mainly including oxidized form reagent such as potassium permanganate, halogen;Such as copper agent, inorganic gold of Non-oxidized reagent Category compound etc..Chemical method is undoubtedly a kind of effect is significant, the effective way of instant effect, but chemical reagent often has poison in itself Evil effect, easily causes secondary pollution, so urgently nontoxic, efficient, the economic algicide of developmental research;(3)Ecological method:It is main Growth of algae etc. is suppressed by rebuilding biocoene by bio operon method.Such as with algae algal control, higher aquatic plants Control algae, filter-feeding fish food algae etc., ecological method are undoubtedly a kind of algae-removing method of environmental protection, but due to long the time required to except algae, And easily rebound and ideal effect can not be reached.
The relevant research and technology for removing algae most at present is concentrated mainly on Microcystis aeruginosa to Cyanophyta, anabena, quiver algae Deng removal on, and the research to the removal of filamentous green algae is less, and the related reagent for going water removal continuous is concentrated mainly on as follows Several aspects:(1)Copper class reagent such as copper sulphate, potato copper, generation silk algae sand etc. is climbed, preferably, but they are that a class is high to its removal effect Malicious chemical substance, easily makes aqueous bio produce Metal toxicity, destroys aquatic ecosystem;(2)Herbicide such as paraquat, grass are sweet Phosphine, prometryn, moss net etc. is killed, the removal of weeds in field is most commonly used to, in it is used in lake, breeding water body, usually to water Body other biological is impacted;(3)The allelochemical such as blade of terrestrial plant camphor tree, willow, pine tree etc. and branch leaching liquor, meeting There is certain inhibitory action to water silk floss, but because materials are difficult, extraction time is long, process is complicated etc. almost without large-scale application reality Example.Although various about the continuous reagent of removal water, all lack it is a kind of efficiently, nonhazardous effect, can be in water bodys such as lake rivers In the extensive invention implemented.
In the improvement of lake eutrophication, the recovery of aquatic vegetation has turned into a kind of efficient, method of ecological, environmental protective.By The survived environment, high organic substrate is depended on often to have necessarily to the recovery of aquatic vegetation in the recovery effects of aquatic vegetation Coercion, it is contemplated that while removing to remove water silk floss, the nutrition of substrate can be effectively reduced, be beneficial to the extensive of aquatic vegetation It is multiple.The present invention is destroyed using the strong oxidizing property of hydrogen peroxide to alga cells;Settled using natural sodium bentonite-clay The adsorptivity of agent is adsorbed and settled to deactivated frustule;Simultaneously also using natural sodium bentonite-clay sedimentation Nutriment in agent absorption high organic substrate, is improved to a certain extent to high organic substrate, and the heavy water in lake is planted The recovery of quilt has certain facilitation.The invention is a kind of environmental protection, and high financial profit can large area, high efficiency removal The continuous method of floating water.
The content of the invention
A kind of method continuous the present invention seeks to there are provided quick removing floating green alga water, the method is simple, operation Convenient, with low cost, non-secondary pollution, the water to water body is continuous with fairly obvious removal effect, while to high organic bottom Matter has the effect for improving, and is that the recovery of lake submerged vegetation creates precondition, and the method has environment very high, economy And social benefit.
To reach above-mentioned purpose, the present invention uses following technical scheme:
A kind of quick removing floats the continuous method of green alga water, and its step is:
1)Regional choice:Selection water silk floss growing power is vigorous and region of floating in blocks, and regional extent is flat less than or equal to 500 Square rice;
2)The preparation of algicide:With distilled water by hydrogen peroxide that mass fraction is 30 %(Analysis is pure)Be diluted to 3 %- The concentration of 5 %, and place in the cool;
3)The preparation of sedimentation agent:It is 10 % -15 % by moisture content(Mass ratio)Clay and bentonite press 6-8: 4 - 2 mass ratioes are configured to sedimentation agent;
4)The consumption and spraying condition of algicide:By step 2)The hydrogen peroxide of preparation presses 1:250 volume ratio is uniform Selected region reclaimed water silk floss surface is sprayed at, spraying time is with fine day 12: 00 - 14 :00 is advisable, after 1-2 hour The continuous upgrowth situation of observation water, if not completely losing activity also, repeats this step 1-2 time;
5)The addition of sedimentation agent:Algicide processes water silk floss after 3-4 hours, according to the area of Experimental Area, by sedimentation agent Uniformly it is sprinkled into water body, every square metre of kg-10 kg sedimentation agent of waters 5, water silk floss sinks to water bottom therewith, makes water bottom The tiling thickness of sedimentation agent is 1 centimeter-2 centimeters, after standing 1-3 day, water body clarification, the anhydrous continuous floating of the water surface;
The continuous abnormality proliferation of described processing region reclaimed water simultaneously floats on water surface influence water landscape in flakes;
Described water is continuous for water common in the poisons in freshwater such as lake, river, pond is continuous, and such as light water is continuous(S. communis), special-shaped water silk floss(S. varians), single water silk floss(S. sigularis)Deng;
The continuous method of described quick removing floating green alga water, it is characterised in that described low concentration hydrogen peroxide is directly sprayed Spill in the continuous bed course for floating of water, other biologies will not be adversely affected;It is sedimentation material to use natural sodium bentonite and clay Material, the water silk floss of inactivation is effectively fixed on water bottom by its good absorption property, while the nutrition that water silk floss is discharged can be adsorbed The materials such as salt;
Described sedimentation agent can improve lake eutrophication high organic substrate physicochemical property, be conducive to submerged plant extensive It is multiple.
The present invention compared with prior art, with advantages below and effect:
1. hydrogen peroxide resolves into H2O and O2, pollution is not resulted in environment.
2. the continuous speed of water is killed fast, the continuous photosynthetic activity of water is greatly lowered after 24 hours, activity reduces scope and is 70 % - 95 %.With the increase of hydrogen peroxide fountain height, continuous its chloroplaset under the microscope of water into different degrees of concentration, The continuous forfeiture cytoactive of water is caused, the phenomenon of fracture dissolving occurs in later stage filament.It is further cultured for 20 days, increasing again for water silk floss does not occur Grow.
3. sedimentation agent is formulated by two kinds of materials of clay and bentonite, using their caking property and adsorptivity by water Silk floss is absorbed and fixed at water bottom.
Brief description of the drawings
Fig. 1 be it is a kind of grow it is vigorous and float on the water surface water silk floss schematic diagram.
The water for growing vigorous period is continuous because photosynthesis discharges a large amount of gases, and gas gathers makes water silk floss float to water body table Face.
Fig. 2 gradually inactivates schematic diagram for water is continuous after a kind of sprinkling algicide.
Water is continuous by after algicide treatment, hydrogen peroxide and water silk floss vigorous reaction, cell is lost activity, frond color from Emerald green is changed into white and floats on the water surface.
Fig. 3 adds water silk floss sinking schematic diagram after sedimentation agent for one kind.
After the sedimentation agent of clay and bentonite composition is added, the water of inactivation is continuous because the Action of Gravity Field of sedimentation agent sinks, together When sedimentation agent special structure water bottom is fixed in the continuous absorption of water.
Fig. 4 is a kind of water silk floss schematic diagram killed after algae is processed under microscope.
When water silk floss after inactivation is examined under a microscope, easily find that cell Chloroplast is changed into black from green, and be in Now different degrees of concentration, cell membrane occasionally has rupture.
Specific embodiment
In order to be better understood from the present invention, with reference to the example content that the present invention is furture elucidated, but it is of the invention in Appearance is not limited solely to the following examples.
Example 1:
A kind of quick removing floats the continuous method of green alga water, and its step is:
1)Regional choice:Prepare the beaker of 1 L sizes, add 2 or 3 centimeters of bottoms gathered go back to from the Hangzhou, Zhejiang province West Lake Mud, adds 1 L Hangzhou West Lake water samples, and it is continuous to add the vigorous Hangzhou West Lake water of vitality that weight in wet base is 5 g or so after clarification, near the window The culture a few days(- 30 days on the 10th), experiment is carried out after water silk floss floats on water surface;
2)The preparation of algicide:With distilled water by hydrogen peroxide that mass fraction is 30 %(Analysis is pure)It is diluted to 3 %'s Concentration;
3)The preparation of sedimentation agent:It is 10 % or 12 % or 14 % or 15 % with moisture content(Mass ratio)Clay and bentonite 8 are made into mass ratio:2 sedimentation agent;
4)The consumption and spraying condition of algicide:Selection one the 12 of fine day:00 comes into effect the content of the invention, will prepare 3 % concentration hydrogen peroxide press 1:250 volume ratio is uniformly sprayed at water silk floss surface, stirs, and stands, after 1 hour Observation water silk floss loses activity, and frond color is changed into white and floats on the water surface from emerald green;
5)The addition of sedimentation agent:By step 3 after 3 hours)The sedimentation agent of preparation is delivered in step 2)On water silk floss after treatment, Stir, stand so that the thickness of the improvement matrix in beaker is 1 centimeter, after sedimentation agent is added, the continuous body of dead water with Sedimentation agent sinks to plastics bottom of the barrel, after standing 2 days, water body clarification, the anhydrous continuous floating of the water surface;
6)By the photosynthetic activity that photosynthesis measurement water is continuous after 24 hours, after treatment, the continuous photosynthetic activity of water from 0.3356 mg/(L·h·g)It is reduced to 0.0326 mg/ (Lhg), its inhibiting rate is up to 90.3 %.After 20 days, substrate total nitrogen contains Amount reduces 20.3 %, and total phosphorus content reduces 8.5 %, and organic matter reduces 15.2 %.
Example 2:
A kind of quick removing floats the continuous method of green alga water, and its step is:
1)Regional choice:There is length in the Plastic Drum of 10 L volumes in the Hangzhou, Zhejiang province West Lake diversion Yuhuang Mount preprocessing field A large amount of vigorous water of the vitality for returning to cultivate that gathered from Hangzhou West Lake are continuous, and float on the water surface a few days (10 days -30 Day), wherein substrate is the high organic substrate of Hangzhou West Lake, there is 3 centimeters of thickness;
2)The preparation of algicide:With distilled water by hydrogen peroxide that mass fraction is 30 %(Analysis is pure)It is diluted to 4 %'s Concentration;
3)The preparation of sedimentation agent:It is 10 % or 11 % or 13 % or 15 % with moisture content(Mass ratio)Clay and bentonite 7 are made into mass ratio:3 sedimentation agent;
4)The consumption and spraying condition of algicide:Selection one the 12 of fine day:00 comes into effect the content of the invention, will prepare 4 % concentration hydrogen peroxide press 1:250 volume ratio is uniformly sprayed at water silk floss surface, stirs, and stands, after 1 hour Observation water silk floss loses activity, and frond color is changed into white and floats on the water surface from emerald green;
5)The addition of sedimentation agent:By step 3 after 3 hours)The sedimentation agent of preparation is delivered in step 2)On water silk floss after treatment, Stir, stand so that the thickness of the improvement matrix in Plastic Drum is 1 centimeter, after sedimentation agent is added, the continuous body of dead water with Sedimentation agent and sink to plastics bottom of the barrel, after standing 2 days, water body clarification, the anhydrous continuous floating of the water surface;
6)By the photosynthetic activity that photosynthesis measurement water is continuous after 24 hours, after treatment, the continuous photosynthetic activity of water from 0.4371 mg/(L·h·g)It is reduced to 0.0538 mg/ (Lhg), its inhibiting rate is up to 87.7 %.After 20 days, substrate total nitrogen contains Amount reduces 17.4 %, and total phosphorus content reduces 8.1 %, and the content of organic matter reduces 13.7 %.
Example 3:
A kind of quick removing floats the continuous method of green alga water, and its step is:
1)Regional choice:It is long in the glass jar of 200 L volumes in the Hangzhou, Zhejiang province West Lake diversion Yuhuang Mount preprocessing field There are a large amount of vigorous water of the vitality for returning to cultivate that gathered from Hangzhou West Lake continuous, and float on (January -2 water surface several months Month), wherein substrate is the high organic substrate of Hangzhou West Lake, there is 3 centimeters of thickness;
2)The preparation of algicide:With distilled water by hydrogen peroxide that mass fraction is 30 %(Analysis is pure)It is diluted to 5 %'s Concentration;
3)The preparation of sedimentation agent:It is 10 % or 11 % or 14 % or 15 % with moisture content(Mass ratio)Clay and bentonite 6 are made into mass ratio:4 sedimentation agent;
4)The consumption and spraying condition of algicide:Selection one the 12 of fine day:00 comes into effect the content of the invention, will prepare 5 % concentration hydrogen peroxide press 1:250 volume ratio is uniformly sprayed at water silk floss surface, stirs, and stands, after 1 hour Observation water silk floss loses activity, and frond color is changed into white and floats on the water surface from emerald green;
5)The addition of sedimentation agent:By step 3 after 3 hours)The sedimentation agent of preparation is delivered in step 2)On water silk floss after treatment, Stir, stand so that the thickness of the improvement matrix in glass jar is 1 centimeter, after sedimentation agent is added, the continuous body of dead water with Sedimentation agent and sink to plastics bottom of the barrel, after standing 3 days, water body clarification, the anhydrous continuous floating of the water surface;
6)By the photosynthetic activity that photosynthesis measurement water is continuous after 24 hours, after treatment, the continuous photosynthetic activity of water from 0.5418 mg/(L·h·g)It is reduced to 0.0694 mg/ (Lhg), its inhibiting rate is up to 87.2 %.After 20 days, substrate total nitrogen contains Amount reduces 15.2 %, and total phosphorus content reduces 6.8 %, and the content of organic matter reduces 13.7 %.

Claims (3)

1. a kind of to remove the continuous method of floating green alga water, its step is:
1) regional choice:Selection water silk floss growing power is vigorous and region of floating in blocks, and regional extent is less than or equal to 500 squares Rice;
2) preparation of algicide:The hydrogen peroxide that mass fraction is 30% is diluted to the concentration of 3%-5% with distilled water, and is put Put in the cool;
3) preparation of sedimentation agent:By bentonite and moisture content for the clay of 10%-15% mass ratioes presses 6-8:4-2 mass ratioes are prepared Into sedimentation agent;
4) consumption and spraying condition of algicide:By step 2) prepare hydrogen peroxide press 1:250 volume ratio is uniformly sprayed at The continuous surface of selected region reclaimed water, spraying time fine day 12:00-14:The continuous upgrowth situation of water is observed after 00,1-2 hour, Activity is not completely lost, this step is repeated 1-2 times;
5) addition of sedimentation agent:Algicide processed water silk floss after 3-4 hours, according to the area of Experimental Area, sedimentation agent was uniformly spread Enter in water body, every square metre of waters 5kg-10kg sedimentation agent, water silk floss sinks to water bottom therewith, makes water bottom sedimentation agent Tiling thickness is 1 centimeter -2 centimeters, after standing 1-3 days, water body clarification, the anhydrous continuous floating of the water surface.
2. a kind of removing according to claim 1 floats the continuous method of green alga water, it is characterised in that:Described processing region Reclaimed water silk floss abnormality proliferation simultaneously floats on water surface in flakes.
3. a kind of removing according to claim 1 floats the continuous method of green alga water, it is characterised in that:Described 3%-5% Hydrogen peroxide is directly sprayed on the continuous bed course for floating of water, and it is settled material to use natural sodium bentonite and clay, and its is good The water silk floss of inactivation is fixed on water bottom by absorption property, can adsorb the nutritive salt material that water silk floss is discharged.
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CN112345702A (en) * 2020-11-06 2021-02-09 四川清和科技有限公司 Method for rapidly testing algae removal effect of algaecide and determining using amount of algaecide

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JP2000153285A (en) * 1998-11-17 2000-06-06 Shinsanso Kagaku Kk Advanced oxidation method
CN101139129A (en) * 2007-08-13 2008-03-12 袁玉平 Method for processing blue algae in pool, riverway or lake
CN101624240A (en) * 2008-07-08 2010-01-13 昆山瑞仕莱斯水处理科技有限公司 Blue algae killing method
CN101880100B (en) * 2010-07-06 2011-11-16 中国科学院水生生物研究所 Water quality improving method by algae control of compound ecological environment-protection algae control agent

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CN114890485A (en) * 2022-06-09 2022-08-12 四川环科检测技术有限公司 Efficient algae removal medicament bag and preparation method and application thereof

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