CN104910836B - One kind patch wood skin glue and preparation method thereof - Google Patents
One kind patch wood skin glue and preparation method thereof Download PDFInfo
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- CN104910836B CN104910836B CN201510257221.1A CN201510257221A CN104910836B CN 104910836 B CN104910836 B CN 104910836B CN 201510257221 A CN201510257221 A CN 201510257221A CN 104910836 B CN104910836 B CN 104910836B
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Abstract
The invention discloses one kind patch wood skin glue and preparation method thereof, the patch wood skin glue, including following raw material composition：Vinylacetate, tertiary ethylene carbonate, n-BMA, acrylic acid, methacrylic acid, environment-friendly plasticizer, polyvinyl alcohol, extraordinary cross-linking monomer, environmentally friendly response type anion emulsifier, environmentally friendly response type nonionic emulsifier and deionized water.Present invention patch wood skin glue finished product meets country's promulgation without formaldehyde, heavy metal, halide etc.《Limits of harmful substances in indoor decorating and refurnishing materials adhesive》The standards of GB18583 2008, nontoxic free from extraneous odour is safe and reliable；Moreover, after laminating for PLASTIC LAMINATED and wood skin, wood skin non yellowing, antiageing effect is good, with pliability, resistant to bending not come unglued, the good characteristic that 45 DEG C of bubbles do not come unglued for 7 days.
Description
Technical field
Wood skin glue and preparation method thereof is pasted the present invention relates to aqueous binder field, more particularly to one kind.
Background technology
Patch wood skin glue is that one kind is mainly used in PLASTIC LAMINATED (melamine plate), clamping plate, fitted with natural veneer.Current one
As use PUR or urea-formaldehyde glue.PUR is oily gum, it is necessary to first colloidal sol is reused, and contains benzene kind solvent,
Air is polluted, human health is severely compromised, in addition, using the easy aging of Hot melt adhesive plaster wood skin, by climatic effect, after half a year
Wood skin, which will start xanthochromia, comes unglued and comes off.And urea-formaldehyde glue is aqueous, but containing a large amount of formaldehyde and urea, pole is not environmentally.And
All there is the problem of needing further to improve using PUR or urea-formaldehyde glue, such as：To easily being bubbled during existing bonding wood materials,
Intolerant to bubble, pliability is poor the problems such as.
Therefore, prior art has yet to be improved and developed.
The content of the invention
It is an object of the invention to provide one kind patch wood skin glue and preparation method thereof, the patch wood skin glue be applied to wood skin and
The laminating of PLASTIC LAMINATED, can be used for wood skin and calcium silicate board, clamping plate, high-density plate and fits, to solve above-mentioned prior art
Middle patch wood skin glue is not environmentally and laminating effect needs the technical problem that further improves.
Technical scheme is as follows：
One kind patch wood skin glue, wherein, the patch wood skin glue, in parts by weight, including following raw material composition：
140~250 parts of vinylacetate, 60~100 parts of tertiary ethylene carbonate, 20~70 parts of n-BMA,
3~10 parts of acrylic acid, 3~10 parts of methacrylic acid, 50~100 parts of environment-friendly plasticizer, 18~50 parts of polyvinyl alcohol, extraordinary crosslinking
4~10 parts of monomer, environmentally friendly 3~5 parts of response type anion emulsifier, 2~5 parts of environmentally friendly response type nonionic emulsifier and deionization
430-570 parts of water；Also include initiator in the patch wood skin glue, the consumption of initiator account for vinylacetate, tertiary ethylene carbonate,
The 0.1~0.2% of butyl acrylate and acrylic acid gross mass.
Described patch wood skin glue, wherein, the extraordinary cross-linking monomer is selected from GMA, diacetone third
Acrylamide, isobornyl methacrylate, allyl glycidyl ether, GDMA, hydroxy-ethyl acrylate,
Methacrylate.
Described patch wood skin glue, wherein, the environment-friendly plasticizer is selected from epoxide modified soybean oil, ATBC, second
Acyl ATBC, dibutyl maleate, dibutyl itaconate.
Described patch wood skin glue, wherein, the environmentally friendly response type anion emulsifier is selected from sodium vinyl sulfonate, pi-allyl
Sodium sulfonate, allyloxy alkyl alcohol ether sulphonate series；The allyloxy alkyl alcohol ether sulphonate series is Japan Ai Dike
Anionic reactive type emulsifying agent SR-10, A-10, SR-3025.
Described patch wood skin glue, wherein, the environment-friendly type nonionic emulsifier is selected from allyloxy alcohol ether series, the alkene
Propoxyl group alcohol ether series is Japan Ai Dike non-ionic reaction emulsifying agents ER-10, ER-20, ER30.
Described patch wood skin glue, wherein, the initiator is the ammonium persulfate that mass fraction is 1~5% or 1~5% mistake
The aqueous solution of potassium sulfate.
Described patch wood skin glue, wherein, in the raw material composition of the patch wood skin glue, count by weight, also including anti-corrosion
2-4 parts of agent；The preservative is Kathon CG.
A kind of preparation method of patch wood skin glue as described above, wherein, comprise the steps：
Deionized water is put into reactor, polyvinyl alcohol rising temperature for dissolving is added, is cooled to 75~85 DEG C；
By reaction monomers vinylacetate, tertiary ethylene carbonate, n-BMA, acrylic acid, methacrylic acid
It is put into dropping tank and is well mixed after metering；
Extraordinary cross-linking monomer, environmentally friendly response type anion emulsifier, environmentally friendly response type nonionic Emulsion are added in reactor
Agent；
Mix monomer is added dropwise, while the initiator of total monomer weight 0.1~0.2% is added dropwise, and was added dropwise in 3~5 hours
Complete；
85~95 DEG C of 40~60min of curing are warming up to after being added dropwise to complete；
Be cooled to 35~45 DEG C, add environment-friendly plasticizer it is well mixed after discharging filter and package.
The present invention by the optimization and improvement to existing formula, make present invention patch wood skin glue finished product without formaldehyde, heavy metal,
Halide etc., meets country's promulgation《Limits of harmful substances in indoor decorating and refurnishing materials adhesive》GB18583-2008 is marked
Standard, nontoxic free from extraneous odour is safe and reliable；Moreover, with lasting internal plasticization and pliability, bonding force is strong, water-fast, resistance to acids and bases
Good, non-aging, wet strength is high, has fabulous anti-flammability, is not trickled at 120 DEG C above freezing, subzero 50 DEG C are not cracked, user
Just, it is adapted to mechanical gluing and manual gluing.After laminating for PLASTIC LAMINATED and wood skin, wood skin non yellowing, antiageing effect is good, tool
There is pliability, resistant to bending not come unglued, the good characteristic that 45 DEG C of bubbles do not come unglued for 7 days.
Embodiment
It is real below by way of being described in detail and lifting to make the objects, technical solutions and advantages of the present invention clearer, clear and definite
The present invention is described in more detail for example.
The present invention provides a kind of patch wood skin glue, passes through adjustment and optimization of C/C composites so that present invention patch wood skin glue be it is aqueous,
Environmental protection, without organic solvent, benzene class, content of formaldehyde meet the GB18583-2008 mandatory standards of country's promulgation, and laminating
Excellent effect.
Specifically, the patch wood skin glue, in parts by weight, including following raw material composition：
140~250 parts of vinylacetate, 60~100 parts of tertiary ethylene carbonate, 20~70 parts of n-BMA,
3~10 parts of acrylic acid, 3~10 parts of methacrylic acid, 50~100 parts of environment-friendly plasticizer, 18~50 parts of polyvinyl alcohol, extraordinary crosslinking
4~10 parts of monomer, environmentally friendly 3~5 parts of response type anion emulsifier, 2~5 parts of environmentally friendly response type nonionic emulsifier and deionization
430-570 parts of water；Also include initiator in the patch wood skin glue, the consumption of initiator accounts for the 0.1~0.2% of monomer gross mass.
Wherein, the extraordinary cross-linking monomer can be selected from GMA, DAAM, methyl
Isobornyl acrylate, allyl glycidyl ether, GDMA, hydroxy-ethyl acrylate, methacrylic acid
Hydroxy butyl ester.
The environment-friendly plasticizer can be selected from epoxide modified soybean oil, ATBC, tributyl 2-acetylcitrate, horse
Come dibutyl phthalate, dibutyl itaconate.
The environmentally friendly response type anion emulsifier can be selected from sodium vinyl sulfonate, ALS, allyloxy
Alkyl alcohol ether sulphonate series.The allyloxy alkyl alcohol ether sulphonate series can be Japan's Ai Dike anionic reactive types
Emulsifying agent SR-10, A-10, SR-3025.
The environment-friendly type nonionic emulsifier can be selected from allyloxy alcohol ether series, and the allyloxy alcohol ether series can
Think Japanese Ai Dike non-ionic reactions emulsifying agent ER-10, ER-20, ER30.
The initiator is the aqueous solution of the ammonium persulfate that mass fraction is 1~5% or 1~5% potassium peroxydisulfate.
Patch wood skin glue provided by the present invention employs multiple unit resins and enters copolymerization, has obtained multi-copolymerization emulsion, has led to
Optimization and improved formulations are crossed, superpower resistant to hydrolysis ability and weatherability changing capability (high temperature not desaturation, low temperature not tortoise is made it have
Split), there is lasting internal plasticization performance again, the function such as bonding strength is extremely strong.Would not be by because of bubble with the sheet material of this glue
Water, high/low temperature, the influence of thump and there is the phenomenon bubbled, come unglued.
Further, in the patch wood skin glue, 2-4 parts of preservative can also be included.The preservative can be Kathon CG, institute
Stating can selectively add as needed in patch wood skin glue, and its main function is optimization effective life.
The patch wood skin glue preparation method is also provided in the present invention, comprised the steps：
(1) deionized water is put into reactor, polyvinyl alcohol rising temperature for dissolving is added, is cooled to 75~85 DEG C；
(2) by reaction monomers vinylacetate, tertiary ethylene carbonate, n-BMA, acrylic acid, metering system
It is put into dropping tank and is well mixed after acid metering；
(3) extraordinary cross-linking monomer, environmentally friendly response type anion emulsifier, environmentally friendly response type nonionic are added in reactor
Emulsifying agent；
(4) mix monomer is added dropwise, while the initiator of total monomer weight 0.1~0.2% is added dropwise, and was dripped in 3~5 hours
Add into；
(5) 85~95 DEG C of 40~60min of curing are warming up to after being added dropwise to complete；
(6) be cooled to 35~45 DEG C, add environment-friendly plasticizer and preservative it is well mixed after discharging filter and package.
Patch wood skin glue provided in the present invention, with lasting internal plasticization and pliability, bonding force is strong, water-fast, resistance to
Acid-base property is good, non-aging, and wet strength is high, has fabulous anti-flammability, is not trickled at 120 DEG C above freezing；Subzero 50 DEG C are not cracked, nothing
Malicious free from extraneous odour, it is safe and reliable, it is easy to use.Fitting for PLASTIC LAMINATED and wood skin is applicable not only to, various sheet materials are also suitable for (fine
Tie up plate, clamping plate, hard board) pasted with more than 0.3mm wood skin, it is adapted to machinery gluing and manual gluing.
And compared with urea-formaldehyde glue, aqueous plaster wood skin glue of the present invention has advantages below：(1) urea-formaldehyde glue is solid using preceding needing
Agent is well mixed, it is necessary to use as early as possible, and present invention patch wood skin glue need not add curing agent, can directly use；(2) use
When ureaformaldehyde glue wood skin and sheet material, urea-formaldehyde glue can ooze out from the wooden eye of wood skin, and can block wooden eye, in veneer surface japanning
Afterwards, veneer surface is because the urea-formaldehyde glue oozed out causes veneer surface after japanning uneven, and uses present invention patch wood skin glue not
Wooden eye can be blocked, colored paint can penetrate into wooden eye, and colouring is uniform natural；(3) because urea-formaldehyde glue can block wooden eye, therefore in hot pressing
In, the air remained between wood skin and sheet material can not be appeared from wooden eye, foaming phenomena occur, and present invention patch wood skin glue is in warm
Residual air can shed from wooden eye during pressure, prevent foaming phenomena；(4) due to there is organic volatile in urea-formaldehyde glue
Matter, in hot pressing, produces irritative gas, and human respiratory tract is caused to stimulate and environment is polluted, and this hair
Bright patch wood skin glue is due to being water-base cement, without organic volatile substance, and unpleasant or stimulation row will not be also produced even if in hot pressing
Gas.
With reference to embodiment, the invention will be further described.
Embodiment 1
Patch wood skin glue in the present embodiment, in parts by weight, including following raw material composition：
143 parts of vinylacetate, 61 parts of tertiary ethylene carbonate, 20 parts of n-BMA, 3 parts of acrylic acid, methyl
3.2 parts of acrylic acid, 52 parts of environment-friendly plasticizer, 18 parts of polyvinyl alcohol, 4 parts of ATBC, sodium vinyl sulfonate 3.5 part, day
2 parts of ER-102 parts of Ben Aidike non-ionic reaction emulsifying agents, 430 parts of deionized water and preservative.
Its preparation method, comprises the steps：
(1) deionized water is put into reactor, polyvinyl alcohol rising temperature for dissolving is added, is cooled to 75~85 DEG C；
(2) by reaction monomers vinylacetate, tertiary ethylene carbonate, n-BMA, acrylic acid, metering system
It is put into dropping tank and is well mixed after acid metering；
(3) extraordinary cross-linking monomer, environmentally friendly response type anion emulsifier, environmentally friendly response type nonionic are added in reactor
Emulsifying agent；
(4) mix monomer is added dropwise, while the persulfuric acid that the initiator quality fraction that total monomer weight 0.1% is added dropwise is 1%
Aqueous ammonium, and be added dropwise to complete in 3~5 hours；
(5) 85~95 DEG C of 40~60min of curing are warming up to after being added dropwise to complete；
(6) be cooled to 35~45 DEG C, add environment-friendly plasticizer and preservative it is well mixed after discharging filter and package.
Patch wood skin glue obtained by the present embodiment is subjected to performance detection, testing result is as shown in table 1.Fire shield surface is carried out
Sanding, patch wood skin glue is equably glued in fire shield surface, every square metre of 80~120 grams of glue-spread (machine paintings), with will be wooden
Skin is fitted, and is using pressure time：Cold pressing 1.5~2 hours, hot pressing 3-5 minutes, pressure is 3-5kg/cm2, check veneer surface
Do not bubble and (irritative gas is not given out in hot pressing).After 24 hours, varnish and 80 DEG C of infrared dryings are crossed, are checked
Veneer surface is not bubbled.Be made after product, the PLASTIC LAMINATED posted be soaked in 45 DEG C of water 7 days, do not ftracture it is non-foaming not
Deformation, can also normally be used after drying.The PLASTIC LAMINATED posted is placed under 750W ultraviolet lamps, Continuous irradiation 72h has no
Aging phenomenon.The PLASTIC LAMINATED posted is bent to angle in 120-160 °, not come unglued.
The embodiment 1 of table 1 pastes the performance indications of wood skin glue
Embodiment 2
Patch wood skin glue in the present embodiment, in parts by weight, including following raw material composition：
200 parts of vinylacetate, 85 parts of tertiary ethylene carbonate, 46 parts of n-BMA, 6.5 parts of acrylic acid, first
5.8 parts of base acrylic acid, 82 parts of environment-friendly plasticizer, 32 parts of polyvinyl alcohol, 7.9 parts of tributyl 2-acetylcitrate, ALS 4
530 parts of part, ER-204 parts of Japan's Ai Dike non-ionic reaction emulsifying agents and deionized water.
Its preparation method, comprises the steps：
(1) deionized water is put into reactor, polyvinyl alcohol rising temperature for dissolving is added, is cooled to 75~85 DEG C；
(2) by reaction monomers vinylacetate, tertiary ethylene carbonate, n-BMA, acrylic acid, metering system
It is put into dropping tank and is well mixed after acid metering；
(3) extraordinary cross-linking monomer, environmentally friendly response type anion emulsifier, environmentally friendly response type nonionic are added in reactor
Emulsifying agent；
(4) mix monomer is added dropwise, while the persulfuric acid that the initiator quality fraction that total monomer weight 0.2% is added dropwise is 3%
Aqueous solutions of potassium, and be added dropwise to complete in 3~5 hours；
(5) 85~95 DEG C of 40~60min of curing are warming up to after being added dropwise to complete；
(6) be cooled to 35~45 DEG C, add environment-friendly plasticizer it is well mixed after discharging filter and package.
Patch wood skin glue obtained by the present embodiment is subjected to performance detection, testing result is as shown in table 2.Fire shield surface is carried out
Sanding, patch wood skin glue is equably glued in fire shield surface, every square metre of 80~120 grams of glue-spread (machine painting), with by wood skin
Fit, be using pressure time：Cold pressing 1.5~2 hours, hot pressing 3-5 minutes, pressure is 3-5kg/cm2, check veneer surface
There is no bubble (irritative gas is not given out in hot pressing).After 24 hours, varnish and 80 DEG C of infrared dryings are crossed, are checked
Veneer surface is not bubbled.Be made after product, the PLASTIC LAMINATED posted be soaked in 45 DEG C of water 7 days, do not ftracture it is non-foaming not
Deformation, can also normally be used after drying.The PLASTIC LAMINATED posted is placed under 750W ultraviolet lamps, Continuous irradiation 72h has no
Aging phenomenon.The PLASTIC LAMINATED posted is bent into angle not come unglued in 120-160 °.
The embodiment 2 of table 2 pastes the performance indications of wood skin glue
Embodiment 3
Patch wood skin glue in the present embodiment, in parts by weight, including following raw material composition：
250 parts of vinylacetate, 98 parts of tertiary ethylene carbonate, 70 parts of n-BMA, 9.8 parts of acrylic acid, first
10 parts of base acrylic acid, 100 parts of environment-friendly plasticizer, 49 parts of polyvinyl alcohol, 10 parts of dibutyl maleate, Japan's Ai Dike anion are anti-
Answer SR-105 parts of type emulsifying agent, ER305 parts of Japan's Ai Dike non-ionic reaction emulsifying agents and 570 parts of deionized water and preservative
2.5 parts.
Its preparation method, comprises the steps：
(1) deionized water is put into reactor, polyvinyl alcohol rising temperature for dissolving is added, is cooled to 75~85 DEG C；
(2) by reaction monomers vinylacetate, tertiary ethylene carbonate, n-BMA, acrylic acid, metering system
It is put into dropping tank and is well mixed after acid metering；
(3) extraordinary cross-linking monomer, environmentally friendly response type anion emulsifier, environmentally friendly response type nonionic are added in reactor
Emulsifying agent；
(4) mix monomer is added dropwise, while the persulfuric acid that the initiator quality fraction that total monomer weight 0.16% is added dropwise is 2%
Aqueous solutions of potassium, and be added dropwise to complete in 3~5 hours；
(5) 85~95 DEG C of 40~60min of curing are warming up to after being added dropwise to complete；
(6) be cooled to 35~45 DEG C, add environment-friendly plasticizer and preservative it is well mixed after discharging filter and package.
Patch wood skin glue obtained by the present embodiment is subjected to performance detection, testing result is as shown in table 3.Fire shield surface is carried out
Sanding, patch wood skin glue is equably glued in fire shield surface, every square metre of 80~120 grams of glue-spread (machine painting), with by wood skin
Fit, be using pressure time：Cold pressing 1.5~2 hours, hot pressing 3-5 minutes, pressure is 3-5kg/cm2, check veneer surface
There is no bubble (irritative gas is not given out in hot pressing).After 24 hours, varnish and 80 DEG C of infrared dryings are crossed, are checked
Veneer surface is not bubbled.Be made after product, the PLASTIC LAMINATED posted be soaked in 45 DEG C of water 7 days, do not ftracture it is non-foaming not
Deformation, can also normally be used after drying.The PLASTIC LAMINATED posted is placed under 750W ultraviolet lamps, Continuous irradiation 72h has no
Aging phenomenon.The PLASTIC LAMINATED posted is bent into angle not come unglued in 120-160 °.
The embodiment 3 of table 3 pastes the performance indications of wood skin glue
In summary, compared with prior art, its advantage is the present invention：(1) materials environmental protection, finished product is free of formaldehyde, a huge sum of money
Category, halide etc., meet country's promulgation《Limits of harmful substances in indoor decorating and refurnishing materials adhesive》GB18583-2008
Standard；(2) product is aqueous, and solidification is not afraid of water logging after drying；(3) after the laminating for being used for PLASTIC LAMINATED and wood skin, wood skin non yellowing,
Antiageing effect is good, with pliability, resistant to bending not come unglued, and 45 DEG C of bubbles do not come unglued for 7 days；(3) low cost.
It should be appreciated that the application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can
To be improved or converted according to the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect scope.
Claims (4)
1. one kind patch wood skin glue, it is characterised in that the patch wood skin glue, in parts by weight, mainly including following raw material group
Into：
140~250 parts of vinylacetate, 60~100 parts of tertiary ethylene carbonate, 20~70 parts of n-BMA, propylene
Sour 3~10 parts, 3~10 parts of methacrylic acid, 50~100 parts of environment-friendly plasticizer, 18~50 parts of polyvinyl alcohol, extraordinary cross-linking monomer
4~10 parts, environmentally friendly 3~5 parts of response type anion emulsifier, 2~5 parts of environmentally friendly response type nonionic emulsifier and deionized water
430-570 parts；Also include initiator in the patch wood skin glue, the consumption of initiator accounts for vinylacetate, tertiary ethylene carbonate, third
The 0.1~0.2% of olefin(e) acid butyl ester and acrylic acid gross mass；
The extraordinary cross-linking monomer is selected from GMA, DAAM, methacrylic acid isoborneol
Ester, allyl glycidyl ether, GDMA, hydroxy-ethyl acrylate, methacrylate；
The environment-friendly plasticizer is selected from epoxide modified soybean oil, ATBC, tributyl 2-acetylcitrate, the fourth of maleic acid two
Ester, dibutyl itaconate；
The environmentally friendly response type anion emulsifier is selected from sodium vinyl sulfonate, ALS, allyloxy alkyl alcohol ether
Sulfonate series；Allyloxy alkyl alcohol ether sulphonate series is Japan Ai Dike anionic reactive type emulsifying agents SR-10,
A-10、SR-3025；
The environment-friendly type nonionic emulsifier is selected from allyloxy alcohol ether series, and the allyloxy alcohol ether series is Japan Ai Di
Section non-ionic reaction emulsifying agent ER-10, ER-20, ER30.
2. patch wood skin glue according to claim 1, it is characterised in that the initiator is the mistake that mass fraction is 1~5%
The aqueous solution of ammonium sulfate or 1~5% potassium peroxydisulfate.
3. patch wood skin glue according to claim 1, it is characterised in that in the raw material composition of the patch wood skin glue, by weight
Number meter, also including 2-4 parts of preservative；The preservative is Kathon CG.
4. the preparation method of a kind of patch wood skin glue as described in claims 1 to 3 is any, it is characterised in that comprise the steps：
Deionized water is put into reactor, polyvinyl alcohol rising temperature for dissolving is added, is cooled to 75~85 DEG C；
By reaction monomers vinylacetate, tertiary ethylene carbonate, n-BMA, acrylic acid, methacrylic acid metering
After be put into dropping tank be well mixed；
Extraordinary cross-linking monomer, environmentally friendly response type anion emulsifier, environmentally friendly response type nonionic emulsifier are added in reactor；
Mix monomer is added dropwise, while the initiator of total monomer weight 0.1~0.2% is added dropwise, and was added dropwise to complete in 3~5 hours；
85~95 DEG C of 40~60min of curing are warming up to after being added dropwise to complete；
Be cooled to 35~45 DEG C, add environment-friendly plasticizer it is well mixed after discharging filter and package.
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| CN106221590A (en) * | 2016-08-19 | 2016-12-14 | 佛山市三水永恒达粘合剂有限公司 | A kind of adhesive used for textiles and preparation method thereof |
| CN106189877A (en) * | 2016-08-19 | 2016-12-07 | 佛山市三水永恒达粘合剂有限公司 | A kind of aggretion type solid wood splicing adhesive and preparation method thereof |
| CN106221622A (en) * | 2016-08-19 | 2016-12-14 | 佛山市三水永恒达粘合剂有限公司 | A kind of splicing adhesive of high-adhesive-strength and preparation method thereof |
| CN107236488A (en) * | 2017-05-16 | 2017-10-10 | 东莞市三宏胶粘材料有限公司 | A kind of wood skin bonds special-purpose aqueous adhesive and preparation method thereof |
| CN107353852B (en) * | 2017-06-21 | 2019-04-23 | 顶立新材料科技有限公司 | A kind of preparation method of the polyvinyl acetate woodworking adhesive stick of long open hour |
| CN107513120A (en) * | 2017-08-18 | 2017-12-26 | 佛山市永恒达新材料科技有限公司 | Preparation method for stainless steel and the gluing adhesive of rubber |
| CN108164635A (en) * | 2017-12-30 | 2018-06-15 | 上海巴德富实业有限公司 | A kind of cracking resistance flexibility uncle the third lacquer lotion and preparation method thereof |
| CN109400794B (en) * | 2018-09-29 | 2020-11-27 | 佛山市三水协佳化工有限公司 | Synthetic method of resin for leather edge oil |
| CN110423577A (en) * | 2019-08-12 | 2019-11-08 | 四川顶立胶业有限公司 | Open compressed wood hide glue of overlength and preparation method thereof |
| CN111635717A (en) * | 2020-07-01 | 2020-09-08 | 顶立新材料科技有限公司 | Soap-free polymeric waterproof paint waterproof veneer glue and preparation method thereof |
| CN114031709A (en) * | 2021-10-20 | 2022-02-11 | 顶立新材料科技有限公司 | High-solid low-viscosity large-particle-size polyvinyl acetate emulsion and preparation method thereof |
| CN115353840B (en) * | 2022-09-30 | 2023-10-27 | 广西里尔新材料有限公司 | Water-based adhesive for cast-in-situ runway and preparation method thereof |
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| CN103952100B (en) * | 2013-10-12 | 2016-01-20 | 台州市顶立胶粘剂有限公司 | Environment-friendly adhesive for hot-fix rhinestone polishing processing of crystals and preparation method thereof |
| CN103709971B (en) * | 2013-12-04 | 2015-08-19 | 台州市顶立胶粘剂有限公司 | A kind of two component splicing adhesive emulsion and synthetic method thereof |
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