CN104893448A - 一种纳米耐候涂料及其制备方法 - Google Patents

一种纳米耐候涂料及其制备方法 Download PDF

Info

Publication number
CN104893448A
CN104893448A CN201510311829.8A CN201510311829A CN104893448A CN 104893448 A CN104893448 A CN 104893448A CN 201510311829 A CN201510311829 A CN 201510311829A CN 104893448 A CN104893448 A CN 104893448A
Authority
CN
China
Prior art keywords
parts
weather
resistant coating
nanometer
aluminium silicate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510311829.8A
Other languages
English (en)
Inventor
秦勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou De Xiang Decorative Engineering Co Ltd
Original Assignee
Suzhou De Xiang Decorative Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou De Xiang Decorative Engineering Co Ltd filed Critical Suzhou De Xiang Decorative Engineering Co Ltd
Priority to CN201510311829.8A priority Critical patent/CN104893448A/zh
Publication of CN104893448A publication Critical patent/CN104893448A/zh
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16Homopolymers or copolymers of vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明公开了一种纳米耐候涂料及其制备方法,所述的纳米耐候涂料包括以下重量份的成分:聚三氟氯乙烯树脂9-17份、聚偏氟乙烯树脂5-12份、三元氯醋树脂4-9份、聚乙二醇6000为3-8份、硅酸铝3-7份、纳米二氧化锆3-5份、2-甲基-1-戊醇12-22份、癸二酸二乙酯3-7份、乙烯基双硬脂酰胺5-10份。本发明的纳米耐候涂料制备方法包括粉碎、混合等步骤。制备的纳米耐候涂料具有良好的耐候特点。

Description

一种纳米耐候涂料及其制备方法
技术领域
本发明属于涂料领域,涉及一种涂料及其制备方法,特别是涉及一种纳米耐候涂料及其制备方法。
背景技术
涂料经涂装后在建筑物内外墙表面形成均匀连续的涂膜。涂膜具有一定的厚度、柔韧性和硬度以及具有耐磨、耐水、耐酸碱腐蚀、耐污染、耐紫外光照射、耐气候变化、耐霉菌侵蚀等特征,可以减少或消除大气、水分、酸雨、灰尘、微生物对建筑物的破坏作用。影响涂料使用寿命的因素很多,概刮起来大致有:紫外线﹑湿度﹑臭氧﹑高温﹑酸雨﹑工业废气等。
耐候涂料是其中一种需求量很大的涂料品种。氟树脂在耐候涂料中也有较多而广泛的应用。氟树脂种类很多,能用作粉末的主要有聚偏氟乙烯(pvdf),这种涂料耐热性﹑机械性能和户外耐久性都非常突出。广泛用在耐高温﹑抗划伤﹑抗粘贴及超耐候等方面。
发明内容
要解决的技术问题:涂料的耐候性质对涂料的性能影响较大,常规的耐候涂料其耐候性能较差,在耐盐雾、耐热等性能上表现较差,并不具有稳固和有效的耐盐雾、耐热强度,因此需要对耐候涂料的性能进行改进,因此提出了一种纳米耐候涂料及其制备方法。
技术方案:本发明公开了一种纳米耐候涂料及其制备方法,所述的纳米耐候涂料包括以下重量份的成分:
聚三氟氯乙烯树脂            9-17份、
聚偏氟乙烯树脂              5-12份、
三元氯醋树脂                 4-9份、
聚乙二醇6000                3-8份、
硅酸铝                       3-7份、
纳米二氧化锆                 3-5份、
2-甲基-1-戊醇                12-22份、
癸二酸二乙酯                 3-7份、
乙烯基双硬脂酰胺             5-10份。
所述的一种纳米耐候涂料,进一步包括以下重量份的成分:
聚三氟氯乙烯树脂            12-16份、
聚偏氟乙烯树脂              7-10份、
三元氯醋树脂                5-8份、
聚乙二醇6000                4-7份、
硅酸铝                       4-6份、
纳米二氧化锆                 4-5份、
2-甲基-1-戊醇                16-20份、
癸二酸二乙酯                 4-6份、
乙烯基双硬脂酰胺             7-9份。
所述的一种纳米耐候涂料,更进一步包括以下重量份的成分:
聚三氟氯乙烯树脂            14份、
聚偏氟乙烯树脂              9份、
三元氯醋树脂                6份、
聚乙二醇6000                5份、
硅酸铝                       5份、
纳米二氧化锆                 4份、
2-甲基-1-戊醇                18份、
癸二酸二乙酯                 5份、
乙烯基双硬脂酰胺             8份。
所述的一种纳米耐候涂料的制备方法,具体步骤如下:
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为400目-500目,备用;
(2)按重量分别取聚三氟氯乙烯树脂9-17份、聚偏氟乙烯树脂5-12份、三元氯醋树脂4-9份、聚乙二醇6000为3-8份、2-甲基-1-戊醇12-22份、癸二酸二乙酯3-7份、乙烯基双硬脂酰胺5-10份,将上述的材料在反应釜中机械搅拌,搅拌转速为40rpm-100rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝3-7份、纳米二氧化锆3-5份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
所述的一种纳米耐候涂料的制备方法,进一步的,步骤(1)中粉碎至硅酸铝目数为500目。
所述的一种纳米耐候涂料的制备方法,进一步的,步骤(2)中搅拌转速为70rpm。
所述的一种纳米耐候涂料的制备方法,进一步的,步骤(3)中加入的硅酸铝为4-6份。
所述的一种纳米耐候涂料的制备方法,进一步的,步骤(3)中加入的纳米二氧化锆为4-5份。
有益效果:通过对耐候涂料的制备工艺和组成配方进行改良,本发明的制备方法制备得到的纳米耐候涂料在耐热性能和耐盐雾性能上表现优异,可以满足绝大多数情况下涂料的耐候需要。本发明的纳米耐候涂料中加入的聚乙二醇6000和纳米二氧化锆对提高涂料的耐候性能有显著的作用。
具体实施方式
实施例1
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为500目,备用;
(2)按重量分别取聚三氟氯乙烯树脂17份、聚偏氟乙烯树脂5份、三元氯醋树脂9份、聚乙二醇6000为8份、2-甲基-1-戊醇22份、癸二酸二乙酯7份、乙烯基双硬脂酰胺10份,将上述的材料在反应釜中机械搅拌,搅拌转速为100rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝7份、纳米二氧化锆5份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
实施例2
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为400目,备用;
(2)按重量分别取聚三氟氯乙烯树脂9份、聚偏氟乙烯树脂12份、三元氯醋树脂4份、聚乙二醇6000为3份、2-甲基-1-戊醇12份、癸二酸二乙酯3份、乙烯基双硬脂酰胺5份,将上述的材料在反应釜中机械搅拌,搅拌转速为40rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝3份、纳米二氧化锆3份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
实施例3
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为500目,备用;
(2)按重量分别取聚三氟氯乙烯树脂16份、聚偏氟乙烯树脂7份、三元氯醋树脂5份、聚乙二醇6000为4份、2-甲基-1-戊醇20份、癸二酸二乙酯4份、乙烯基双硬脂酰胺9份,将上述的材料在反应釜中机械搅拌,搅拌转速为100rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝6份、纳米二氧化锆4份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
实施例4
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为400目,备用;
(2)按重量分别取聚三氟氯乙烯树脂12份、聚偏氟乙烯树脂10份、三元氯醋树脂8份、聚乙二醇6000为7份、2-甲基-1-戊醇16份、癸二酸二乙酯6份、乙烯基双硬脂酰胺7份,将上述的材料在反应釜中机械搅拌,搅拌转速为40rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝4份、纳米二氧化锆5份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
实施例5
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为500目,备用;
(2)按重量分别取聚三氟氯乙烯树脂14份、聚偏氟乙烯树脂9份、三元氯醋树脂6份、聚乙二醇6000为5份、2-甲基-1-戊醇18份、癸二酸二乙酯5份、乙烯基双硬脂酰胺8份,将上述的材料在反应釜中机械搅拌,搅拌转速为70rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝5份、纳米二氧化锆4份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
对比例1
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为400目,备用;
(2)按重量分别取聚三氟氯乙烯树脂9份、聚偏氟乙烯树脂12份、三元氯醋树脂4份、聚乙二醇400为3份、2-甲基-1-戊醇12份、癸二酸二乙酯3份、乙烯基双硬脂酰胺5份,将上述的材料在反应釜中机械搅拌,搅拌转速为40rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝3份、纳米二氧化锆3份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
对比例2
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为400目,备用;
(2)按重量分别取聚三氟氯乙烯树脂9份、聚偏氟乙烯树脂12份、三元氯醋树脂4份、聚乙二醇6000为3份、2-甲基-1-戊醇12份、癸二酸二乙酯3份、乙烯基双硬脂酰胺5份,将上述的材料在反应釜中机械搅拌,搅拌转速为40rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝3份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
将实施例和对比例的涂料涂在器材表面后,用盐雾箱测定其耐盐雾性能。测定方法为国标,耐盐雾循环次数为70次。观察涂层的变化。另外将实施例和对比例的涂料在高温箱中测定其耐热效果,耐热温度为85℃,耐热测试时间为800h。情况如下: 
  耐盐雾情况 耐热情况
实施例1 54次后涂料有起泡 630h后有开裂情况
实施例2 55次后涂料有起泡 610h后有开裂情况
实施例3 64次后涂料有起泡 720h后有开裂情况
实施例4 62次后涂料有起泡 690h后有开裂情况
实施例5 70次后涂料无变化 800h后无开裂、鼓泡
与实施例相比,对比例如下:
  耐盐雾情况 耐热情况
对比例1 35次后涂料有起泡 470h后有开裂情况
对比例2 39次后涂料有起泡 550h后有开裂情况

Claims (8)

1. 一种纳米耐候涂料,其特征在于,所述的纳米耐候涂料包括以下重量份的成分:
聚三氟氯乙烯树脂            9-17份、
聚偏氟乙烯树脂              5-12份、
三元氯醋树脂                 4-9份、
聚乙二醇6000                3-8份、
硅酸铝                       3-7份、
纳米二氧化锆                 3-5份、
2-甲基-1-戊醇                12-22份、
癸二酸二乙酯                 3-7份、
乙烯基双硬脂酰胺             5-10份。
2. 根据权利要求1所述的一种纳米耐候涂料,其特征在于,所述的纳米耐候涂料包括以下重量份的成分:
聚三氟氯乙烯树脂            12-16份、
聚偏氟乙烯树脂              7-10份、
三元氯醋树脂                5-8份、
聚乙二醇6000                4-7份、
硅酸铝                       4-6份、
纳米二氧化锆                 4-5份、
2-甲基-1-戊醇                16-20份、
癸二酸二乙酯                 4-6份、
乙烯基双硬脂酰胺             7-9份。
3. 根据权利要求1所述的一种纳米耐候涂料,其特征在于,所述的纳米耐候涂料包括以下重量份的成分:
聚三氟氯乙烯树脂            14份、
聚偏氟乙烯树脂              9份、
三元氯醋树脂                6份、
聚乙二醇6000                5份、
硅酸铝                       5份、
纳米二氧化锆                 4份、
2-甲基-1-戊醇                18份、
癸二酸二乙酯                 5份、
乙烯基双硬脂酰胺             8份。
4. 根据权利要求1所述的一种纳米耐候涂料的制备方法,其特征在于,所述的纳米耐候涂料制备方法具体步骤如下:
(1)将硅酸铝用粉碎机机械粉碎,粉碎至硅酸铝为粉末,粉碎至硅酸铝目数为400目-500目,备用;
(2)按重量分别取聚三氟氯乙烯树脂9-17份、聚偏氟乙烯树脂5-12份、三元氯醋树脂4-9份、聚乙二醇6000为3-8份、2-甲基-1-戊醇12-22份、癸二酸二乙酯3-7份、乙烯基双硬脂酰胺5-10份,将上述的材料在反应釜中机械搅拌,搅拌转速为40rpm-100rpm,搅拌至所有成分混合均匀;
(3)再向步骤(2)的混合成分中加入硅酸铝3-7份、纳米二氧化锆3-5份,再进行搅拌,搅拌均匀后,静置,为纳米耐候涂料。
5. 根据权利要求4所述的一种纳米耐候涂料的制备方法,其特征在于,步骤(1)中粉碎至硅酸铝目数为500目。
6. 根据权利要求4所述的一种纳米耐候涂料的制备方法,其特征在于,步骤(2)中搅拌转速为70rpm。
7. 根据权利要求4所述的一种纳米耐候涂料的制备方法,其特征在于,步骤(3)中加入的硅酸铝为4-6份。
8. 根据权利要求4所述的一种纳米耐候涂料的制备方法,其特征在于,步骤(3)中加入的纳米二氧化锆为4-5份。
CN201510311829.8A 2015-06-09 2015-06-09 一种纳米耐候涂料及其制备方法 Pending CN104893448A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510311829.8A CN104893448A (zh) 2015-06-09 2015-06-09 一种纳米耐候涂料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510311829.8A CN104893448A (zh) 2015-06-09 2015-06-09 一种纳米耐候涂料及其制备方法

Publications (1)

Publication Number Publication Date
CN104893448A true CN104893448A (zh) 2015-09-09

Family

ID=54026427

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510311829.8A Pending CN104893448A (zh) 2015-06-09 2015-06-09 一种纳米耐候涂料及其制备方法

Country Status (1)

Country Link
CN (1) CN104893448A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019094370A (ja) * 2017-11-17 2019-06-20 ダイキン工業株式会社 フッ素ゴム組成物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6362271B1 (en) * 1998-03-05 2002-03-26 Ausimont Usa, Inc. Polyvinylidene fluoride weather resistant coating compositions including polymethyl methacrylate
CN101824251A (zh) * 2010-05-07 2010-09-08 杭州美多乐化工有限公司 聚偏氟乙烯型氟碳树脂超耐候涂料及其生产方法
CN102784565A (zh) * 2012-08-08 2012-11-21 北京碧水源膜科技有限公司 一种增强型中空纤维复合膜的配方及其生产方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6362271B1 (en) * 1998-03-05 2002-03-26 Ausimont Usa, Inc. Polyvinylidene fluoride weather resistant coating compositions including polymethyl methacrylate
CN101824251A (zh) * 2010-05-07 2010-09-08 杭州美多乐化工有限公司 聚偏氟乙烯型氟碳树脂超耐候涂料及其生产方法
CN102784565A (zh) * 2012-08-08 2012-11-21 北京碧水源膜科技有限公司 一种增强型中空纤维复合膜的配方及其生产方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
徐滨士等: "《表面工程技术手册.下》", 31 July 2009, 化学工业出版社 *
李东光: "《涂料配方与生产(二)》", 31 January 2011, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019094370A (ja) * 2017-11-17 2019-06-20 ダイキン工業株式会社 フッ素ゴム組成物
JP7037042B2 (ja) 2017-11-17 2022-03-16 ダイキン工業株式会社 フッ素ゴム組成物

Similar Documents

Publication Publication Date Title
CN102732079B (zh) 一种外墙涂料及其制备方法
CN100357378C (zh) 一种隔热涂料及其用途
CN107573845B (zh) 一种有机硅超耐候型抗开裂防腐涂料
CN101831221A (zh) 水性氟碳涂料及其制备方法
CN105086746A (zh) 一种脚手架专用耐候性油漆
CN102311690A (zh) 一种水性外用弹性反射隔热涂料及其生产方法
CN102584164B (zh) 一种水性涂料及其制备方法
CN110229601A (zh) 氟碳涂料及其制备方法和涂装方法
CN105176211A (zh) 有机无机复合隔热涂料及其制备方法
CN106752726A (zh) 水性环氧煤沥青防腐涂料
CN101993642A (zh) 抗光热辐射纳米复合建筑物涂料及其制备方法
CN113234365A (zh) 一种水性耐候自洁涂料及其制备方法、应用
CN101845254A (zh) 外墙弹性水性氟碳涂料
CN103482905B (zh) 一种环保型建筑物外墙用抗紫外线、耐高温涂料
CN102585620B (zh) 一种耐高温蒸汽的内墙环保乳胶漆
CN102127330B (zh) 一种耐酸雨水性外墙底漆
CN103483944A (zh) 一种光反射隔热防腐涂料及其制备方法
CN104893448A (zh) 一种纳米耐候涂料及其制备方法
CN107760072A (zh) 一种硅溶胶与石墨烯聚合建筑外墙纳米自洁涂料及制备技术
CN104592792B (zh) 一种无机抗裂耐老化涂料及其制备方法
CN109370394A (zh) 一种聚醚醚酮改性水性醇酸防锈涂料
CN106752539B (zh) 具有保温抗甲醛功效的厚浆型内墙涂料及其制备方法
CN112724755A (zh) 建筑外墙隔热保温涂料及其制备方法
CN100516147C (zh) 水性防腐隔热保温涂料及其制备方法
CN110643237A (zh) 一种超耐候反射隔热涂料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150909

RJ01 Rejection of invention patent application after publication