CN104897850B - A kind of portable air toxic biological detection device - Google Patents

A kind of portable air toxic biological detection device Download PDF

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Publication number
CN104897850B
CN104897850B CN201510217840.8A CN201510217840A CN104897850B CN 104897850 B CN104897850 B CN 104897850B CN 201510217840 A CN201510217840 A CN 201510217840A CN 104897850 B CN104897850 B CN 104897850B
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China
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detection
room
syringe
container
mainframe box
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Expired - Fee Related
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CN201510217840.8A
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Chinese (zh)
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CN104897850A (en
Inventor
姜剑
岳川
姜孟希
张栩晨
牟赵杰
李晓玲
郝斌
耿波
管琛
贾玉玺
刘占涛
岳旺
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Qingdao Co Ltd Of Prosperous Middle Sky Innovation Biological Medicine Technological Research Institute
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Qingdao Co Ltd Of Prosperous Middle Sky Innovation Biological Medicine Technological Research Institute
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Publication of CN104897850A publication Critical patent/CN104897850A/en
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Abstract

The invention belongs to gas toxic biological detection technique field, relate to a kind of portable air toxic biological detection device, mainframe box offers battery compartment, wall folder cave and sensing chamber, the first room of detection, detection seed cell and detection tail room are equipped with sealing baffle, detection first bottom, room pipeline docks with air inlet, detection tail room tip duct docks with the air inlet port of getter device, and the air outlet of getter device connects with gas outlet, and getter device is provided with barometric damper;Syringe is detachable docks with detection for the right-hand member of detection tail room, and joint is embedded with gas flowmeter, and the detection syringe other end is used for placing the detection container of built-in running water and zebra fish;Mainframe box is provided with observation window, display, power switch and timer switch, and display is connected with power-supply system by timer switch, and power switch electrical connection controls getter device and power-supply system;This device structure novelty, economical and practical, accurately, detection range wide spectrum, range is wide in detection.

Description

A kind of portable air toxic biological detection device
Technical field:
The invention belongs to gas toxic biological detection technique field, be specifically related to a kind of portable air toxicity raw Analyte detection device, it is adaptable to rescue and relief work, geological exploration, travel life, field rescue, industrial environment inspection Survey, urban waste gas detection, underground installation environmental monitoring, domestic environment detection etc., it is possible to effectively detect sky Whether gas contains noxious material.
Background technology:
Produce or life process in, have the factors such as numerous physics, chemistry, biology threaten human life and Property safety, one of most important of which stealth killer is toxic and harmful, common are chlorine, light Gas, surpalite, sulfur dioxide, nitrogen oxides, formaldehyde, ammonia, ozone, carbon monoxide, hydrogen sulfide, The thousands of kinds of different toxic and harmfuls that and laboratory industrial with hydrocyanic acid etc. produces, owing to major part has poison gas Body colorless and odorless, people are difficult to discover for the moment, but are chronically at and the most then can cause slow poisoning.In recent years The most serious with industrial expansion air pollution, haze, PM2.5, dust, vehicle exhaust, formaldehyde, What's frequently heard can be repeated in detail already for the nouns such as nitrogen oxides, big discharges to industrial waste gas, little to life staying idle at home finishing, The problems such as dismounting, gas leak, all affect the normal life of people, but existing gas detection equipment All there is detection range not wide spectrum, it is impossible to be detected simultaneously by air defects such as biological poisonous and hazardous materials.
The most general is to represent the pollution level of air, i.e. surrounding air with air pollution index PM 2.5 The content concn of the middle aerodynamics equivalent diameter particulate matter less than or equal to 2.5 microns, it contains in atmosphere Amount concentration is the highest, just represents air pollution the most serious;But its scope is the most general, it is impossible to effective expression is empty In gas, the concrete toxicity of poisonous and harmful substance and interaction between it, more can not accurately measure much dense People's existence it has been unsuitable in the range of degree.Although prior art exists numerous gas measuring apparatus, analysis Equipment, but the choosing of the undispersed infrared method used, gas chromatography, the Saltzman method of improvement, ion Select the method such as electrode method, formaldehyde absorption-Pararosaniline AAS, be used for detect carbon monoxide, benzene, During the toxic and harmfuls such as toluene, dimethylbenzene, two change nitrogen, sulfur dioxide, ammonia, all can only realize the most several The detection of item gas, pernicious gas detection spectrum is narrow, not only can not accomplish comprehensive covering of various toxic gas, And cost is high, it is big to spend, the time is long, it is difficult to be generally applicable in daily life.Such as Chinese patent 201420774666.8 disclosed a kind of intelligent online gas detection analyzer, it is possible to fuel gas and oxygen Detect, but cannot accurately detect whether air ambient is suitable to human body;Chinese patent 201420650759.X Disclosed a kind of VOC gas and NMHC gas-detecting device, although this device is capable of detecting when people The gas that body is harmful, but manufacturing cost is higher, floor space is relatively big, be difficult to extensively apply;Chinese patent 201410756919.3 disclosed a kind of portable micro gas detecting system, although this equipment solves volume Huge, be difficult to technical problems such as carrying, but still can not very guarantee the security of air ambient.
It is known that the mankind and other animals have numerous similitude to the accreditation of environment and adaptation, and very The sense of smell of many animals, the sense of taste and to the reaction sensitivity of poisonous substance all on the mankind, it is contemplated that if animal can Normally survive under certain air ambient, then this air ambient is the most safer;Therefore, Inventor concentrates on studies through for many years, and creative has carried out preferable combination, i.e. by biology and environmentology Use zebra fish, black lotus lamp, head Triphoturus and clown lamp fish etc. that vertebrate class is close with human gene As natural detection instrument, to realize the detection to air ambient complexity toxicant, overcome existing equipment To the air venomous injurant quality detection narrow defect of spectrum, not only detection wide spectrum and sensitive, the most forward-looking with Practicality.
Summary of the invention:
It is an object of the invention to the shortcoming overcoming prior art to exist, seeking design provides a kind of portable sky Gas toxic biological detection device, the method eluted by gradient water body, gather poisonous and harmful substance in air, And by the fingerling using vertebrate class to be close with human gene, the toxicity in gas is reached comprehensive Performance detects, to guarantee the safety of air ambient.
To achieve these goals, the gas toxic biological detection apparatus main body structure that the present invention relates to includes main Cabinet, battery compartment, wall press from both sides cave, display, power switch, barometric damper, timer switch, give vent to anger Mouth, getter device, detection syringe, detection container, wall folder, gas flowmeter, sealing baffle, detection Tail room, enclosed switch, sensing chamber, detection seed cell, the first room of detection, air inlet, observation window and pipeline, interior The mainframe box of empty formula body structure offers the battery compartment of internal electric source system and the wall folder cave of hollow structure, Being provided with the wall folder of drawing and pulling type structure in wall folder cave, fixedly secured in mainframe box have by the first room of detection, detection The sensing chamber of the most through docking in room and detection tail room composition, in the first room of detection, detection seed cell and detection tail room Be provided with structure identical by the sealing baffle of enclosed switch connecting move control, the pipe that the first bottom, room of detection is offered The air inlet that road is offered with mainframe box left upper end docks, with the door of knob structure on air inlet, and detection The pipeline that tail ceiling end is offered docks with the air inlet port of getter device, the air outlet of getter device with offer Connect in the gas outlet of mainframe box upper right side, getter device is provided with barometric damper for controlling gas stream Amount;The right-hand member of detection tail room is embedded on the wall body of mainframe box and by helicitic texture and the one of detection syringe Holding detachable docking, joint is embedded with gas flowmeter for detecting air mass flow, detection syringe The other end is placed with detection container, equipped with the inspection that running water and 1-3 are the most healthy in the detection container of enclosed construction Survey fish to be used for detecting air toxic;Transparent observation window is offered for observing on mainframe box above sensing chamber Sensing chamber, mainframe box is additionally provided with display, power switch and timer switch, and display passes through timing Device switch is connected with the power-supply system in battery compartment, and power switch electrical connection controls getter device and battery compartment The break-make of middle power-supply system.
Preferably, detection fish includes zebra fish, black lotus lamp fish, head Triphoturus, clown lamp fish etc..
Preferably, sensing chamber also includes bubble generator and baffle plate limiter, the first room of detection, detection seed cell It is mounted on bubble generator with on the bottom pipeline of detection tail room;Baffle plate limiter is protruding right angle block Shape structure.
Preferably, can be detachable with one and above detection seed cell between the first room of detection and detection tail room Seal docking, pipeline that the pipeline that the first ceiling end of detection is offered is offered with detection bottom, seed cell, detect Zi Shiding The pipeline that end is offered connection the most corresponding with the pipeline that detection bottom, tail room is offered, it is achieved air is entered by air inlet The first room of the most through detection, detection seed cell and detection tail room after entering;By detection syringe to detection during detection Room is injected running water or the running water dissolved with surfactant.
The detection syringe body structure that the present invention relates to includes circular hole cutter, flexible pipe and spiral interface, cylinder One end of the detection syringe of shape pipeline configuration is that spiral interface is for detachable right with the right-hand member of detection tail room Connect, be provided with the circular hole cutter of protruding laminated structure inside the other end of detection syringe for cutting open detection container Sealing, the diameter of circular hole cutter less than detection syringe diameter, detection syringe middle part be soft Pipe.
The agent structure of the detection container that the present invention relates to includes circular hole tongue and groove, end cover and sealing film, The openend of the detection container of tubular structure is provided with circular hole tongue and groove, equipped with cladding sealing film on circular hole tongue and groove End cover;The diameter of circular hole tongue and groove is more than the diameter of circular hole cutter, the diameter of detection container and detection note The difference of the diameter of emitter is 0.1-0.5 millimeter (mm), the most healthy equipped with running water and 1-3 in detection container Detection fish;During use, being downwardly in detection syringe by the end cover of detection container, circular hole cutter touches Cut after contacting sealing film and be socketed in circular hole tongue and groove, the running water in detection container and detection fish Enter in sensing chamber along detection syringe.
Preferably, a diameter of 10 100mm of described detection syringe, height is 10 2000mm;Institute Stating a diameter of 10 100mm of detection container, height is 10 500mm, and the volume of its built-in running water is The 1/10 9/10 of detection container own vol;Described detection syringe can be as running water before detection or dissolved with table The flow in pipes of the running water of face activating agent and detection terminate the discharge line of rear sewage, detection first room, detection Running water in seed cell and detection tail room or the injection rate dissolved with the running water of surfactant are 5 40000 millis Rise (ml);Described gas flow is calculated as small-sized conventional equipment of the prior art, and described bubble generator is Cellular bubble generator.
The present invention compared with prior art, first pass through the running water in sensing chamber or dissolved with surfactant from Water carries out washing to poisonous and harmful substance in gas and retains, then is detected by the time-to-live of zebra fish The toxicity of poisonous and harmful substance in gas, i.e. detects the whole of all substances in gas by the method for biological detection Body toxicity, and it is not specific, single harmful toxic matter;This device structure novelty, design science, warp Ji practicality, safe and reliable, simple and effective, detection is accurate, pernicious gas detection range wide spectrum, range Extensively.
Accompanying drawing illustrates:
Fig. 1 is the agent structure principle schematic of the present invention.
Fig. 2 is the cross-section structure principle schematic of the sensing chamber related to of the present invention.
Fig. 3 is the structure for amplifying schematic diagram of the baffle plate limiter that the present invention relates to.
Fig. 4 is the agent structure principle schematic of the detection syringe that the present invention relates to.
Fig. 5 is the agent structure principle schematic of the detection container that the present invention relates to.
Detailed description of the invention:
Below in conjunction with the accompanying drawings and by embodiment the present invention is made further description.
Embodiment 1:
Air toxic biological monitor agent structure (as shown in Figure 1) that the present embodiment relates to includes main frame Case 1, battery compartment 2, wall folder cave 3, display 4, power switch 5, barometric damper 6, timer switch 7, gas outlet 8, getter device 9, detection syringe 10, detection container 11, wall folder 12, gas flowmeter 13, sealing baffle 14, detection tail room 15, enclosed switch 16, sensing chamber 17, detection seed cell 18, detection First room 19, air inlet 20, observation window 21 and pipeline 22, offer in the mainframe box 1 of hollow type body structure Having the battery compartment 2 of internal electric source system and the wall folder cave 3 of hollow structure, wall folder is provided with drawing and pulling type knot in cave 3 The wall folder 12 of structure, fixedly secured in mainframe box 1 have by the first room 19 of detection, detection seed cell 18 and detection tail room The sensing chamber 17 of 15 the most through docking compositions, in the first room 19 of detection, detection seed cell 18 and detection tail room 15 Be provided with structure identical by the sealing baffle 14 of enclosed switch 16 connecting move control, the first bottom, room 19 of detection The air inlet 20 that the pipeline 22 offered is offered with mainframe box 1 left upper end docks, with knob on air inlet 20 The door of formula structure, the pipeline 22 that detection top, tail room 15 is offered docks with the air inlet port of getter device 9, The air outlet of getter device 9 connects with the gas outlet 8 being opened in mainframe box 1 upper right side, getter device 9 On barometric damper 6 is installed for controlling gas flow;The right-hand member of detection tail room 15 is embedded at mainframe box 1 Wall body on and detachable docked with the one end detecting syringe 10 by helicitic texture, joint is embedded with Gas flowmeter 13 is used for detecting air mass flow, and the other end of detection syringe 10 is placed with detection container 11, The detection container 11 of enclosed construction is used for detecting air poison equipped with the detection fish that running water and 1-3 are the most healthy Property;Transparent observation window 21 is offered for observing sensing chamber 17 on mainframe box 1 above sensing chamber 17, Being additionally provided with display 4, power switch 5 and timer switch 7 on mainframe box 1, display 4 passes through timing Device switch 7 is connected with the power-supply system in battery compartment 2, and power switch 5 electrical connection controls getter device 9 With the break-make of power-supply system in battery compartment 2.
Sensing chamber 17 agent structure (as shown in Figure 2) that the present embodiment relates to, also includes bubble generator 23 and baffle plate limiter 24, the first room 19 of detection, detection seed cell 18 and the bottom pipeline 22 of detection tail room 15 On be mounted on bubble generator 23, for the gas of suction being dispersed into micro-bubble, to increase gas With in sensing chamber 17 inject running water or dissolved with surfactant running water contact area thus improve wash Gas effect;Baffle plate limiter 24 is protruding right angle block structure (as shown in Figure 3), is used for preventing from sealing Baffle plate 14 over-tilting;Can be with one and above detection between the first room 19 of detection and detection tail room 15 Room 18 detachable-type sealed docking, the pipeline 22 that the first top, room 19 of detection is offered and detection bottom, seed cell 18 The pipeline 22 that the pipeline 22 offered, detection top, seed cell 18 are offered with detect the pipeline that bottom, tail room 15 is offered 22 correspondence connections respectively, it is achieved air is the first room 19 of the most through detection, detection after being entered by air inlet 20 Room 18 and detection tail room 15.
The detection syringe 10 agent structure (as shown in Figure 4) that the present embodiment relates to include circular hole cutter 26, Flexible pipe 27 and spiral interface 28, one end of the detection syringe 10 of cylindrical tube structure is spiral interface 28 Dock for detachable with the right-hand member of detection tail room 15, be provided with convex inside the other end of detection syringe 10 The circular hole cutter 26 playing laminated structure is used for cutting open the sealing of detection container, and the diameter of circular hole cutter 26 is less than The diameter of detection syringe 10, the middle part of detection syringe 10 is flexible pipe 27, detection is noted during use Emitter 10 is by the groove being buckled on wall folder 12.
The present embodiment relate to detection container 11 agent structure (as shown in Figure 5) include circular hole tongue and groove 29, End cover 30 and sealing film 31, the openend of the detection container 11 of tubular structure is provided with circular hole tongue and groove 29, Equipped with the end cover 30 of cladding sealing film 31 on circular hole tongue and groove 29;The diameter of circular hole tongue and groove 29 is more than The diameter of circular hole cutter 26, the diameter of detection container 11 with the difference of the diameter of detection syringe 10 is Between 0.1-0.5mm, equipped with the detection fish that running water and 1-3 are the most healthy in detection container;During use, will inspection The end cover 30 of xylometer 11 is downwardly in detection syringe 10, and circular hole cutter 26 touches sealing Cut after film 31 and be socketed in circular hole tongue and groove 29, the running water in detection container 11 and detection fish Enter in sensing chamber 17 along detection syringe 10.
In the air toxic biological monitor that the present embodiment relates to, a diameter of the 10 of described detection syringe 10 100mm, height is 10 2000mm;A diameter of 10 100mm of described detection container 11, highly Being 10 500mm, the volume of its built-in running water is the 1/10 9/10 of detection container 11 own vol, Under its air-proof condition, 1-3 bar detection fish can survive more than 24 hours (h);Described detection syringe 10 can be made For before detection in sensing chamber 17 running water or the flow in pipes of running water and detection dissolved with surfactant terminate The discharge line of rear sewage, the running water or molten in the first room 19 of detection, detection seed cell 18 and detection tail room 15 The running water injection rate having surfactant is 5 40000ml;Described detection fish be zebra fish, black lotus lamp fish, The head apparent replaceable biological variety such as Triphoturus, clown lamp fish;Described gas flowmeter 13 is existing Small-sized conventional equipment in technology, described bubble generator 2 is cellular bubble generator.
Embodiment 2:
In the present embodiment with the air toxic biological monitor described in embodiment 1 to diesel automobile exhaust, 93 Number gasoline automobile tail gas, No. 97 gasoline automobile tail gas and common filter tipped cigarette gas carry out bio-toxicity inspection respectively Survey, and using pure air as blank group;Detailed process is: detection fish selects the zebra fish at 3-5 monthly age, AB strain, male and female dual-purpose, body weight (240 ± 20 milligrams), it is randomly divided into 5 groups, often 6 (n=6) of group, 10-50ml running water or the running water dissolved with surfactant, regulation air-flow regulation is injected in sensing chamber 17 Valve 6, gas flow is 1-5L/min to make gas flowmeter 13 show, closes power supply and open after air-breathing 1-20min Close 5, by detection syringe 10, the detection fish in detection container 11 is transported in sensing chamber 17, observe Zebra fish rollover situation also records time (rollover is the clear and definite observable index that zebra fish goes into a coma), the present embodiment In within 5 seconds, in (s), do not revert to standard with zebra fish for the first time rollover;Test data sheet is as shown in table 1:
The stupor rollover timing of table 1 zebra fish (n=6,)
Experiment results proved, the air toxic biological monitor designed by the present invention can comprehensive to gas Toxicity detects, and easy and simple to handle, be quick on the draw, result accurate;The toxicity of the toxicity detection of zebra fish Classification can consider that according to control group the parameters such as time, air inflow and water volume formulate professional standard voluntarily.
The above, the only detailed description of the invention of the present invention, but protection scope of the present invention is not limited to This, described detection fish selects and as zebra fish, low profile thermal hairtail also has close testing result, therefore Use other close biological detection also within the protection domain of this patent;Any skill belonging to the art Art personnel in the technical scope that the invention discloses, the change that can readily occur in or replacement, all should contain this Within the protection domain of invention.

Claims (6)

1. a portable air toxic biological detection device, it is characterised in that agent structure bag Include mainframe box, battery compartment, wall folder cave, display, power switch, barometric damper, timing Device switch, gas outlet, getter device, detection syringe, detection container, wall folder, gas stream Gauge, sealing baffle, detection tail room, enclosed switch, sensing chamber, detection seed cell, detection head Room, air inlet, observation window and pipeline, offer built-in in the mainframe box of hollow type body structure The battery compartment of power-supply system and the wall folder cave of hollow structure, wall folder is provided with drawing and pulling type structure in cave Wall folder, fixedly secured in mainframe box have by the first room of detection, detection seed cell and detection tail room successively The sensing chamber of through docking composition, is provided with in the first room of detection, detection seed cell and detection tail room Structure identical by the sealing baffle of enclosed switch connecting move control, the pipe that the first bottom, room of detection is offered The air inlet that road is offered with mainframe box left upper end docks, with the gear of knob structure on air inlet Lid, the pipeline that detection tail ceiling end is offered docks with the air inlet port of getter device, getter device Air outlet connect with the gas outlet being opened in mainframe box upper right side, getter device is provided with Barometric damper is used for controlling gas flow;The right-hand member of detection tail room is embedded the wall body at mainframe box Going up and pass through helicitic texture and detachable dock with one end of detection syringe, joint is embedded with Gas flowmeter is used for detecting air mass flow, and the other end of detection syringe is placed with detection to be held Device, is used for equipped with the detection fish that running water and 1-3 are the most healthy in the detection container of enclosed construction Detection air toxic;Transparent observation window is offered for observing on mainframe box above sensing chamber Sensing chamber, mainframe box is additionally provided with display, power switch and timer switch, display Being connected with the power-supply system in battery compartment by timer switch, power switch electrical connection controls Getter device and the break-make of power-supply system in battery compartment;Can between the first room of detection and detection tail room Dock with one and above detection seed cell detachable-type sealed, the pipe that the first ceiling end of detection is offered Pipeline, the pipeline offered of detection top, seed cell and the detection tail room that road is offered with detection bottom, seed cell The pipeline that bottom is offered correspondence connection respectively, it is achieved air is the most through inspection after being entered by air inlet Survey first room, detection seed cell and detection tail room.
Portable air toxic biological the most according to claim 1 detection device, it is special Levy and be that described detection fish includes zebra fish, black lotus lamp fish, head Triphoturus or clown lamp fish.
Portable air toxic biological the most according to claim 1 detection device, it is special Levy and be that sensing chamber also includes bubble generator and baffle plate limiter, the first room of detection, detection It is mounted on bubble generator on the bottom pipeline of room and detection tail room;Baffle plate limiter is convex The right angle block structure risen.
Portable air toxic biological the most according to claim 1 detection device, it is special Levy and be that detecting syringe body structure includes circular hole cutter, flexible pipe and spiral interface, cylindric One end of the detection syringe of pipeline configuration is that spiral interface can for the right-hand member with detection tail room Detachable docks, and is provided with the circular hole cutter of protruding laminated structure inside the other end of detection syringe For cutting open the sealing of detection container, the diameter of circular hole cutter is less than the diameter of detection syringe, The middle part of detection syringe is flexible pipe.
Portable air toxic biological the most according to claim 1 detection device, it is special Levy the agent structure being to detect container and include circular hole tongue and groove, end cover and sealing film, pipe The openend of the detection container of shape structure is provided with circular hole tongue and groove, equipped with cladding envelope on circular hole tongue and groove The end cover of mouth film;The diameter of circular hole tongue and groove, more than the diameter of circular hole cutter, detects container The difference of diameter of diameter and detection syringe be 0.1-0.5mm, equipped with from the beginning in detection container The detection fish of water and 1-3 only health.
Portable air toxic biological the most according to claim 1 detection device, it is special Levying a diameter of 10 100mm being described detection syringe, height is 10 2000mm; A diameter of 10 100mm of described detection container, height is 10 500mm, and it is built-in certainly The volume of water is the 1/10 9/10 of detection container own vol.
CN201510217840.8A 2015-04-30 2015-04-30 A kind of portable air toxic biological detection device Expired - Fee Related CN104897850B (en)

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CN105510539A (en) * 2015-12-31 2016-04-20 北京雪迪龙科技股份有限公司 Gas toxicity detection method and system
CN113702376A (en) * 2021-08-03 2021-11-26 温州大学 Evaluation of environmental pollutants H by using zebra fish2Method of S developmental toxicity

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CN1054834A (en) * 1990-03-15 1991-09-25 兰州大学 A kind of biological monitoring thing of monitoring atmospheric pollution
CN101285809A (en) * 2008-05-23 2008-10-15 上海师范大学 Method for detecting gas rate for entering into water
JP2014178184A (en) * 2013-03-14 2014-09-25 Hiroshima Univ Water quality inspection system and fish monitoring system
CN104345122A (en) * 2013-07-26 2015-02-11 中国人民解放军63976部队 Integrated experiment platform for evaluating chemical contamination biological effect in outdoor air
CN204228695U (en) * 2014-12-11 2015-03-25 大庆市三和科技有限公司 Intelligent online gas detection analyzer
CN204556603U (en) * 2015-04-30 2015-08-12 青岛鑫中天创新生物医药科技研究所有限公司 A kind of portable air toxic biological pick-up unit

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