CN104893413A - Printing ink for outdoor metal decorative sheet and preparation method of printing ink - Google Patents
Printing ink for outdoor metal decorative sheet and preparation method of printing ink Download PDFInfo
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- CN104893413A CN104893413A CN201510337360.5A CN201510337360A CN104893413A CN 104893413 A CN104893413 A CN 104893413A CN 201510337360 A CN201510337360 A CN 201510337360A CN 104893413 A CN104893413 A CN 104893413A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
- C09D11/105—Alkyd resins
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to printing ink for an outdoor metal decorative sheet and a preparation method of the printing ink. The printing ink comprises components in parts by mass as follows: 6-12 parts of benzidine yellow HR, 1-5 parts of medium chrome yellow, 20-32 parts of kaolin, 10-22 parts of precipitated barium sulfate, 5-12 parts of zinc borate, 40-55 parts of castor oil alkyd resin, 1.5-5.5 parts of cobalt naphthenate, 14-25 parts of cyclohexanone, 3-8 parts of glycerin, 2.5-6 parts of alumina gel, 0.5-4.5 parts of hydroquinone, 3-9 parts of ethylene glycol polymethyl ether, 0.4-3.5 parts of a pure acrylic emulsion and 0.2-0.9 parts of polyether modified dimethyl siloxane. The printing ink can well protect and decorate the outdoor metal decorative sheet and has good anti-cracking, anti-freezing, anti-aging, anti-wear and flame-retardant performance.
Description
Technical field
The present invention relates to decorative materials technology, particularly relate to a kind of outdoor metal decorative sheet ink and preparation method thereof.
Background technology
Metal lagging refer to a kind of be the finishing material that surfacing is composited with metal, be to be pasted by edge with metal sheet, packaged exterior material or structure such as to be connected and installed at the decoration aspect that technique and surface of wall formed.Decoration aspect directly can embody the decorative effect of buildings, makes full use of Art Design style that is natural or artificial material performance Designers, rises cover preferably and provide protection metope.Metal lagging is mainly used in building decoration and fitment, and it not only can the outside surface of decorative architecture, also plays protection by the effect of facing from the erosion of sleet etc. simultaneously.Particularly for some novel wall materials, as more suitable in Lightgage Steel Joist Thistle board body of wall, straw board body of wall etc.
In order to decorative metal decorative sheet better, need at its surface-coated ink.Current existing ink to the decoration ability of metal lagging, and does not have good cracking resistance, ageing-resistant, wear-resisting, frost resistance energy.Such as Chinese invention patent (patent No. 201410395155.X, applying date 2014.08.12) disclose and a kind of flame retardant type printing-ink containing straw superfine, this ink is made up of the raw material of following weight part: potassium pyrosulfite 0.8-1, mica powder 4-5, zinc hydroxyl stannate 0.4-0.5, straw superfine 5-8, minaline alkane keto-earboxylic acid sodium 0.1-0.2,1,2-propylene glycol 4-5, urethane-ACRYLIC EMULSION 35-40, water-based paint 12-14, deionized water 22-28, auxiliary agent 2-4.Ink thixotropy prepared by the present invention is good, and tinting strength is strong, and color is more lastingly vivid, and viscosity is controlled, and printing finished product is good colour, heat-proof combustion-resistant, and safety performance is high, and produce simple efficient, cost is lower, has the great market competitiveness.
Summary of the invention
the technical problem solved:for the decoration ability of existing ink to metal lagging, and not there is the shortcomings such as good cracking resistance, ageing-resistant, wear-resisting, frost resistance energy, the invention provides a kind of outdoor metal decorative sheet ink and preparation method thereof.
technical scheme:a kind of outdoor metal decorative sheet ink, in mass parts containing following composition: diarylide yellow HR 6 ~ 12 parts, medium chrome yellow medium yellow 1 ~ 5 part, kaolin 20 ~ 32 parts, process white 10 ~ 22 parts, zinc borate 5 ~ 12 parts, ricinoleyl alcohol acid resin 40 ~ 55 parts, cobalt naphthenate 1.5 ~ 5.5 parts, pimelinketone 14 ~ 25 parts, glycerol 3 ~ 8 parts, alumina gel agent 2.5 ~ 6 parts, Resorcinol 0.5 ~ 4.5 part, the many methyl ethers of ethylene glycol 3 ~ 9 parts, pure acrylic latex 0.4 ~ 3.5 part, polyether-modified dimethyl siloxane 0.2 ~ 0.9 part.
A kind of outdoor metal decorative sheet ink described above, in mass parts containing following composition: diarylide yellow HR 8 ~ 11 parts, medium chrome yellow medium yellow 2 ~ 4.5 parts, kaolin 23 ~ 30 parts, process white 12 ~ 20 parts, zinc borate 7 ~ 11 parts, ricinoleyl alcohol acid resin 43 ~ 50 parts, cobalt naphthenate 2 ~ 5 parts, pimelinketone 16 ~ 23 parts, glycerol 4 ~ 7 parts, alumina gel agent 3 ~ 5 parts, Resorcinol 1.5 ~ 4 parts, the many methyl ethers of ethylene glycol 4 ~ 8 parts, pure acrylic latex 1.2 ~ 3 parts, polyether-modified dimethyl siloxane 0.3 ~ 0.8 part.
A kind of outdoor metal decorative sheet ink described above, in mass parts containing following composition: diarylide yellow HR 9 parts, medium chrome yellow medium yellow 2.8 parts, kaolin 25 parts, process white 14 parts, zinc borate 8 parts, ricinoleyl alcohol acid resin 45 parts, cobalt naphthenate 3 parts, pimelinketone 18 parts, glycerol 5 parts, alumina gel agent 3.5 parts, Resorcinol 2 parts, the many methyl ethers of ethylene glycol 5 parts, pure acrylic latex 1.8 parts, polyether-modified dimethyl siloxane 0.4 part.
A kind of outdoor metal decorative sheet ink described above, in mass parts containing following composition: diarylide yellow HR 9.5 parts, medium chrome yellow medium yellow 3.4 parts, kaolin 27 parts, process white 16 parts, zinc borate 9 parts, ricinoleyl alcohol acid resin 47 parts, cobalt naphthenate 3.5 parts, pimelinketone 20 parts, glycerol 5.5 parts, alumina gel agent 4 parts, Resorcinol 2.8 parts, the many methyl ethers of ethylene glycol 6 parts, pure acrylic latex 2.1 parts, polyether-modified dimethyl siloxane 0.55 part.
The preparation method of a kind of outdoor metal decorative sheet ink described above, the preparation process of the method is as follows:
The first step: pimelinketone, glycerol are joined in reactor, start to stir, low whipping speed is add ricinoleyl alcohol acid resin under 200 ~ 250r/min, is uniformly mixed;
Second step: add cobalt naphthenate, alumina gel agent, Resorcinol, the many methyl ethers of ethylene glycol, pure acrylic latex, polyether-modified dimethyl siloxane again, mixing and stirring;
3rd step: add diarylide yellow HR, medium chrome yellow medium yellow, kaolin, process white, zinc borate again, discharging after stirring 2 ~ 4h, ground by material, being ground to fineness is 3 ~ 10 μm, obtains outdoor metal decorative sheet ink.
Stirring velocity in the first step described above is 225r/min.
Churning time in the 3rd step described above is 3h.
The fineness that is ground in the 3rd step described above is 6 μm.
beneficial effect:a kind of outdoor metal decorative sheet ink provided by the invention and preparation method thereof, this ink has good protection and decorative effect to outdoor metal decorative sheet, and there is good cracking resistance, resistance toly to freeze, ageing-resistant, wear-resisting and flame retardant properties.
Embodiment
embodiment 1
A kind of outdoor metal decorative sheet ink, in mass parts containing following composition: diarylide yellow HR 12 parts, medium chrome yellow medium yellow 5 parts, kaolin 32 parts, process white 22 parts, zinc borate 12 parts, ricinoleyl alcohol acid resin 55 parts, cobalt naphthenate 5.5 parts, pimelinketone 25 parts, glycerol 8 parts, alumina gel agent 6 parts, Resorcinol 4.5 parts, the many methyl ethers of ethylene glycol 9 parts, pure acrylic latex 3.5 parts, polyether-modified dimethyl siloxane 0.9 part.
A preparation method for outdoor metal decorative sheet ink, the preparation process of the method is as follows:
The first step: pimelinketone, glycerol are joined in reactor, start to stir, low whipping speed is add ricinoleyl alcohol acid resin under 200r/min, is uniformly mixed;
Second step: add cobalt naphthenate, alumina gel agent, Resorcinol, the many methyl ethers of ethylene glycol, pure acrylic latex, polyether-modified dimethyl siloxane again, mixing and stirring;
3rd step: add diarylide yellow HR, medium chrome yellow medium yellow, kaolin, process white, zinc borate again, discharging after stirring 2h, ground by material, being ground to fineness is 3 μm, obtains outdoor metal decorative sheet ink.
embodiment 2
A kind of outdoor metal decorative sheet ink, in mass parts containing following composition: diarylide yellow HR 6 parts, medium chrome yellow medium yellow 1 part, kaolin 20 parts, process white 10 parts, zinc borate 5 parts, ricinoleyl alcohol acid resin 40 parts, cobalt naphthenate 1.5 parts, pimelinketone 14 parts, glycerol 3 parts, alumina gel agent 2.5 parts, Resorcinol 0.5 part, the many methyl ethers of ethylene glycol 3 parts, pure acrylic latex 0.4 part, polyether-modified dimethyl siloxane 0.2 part.
A preparation method for outdoor metal decorative sheet ink, the preparation process of the method is as follows:
The first step: pimelinketone, glycerol are joined in reactor, start to stir, low whipping speed is add ricinoleyl alcohol acid resin under 250r/min, is uniformly mixed;
Second step: add cobalt naphthenate, alumina gel agent, Resorcinol, the many methyl ethers of ethylene glycol, pure acrylic latex, polyether-modified dimethyl siloxane again, mixing and stirring;
3rd step: add diarylide yellow HR, medium chrome yellow medium yellow, kaolin, process white, zinc borate again, discharging after stirring 4h, ground by material, being ground to fineness is 10 μm, obtains outdoor metal decorative sheet ink.
embodiment 3
A kind of outdoor metal decorative sheet ink, in mass parts containing following composition: diarylide yellow HR 11 parts, medium chrome yellow medium yellow 4.5 parts, kaolin 30 parts, process white 20 parts, zinc borate 11 parts, ricinoleyl alcohol acid resin 50 parts, cobalt naphthenate 5 parts, pimelinketone 23 parts, glycerol 7 parts, alumina gel agent 5 parts, Resorcinol 4 parts, the many methyl ethers of ethylene glycol 8 parts, pure acrylic latex 3 parts, polyether-modified dimethyl siloxane 0.8 part.
A preparation method for outdoor metal decorative sheet ink, the preparation process of the method is as follows:
The first step: pimelinketone, glycerol are joined in reactor, start to stir, low whipping speed is add ricinoleyl alcohol acid resin under 225r/min, is uniformly mixed;
Second step: add cobalt naphthenate, alumina gel agent, Resorcinol, the many methyl ethers of ethylene glycol, pure acrylic latex, polyether-modified dimethyl siloxane again, mixing and stirring;
3rd step: add diarylide yellow HR, medium chrome yellow medium yellow, kaolin, process white, zinc borate again, discharging after stirring 3h, ground by material, being ground to fineness is 6 μm, obtains outdoor metal decorative sheet ink.
embodiment 4
A kind of outdoor metal decorative sheet ink, in mass parts containing following composition: diarylide yellow HR 9 parts, medium chrome yellow medium yellow 2.8 parts, kaolin 25 parts, process white 14 parts, zinc borate 8 parts, ricinoleyl alcohol acid resin 45 parts, cobalt naphthenate 3 parts, pimelinketone 18 parts, glycerol 5 parts, alumina gel agent 3.5 parts, Resorcinol 2 parts, the many methyl ethers of ethylene glycol 5 parts, pure acrylic latex 1.8 parts, polyether-modified dimethyl siloxane 0.4 part.
A preparation method for outdoor metal decorative sheet ink, the preparation process of the method is as follows:
The first step: pimelinketone, glycerol are joined in reactor, start to stir, low whipping speed is add ricinoleyl alcohol acid resin under 225r/min, is uniformly mixed;
Second step: add cobalt naphthenate, alumina gel agent, Resorcinol, the many methyl ethers of ethylene glycol, pure acrylic latex, polyether-modified dimethyl siloxane again, mixing and stirring;
3rd step: add diarylide yellow HR, medium chrome yellow medium yellow, kaolin, process white, zinc borate again, discharging after stirring 3h, ground by material, being ground to fineness is 6 μm, obtains outdoor metal decorative sheet ink.
embodiment 5
A kind of outdoor metal decorative sheet ink, in mass parts containing following composition: diarylide yellow HR 9.5 parts, medium chrome yellow medium yellow 3.4 parts, kaolin 27 parts, process white 16 parts, zinc borate 9 parts, ricinoleyl alcohol acid resin 47 parts, cobalt naphthenate 3.5 parts, pimelinketone 20 parts, glycerol 5.5 parts, alumina gel agent 4 parts, Resorcinol 2.8 parts, the many methyl ethers of ethylene glycol 6 parts, pure acrylic latex 2.1 parts, polyether-modified dimethyl siloxane 0.55 part.
A preparation method for outdoor metal decorative sheet ink, the preparation process of the method is as follows:
The first step: pimelinketone, glycerol are joined in reactor, start to stir, low whipping speed is add ricinoleyl alcohol acid resin under 225r/min, is uniformly mixed;
Second step: add cobalt naphthenate, alumina gel agent, Resorcinol, the many methyl ethers of ethylene glycol, pure acrylic latex, polyether-modified dimethyl siloxane again, mixing and stirring;
3rd step: add diarylide yellow HR, medium chrome yellow medium yellow, kaolin, process white, zinc borate again, discharging after stirring 3h, ground by material, being ground to fineness is 6 μm, obtains outdoor metal decorative sheet ink.
comparative example 1
Patent of invention publication number is the patent of CN 104194474 A, this ink is made up of the raw material of following weight part: potassium pyrosulfite 0.8, mica powder 5, zinc hydroxyl stannate 0.4, straw superfine 8, minaline alkane keto-earboxylic acid sodium 0.1,1,2-propylene glycol 5, urethane-ACRYLIC EMULSION 40, water-based paint 14, deionized water 28, auxiliary agent 4; Wherein auxiliary agent is made up of the raw material of following weight part: carbomer 4, trolamine 2, nano-stannic oxide 3, emulsifier op-10 5, ferric acetyl acetonade 0.1, dehydrated alcohol 25, N.F,USP MANNITOL 5.
Preparation method is: first add in dehydrated alcohol by carbomer, trolamine, after dispersed with stirring 50min, then adds nano-stannic oxide, ferric acetyl acetonade, mixture ball milling 1.5h after stirring, add other remaining component subsequently, continue dispersion 50min, to obtain final product.
The above-mentioned technical performance index stating the ink of embodiment 1 ~ embodiment 5 and comparative example 1, its detected result is as follows:
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 |
| The temper(ing) time | 965h is without exception | 967h is without exception | 982h is without exception | 975h is without exception | 985h is without exception | 437h is without exception |
| Wear resistance | 1232 times | 1235 times | 1239 times | 1243 times | 1245 times | 576 times |
| Lower temperature resistance | -45 DEG C without exception | -46 DEG C without exception | -48 DEG C without exception | -51 DEG C without exception | -52 DEG C without exception | -23 DEG C without exception |
Above the embodiment of the present invention is described in detail, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (8)
1. an outdoor metal decorative sheet ink, to it is characterized in that in mass parts containing following composition: diarylide yellow HR 6 ~ 12 parts, medium chrome yellow medium yellow 1 ~ 5 part, kaolin 20 ~ 32 parts, process white 10 ~ 22 parts, zinc borate 5 ~ 12 parts, ricinoleyl alcohol acid resin 40 ~ 55 parts, cobalt naphthenate 1.5 ~ 5.5 parts, pimelinketone 14 ~ 25 parts, glycerol 3 ~ 8 parts, alumina gel agent 2.5 ~ 6 parts, Resorcinol 0.5 ~ 4.5 part, the many methyl ethers of ethylene glycol 3 ~ 9 parts, pure acrylic latex 0.4 ~ 3.5 part, polyether-modified dimethyl siloxane 0.2 ~ 0.9 part.
2. a kind of outdoor metal decorative sheet ink according to claim 1, to it is characterized in that in mass parts containing following composition: diarylide yellow HR 8 ~ 11 parts, medium chrome yellow medium yellow 2 ~ 4.5 parts, kaolin 23 ~ 30 parts, process white 12 ~ 20 parts, zinc borate 7 ~ 11 parts, ricinoleyl alcohol acid resin 43 ~ 50 parts, cobalt naphthenate 2 ~ 5 parts, pimelinketone 16 ~ 23 parts, glycerol 4 ~ 7 parts, alumina gel agent 3 ~ 5 parts, Resorcinol 1.5 ~ 4 parts, the many methyl ethers of ethylene glycol 4 ~ 8 parts, pure acrylic latex 1.2 ~ 3 parts, polyether-modified dimethyl siloxane 0.3 ~ 0.8 part.
3. a kind of outdoor metal decorative sheet ink according to claim 1, to is characterized in that in mass parts containing following composition: diarylide yellow HR 9 parts, medium chrome yellow medium yellow 2.8 parts, kaolin 25 parts, process white 14 parts, zinc borate 8 parts, ricinoleyl alcohol acid resin 45 parts, cobalt naphthenate 3 parts, pimelinketone 18 parts, glycerol 5 parts, alumina gel agent 3.5 parts, Resorcinol 2 parts, the many methyl ethers of ethylene glycol 5 parts, pure acrylic latex 1.8 parts, polyether-modified dimethyl siloxane 0.4 part.
4. a kind of outdoor metal decorative sheet ink according to claim 1, to is characterized in that in mass parts containing following composition: diarylide yellow HR 9.5 parts, medium chrome yellow medium yellow 3.4 parts, kaolin 27 parts, process white 16 parts, zinc borate 9 parts, ricinoleyl alcohol acid resin 47 parts, cobalt naphthenate 3.5 parts, pimelinketone 20 parts, glycerol 5.5 parts, alumina gel agent 4 parts, Resorcinol 2.8 parts, the many methyl ethers of ethylene glycol 6 parts, pure acrylic latex 2.1 parts, polyether-modified dimethyl siloxane 0.55 part.
5. the preparation method of a kind of outdoor metal decorative sheet ink as claimed in claim 1, is characterized in that the preparation process of the method is as follows:
The first step: pimelinketone, glycerol are joined in reactor, start to stir, low whipping speed is add ricinoleyl alcohol acid resin under 200 ~ 250r/min, is uniformly mixed;
Second step: add cobalt naphthenate, alumina gel agent, Resorcinol, the many methyl ethers of ethylene glycol, pure acrylic latex, polyether-modified dimethyl siloxane again, mixing and stirring;
3rd step: add diarylide yellow HR, medium chrome yellow medium yellow, kaolin, process white, zinc borate again, discharging after stirring 2 ~ 4h, ground by material, being ground to fineness is 3 ~ 10 μm, obtains outdoor metal decorative sheet ink.
6. the preparation method of a kind of outdoor metal decorative sheet ink according to claim 5, is characterized in that: the stirring velocity in the described the first step is 225r/min.
7. the preparation method of a kind of outdoor metal decorative sheet ink according to claim 5, is characterized in that: the churning time in the 3rd described step is 3h.
8. the preparation method of a kind of outdoor metal decorative sheet ink according to claim 5, is characterized in that: the fineness that is ground in the 3rd described step is 6 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510337360.5A CN104893413A (en) | 2015-06-18 | 2015-06-18 | Printing ink for outdoor metal decorative sheet and preparation method of printing ink |
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| CN201510337360.5A CN104893413A (en) | 2015-06-18 | 2015-06-18 | Printing ink for outdoor metal decorative sheet and preparation method of printing ink |
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| CN104893413A true CN104893413A (en) | 2015-09-09 |
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| CN201510337360.5A Pending CN104893413A (en) | 2015-06-18 | 2015-06-18 | Printing ink for outdoor metal decorative sheet and preparation method of printing ink |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102666748A (en) * | 2009-12-28 | 2012-09-12 | 松井化学股份有限公司 | Printing ink composition for metal and printed metal sheet obtained using same |
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- 2015-06-18 CN CN201510337360.5A patent/CN104893413A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102666748A (en) * | 2009-12-28 | 2012-09-12 | 松井化学股份有限公司 | Printing ink composition for metal and printed metal sheet obtained using same |
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Application publication date: 20150909 |
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