CN104893607B - A kind of antistatic explosive-proof protector film - Google Patents

A kind of antistatic explosive-proof protector film Download PDF

Info

Publication number
CN104893607B
CN104893607B CN201510288012.3A CN201510288012A CN104893607B CN 104893607 B CN104893607 B CN 104893607B CN 201510288012 A CN201510288012 A CN 201510288012A CN 104893607 B CN104893607 B CN 104893607B
Authority
CN
China
Prior art keywords
antistatic
proof
layer
explosive
explosion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510288012.3A
Other languages
Chinese (zh)
Other versions
CN104893607A (en
Inventor
何禄美
肖冰
翁畅健
张国臻
陈庆松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhangjiagang Kangdexin Optronics Material Co Ltd
Original Assignee
Zhangjiagang Kangdexin Optronics Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhangjiagang Kangdexin Optronics Material Co Ltd filed Critical Zhangjiagang Kangdexin Optronics Material Co Ltd
Priority to CN201510288012.3A priority Critical patent/CN104893607B/en
Publication of CN104893607A publication Critical patent/CN104893607A/en
Application granted granted Critical
Publication of CN104893607B publication Critical patent/CN104893607B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Laminated Bodies (AREA)

Abstract

The invention provides a kind of antistatic explosive-proof protector film, including antistatic explosion-proof layer, transparent substrate layer, optical cement layer and the release film layer contacted successively;The antistatic explosion-proof layer includes antistatic additive and UV-cured resin.The antistatic explosive-proof protector film that the present invention is provided includes antistatic explosion-proof layer so that antistatic explosive-proof protector film has excellent antistatic and explosion-proof performance.In addition, the antistatic explosive-proof protector film that the present invention is provided also has excellent translucency, mist degree, wearability and hardness.Test result indicates that:The surface pencil hardness for the antistatic explosive-proof protector film that the present invention is provided is up to more than 2H, and surface resistivity is up to 1012, light transmittance is 81%~86.3%, and mist degree is 0.79%~0.89%, and elongation at break is up to 16%, and adhesive force is excellent.

Description

A kind of antistatic explosive-proof protector film
Technical field
The present invention relates to protective film of electronic product technical field, more particularly to a kind of antistatic rupture pressure disc.
Background technology
At present, the electronic product such as mobile phone, computer, ipad has been widely used, and majority is all to use touch-screen, is moving During dynamic and use, its surface can produce a large amount of electrostatic, cause its surface to be highly susceptible to contact staining or scratch, no But there is injury to human body, and life-span on electronic product and normal using will also result in very big influence.In addition, existing frequently-used Electronic product screen is glass material, in the presence of external force, is easily crushed, the service life of product will shorten.So, need To be protected in product surface laminating layer protecting film.
Only have single antistatic property or single explosion-proof in diaphragm in the market:(1) it is commercially available anti- Electrostatic protection film is usually that antistatic additive or liquid antistatic are directly added in laminating layer, is possessed with antistatic property, but not Resist the effect of foreign impacts;(2) explosion-proof using base material in itself, in surface gum, is attached on screen, that is, forms explosion-proof Layer, but only with base material as explosion-proof layer, explosion-proof is limited, and also the electrostatic that this structure is produced to surface also can without meter Apply.
The content of the invention
In view of this, it is an object of the invention to provide a kind of antistatic explosive-proof protector film, it is antistatic that the present invention is provided Explosive-proof protector film has excellent antistatic and explosion prevention function.
The invention provides a kind of antistatic explosive-proof protector film, including antistatic explosion-proof layer, the transparent base contacted successively Layer, optical cement layer and release film layer;
The antistatic explosion-proof layer includes antistatic additive and UV-cured resin.
Preferably, the thickness of the antistatic explosion-proof layer is 1 μm~10 μm.
Preferably, the preparation method of the antistatic explosion-proof layer comprises the following steps:
Antistatic additive and UV-cured resin are dissolved in solvent, masking liquid is obtained;
The masking liquid is coated with and ultraviolet light, antistatic explosion-proof layer is obtained.
Preferably, solid content is 10%~60% in the masking liquid.
Preferably, the UV-cured resin includes acrylic resin, epoxy acrylic resin, polyester acrylic tree One or more in fat, polyurethane acrylic resin, epoxy resin and vinyl ether resin.
Preferably, the mass ratio of the antistatic additive and UV-cured resin is 1:3~10.
Preferably, the solvent includes ethyl acetate, ethyl lactate, methylisobutylketone, propylene glycol methyl ether acetate, acetic acid One or both of butyl ester, propylene glycol monomethyl ether, methyl acetoacetate and ethyl acetoacetate.
Preferably, the antistatic additive is antistatic including alkyl quaternaries antistatic additive, alkyl sulfonic acid alkaline metal salt Agent, amine surfactants, many polyethylene glycol oxide ether nonionic type surfactants of primary alconol, the phosphoric acid of polychloride vinyl ether alcohol One or more in derivative and ethoxylated fat race alkylamine.
Preferably, the thickness of the transparent substrate layer is 25 μm~250 μm.
Preferably, the material of the transparent substrate layer is pet resin basement membrane, makrolon base One kind in film and Triafol T basement membrane.
The invention provides a kind of antistatic explosive-proof protector film, including antistatic explosion-proof layer, the transparent base contacted successively Layer, optical cement layer and release film layer;The antistatic explosion-proof layer includes antistatic additive and UV-cured resin.The present invention is carried The antistatic explosive-proof protector film supplied includes antistatic explosion-proof layer so that antistatic explosive-proof protector film has excellent antistatic and anti- Quick-fried performance.In addition, the antistatic explosive-proof protector film that the present invention is provided also has excellent translucency, mist degree, wearability and hardness. Test result indicates that:The surface pencil hardness for the antistatic explosive-proof protector film that the present invention is provided is up to more than 2H, surface resistivity Up to 1012, light transmittance is 81%~86.3%, and mist degree is 0.79%~0.89%, and elongation at break is up to 16%, and adhesive force is excellent It is good.
Brief description of the drawings
The structural representation for the antistatic explosive-proof protector film that Fig. 1 provides for the present invention.
Embodiment
The invention provides a kind of antistatic explosive-proof protector film, including antistatic explosion-proof layer, the transparent base contacted successively Layer, optical cement layer and release film layer;
The antistatic explosion-proof layer includes antistatic additive and UV-cured resin.
Referring to Fig. 1, the structural representation for the antistatic explosive-proof protector film that Fig. 1 provides for the present invention, wherein A is antistatic Agent, B is antistatic explosion-proof layer, and C is transparent substrate layer, and D is optical cement layer, and E is release film layer.
The antistatic explosive-proof protector film that the present invention is provided includes antistatic explosive-proof protector layer B.In the present invention, it is described anti-quiet Electric explosive-proof protector layer includes antistatic additive A and UV-cured resin.In the present invention, in the antistatic explosive-proof protector layer The mass ratio of antistatic additive and UV-cured resin is preferably 1:3~10, more preferably 1:4~9.In the present invention, it is described The thickness of antistatic explosive-proof protector layer is preferably 1 μm~10 μm, more preferably 2 μm~7 μm, most preferably 3 μm~4 μm.
In the present invention, the preparation method of the antistatic explosive-proof protector layer preferably includes following steps:
Antistatic additive and UV-cured resin are dissolved in solvent, masking liquid is obtained;
The masking liquid is coated on base material, through ultraviolet light, antistatic explosion-proof layer is obtained.
Antistatic additive and UV-cured resin are dissolved in solvent by the present invention, obtain masking liquid.
In the present invention, the UV-cured resin preferably includes acrylic resin, epoxy acrylic resin, polyester third One or more in olefin(e) acid resin, polyurethane acrylic resin, epoxy resin and vinyl ether resin, more preferably including epoxy One kind in acrylic resin, acrylic resin and vinyl ether resin.In a particular embodiment of the present invention, the ultraviolet light Solidified resin is preferably model CB-2707 UV-cured resin, and producer is that big chemical industry is found in Taiwan.
The present invention does not have special limitation to the species of the antistatic additive and source, is known using those skilled in the art Antistatic additive.In the present invention, the antistatic additive include cationic antistatic agent, anionic antistatic agent and Any one in non-ionic antistatic agent.In the present invention, the antistatic additive preferably include alkyl quaternaries resist it is quiet Electric agent, alkyl sulfonic acid alkaline metal salt antistatic additive, amine surfactants, many polyethylene glycol oxide ether nonionic type tables of primary alconol One or more in face activating agent, the phosphoric acid derivatives of polychloride vinyl ether alcohol and ethoxylated fat race alkylamine.At this In some embodiments of invention, the antistatic additive is preferably model EF-N115 organolithium type antistatic additive.
In the present invention, the mass ratio of the antistatic additive and UV-cured resin is preferably 1:3~10, more preferably 1:4~9.
In the present invention, the solvent preferably includes ethyl acetate, ethyl lactate, methylisobutylketone, propylene glycol monomethyl ether vinegar One or both of acid esters, butyl acetate, propylene glycol monomethyl ether, methyl acetoacetate and ethyl acetoacetate;More preferably include Propylene glycol monomethyl ether and ethyl acetate.
In the present invention, solid content is preferably 10%~60% in the masking liquid, and more preferably 20%~50%.
Obtain after masking liquid, the masking liquid is coated and ultraviolet light by the present invention, obtains antistatic explosion-proof layer.
The present invention does not have special limitation to the method that masking liquid is coated, using coating well known to those skilled in the art Technical scheme.
The wet film that the present invention is obtained after preferably masking liquid is coated with is dried.The present invention is preferably in those skilled in the art tree Dried in the circulation baking oven of fat.In the present invention, the temperature of the drying is preferably 75 DEG C~85 DEG C;The time of the drying is excellent Elect 1.5min~2.5min as.
It is 480mJ/cm present invention preferably employs dosage2~520mJ/cm2Ultraviolet light, more preferably 500mJ/ cm2.In the present invention, the time of the ultraviolet light is preferably 10s~30s, more preferably 15s~25s.
The antistatic explosive-proof protector film that the present invention is provided includes the transparent substrate layer C contacted with the antistatic explosion-proof layer. In the present invention, the thickness of the transparent substrate layer is preferably 25 μm~250 μm, more preferably 50 μm~200 μm.
In the present invention, the material of the transparent substrate layer is preferably pet resin (PET) base One kind in film, makrolon (PC) basement membrane and Triafol T (TAC) basement membrane.
The antistatic explosive-proof protector film that the present invention is provided includes optical cement layer D.In the present invention, the optical cement layer is preferred Obtained by optical cement coating.The present invention originates without special limitation to the optical cement, using those skilled in the art Well known optical cement.In the present invention, the optical cement is preferably OCA optical cements, natural resin optical cement and synthesis tree One kind in fat optical cement;More preferably OCA optical cements.In the present invention, the thickness of the optical cement layer be preferably 10 μm~ 50μm。
The antistatic explosive-proof protector film that the present invention is provided includes release film layer E.In the present invention, the release film layer is preferred To apply silicon mould release membrance.In the present invention, the thickness of the release film layer is preferably 50 μm.Source of the present invention to the mould release membrance There is no special limitation, using mould release membrance well known to those skilled in the art, can such as use its commercial goods.
In the present invention, the preparation method of the antistatic explosive-proof protector film preferably includes following steps:
Antistatic additive and UV-cured resin are dissolved, masking liquid is obtained;
The masking liquid is coated on to the surface of transparent base, ultraviolet light is then carried out, antistatic explosion-proof layer is obtained;
Optical cement is coated in another surface of transparent base, optical cement layer is obtained, mould release membrance is compounded in the optics The surface of glue-line, obtains antistatic explosive-proof protector film.
The present invention dissolves antistatic additive and UV-cured resin, obtains masking liquid.Preparation process of the present invention to masking liquid It is consistent with the preparation process of masking liquid described in above-mentioned technical proposal, it will not be repeated here.
Obtain after masking liquid, the masking liquid is coated on the surface of transparent base by the present invention, then carries out ultraviolet light, obtains To antistatic explosion-proof layer.
The present invention is to the species of transparent base and source and the species of transparent base described in above-mentioned technical proposal and source one Cause, will not be repeated here.The method that the present invention is coated on transparent base to masking liquid does not have special limitation, using art technology Coating technique scheme known to personnel.
Obtain after antistatic explosion-proof layer, optical cement is coated in another surface of transparent base by the present invention, obtains optical cement Layer, then mould release membrance is compounded in the surface of optical cement layer, obtain antistatic explosive-proof protector film.
The present invention is to the species of the optical cement and source and the species of optical cement described in above-mentioned technical proposal and source one Cause, will not be repeated here.
The method on another surface that the present invention is coated in the transparent base to optical cement does not have special limitation, using this Paint-on technique scheme known to art personnel.
The present invention is to the species of the mould release membrance and source and the species of mould release membrance described in above-mentioned technical proposal and source one Cause, will not be repeated here.
The method that the present invention is compounded in the optical cement layer surface to mould release membrance does not have special limitation, using this area skill Complex technique scheme known to art personnel.
According to JIS K7105-1981 in the present invention《The method of testing of plastic optics performance》Standard, test antistatic anti- The total light transmittance and mist degree of quick-fried diaphragm;The present invention is according to JIS K5400-1990《Powdery paints coating adhesion energy Determine》Standard, test the pencil hardness of antistatic explosive-proof protector film;According to HG/T 4303-2012《Surface hardened layer polyester Film wearability assay method》Standard, test the wearability of antistatic explosive-proof protector film;According to GB 1720-1979《Paint film is attached Amylograph》Standard, test the HC adhesive force of antistatic explosive-proof protector film, wherein 5B represents not demoulding completely;The present invention According to GB/T 15662-1995《Conductive, antistatic plastic specific insulation method of testing》Standard, testing film sheet resistance Rate value, its value is higher, shows that the antistatic effect of antistatic explosive-proof protector film is better;The present invention is according to GB/T 25255-2010 《Optical functional film polyethylene terephthalate (PET) film stretchability energy assay method》Standard, test it is antistatic The elongation at break of explosive-proof protector film, its elongation at break is bigger, and toughness is better, i.e., explosion-proof performance is better.
The invention provides a kind of antistatic explosive-proof protector film, including antistatic explosion-proof layer, the transparent base contacted successively Layer, optical cement layer and release film layer;The antistatic explosion-proof layer includes antistatic additive and UV-cured resin.The present invention is provided Antistatic explosive-proof protector film include antistatic explosion-proof layer so that antistatic explosive-proof protector film has excellent antistatic and explosion-proof Performance.In addition, the antistatic explosive-proof protector film that the present invention is provided also has excellent translucency, mist degree, wearability and hardness.It is real Result is tested to show:The surface pencil hardness for the antistatic explosive-proof protector film that the present invention is provided is up to more than 2H, and surface resistivity can Up to 1012, light transmittance is 81%~86.3%, and mist degree is 0.79%~0.89%, and elongation at break is up to 16%, and adhesive force is excellent It is good.
The antistatic explosive-proof protector membrane structure that the present invention is provided is simple, prepares with low cost.
In order to further illustrate the present invention, a kind of antistatic explosive-proof protector film provided with reference to embodiment the present invention It is described in detail, but they can not be interpreted as limiting the scope of the present invention.
In example below, the manufacturer of the PET transparent bases is Mitsubishi resin;
The manufacturer for applying silicon mould release membrance is Mitsubishi resin.
Embodiment 1
The EF-N115 antistatic additive propylene glycol monomethyl ether and ethyl acetate of 5 parts by weight are dissolved, then add 50 weights thereto The UV-cured resin CERABEAM CB-2707 (vertical big chemical industry is provided) of part are measured, the masking liquid of solid content 30% is diluted to;Will The masking liquid is coated on the PET transparent bases of 100 μm of thickness, is placed in 80 DEG C of circulation baking oven and is dried 2 minutes, afterwards via agent Measure 500mJ/cm2Ultraviolet light, be made antistatic explosion-proof cured film;Carried on the back again in thickness for 100 μm of PET transparent bases The OCA glue-lines that a layer thickness is 25 μm are applied, the painting silicon mould release membrance that thickness is 50 μm is covered, antistatic explosive-proof protector film is made.
The present invention carries out performance test to antistatic explosive-proof protector film made from the present embodiment 1, and test result is shown in Table 1 institute Show, table 1 implements the performance test results of diaphragm made from 1~6 and comparative example 1~2 for the present invention.
Embodiment 2
The EF-N115 antistatic additive propylene glycol monomethyl ether and ethyl acetate of 10 parts by weight are dissolved, then add 50 thereto The UV-cured resin CERABEAM CB-2707 (vertical big chemical industry is provided) of parts by weight, are diluted to the masking liquid of solid content 30%; On the PET transparent bases that the masking liquid is coated on to 100 μm of thickness, be placed in 80 DEG C of circulation baking oven dry 2 minutes, afterwards via Dosage 500mJ/cm2Ultraviolet light, antistatic explosion-proof cured film is made, is 100 μm of PET transparent bases then at thickness The back of the body applies the OCA glue-lines that a layer thickness is 25 μm, covers the painting silicon mould release membrance that thickness is 50 μm, antistatic explosive-proof protector film is made.
The present invention carries out performance test to antistatic explosive-proof protector film made from the present embodiment 2, and test result is shown in Table 1 institute Show, table 1 implements the performance test results of diaphragm made from 1~6 and comparative example 1~2 for the present invention.
Embodiment 3
The EF-N115 antistatic additive propylene glycol monomethyl ether and ethyl acetate of 15 parts by weight are dissolved, then add 50 thereto The UV-cured resin CERABEAM CB-2707 (vertical big chemical industry is provided) of parts by weight, are diluted to the masking liquid of solid content 30%; On the PET transparent bases that the masking liquid is coated on to 100 μm of thickness, be placed in 80 DEG C of circulation baking oven dry 2 minutes, afterwards via Dosage 500mJ/cm2Ultraviolet light, antistatic explosion-proof cured film is made, then in thickness be 100 μm of PET transparent bases The back of the body applies the OCA glue-lines that a layer thickness is 25 μm, covers mould release membrance, and antistatic explosive-proof protector film is made.
The present invention carries out performance test to antistatic explosive-proof protector film made from the present embodiment 3, and test result is shown in Table 1 institute Show, table 1 implements the performance test results of diaphragm made from 1~6 and comparative example 1~2 for the present invention.
Embodiment 4
The EF-N115 antistatic additive propylene glycol monomethyl ether and ethyl acetate of 10 parts by weight are dissolved, then add 45 thereto The UV-cured resin CERABEAM CB-2707 (vertical big chemical industry is provided) of parts by weight, are diluted to the masking liquid of solid content 25%; On the PET transparent bases that the masking liquid is coated on to 100 μm of thickness, be placed in 80 DEG C of circulation baking oven dry 2 minutes, afterwards via Dosage 500mJ/cm2Ultraviolet light, that is, antistatic explosion-proof cured film is made, is 100 μm of transparent bases of PET then at thickness The material back of the body applies the OCA glue-lines that a layer thickness is 25 μm, covers the painting silicon mould release membrance that thickness is 50 μm, antistatic explosive-proof protector film is made.
The present invention carries out performance test to antistatic explosive-proof protector film made from the present embodiment 4, and test result is shown in Table 1 institute Show, table 1 implements the performance test results of diaphragm made from 1~6 and comparative example 1~2 for the present invention.
Embodiment 5
The EF-N115 antistatic additive propylene glycol monomethyl ether and ethyl acetate of 10 parts by weight are dissolved, then add 60 thereto The UV-cured resin CERABEAM CB-2707 (vertical big chemical industry is provided) of parts by weight, are diluted to the masking liquid of solid content 35%; On the PET transparent bases that the masking liquid is coated on to 100 μm of thickness, be placed in 80 DEG C of circulation baking oven dry 2 minutes, afterwards via Dosage 500mJ/cm2Ultraviolet light, an antistatic explosion-proof cured film is made, is 100 μm of transparent bases of PET then at thickness The material back of the body applies the OCA glue-lines that a layer thickness is 25 μm, covers the painting silicon mould release membrance that thickness is 50 μm, antistatic explosive-proof protector film is made.
The present invention carries out performance test to antistatic explosive-proof protector film made from the present embodiment 5, and test result is shown in Table 1 institute Show, table 1 implements the test result of diaphragm made from 1~6 and comparative example 1~2 for the present invention.
Embodiment 6
The EF-N115 antistatic additive propylene glycol monomethyl ether and ethyl acetate of 10 parts by weight are dissolved, then add 50 thereto The UV-cured resin CERABEAM SA001 (vertical big chemical industry is provided) of parts by weight, are diluted to the masking liquid of solid content 30%;Will The masking liquid is coated on the PET transparent bases of 100 μm of thickness, is placed in 80 DEG C of circulation baking oven and is dried 2 minutes, afterwards via agent Measure 500mJ/cm2Ultraviolet light, be made antistatic explosion-proof cured film, then at thickness for 100 μm PET transparent bases carry on the back The OCA glue-lines that a layer thickness is 25 μm are applied, the painting silicon mould release membrance that thickness is 50 μm is covered, antistatic explosive-proof protector film is made.
Comparative example 1
By the UV-cured resin CERABEAM CB-2707 (vertical big chemical industry is provided) of 100 parts by weight, propane diols first is used Ether and ethyl acetate are diluted to the masking liquid of solid content 30%, on the PET transparent bases that the masking liquid is coated on to 100 μm of thickness, put Dried 2 minutes in 80 DEG C of circulation baking oven, afterwards via dosage 500mJ/cm2Ultraviolet light, be made explosion-proof cured film Layer, applies the OCA glue-lines that a layer thickness is 25 μm then at the PET transparent bases back of the body that thickness is 100 μm, covers the painting silicon that thickness is 50 μm Mould release membrance, is made explosive-proof protector film.
The present invention carries out performance test to explosive-proof protector film made from comparative example 1, and test result is shown in Table 1, and table 1 is this The performance test results of diaphragm made from 1~6 and comparative example 1~2 are implemented in invention.
Comparative example 2
The EF-N115 propylene glycol monomethyl ethers and ethyl acetate of 10 parts by weight are dissolved, then add 50 parts by weight thereto UV-cured resin CERABEAM CB-33057 (vertical big chemical industry is provided) are diluted to solid content about 30% in above-mentioned solvent Masking liquid.On the PET transparent bases that the masking liquid is coated on to 100 μm of thickness, it is placed in 80 DEG C of circulation baking oven and dries 2 minutes, Afterwards via dosage 500mJ/cm2Ultraviolet light, antistatic cured film is made, it is transparent for 100 μm of PET then at thickness The base material back of the body applies the OCA glue-lines that a layer thickness is 25 μm, covers the painting silicon mould release membrance that thickness is 50 μm, Antistatic protective film is made.
The present invention carries out performance test to Antistatic protective film made from comparative example 2, and test result is shown in Table 1, and table 1 is The present invention implements the test result of diaphragm made from 1~6 and comparative example 1~2.
The performance test results of diaphragm made from the embodiment of the present invention 1~6 of table 1 and comparative example 1~2
It can be seen from Table 1 that, the present invention can adjust antistatic rupture pressure disc by adjusting the addition of antistatic additive Antistatic property, pass through the raising of antistatic dosage, antistatic property enhancing;The present invention can by masking liquid total solid content come Change the thickness of antistatic explosion-proof layer, and then adjust elongation at break, solid content rise, elongation at break is in a slight decrease.
By the contrast of embodiment 2 and comparative example 1, find after addition antistatic additive, do not influence elongation at break, also have Effect improves antistatic effect.By comparative example 2 and comparative example 2, the explosion-proof of material can be effectively improved by illustrating the use of masking liquid Performance does not influence the antistatic effect of material again.
The difference of solid content, is changing the same of resistance value either in the difference or masking liquid of antistatic additive addition When, can't there are obvious influence, i.e. structure constructed by the present invention to ensure that material surface is good to elongation at break Antistatic effect, can assign material excellent explosion-proof performance again.
As seen from the above embodiment, the invention provides a kind of antistatic explosive-proof protector film, including contact successively it is anti-quiet Electric explosion-proof layer, transparent substrate layer, optical cement layer and release film layer;The antistatic explosion-proof layer includes antistatic additive and UV-curing Change resin.The antistatic explosive-proof protector film that the present invention is provided includes antistatic explosion-proof layer so that antistatic explosive-proof protector film has Excellent antistatic and explosion-proof performance.In addition, the antistatic explosive-proof protector film that the present invention is provided also has excellent translucency, mist Degree, wearability and hardness.Test result indicates that:The surface pencil hardness for the antistatic explosive-proof protector film that the present invention is provided is up to 2H More than, surface resistivity is up to 1012, light transmittance is 81%~86.3%, and mist degree is 0.79%~0.89%, and elongation at break can Up to 16%, adhesive force is excellent.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (6)

1. a kind of antistatic explosive-proof protector film, including contact successively antistatic explosion-proof layer, transparent substrate layer, optical cement layer and from Type film layer;
The antistatic explosion-proof layer includes antistatic additive and UV-cured resin;
The thickness of the antistatic explosion-proof layer is 1 μm~10 μm;
The antistatic additive includes model EF-N115 organolithium type antistatic additive, and the UV-cured resin includes type Number UV-cured resin for being CB-2707, the mass ratio of the antistatic additive and UV-cured resin is 1: 3~10.
2. antistatic explosive-proof protector film according to claim 1, it is characterised in that the preparation side of the antistatic explosion-proof layer Method comprises the following steps:
Antistatic additive and UV-cured resin are dissolved in solvent, masking liquid is obtained;
The masking liquid is coated with and ultraviolet light, antistatic explosion-proof layer is obtained.
3. antistatic explosive-proof protector film according to claim 2, it is characterised in that in the masking liquid solid content be 10%~ 60%.
4. antistatic explosive-proof protector film according to claim 2, it is characterised in that the solvent includes ethyl acetate, breast Acetoacetic ester, methylisobutylketone, propylene glycol methyl ether acetate, butyl acetate, propylene glycol monomethyl ether, methyl acetoacetate and acetoacetate One or both of ethyl ester.
5. antistatic explosive-proof protector film according to claim 1, it is characterised in that the thickness of the transparent substrate layer is 25 μm~250 μm.
6. antistatic explosive-proof protector film according to claim 1, it is characterised in that the material of the transparent substrate layer is poly- One kind in ethylene glycol terephthalate resin basement membrane, makrolon basement membrane and Triafol T basement membrane.
CN201510288012.3A 2015-05-29 2015-05-29 A kind of antistatic explosive-proof protector film Active CN104893607B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510288012.3A CN104893607B (en) 2015-05-29 2015-05-29 A kind of antistatic explosive-proof protector film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510288012.3A CN104893607B (en) 2015-05-29 2015-05-29 A kind of antistatic explosive-proof protector film

Publications (2)

Publication Number Publication Date
CN104893607A CN104893607A (en) 2015-09-09
CN104893607B true CN104893607B (en) 2017-09-12

Family

ID=54026583

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510288012.3A Active CN104893607B (en) 2015-05-29 2015-05-29 A kind of antistatic explosive-proof protector film

Country Status (1)

Country Link
CN (1) CN104893607B (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105856759A (en) * 2016-04-15 2016-08-17 东莞市睿泰涂布科技有限公司 Anti-blue-light flexible-glass explosion-proof membrane and preparing technology thereof
CN105882096B (en) * 2016-04-15 2018-12-21 东莞市睿泰涂布科技有限公司 A kind of flexible glass rupture pressure disc and its preparation process
CN105694084A (en) * 2016-04-18 2016-06-22 东莞市纳利光学材料有限公司 Release film and preparation method thereof
CN105897970B (en) * 2016-06-15 2019-08-27 苏州腾盛薄膜科技有限公司 A kind of antiexplosion telephone film
CN106244037B (en) * 2016-07-28 2019-05-21 东莞市纳利光学材料有限公司 Rupture pressure disc and preparation method in a kind of screen
CN106280646B (en) * 2016-08-17 2018-09-25 深圳正峰印刷有限公司 The preparation method of anti-static release coating and film
CN108795312A (en) * 2018-06-29 2018-11-13 东莞市航达电子有限公司 Rupture pressure disc in a kind of 3D glass back-cover
CN111844934A (en) * 2019-04-30 2020-10-30 东莞市旭嘉实业投资有限公司 Protective film for flexible display panel
CN111117500A (en) * 2019-12-31 2020-05-08 江苏天时新材料科技有限公司 Antistatic decontamination automobile protection film
CN111944439A (en) * 2020-08-21 2020-11-17 四川羽玺科技有限公司 Ultra-smooth protective film and preparation method and application thereof
CN115287007A (en) * 2022-08-10 2022-11-04 广东华丽宝实业有限公司 Antistatic protective film for optical glass and preparation method thereof
CN116875128B (en) * 2023-07-18 2024-08-13 绍兴翔宇绿色包装有限公司 Release film and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0758366B1 (en) * 1994-05-06 1999-01-27 Minnesota Mining And Manufacturing Company High temperature resistant antistatic pressure-sensitive adhesive tape
KR100800182B1 (en) * 2005-11-08 2008-02-01 광 석 서 Antismudge, water repellent, and antistatic pressure sensitive or adhesive tape for protection treated
JP5723618B2 (en) * 2011-02-04 2015-05-27 日東電工株式会社 Adhesive sheet and surface protective film

Also Published As

Publication number Publication date
CN104893607A (en) 2015-09-09

Similar Documents

Publication Publication Date Title
CN104893607B (en) A kind of antistatic explosive-proof protector film
CN104152006B (en) A kind of cured coating and the easy tear utilizing cured coating to prepare easily position diaphragm
CN107531037B (en) Laminated body
CN202975539U (en) Image display device
CN105764688B (en) Plastic film layers rolled-up stock
CN107057595A (en) A kind of anti-blue light TPU rupture pressure discs with anti-fingerprint effect and preparation method thereof
CN104893595B (en) Method for producing laminate, and laminate
KR101110534B1 (en) Surface protective film
CN108884368A (en) Adhesion agent composition and adhesive sheet
TW200704685A (en) Anti-static polyester film
CN108690519A (en) Pressure-sensitive-adhesive composition, contact adhesive, pressure sensitive adhesion sheet and display body
KR101444374B1 (en) Waterproof thin film for mobile device
CN102549098A (en) Process for production of pressure-sensitive adhesive composition, process for production of pressure-sensitive adhesive film, raw material composition for pressure-sensitive adhesive, and pressure-sensitive adhesive film
CN104946144A (en) Polysiloxane adhesive tape
TWI570214B (en) Method for producing adhesive film, and adhesive composition and adhesive film
CN105505245A (en) AB adhesive film with antistatic effect and preparation method thereof
CN109970919A (en) The manufacturing method of photo-curable resin composition and the window member using it
CN106047207A (en) Antistatic protective film and preparation method thereof
CN106318262B (en) A kind of anti-blue light double-sided adhesive rubberizing of pearly-lustre and screen protecting film
CN108285747A (en) A kind of production technology of Antistatic protective film
CN109401655A (en) A kind of soft protective film of functional form and preparation method thereof
CN105331277B (en) A kind of multilayered structure protective film and its preparation method and application
CN106827740A (en) A kind of colored rupture pressure disc and its manufacture method
CN104946143A (en) Adhesive tape
CN111944439A (en) Ultra-smooth protective film and preparation method and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PP01 Preservation of patent right
PP01 Preservation of patent right

Effective date of registration: 20190121

Granted publication date: 20170912

PD01 Discharge of preservation of patent
PD01 Discharge of preservation of patent

Date of cancellation: 20220121

Granted publication date: 20170912