CN104894913A - Flame-retardant air filter paper, preparation method therefor and application thereof - Google Patents

Flame-retardant air filter paper, preparation method therefor and application thereof Download PDF

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Publication number
CN104894913A
CN104894913A CN201510237574.5A CN201510237574A CN104894913A CN 104894913 A CN104894913 A CN 104894913A CN 201510237574 A CN201510237574 A CN 201510237574A CN 104894913 A CN104894913 A CN 104894913A
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paper
fire
agent
pulp
retardant air
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吴安波
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Hangzhou Special Paper Industry Co Ltd
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Hangzhou Special Paper Industry Co Ltd
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Abstract

The invention discloses air flame-retardant air filter paper which comprises raw paper and an imprgnant for impregnating the raw paper, wherein the raw paper comprises glass fibers, cotton linter pulp treated by alkali, polylactic acid fibers, a defoaming agent, a dispersant,a wet strength agent, a water-proofing agent and a brightening agent; the imprgnant comprises phenolic resin, styrene-acrylic emulsion, normal hexane, methanol, N-hydroxymethyl acrylamide, a wetting agent, a flame retardant N, N '-piperazinetetra(phenol) phosphoramidate and a flame retardant decabromodiphenyl ethane. The invention further discloses a preparation method for the flame-retardant air filter paper. The air filter paper prepared by the preparation method is remarkable, high and lasting in flame retardant efficiency, has no great effect on the mechanical performance of the filter paper, and can be widely applied to the field of engines.

Description

Fire-retardant air paper and its preparation method and application
Technical field
The present invention relates to filter paper technical field, be specifically related to a kind of fire-retardant air paper and its preparation method and application.
Background technology
Fire-retardant air paper is used to make the paper filter core in air filter, and this paper filter core is the critical piece in air filter, decides the performance of air filter.The filter efficiency that should have, the fire resistance had again.In recent years, the air filter paper pyrophoricity accident that the reason such as high temperature, hot gas re-flow due to cylinder causes takes place frequently, and the fire resistance of increasing main engine manufacturer to air filter paper proposes requirement.This series products many uses additive flame retardant on domestic market, this based flame retardant has two large shortcomings, first flame retarding efficiency is low, the amount added is general all larger, thus cause filter paper mechanical properties decrease, it two is that flame retardant effect can not be lasting, has the phenomenon returning the halogen moisture absorption and produces, cause environmental pollution.Along with improving constantly of people's environmental protection and energy saving consciousness, this series products more and more can not meet the demand in market.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of fire-retardant air paper, it uses environment friendly flame retardant, has the good physical property of filter paper and high efficiency flame retardance, present invention also offers the preparation method and application of this fire-retardant air paper.
For realizing goal of the invention, the present invention by the following technical solutions:
A kind of fire-retardant air paper filter paper, the impregnating agent comprising body paper and body paper is flooded, described body paper, by mass percentage, is prepared from by following component:
Here cotton linter pulp alkali carries out processing the wax that can fully remove in cotton linter and soluble impurity; Cotton linter pulp viscosity 280 ~ 300mPas after described alkali treatment, alpha-cellulose content 98% ~ 99%, ash content 0.2% ~ 0.3%;
Described impregnating agent, by mass percentage, is prepared from by following component:
As preferably, the defoamer in described body paper is selected from one or more of butanols, octanol, silicone oil or pine tar.
As preferably, the dispersant in described body paper is selected from one or more of carboxymethyl cellulose, sodium pyrophosphate or calgon.
As preferably, the wet strength agent in described body paper is polyamide Hydrin resin.
As preferably, the waterproofing agent in described body paper is selected from one or more of melamine resinoid, water resistant solution or Lauxite.
As preferably, the brightening agent in described body paper is selected from fluorescent whitening agent 85.
As preferably, described body paper be quantitatively 140 ± 5g/m 2, thickness is 0.45 ± 0.05mm.
As preferably, the wetting agent in described impregnating agent be selected from alkyl sulfate, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic soap class, phosphate one or more.
As preferably, described fire-retardant air paper be quantitatively 160 ± 5g/m 2, thickness is 0.50 ± 0.05mm.
The invention still further relates to the preparation method of above-mentioned fire-retardant air paper, the technological means taked is:
A preparation method for fire-retardant air paper, comprises the steps:
1) NaOH of 8% ~ 12% is joined in cotton linter pulp, stir 4-6hr in 120 DEG C ~ 130 DEG C, fully remove the wax in cotton linter and soluble impurity; Cotton linter pulp viscosity 280 ~ 300mPas after process, alpha-cellulose content 98% ~ 99%, ash content 0.2% ~ 0.3%;
2) by 1) cotton linter pulp of gained at room temperature processes with the HCl of 5% ~ 8% again, and the preferred time is 3hr;
3) through step 2) cotton linter pulp and acid fiber by polylactic use beater making beating, then polish online through double disc refiner and obtain slurry, beating consistency is 1.98 ~ 2.67%, pulls an oar to 15 ~ 18 ° of SR and 20 ~ 30 ° SR respectively;
4) glass fibre is joined step 3) form pulp in the slurry of gained;
5) by the wet strength agent dilute with water of formula ratio, stir, slowly join in pulp;
6) by the defoamer of formula ratio, dispersant, waterproofing agent, brightening agent joins step 5) pulp in, stir, obtain pulping, slurry concentration is 1.58 ~ 1.98%;
7) by step 6) pulping that obtains routinely condition online manufacture paper with pulp and squeeze and obtain body paper;
8) impregnating agent is configured, by the phenolic resins of formula ratio, benzene emulsion, n-hexane, methyl alcohol, N hydroxymethyl acrylamide, wetting agent, N, N'-piperazine four phenoxy urethane phosphate, TDE are put into reactor at the temperature of 70 ~ 90 DEG C and are stirred fully, mixing time is 2 ~ 6hr, then be cooled to room temperature, obtain impregnating agent by 50 ~ 100 order filtered through gauze;
9) by step 7) obtain body paper and be immersed in step 8) in impregnating agent in, adopt the print roll coating mode of intaglio plate reticulate patterned surface to flood, controlling spread is 20% ± 0.5%;
10) after dipping, pattern solidifies in 150 DEG C ~ 160 DEG C circulating airs.
The application of above-mentioned fire-retardant air paper in engine art.
Filter paper has has resistance to flowing, the characteristic that filter efficiency is high and dust capaciting ability is strong, these performances are all relevant with the distribution of porosity and pore size, and fibrous raw material directly can affect the aperture of filter paper, micron filter efficiency, the intensity of wet web when porosity and paper machine operation, so select which type of fibrous raw material, most important to the preparation of filter paper, the present invention adopts and selects glass fibre, all-glass paper is owing to having high filter efficiency, good stability and lower resistance and become the preferred material of efficient especially ultra high efficiency air filter, and its outer cotton pulp that adds selected extends cleaner life-span and pollutant energy to improve dust containing capacity, add synthetic fiber and add ultrasonic wave end socket needs in man-hour to improve filter paper deflection and to meet filter core, ensure that the stability of quality.
Beneficial effect of the present invention:
1. the present invention adopts the mixing of glass fibre, short fibered pulp and acid fiber by polylactic to join the high porosity and enough little aperture copying and ensure that filter paper, aperture is enough little can effectively tackle passing through of dust, wherein acid fiber by polylactic manufactured goods can be analyzed to carbon dioxide and water after discarding in soil, during burning, poison gas can not be distributed, can not pollute, be a kind of ecological fiber of sustainable development.
2. use PPE wet strength agent, obtained body paper wet strength is high, long service life, and PPE wet strength agent has the effect of retention, drainage in paper-making process simultaneously, promotes paper quality; Add waterproofing agent, the WATER RESISTANCE of filter paper can be increased; Add dispersant, synthetic fiber uniformity in the slurry can be improved; Add defoamer, the stability of filter paper quality can be ensured; Add brightening agent, increase the whiteness of filter paper.
3. adopt long fiber pulp, the short fibered pulp through special process process, the combination both ensureing can form aperture and the porosity of expection, also removes the impurity in fiber, guarantees the content of fiber, ensure the quality of filter paper.
4. adopt the print roll coating mode of special impregnating agent and intaglio plate reticulate patterned surface to rely on the natural absorbability of body paper, resin is adsorbed onto in body paper equably, and the evaporation of solvent or resin are reclaimed, reduce production cost and enhance productivity all being highly profitable.
5. two kinds of reactive flame retardant N introduced by chemical reaction method in impregnating agent, have been used, N'-piperazine four phenoxy urethane phosphate and TDE, TDE belongs to bromide fire retardant, poisonous many bromos dibenzodioxin alkane (D B D O) and PBDF (D B D F) is not produced when its thermal cracking or burning, the environmental requirement that fire-retardant material meets American-European countries is done with it, and its Heat stability is good, anti-ultraviolet property is good, exudative low compared with other fire retardants; N, N'-piperazine four phenoxy urethane phosphate is a kind of nitrogen phosphorus flame retardant, has significant flame retardant effect, both is combined, not only make flame retardant effect high, and flame retardant effect is lasting, does not have again great impact to the mechanical property of filter paper;
6. each cost of material of the present invention is reasonable, and production technology is simple, be convenient to control, and is beneficial to and promotes the use of.
Detailed description of the invention
The invention is further illustrated by the following examples, but the present invention is not only confined to following examples.
Embodiment 1
A manufacture craft for fire-retardant air paper, comprises the steps:
1) NaOH of 8% is joined in cotton linter pulp 15kg, stir 4hr in 120 DEG C, fully remove the wax in cotton linter and soluble impurity; Cotton linter pulp viscosity 300mPas after process, alpha-cellulose content 98%, ash content 0.2%;
2) by 1) cotton linter pulp of gained at room temperature processes 3hr with the HCl of 5% again;
3) by glass fibre 60kg with 5% HCl at room temperature process 3hr;
4) by step 3) glass fibre, through step 2) cotton linter pulp and acid fiber by polylactic 15kg use beater making beating, polish online through double disc refiner again and obtain pulp, beating consistency is 1.98%, pulls an oar to 50 ° of SR, 16 ° of SR and 22 ° SR respectively;
5) by polyamide Hydrin resin 2kg dilute with water, stir, slowly join in pulp;
6) by butanols 3kg, carboxymethyl cellulose 3kg, melamine resinoid 1kg, fluorescent whitening agent 851kg joins step 5) pulp in, stir, obtain pulping, slurry concentration is 1.58%;
7) by step 6) pulping that obtains routinely condition online manufacture paper with pulp and squeeze and obtain body paper;
8) impregnating agent is configured, by phenolic resins 25kg, benzene emulsion 10kg, n-hexane 7kg, methyl alcohol 20kg, N hydroxymethyl acrylamide 2.5kg, wetting agent alkyl sulfate 0.5kg, N, N'-piperazine four phenoxy urethane phosphate 18kg, TDE 17kg put into reactor at the temperature of 70 DEG C and stir fully, mixing time is 2 ~ 6hr, then be cooled to room temperature, obtain impregnating agent by 50 order filtered through gauze;
9) by step 7) obtain body paper and be immersed in step 8) in impregnating agent in, adopt the print roll coating mode of intaglio plate reticulate patterned surface to flood, controlling spread is 20% ± 0.5%;
10) after dipping, pattern solidifies in 150 DEG C of circulating airs.
Embodiment 2
A manufacture craft for fire-retardant air paper, comprises the steps:
1) NaOH of 12% is joined in cotton linter pulp 18kg, stir 4hr in 140 DEG C, fully remove the wax in cotton linter and soluble impurity; Cotton linter pulp viscosity 290mPas after process, alpha-cellulose content 99%, ash content 0.3%;
2) by 1) cotton linter pulp of gained at room temperature processes 3hr with the HCl of 8% again;
3) by glass fibre 55kg with 8% HCl at room temperature process 3hr;
4) by step 3) glass fibre, through step 2) cotton linter pulp and acid fiber by polylactic 14kg use beater making beating, polish online through double disc refiner again and obtain pulp, beating consistency is 2.67%, pulls an oar to 42 ° of SR, 15 ° of SR and 26 ° SR respectively;
5) by polyamide Hydrin resin 2kg dilute with water, stir, slowly join in pulp;
6) by silicone oil 4kg, sodium hexametaphosphate 4kg, Lauxite 2kg, fluorescent whitening agent 851kg joins step 5) pulp in, stir, obtain pulping, slurry concentration is 1.98%;
7) by step 6) pulping that obtains routinely condition online manufacture paper with pulp and squeeze and obtain body paper;
8) impregnating agent is configured, by phenolic resins 30kg, benzene emulsion 13kg, n-hexane 8kg, methyl alcohol 20kg, N hydroxymethyl acrylamide 7kg, wetting agent aliphatic acid 2kg, N, N'-piperazine four phenoxy urethane phosphate 10kg, TDE 10kg put into reactor at the temperature of 70 DEG C and stir fully, mixing time is 2 ~ 6hr, then be cooled to room temperature, obtain impregnating agent by 80 order filtered through gauze;
9) by step 7) obtain body paper and be immersed in step 8) in impregnating agent in, adopt the print roll coating mode of intaglio plate reticulate patterned surface to flood, controlling spread is 20% ± 0.5%;
10) after dipping, pattern solidifies in 160 DEG C of circulating airs.
Embodiment 3
A manufacture craft for fire-retardant air paper, comprises the steps:
1) NaOH of 10% is joined in cotton linter pulp 12kg, stir 4hr in 120 DEG C, fully remove the wax in cotton linter and soluble impurity; Cotton linter pulp viscosity 280mPas after process, alpha-cellulose content 98.5%, ash content 0.2%;
2) by 1) cotton linter pulp of gained at room temperature processes 3hr with the HCl of 6% again;
3) by glass fibre 60kg with 6% HCl at room temperature process 3hr;
4) by step 3) glass fibre, through step 2) cotton linter pulp and acid fiber by polylactic 18kg use beater making beating, polish online through double disc refiner again and obtain pulp, beating consistency is 2.08%, pulls an oar to 58 ° of SR, 18 ° of SR and 20 ° SR respectively;
5) by polyamide Hydrin resin 2kg dilute with water, stir, slowly join in pulp;
6) by pine tar 3kg, sodium pyrophosphate 3kg, water resistant solution 0.5kg, fluorescent whitening agent 851.5kg joins step 5) pulp in, stir, obtain pulping, slurry concentration is 1.78%;
7) by step 6) pulping that obtains routinely condition online manufacture paper with pulp and squeeze and obtain body paper;
8) impregnating agent is configured, by phenolic resins 20kg, benzene emulsion 20kg, n-hexane 3kg, methyl alcohol 25kg, N hydroxymethyl acrylamide 6kg, wetting agent carboxylic soap class 0.5kg, N, N'-piperazine four phenoxy urethane phosphate 15kg, TDE 10.5kg put into reactor at the temperature of 90 DEG C and stir fully, mixing time is 2 ~ 6hr, then be cooled to room temperature, obtain impregnating agent by 100 order filtered through gauze;
9) by step 7) obtain body paper and be immersed in step 8) in impregnating agent in, adopt the print roll coating mode of intaglio plate reticulate patterned surface to flood, controlling spread is 20% ± 0.5%;
10) after dipping, pattern solidifies in 150 DEG C of circulating airs.
The fire-retardant air paper technical indicator that above-described embodiment obtains is as shown in the table:
Project Unit Technical requirement Embodiment 1 Embodiment 2 Embodiment 3
Body paper is quantitative g/m 2 140±5 142 143 138
Body paper thickness mm 0.45±0.05 0.45 0.47 0.48
Filter paper is quantitative g/m 2 160±5 162 161 159
Filter paper thickness mm 0.50±0.05 0.46 0.48 0.51
Body paper bursting strength kPa - 78 81 79
Filter paper bursting strength kPa - 340 345 339
Filter paper maximum diameter of hole μm - 60 61 63
Filter paper average pore size μm - 48 49 47
Filter paper filtering efficiency μm - 8~15 8~15 8~15
Filter paper air permeability L/m2.S - 80-90 80-90 80-90
Filter paper oxygen index (OI) - 25~28 25~28 25~28

Claims (10)

1. a fire-retardant air paper filter paper, comprises body paper and to the impregnating agent that body paper floods, it is characterized in that described body paper, by mass percentage, be prepared from by following component:
Cotton linter pulp viscosity 280 ~ 300mPas after described alkali treatment, alpha-cellulose content 98% ~ 99%, ash content 0.2% ~ 0.3%;
Described impregnating agent, by mass percentage, is prepared from by following component:
2. the fire-retardant air paper of one according to claim 1, the defoamer that it is characterized in that in described body paper is selected from one or more of butanols, octanol, silicone oil or pine tar.
3. the fire-retardant air paper of one according to claim 1, the dispersant that it is characterized in that in described body paper is selected from one or more of carboxymethyl cellulose, sodium pyrophosphate or calgon.
4. the fire-retardant air paper of one according to claim 1, the waterproofing agent that it is characterized in that in described body paper is selected from one or more of melamine resinoid, water resistant solution or Lauxite.
5. the fire-retardant air paper of one according to claim 1, that it is characterized in that described body paper is quantitatively 140 ± 5g/ ㎡, and thickness is 0.45 ± 0.05mm.
6. the fire-retardant air paper of one according to claim 1, the wetting agent that it is characterized in that in described impregnating agent be selected from alkyl sulfate, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic soap class, phosphate one or more.
7. the fire-retardant air paper of one according to claim 1, what it is characterized in that described fire-retardant air paper is quantitatively
160 ± 5g/ ㎡, thickness is 0.50 ± 0.05mm.
8. the fire-retardant air paper of one according to claim 1, the wetting agent that it is characterized in that in described impregnating agent be selected from alkyl sulfate, sulfonate, aliphatic acid or fatty acid ester sulfate, carboxylic soap class, phosphate one or more.
9. the preparation method of the arbitrary described a kind of fire-retardant air paper of claim 1 to 8, is characterized in that comprising the steps:
1) NaOH of 8% ~ 12% is joined in cotton linter pulp, stir 4-6hr in 120 DEG C ~ 130 DEG C, fully remove the wax in cotton linter and soluble impurity; Cotton linter pulp viscosity 280 ~ 300mPas after process, alpha-cellulose content 98% ~ 99%, ash content 0.2% ~ 0.3%;
2) by 1) cotton linter pulp of gained at room temperature processes with the HCl of 5% ~ 8% again, and the preferred time is 3hr;
3) through step 2) cotton linter pulp and acid fiber by polylactic use beater making beating, then polish online through double disc refiner and obtain slurry, beating consistency is 1.98 ~ 2.67%, pulls an oar to 15 ~ 18 ° of SR and 20 ~ 30 ° SR respectively;
4) glass fibre is joined step 3) form pulp in the slurry of gained;
5) by the wet strength agent dilute with water of formula ratio, stir, slowly join in pulp;
6) by the defoamer of formula ratio, dispersant, waterproofing agent, brightening agent joins step 5) pulp in, stir, obtain pulping, slurry concentration is 1.58 ~ 1.98%;
7) by step 6) pulping that obtains routinely condition online manufacture paper with pulp and squeeze and obtain body paper;
8) impregnating agent is configured, by the phenolic resins of formula ratio, benzene emulsion, n-hexane, methyl alcohol, N hydroxymethyl acrylamide, wetting agent, N, N'-piperazine four phenoxy urethane phosphate, TDE are put into reactor at the temperature of 70 ~ 90 DEG C and are stirred fully, mixing time is 2 ~ 6hr, then be cooled to room temperature, obtain impregnating agent by 50 ~ 100 order filtered through gauze;
9) by step 7) obtain body paper and be immersed in step 8) in impregnating agent in, adopt the print roll coating mode of intaglio plate reticulate patterned surface to flood, controlling spread is 20% ± 0.5%;
10) after dipping, pattern solidifies in 150 DEG C ~ 160 DEG C circulating airs.
10. the arbitrary described application of a kind of fire-retardant air paper in engine art of claim 1 to 8.
CN201510237574.5A 2015-05-11 2015-05-11 Flame-retardant air filter paper, preparation method therefor and application thereof Pending CN104894913A (en)

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CN105672045A (en) * 2016-02-02 2016-06-15 天津科技大学 Flame-retardant air filter paper and preparation method
CN107008160A (en) * 2017-04-27 2017-08-04 舒尔环保科技(合肥)有限公司 A kind of high-temp. resistant air filter membrane and preparation method
CN107237206A (en) * 2017-07-25 2017-10-10 沧州洁帝欧滤清器有限公司 A kind of oleophobic air paper and preparation method thereof
CN109594421A (en) * 2018-12-05 2019-04-09 中国制浆造纸研究院有限公司 A kind of Novel flue gas conventional chemical detection filter paper and preparation method thereof
CN109610238A (en) * 2018-11-19 2019-04-12 杭州特种纸业有限公司 Fire-retardant solidification filter paper of one kind and preparation method thereof
CN109653024A (en) * 2018-11-21 2019-04-19 杭州特种纸业有限公司 A kind of single side applies solidification filter paper and preparation method thereof
CN111254747A (en) * 2020-02-13 2020-06-09 山东仁丰特种材料股份有限公司 Flame-retardant and efficient air filter paper
CN112663398A (en) * 2020-12-23 2021-04-16 西安爱德乐环保科技有限公司 Flexible glass fiber paper and preparation method thereof
CN113445364A (en) * 2020-03-26 2021-09-28 杭州特种纸业有限公司 Flame-retardant air filter paper and preparation method thereof
CN114059384A (en) * 2020-08-01 2022-02-18 杭州特种纸业有限公司 Nano air filter paper and preparation method thereof
CN115400508A (en) * 2022-11-03 2022-11-29 丰电科技集团股份有限公司 Oil content filter element and manufacturing method thereof, oil-gas separator and air compression system

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105672045A (en) * 2016-02-02 2016-06-15 天津科技大学 Flame-retardant air filter paper and preparation method
CN107008160A (en) * 2017-04-27 2017-08-04 舒尔环保科技(合肥)有限公司 A kind of high-temp. resistant air filter membrane and preparation method
CN107237206B (en) * 2017-07-25 2019-07-02 沧州洁帝欧滤清器有限公司 A kind of oleophobic air paper and preparation method thereof
CN107237206A (en) * 2017-07-25 2017-10-10 沧州洁帝欧滤清器有限公司 A kind of oleophobic air paper and preparation method thereof
CN109610238A (en) * 2018-11-19 2019-04-12 杭州特种纸业有限公司 Fire-retardant solidification filter paper of one kind and preparation method thereof
CN109653024A (en) * 2018-11-21 2019-04-19 杭州特种纸业有限公司 A kind of single side applies solidification filter paper and preparation method thereof
CN109594421A (en) * 2018-12-05 2019-04-09 中国制浆造纸研究院有限公司 A kind of Novel flue gas conventional chemical detection filter paper and preparation method thereof
CN111254747A (en) * 2020-02-13 2020-06-09 山东仁丰特种材料股份有限公司 Flame-retardant and efficient air filter paper
CN113445364A (en) * 2020-03-26 2021-09-28 杭州特种纸业有限公司 Flame-retardant air filter paper and preparation method thereof
CN113445364B (en) * 2020-03-26 2023-11-14 杭州特种纸业有限公司 Flame-retardant air filter paper and preparation method thereof
CN114059384A (en) * 2020-08-01 2022-02-18 杭州特种纸业有限公司 Nano air filter paper and preparation method thereof
CN114059384B (en) * 2020-08-01 2023-11-28 杭州特种纸业有限公司 Nanometer air filter paper and preparation method thereof
CN112663398A (en) * 2020-12-23 2021-04-16 西安爱德乐环保科技有限公司 Flexible glass fiber paper and preparation method thereof
CN115400508A (en) * 2022-11-03 2022-11-29 丰电科技集团股份有限公司 Oil content filter element and manufacturing method thereof, oil-gas separator and air compression system

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