CN104923084A - Internal-external pressure pre-coating type dynamic membrane support and dynamic membrane system - Google Patents
Internal-external pressure pre-coating type dynamic membrane support and dynamic membrane system Download PDFInfo
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- CN104923084A CN104923084A CN201510354291.9A CN201510354291A CN104923084A CN 104923084 A CN104923084 A CN 104923084A CN 201510354291 A CN201510354291 A CN 201510354291A CN 104923084 A CN104923084 A CN 104923084A
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- dynamic membrane
- support body
- membrane support
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- external pressure
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- 239000012528 membrane Substances 0.000 title claims abstract description 91
- 239000011248 coating agent Substances 0.000 title abstract description 4
- 238000000576 coating method Methods 0.000 title abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 53
- 230000015572 biosynthetic process Effects 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- 239000012752 auxiliary agent Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000001471 micro-filtration Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 238000000275 quality assurance Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000011001 backwashing Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920002239 polyacrylonitrile Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The invention provides an internal-external pressure pre-coating type dynamic membrane support comprising a plurality of ring sheets. The ring sheets are overlapped along the Z-axis direction and assembled and fixed through rod pieces, and a clearance is formed between every two adjacent ring sheets.
Description
Technical field
The present invention relates to dynamic membrane system, particularly relate to a kind of interior external pressure precoating formula dynamic membrane support body and dynamic membrane system.
Background technology
Enter 21 century, water treatment application of membrane separation technology is more and more extensive.Dynamic membrane separation technology, because tool counter investment cost is low, fouling membrane easily controls, low power consumption and other advantages, becomes when cephacoria study hotspot.
Dynamic Membrane (Dynamic membrane) can become again secondary film (second membrane), refers to the new film formed in microfiltration membranes, milipore filter or large aperture supporting body surface by precoating paint or activated sludge.The formation of Dynamic Membrane can slow down microfiltration membranes, the blocking of ultrafiltration face (Block) and fouling membrane (Fouling), or improves the interception capacity of macropore supporter.Dynamic Membrane is generally divided into spontaneous film and pre-coating film two type, material in the mixed liquor that spontaneous film only needs dependence to be separated, and pre-coating film then needs to add one or more specific components materials in the water be separated, and is formed by direct or precoating circulation.
Can as the material of dynamic membrane support body and dynamic membrane device form a lot, such as, with organic material cellulose acetate, polyacrylonitrile (PAN), Kynoar (PVDF), polyvinyl chloride (PVC), sintering polyethylene (PE), polysulfones (PS) etc., and inorganic material sintered ceramic, sintering metal particulate filter stick etc. support microfiltration membranes or milipore filter, and macropore through net (as plastic wire, wire netting etc.) or nonwoven cloth material, all can as the supporter of Dynamic Membrane.
Generally, the backing material sintered by plastics, pottery, metal etc. is called porous material, and stainless (steel) wire, nylon wire, polythene net and the backing material such as industrial filter cloth, non-woven fabrics are called large aperture net.Porous material and large aperture net are played a supporting role to Dynamic Membrane, so be called the supporter of Dynamic Membrane.
Visible, supporting surface of the prior art is the soft composition such as silk screen, non-woven fabrics, and the inside and outside differential pressure change of film causes soft supporting body to loosen, and making to build bridge loosens, and affects water quality.
Summary of the invention
The technical problem to be solved in the present invention is that soft supporting body loosens because the inside and outside differential pressure change of film causes Dynamic Membrane to build bridge, affects water quality.
In order to solve this technical problem, the invention provides, a kind of in external pressure precoating formula dynamic membrane support body, comprise some annular wafer, some described annular wafer superpose along Z-direction, and fixing by rod member assembling, be provided with gap between two adjacent annular wafer.
Optionally, between the upper surface of described annular wafer and inside and outside side, be provided with fillet surface, between the lower surface of described annular wafer and inside and outside side, be provided with lower fillet surface.
Optionally, the described upper and lower fillet surface of correspondence position is connected to each other.
Optionally, the described upper and lower fillet surface angle of inclination of correspondence position, size match.
Optionally, between two adjacent described annular flakes, be provided with pad, between two adjacent annular wafer, form described gap by described pad.
Optionally, an end face of described annular flake is provided with raised points, forms described gap between two adjacent annular wafer by described raised points.
Optionally, described annular flake is provided with installing hole, and described rod member passes some described installing holes along Z-direction, thus the assembling realizing some described annular flakes is fixed.
Present invention also offers a kind of dynamic membrane system, comprise card, cylindrical shell, end socket and dynamic membrane support body provided by the invention, described dynamic membrane support body is installed on described card by card hole, described cylindrical shell and end socket are individually fixed in the both sides of described card, described cylindrical shell and described card enclose formation first space, described end socket and described card enclose formation second space, and described dynamic membrane support body is positioned at the inner side of described cylindrical shell and end socket, and are communicated with described second space and the first space.
Optionally, described dynamic membrane system also comprises water tank, and described water tank is communicated to described second space and the first space respectively.
Optionally, described card is also provided with the pod apertures in order to the liquid of second space or the first space to be guided dynamic membrane support body described in inflow and outflow.
The present invention changes dynamic membrane support body supporting surface into hard material, enhances support effect, and bridge formation is not easily loosened, and effluent quality improves, and meanwhile, the present invention also enhances backwash effect; Can be used as External Pressure Type supporter, also can be used as interior die mould supporter, principle communicates, and can change as required; In addition, annular flake provided by the invention is formed by stacking, and easily processes, and cost reduces, quality assurance.
Accompanying drawing explanation
Fig. 1 is the schematic top plan view of annular wafer in one embodiment of the invention;
Fig. 2 is the side-glance shape principle schematic of annular wafer in one embodiment of the invention;
Fig. 3 is the side-glance shape principle schematic figure of annular wafer in one embodiment of the invention;
Fig. 4 is the arrangement principle schematic of dynamic membrane support body in one embodiment of the invention;
Fig. 5 is the schematic diagram of dynamic membrane support body in one embodiment of the invention;
Fig. 6 is the connection diagram of dynamic membrane support body and card in one embodiment of the invention;
Fig. 7 is the schematic diagram of dynamic membrane system in one embodiment of the invention;
Fig. 8 is the effect schematic diagram of dynamic membrane system in one embodiment of the invention;
Fig. 9 is the bridge formation schematic diagram of dynamic membrane system in one embodiment of the invention;
In figure, 1-dynamic membrane support body; 10-annular wafer; The upper fillet surface of 11-; 12-installing hole; 13-raised points; 14-upper surface; Fillet surface under 15-; 16-lower surface; 17-medial surface; 18-lateral surface; 19-rod member; 2-card; 21-card hole; 3-end socket; 31-first space; 4-cylindrical shell; 41-second space; 5-water tank.
Detailed description of the invention
Below with reference to Fig. 1 to Fig. 9, interior external pressure precoating formula dynamic membrane support body provided by the invention and dynamic membrane system are described in detail, it is optional embodiment of the present invention, can think, those skilled in the art modify to it and polish in the scope not changing the present invention's spirit and content.
Please comprehensive reference Fig. 1 to Fig. 5, the invention provides a kind of interior external pressure precoating formula dynamic membrane support body 1, comprise some annular wafer 10, some described annular wafer 10 superpose along Z-direction, and assembled fixing by rod member 19, be provided with gap between two adjacent annular wafer 10.
In the embodiment of Fig. 2 and Fig. 3 signal, be provided with fillet surface 11 between the upper surface 14 of described annular wafer 10 and inside and outside side 17,18, between the lower surface 16 of described annular wafer 10 and inside and outside side 17,18, be provided with lower fillet surface 15.Furthermore, in the embodiment of Fig. 2 signal, the described upper and lower fillet surface 11,15 of correspondence position is connected to each other.In the embodiment of Fig. 3 signal, the described upper and lower fillet surface 11,15 of correspondence position is connected by inside and outside side 17,18.Optionally, described upper and lower fillet surface 11 and 15 angle of inclination of correspondence position, size match.
Relevant described gap, optionally schemes in the embodiment do not shown in the present invention, be provided with pad between two adjacent described annular flakes, forms described gap between two adjacent annular wafer by described pad.In the embodiment shown in fig. 1, an end face of described annular flake 10 is provided with raised points 13, can be that upper surface 14 also can be located at lower surface 16, forms described gap between two adjacent annular wafer 10 by described raised points 13.
In the embodiment of Fig. 1 and Fig. 5 signal, described annular flake 10 is also provided with installing hole 12, described rod member 19 passes some described installing holes 12 along Z-direction, thus the assembling realizing some described annular flakes 10 is fixed.Described rod member 19 is chosen as screw mandrel in the present invention, and Z-direction can be defined as the direction of the annularly upper and lower end face of thin slice 10.In other words, annular wafer 10 there is installing hole 12, by screw mandrel, annular wafer 10 is superposed assembling.On annular wafer 10 and (or) lower plane be provided with raised points 13, annular wafer 10 superpose assembling time because there are these raised points 13, make between thin slice, to produce certain gap.Raised points 13 can not certainly be set, and between thin slice, fill in certain thickness pad, can produce certain gap between thin slice equally like this.
The present invention changes dynamic membrane support body supporting surface into hard material, enhances support effect, and bridge formation is not easily loosened, and effluent quality improves, and meanwhile, the present invention also enhances backwash effect; Can be used as External Pressure Type supporter, also can be used as interior die mould supporter, principle communicates, and can change as required; In addition, annular flake provided by the invention is formed by stacking, and easily processes, and cost reduces, quality assurance.
On basis described above, please comprehensive reference Fig. 6 to Fig. 9, present invention also offers a kind of dynamic membrane system, comprise card 2, cylindrical shell 4, end socket 3 and dynamic membrane support body provided by the invention 1, described dynamic membrane support body 1 is installed on described card 2 by card hole 21, described cylindrical shell 4 and end socket 3 are individually fixed in the both sides of described card 2, described cylindrical shell 4 encloses formation first space 41 with described card 2, described end socket 3 encloses with described card 2 and forms second space 31, described dynamic membrane support body 1 is positioned at the inner side of described cylindrical shell 4 and end socket 3, and be communicated with described second space 31 and the first space 41.
In the embodiment of Fig. 8 signal, described dynamic membrane system also comprises water tank 5, and described water tank 5 is communicated to described second space 31 and the first space 41 respectively.In addition, described card 2 is also provided with the pod apertures (not shown) in order to the liquid of second space 31 or the first space 41 to be guided dynamic membrane support body described in inflow and outflow.
In other words, annular wafer 10 superposes the supporter of formation one column from level to level.Single or branched dynamic membrane support body 1 are fixed on card 2, card 2 there are installing hole 21 and pod apertures (not shown), installing hole 21 is used for fixing dynamic membrane support body 1, and pod apertures is used for allowing liquid can the inside of inflow/outflow dynamic membrane support body 1.Card 2 is fixed between cylindrical shell 4 and end socket 3, forms two regions: the first space 41 and second space 31.The connection of cylindrical shell 4, end socket 3 and pipeline, valve, water pump, water tank 5 etc., just can form complete dynamic membrane system.
In prior art, bridge formation effect just refers in the aperture above filter medium the granule plugging a part of diameter and be less than filter opening diameter above medium, Here it is arch formation, after arch formation there occurs, even the particle that diameter is less than channel diameter also can be filtered.
Be described in detail below by way of the operation logic of process to interior external pressure precoating formula dynamic membrane support body provided by the invention and dynamic membrane system such as internal pressure, external pressure, backwashes:
External pressure process:
Poured into by coalescents in water tank 5, open water pump, water enters cylindrical shell 4 together with coalescents, then whole cylindrical shell 4 is full of, water enters into supporter inside by the gap on dynamic membrane support body 1, and the pipeline formed from inside flow into end socket 3, then by pipeline reflow tank 5.Coalescents in water is when water flows through dynamic membrane support body 1, and a part is through gap, and major part is dammed by gap, or self forms bridge formation.Thereafter coalescents is built bridge stop, and constantly increases the thickness of bridge formation.Bridge formation is compacted, and water can through the hole of the gap between coalescents and coalescents particle self, to dynamic membrane support body 1 intermediate flow.Suspension in water is stopped by the bridge formation that coalescents is formed, and can not enter the middle part of dynamic membrane support body 1, and the water entered in the middle part of dynamic membrane support body 1 is processed water, i.e. water purification.Connected region in the middle part of the first space 31 in such end socket 3, card hole 21, dynamic membrane support body 1 can be referred to as clean water area; The region that second space 41 and dynamic membrane support body 1 outside of cylindrical shell 4 inside are formed is referred to as former pool.The bridge formation that coalescents is formed and the former pool of dynamic membrane support body separate with clean water area.
Inside press through journey:
Coalescents is poured in water tank 5, open water pump, water enters the first space 31 in end socket 3 together with coalescents, then whole first space 31 is full of, and the inside of thermally coupled flow film support 1, water enters into supporter outside by the gap on dynamic membrane support body 1, is full of the second space 41 in whole cylindrical shell 4, then by pipeline reflow tank 5.Coalescents in water is when water flows through dynamic membrane support body 1, and a part is through gap, and major part is dammed by gap, or self forms bridge formation.Thereafter coalescents is built bridge stop, and constantly increases the thickness of bridge formation.Bridge formation is compacted, and water can through the hole of the gap between coalescents and coalescents particle self, to dynamic membrane support body 1 flows outside.Suspension in water is stopped by the bridge formation that coalescents is formed, and can not enter the outside of dynamic membrane support body 1, and the water entering dynamic membrane support body 1 outside is processed water, i.e. water purification.Connected region in the middle part of first space of such end socket 3 inside, card hole 21, dynamic membrane support body 1 is referred to as former pool; The region that the second space of cylindrical shell 4 inside and dynamic membrane support body 1 outside are formed is referred to as clean water area.The bridge formation that coalescents is formed and the former pool of dynamic membrane support body separate with clean water area.
Visible, the crack that the angle that the chamfering of upper and lower two panels annular wafer is formed is formed to upper and lower two panels annular wafer superposition is all descending (no matter inner pressed or external-compression type), because this angle exists, the coalescents of precoating is easy to form " bridge formation effect ", formative dynamics film.Suspension in former water is stopped by the outer auxiliary agent of Dynamic Membrane, and water is drill-through by the space between the hole of Dynamic Membrane coalescents particle itself and coalescents.Intermembranous pressure reduction strengthens, and by the bridge formation compacting that Dynamic Membrane auxiliary agent is formed, not easily loosens, ensure that effluent quality.The supporter of other material such as stainless steel cloth, non-woven fabrics, is easily out of shape after being under pressure, and makes the bridge formation local failure of auxiliary agent, causes auxiliary agent to leak, and the water quality of water is produced in impact.Thin slice adopts hard material, and be not easy distortion after film forming is under pressure, the bridge formation of auxiliary agent is survivable, and auxiliary agent can not leak, and the water quality of producing water keeps stable.
Backwash process:
Current superpose from upper and lower two panels annular wafer 10 crack formed and impact toward angle, the bridge formation that coalescents is formed is broken up, crack is very thin, the outside impact that flushing water is just very concentrated, the surge of every bar crack is large and even, the filter cake that filter aid can be formed is washed open from supporter and breaks up, and effectively can reduce the water yield and the time of backwash.In contrast, the supporter of other materials such as stainless steel cloth of the prior art, non-woven fabrics, Yuan Shui side is substantially identical with the area producing water side, backwash hydraulic pressure skewness, comparatively large close to water inlet, cake layer is easily rushed to open and breaks up, and backwashing water major part is from flowing away here, pressure away from place side's flushing water of water inlet is just very little, and cake layer is not easily washed out.Some position is easily washed out, and backwashing water pours off from these positions in a large number, and some position is not easy to be flushed to, and coalescents is just adsorbed on online always.
In sum, the present invention changes dynamic membrane support body supporting surface into hard material, enhances support effect, and bridge formation is not easily loosened, and effluent quality improves, and meanwhile, the present invention also enhances backwash effect; Can be used as External Pressure Type supporter, also can be used as interior die mould supporter, principle communicates, and can change as required; In addition, annular flake provided by the invention is formed by stacking, and easily processes, and cost reduces, quality assurance.
Claims (10)
1. in, an external pressure precoating formula dynamic membrane support body, is characterized in that: comprise some annular wafer, and some described annular wafer superpose along Z-direction, and fixing by rod member assembling, is provided with gap between two adjacent annular wafer.
2. interior external pressure precoating formula dynamic membrane support body as claimed in claim 1, is characterized in that: be provided with fillet surface between the upper surface of described annular wafer and inside and outside side, is provided with lower fillet surface between the lower surface of described annular wafer and inside and outside side.
3. interior external pressure precoating formula dynamic membrane support body as claimed in claim 2, is characterized in that: the described upper and lower fillet surface of correspondence position is connected to each other.
4. interior external pressure precoating formula dynamic membrane support body as claimed in claim 2, is characterized in that: the described upper and lower fillet surface angle of inclination of correspondence position, size match.
5. interior external pressure precoating formula dynamic membrane support body as claimed in claim 1, is characterized in that: be provided with pad between two adjacent described annular flakes, forms described gap between two adjacent annular wafer by described pad.
6. interior external pressure precoating formula dynamic membrane support body as claimed in claim 1, is characterized in that: an end face of described annular flake is provided with raised points, forms described gap between two adjacent annular wafer by described raised points.
7. interior external pressure precoating formula dynamic membrane support body as claimed in claim 1, it is characterized in that: described annular flake is provided with installing hole, described rod member passes some described installing holes along Z-direction, thus the assembling realizing some described annular flakes is fixed.
8. a dynamic membrane system, it is characterized in that: comprise card, cylindrical shell, end socket and one of as any in claim 1 to 7 as described in dynamic membrane support body, described dynamic membrane support body is installed on described card by card hole, described cylindrical shell and end socket are individually fixed in the both sides of described card, described cylindrical shell and described card enclose formation first space, described end socket and described card enclose formation second space, described dynamic membrane support body is positioned at the inner side of described cylindrical shell and end socket, and is communicated with described second space and the first space.
9. dynamic membrane system as claimed in claim 8, it is characterized in that: also comprise water tank, described water tank is communicated to described second space and the first space respectively.
10. dynamic membrane system as claimed in claim 8, is characterized in that: described card is also provided with the pod apertures in order to the liquid of second space or the first space to be guided dynamic membrane support body described in inflow and outflow.
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Cited By (2)
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CN111233252A (en) * | 2020-01-15 | 2020-06-05 | 北京建筑大学 | Zeolite imidazolate-like framework-horseradish peroxidase biomineralization embedding precoat, preparation thereof and application thereof in ultrafiltration membrane water purification |
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