CN104923063A - Stable and energy-saving desulfurization tower and desulfurization method for flue gas - Google Patents

Stable and energy-saving desulfurization tower and desulfurization method for flue gas Download PDF

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Publication number
CN104923063A
CN104923063A CN201510247325.4A CN201510247325A CN104923063A CN 104923063 A CN104923063 A CN 104923063A CN 201510247325 A CN201510247325 A CN 201510247325A CN 104923063 A CN104923063 A CN 104923063A
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CN
China
Prior art keywords
tower
flue gas
tower body
stable
desulfurizing
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Pending
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CN201510247325.4A
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Chinese (zh)
Inventor
林伟东
许意志
范德茗
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GUANGDONG HESTIA ENERGY SAVING & ENVIRONMENT PROTECTION Co Ltd
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GUANGDONG HESTIA ENERGY SAVING & ENVIRONMENT PROTECTION Co Ltd
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Priority to CN201510247325.4A priority Critical patent/CN104923063A/en
Publication of CN104923063A publication Critical patent/CN104923063A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a stable and energy-saving desulfurization tower. The tower comprises a tower body, wherein the upper end of the tower body is provided with a flue gas inlet; one side of the flue gas inlet is provided with a desulfurizer inlet; the interior of the tower body is provided with a mixing device; the mixing device is provided with a tapered member which is mounted on a supporting frame; the lower part of the tapered member is provided with a funnel member; the outer side of the funnel member is fixed in the interior of the tower body via a supporting rod; the lower end of the tower body is provided with a desulfurizer outlet; one side of the lower part of the tower body is connected with a chimney via a flue gas outlet; the interior of the chimney is provided with a demister; and the upper part of the demister is provided with a demister cleaner. The invnetion aims to provide the stable and energy-saving desulfurization tower capable of fully mixing gas and liquid and reducing equipment cost, and a desulfurization method for the flue gas by using the desulfurization tower.

Description

A kind of stable desulfurizing tower energy-conservation again and fume desulphurization method
Technical field
The present invention relates to a kind of method of flue gas desulfurization, more particularly, especially a kind of stable desulfurizing tower energy-conservation again and fume desulphurization method.
Background technology
Along with socioeconomic high speed development, the flue gas of generation gets more and more, containing a large amount of SO in flue gas 2deng sour gas, if be directly discharged in air, the generation of acid rain can be caused, so desulfurization process must be carried out to flue gas before discharging.Adopt gas, the reverse mode of colliding of liquid substantially in current industry, flue gas enters from desulfurizing tower bottom, three layers of downward opening spiral nozzle are arranged on top, every one deck carries desulfurizing agent by a high-lift acid-proof pump, high pressure desulfurizing agent by spiral nozzle time by high speed atomisation, the flue gas come with bottom fully mixes, and reaches the object of desulfurization.But this method needs to configure One's name is legion, expensive spiral nozzle, and in order to reach good atomizing effect, the energy consumption that the pressure loss causes also is very considerable; Key is the essence of desulfurization is that acid-base neutralization generates water-fast sulfate, because desulfurizing agent recycles, causes spiral nozzle fouling and clogging and wearing and tearing, and desulfurizing agent atomization conditions worsen, the reduction of desulfurizing tower desulfuration efficiency even cannot work.
Summary of the invention
For above-mentioned the deficiencies in the prior art, the invention provides a kind of gas-liquid mixed fully, reduce equipment cost and stable desulfurizing tower energy-conservation again and by the method for this desulfurizing tower to flue gas desulfurization.
Technical scheme of the present invention is achieved in that a kind of stable desulfurizing tower energy-conservation again, comprise tower body, described tower body upper end is provided with gas approach, it is characterized in that, described gas approach side is provided with desulfurizing agent import, mixing arrangement is provided with in described tower body, described mixing arrangement is provided with conical part, this conical part is erected on bracing frame, funnel component is provided with below described conical part, be fixed in tower body by support bar outside described funnel component, described tower body lower end is provided with desulfurizing agent outlet, below this tower body, side is connected with chimney by exhanst gas outlet, demister is provided with in described chimney, demister cleaning device is provided with above described demister.
In above-mentioned a kind of stable desulfurizing tower energy-conservation again, be provided with steady rest in described conical part, described steady rest is connected with bracing frame.
In above-mentioned a kind of stable desulfurizing tower energy-conservation again, described mixing arrangement is at least provided with three.
The present invention also provides a kind of method of flue gas desulfurization, the method of this flue gas desulfurization in circulation stock tank, extracts desulfurizing agent with an acid-proof pump to enter desulfurizing tower top, flue gas also enters from desulfurizing tower top simultaneously, desulfurizing agent and flue gas is made naturally to flow to mixing arrangement downwards, under the repeatedly dispersion and collision effect of conical part and funnel component, continuous change flow velocity and flow direction, extend the time of staying of gas liquid mixture in desulfurizing tower, make gas-liquid fully be atomized mixing, make acid-base neutralization react more abundant.
In the method for above-mentioned flue gas desulfurization, described desulfurizing agent is normal temperature limewash.
In the method for above-mentioned flue gas desulfurization, described flue-gas temperature is 80 ~ 105 DEG C.
Beneficial effect of the present invention is: only in circulatory pool, extracting desulfurizing agent with one instead of three acid-proof pumps enters desulfurizing tower top, and flue gas can automatically fully mix with desulfurizing agent flow process in desulfurizing tower and produce multiple impacts, gas liquid mixture is fully atomized, without the need to configuring spiral nozzle, decrease equipment investment, also reduce energy consumption.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 is the flow chart of the method for flue gas desulfurization of the present invention.
Fig. 3 is that gas-liquid flow is through mixing arrangement schematic diagram.
Detailed description of the invention
As shown in Figure 1, a kind of stable desulfurizing tower energy-conservation again, comprise tower body 14, described tower body 14 upper end is provided with gas approach 1, described gas approach 1 side is provided with desulfurizing agent import 2, mixing arrangement 3 is provided with in described tower body 14, this mixing arrangement 3 is at least provided with three, described mixing arrangement 3 is provided with conical part 4, this conical part 4 is erected on bracing frame 5, steady rest 13 is provided with in described conical part 4, described steady rest 13 is connected with bracing frame 5, funnel component 6 is provided with below described conical part 4, be fixed in tower body 14 by support bar 7 outside described funnel component 6, described tower body 14 lower end is provided with desulfurizing agent outlet 8, below this tower body 14, side is connected with chimney 10 by exhanst gas outlet 9, demister 12 is provided with in described chimney 10, demister cleaning device 11 is provided with above described demister 12.
As shown in Figures 2 and 3, adopt this desulfurizing tower to the method for flue gas desulfurization, in circulation stock tank, extract desulfurizing agent with an acid-proof pump and enter desulfurizing tower top, described desulfurizing agent is normal temperature limewash, simultaneous temperature is that the flue gas of 80 ~ 105 DEG C also enters from desulfurizing tower top, desulfurizing agent and flue gas is made naturally to flow to mixing arrangement 3 downwards, make when desulfurizing agent and flue gas flow to conical part 4 from the top down, desulfurizing agent and flue gas disperse to surrounding, then flow in funnel component 6 and assemble, under the effect of multiple mixing arrangement 3, desulfurizing agent and flue gas are through the repeatedly dispersion of conical part 4 and funnel component 6 and collision, continuous change flow velocity and flow direction, extend the time of staying of gas liquid mixture in desulfurizing tower, gas-liquid is made fully to be atomized mixing, acid-base neutralization is made to react more abundant, its reaction principle equation is as follows:
SO 2+H 20→H 2SO 3
H 2SO 3+Ca(OH) 2→CaSO 3
SO 2+CaSO 3→Ca(HSO 3) 2
Ca(HSO 3) 2+Ca(OH) 2→2CaSO 3
CaSO 3+O 2→CaSO 4
Solution after last fully reflection enters in circulation stock tank.
Compared with reverse desulfurization method, the energy consumption of the manner is only an acid-proof pump power of motor, saves large energy, but also eliminate whole spiral nozzle, reduce equipment investment and can guarantee long-term stable operation again, so adopt the manner to carry out desulfurization to flue gas, prospect is boundless.

Claims (6)

1. a stable desulfurizing tower energy-conservation again, comprise tower body (14), described tower body (14) upper end is provided with gas approach (1), it is characterized in that, described gas approach (1) side is provided with desulfurizing agent import (2), mixing arrangement (3) is provided with in described tower body (14), described mixing arrangement (3) is provided with conical part (4), this conical part (4) is erected on bracing frame (5), described conical part (4) below is provided with funnel component (6), described funnel component (6) outside is fixed in tower body (14) by support bar (7), described tower body (14) lower end is provided with desulfurizing agent outlet (8), side, this tower body (14) below is connected with chimney (10) by exhanst gas outlet (9), demister (12) is provided with in described chimney (10), described demister (12) top is provided with demister cleaning device (11).
2. a kind of stable desulfurizing tower energy-conservation again according to claim 1, it is characterized in that, be provided with steady rest (13) in described conical part (4), described steady rest (13) is connected with bracing frame (5).
3. a kind of stable desulfurizing tower energy-conservation again according to claim 1, it is characterized in that, described mixing arrangement (3) is at least provided with three.
4. adopt a kind of stable desulfurizing tower energy-conservation again as claimed in claim 1 to the method for flue gas desulfurization, it is characterized in that, in circulation stock tank, extract desulfurizing agent with an acid-proof pump and enter desulfurizing tower top, flue gas also enters from desulfurizing tower top simultaneously, desulfurizing agent and flue gas is made naturally to flow to mixing arrangement (3) downwards, under the repeatedly dispersion and collision effect of conical part (4) and funnel component (6), continuous change flow velocity and flow direction, extend the time of staying of gas liquid mixture in desulfurizing tower, gas-liquid is made fully to be atomized mixing, acid-base neutralization is made to react more abundant.
5. the method for flue gas desulfurization according to claim 4, is characterized in that, described desulfurizing agent is normal temperature limewash.
6. a kind of stable fume desulphurization method energy-conservation again according to claim 4, it is characterized in that, described flue-gas temperature is 80 ~ 105 DEG C.
CN201510247325.4A 2015-05-14 2015-05-14 Stable and energy-saving desulfurization tower and desulfurization method for flue gas Pending CN104923063A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105698237A (en) * 2016-04-13 2016-06-22 邹联中 Physical oil flue waste gas shielding and purifying device for smoke exhaust ventilator in food and beverage industry

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202010513U (en) * 2011-04-08 2011-10-19 武汉兴能环保技术有限公司 Downstream jet bubbling wet-method desulfurizing device
CN202410502U (en) * 2011-12-22 2012-09-05 福建省亿利达环保工程有限公司 Automatic gas and liquid mixed gas-impact spray desulfurizing and dedusting tower
CN103521063A (en) * 2013-09-09 2014-01-22 广西奥士达环境工程有限公司 Flue gas desulfurization method
CN203469805U (en) * 2013-09-09 2014-03-12 江阴市宏能科技有限公司 Absorption tower device capable of simultaneously desulfurizing and denitrifying smoke through bubbling and spraying
CN204710098U (en) * 2015-05-14 2015-10-21 广东华信达节能环保有限公司 A kind of stable desulfurizing tower energy-conservation again

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202010513U (en) * 2011-04-08 2011-10-19 武汉兴能环保技术有限公司 Downstream jet bubbling wet-method desulfurizing device
CN202410502U (en) * 2011-12-22 2012-09-05 福建省亿利达环保工程有限公司 Automatic gas and liquid mixed gas-impact spray desulfurizing and dedusting tower
CN103521063A (en) * 2013-09-09 2014-01-22 广西奥士达环境工程有限公司 Flue gas desulfurization method
CN203469805U (en) * 2013-09-09 2014-03-12 江阴市宏能科技有限公司 Absorption tower device capable of simultaneously desulfurizing and denitrifying smoke through bubbling and spraying
CN204710098U (en) * 2015-05-14 2015-10-21 广东华信达节能环保有限公司 A kind of stable desulfurizing tower energy-conservation again

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105698237A (en) * 2016-04-13 2016-06-22 邹联中 Physical oil flue waste gas shielding and purifying device for smoke exhaust ventilator in food and beverage industry

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Application publication date: 20150923