CN104893259A - PET beer bottle and preparation method therefor - Google Patents
PET beer bottle and preparation method therefor Download PDFInfo
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- CN104893259A CN104893259A CN201510134010.9A CN201510134010A CN104893259A CN 104893259 A CN104893259 A CN 104893259A CN 201510134010 A CN201510134010 A CN 201510134010A CN 104893259 A CN104893259 A CN 104893259A
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Abstract
The application discloses a PET beer bottle and a preparation method therefor. The method comprises: weighing out the following components in parts by weight: PET, ethylene, PEG, N-butyl acrylate, nano-silica, glycidyl methacrylate, an antioxidant, nano-barium sulfate, PVA, talcum powder, an ultraviolet absorber, POM, PA6, DecaBDE and HDPE; mixing the components; and extruding the mixture. For a product, the izod impact strength is 1200-1400 J/m, and the Vicat softening point is 180-200 DEG C; the tensile strength is 50-70 MPa, and the bending strength is 70-90 MPa; and the light transmittance is 80-90%, and the oxygen barrier property is improved to be three times of that of PET.
Description
Technical field
The application belongs to PET preparation field, particularly relates to a kind of PET Beer Bottle and preparation method thereof.
Background technology
Beer is the most ancient alcoholic beverage of the mankind, the beverage that is number three of consumption in the world after being water and tea.Beer imports China in earlier 1900s, belongs to external wine kind.Beer is translated into Chinese " beer " according to English Beer, is called " beer ", uses till today.Beer with Fructus Hordei Germinatus, hops, water for main raw material, through the full carbonated low-alcoholic wine of yeast fermentation effect brew.Present international beer major part all adds auxiliary material.The consumption of some national regulation auxiliary materials amounts to and is no more than 50% of Fructus Hordei Germinatus consumption.In Germany, except export beers, German home sale beer does not use auxiliary material without exception.In 2009, beer production about 5,867 ten thousand kilolitre in Asia, first excursion Europe, became the beer production ground that the whole world is maximum.Hops contains protein, VITAMIN, volatile oil, bitter principle, resin etc., has cardiac stimulant, stomach invigorating, diuresis, the medical effects such as analgesia, all has good auxiliary curative effect to essential hypertension, heart trouble and tuberculosis etc.Puerpera has the beer, and to increase parent milk, makes baby obtain nutrition more fully.Beer is that reducing temperature of heatstroke prevention summer and autumn is quenched one's thirst the refreshment drink of hidroschesis, and study according to medical science and beverage experts, beer contains the alcohol of 4%, can stimulate circulation.Excessively drink freezing beer imapirment of the spleen and stomach, increase the weight of moisture in body, unhealthful.PET Beer Bottle is also in the test spread stage at home, and its barrier and antioxidant are to be further improved in addition, high price and be difficult to recycle, and is its key applied of restriction.` he also illustrate: ` vial bid 0.8 yuan, the PET bottle with capacity is 0.9 ~ 1.2 yuan, if consider the advantages such as PET bottle is light, safety, trucking costs are low, expensive one or two mao of PET bottle, enterprise can accept reluctantly.But the vial overwhelming majority can reclaim, and can be recycled, and PET bottle can only be used as recovery and regeneration of waste plastics, all will buy new bottle exactly to beer producers after cleaning, sterilization and disinfection at every turn.And this also directly affects the purchase of human consumer, the such as Yanjing Brewery of price 2 yuan, with glass bottle, if human consumer returns the bottle cash pledge that bottle can obtain 0.5 yuan, be equivalent to every bottled beer and only sell 1.5 yuan, PET bottle dress beer does not then have cash pledge and returns problem, such one calculates, the price difference of PET bottle and vial is not just the problem of a jiao two jiaos, but five jiaos of anises are even more, and Here it is, and enterprise is reluctant uses the reason of PET bottle.
Beer Bottle mostly is vial, and neck is lower thick shape carefully, nails on bottle cap, can dispatch from the factory after being extracted out by air.Finish off rear beer dead soldier and can be recovered utilization.At high temperature similar pop bottle is easily blasted.Beer Bottle is used for celebration, and what such as west was popular open, and wine celebrates that ceremony utilizes the air pressure in Beer Bottle that the beer of the inside is gushed out just, and expression is celebrated joyously.In Zhuhai, richness is one of national maximum pet bottle production base, and its product, through Coca-Cola and pepsi cola accreditation, is that " two is happy " specifies product purchasing.Current the said firm intends upper polyester beer bottle project.Project situation: utilize the said firm and this new high-tech product achievement of the successful pet Beer Bottle of external joint development, significantly improve the performance of pet bottle resistance oxygen and isolated carbonic acid gas, meet the requirement of beer preservation and can pasteurization be passed through, make pet Beer Bottle carry out commercialization, scale operation, thus provide novel packaging for beer enterprise.The said firm is the domestic enterprise entering this new high-tech product business development the earliest at present.Gross investment and rights and interests ratio: project adopts Chinese-foreign joint mode to manage, gross investment 1,900 ten thousand dollars (amounting to Renminbi 15,770 ten thousand yuan), the said firm provides funds 1,425 ten thousand dollars (amounting to Renminbi 11827.5 ten thousand yuan), occupies co-partnership company 75% rights and interests.Three nine-day periods after the winter solstice brew-house in Shijiazhuang has carried out the test of Plastic Bottle.This factory is attempting adopting the pure draught beer of plastic bottle at present, mainly consider that the level of the anti-high pressure of Plastic Bottle has no problem, but the performance of high temperature resistance and gas barrier gas need further observation.Because beer needs in process of production through high-temperature sterilization, require that bottle can be high temperature resistant about 300 DEG C, and the sensitivity shortcoming that plastics are fatal just to temperature.In addition, Beer Bottle barrier not only has influence on the mouthfeel of wine, also affects the shelf lives of wine.Decision plastic beer bottle is proceeded technique improvement or promotes the use of on a large scale by test result.
Pet Beer Bottle is a kind of take polyethylene terephthalate as the Beer Bottle that material is made, and the English of polyethylene terephthalate is called Polythylene terephthalate, is called for short pet, pet Beer Bottle and gains the name thus.The beer packed brand of the pet that current Chinese market can be seen mainly contains three and to get profit M Ⅸ beer, belongs to fruity beer series, packs bright-coloured, have three kinds of tastes such as honey peach; Belgium's Maxwell beer, this beer follows Belgian Martens local flavor, mellow; Silver lion beer, this beer acts on American smart wine theory, and pack draft beer by PET bottle, mouthfeel is fresh pure; Blue shellfish beer, after integrating with blue zone China, release pet bottle, mouthfeel is heavier, and it is strong to kill mouthful power.Due to the inherent defect of beer bottle and the superiority of plastic containers, plastic beer bottle is the high-tech product that International Beer industry and packing business are are competitively researched and developed energetically, and plastic beer bottle is brought into use in European and American developed countries.Predict that the whole world in 2000 will reach 1,000,000 tons for the production of the pet of plastic beer bottle.Estimate that becoming biggest market reaches 250,000 tons to North America in 2005, take second place in Asia-Pacific, West Europe reaches 200,000 tons.China is second-biggest-in-the-world beer production state, and within 1998, Chinese beer output is 1,987 ten thousand tons, amounts to 640ml calculation of capacity, about needs Beer Bottle about 25,000,000,000.According to national regulation, beer enterprise must all use the Beer Bottle meeting GB gb4544-1996 from 1 day April in 1999, non-" b " bottle will be eliminated in recent years from beer brewery, add that " b " bottle arriving the time limit starts to replace successively, on annual market, the breach of Beer Bottle is very big, with 2000 afterwards every year improve 1-3 percentage point of expectation, calendar year 2001 Beer Bottle sales volume just can have 5,000 ten thousand-10,000 ten thousand, 1.5 hundred million-2 hundred million within 2002, can be reached.Therefore, beer container be need Chinese synthetic resins and plastic industry exploitation a large market.
Polyethylene terephthalate (P E T) bottle has many advantages, and the performance as resistance CO2, O2 and vapor permeation is high, and intensity, shock-resistance, chemical resistance and resistance to pressure are high, and very well, appearance property is good for transparency and glossiness.These advantages make P E T bottle be widely used in packaging soft drink, tea drink, fruit juice, medicine, food etc., such as, in packaging soda pop, mineral water etc., achieve very large success.But, because beer is to the particular requirement of wrapping material, make PET still be difficult to the traditional wrapping material (glass and metal) of a large amount of replacement.Realize beer packed plastic, 3 problems the most basic must be solved.First be barrier problem.The beer usual shelf lives is 120 d, so require that Beer Bottle can not be greater than 1 × 10-6 g to the infiltration capacity of O2 at 120d, is no more than 15% to the loss of CO2, and this requirement is 2 ~ 5 times of common PET bottle barrier.Next is temperature resistance problem.Require that bottle can stand the pasteurize carrying out 15 min at 78 DEG C, second-order transition temperature is that the PET of 78 DEG C cannot bear this processing requirement.3rd is price factor, and PET bottle cost is higher than vial cost.Mainly concentrate on the research of PET bottle and improve its heat-resisting and barrier property aspect, barrier property becomes the focus closely studied during the last ten years.And popularizing along with humanity concept, and the formation of novel harmonious society, design PET Beer Bottle that a kind of oxygen-barrier property is good, transmittance is high and shock strength is high and preparation method thereof and be very important.
Summary of the invention
the technical problem solved:
The application, for above-mentioned technical problem, provides a kind of PET Beer Bottle and preparation method thereof, solves that existing PET oxygen-barrier property is poor, transmittance is low and the technical problem such as shock strength is low.
technical scheme:
A kind of PET Beer Bottle, the raw materials by weight portion proportioning of described PET Beer Bottle is as follows: PET100 part; Ethene 5-25 part; PEG2-8 part; N-butyl acrylate 1-20 part; Nano silicon 1-10 part; Glycidyl methacrylate 4-16 part; Oxidation inhibitor 0.1-0.5 part; Nano barium sulfate 3-7 part; PVA10-30 part; Talcum powder is 30-50 part; UV light absorber 0.1-1 part; POM is 15-35 part; PA6 is 1-5 part; Decabromodiphynly oxide 5-15 part; HDPE is 20-40 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described PET Beer Bottle is as follows: PET100 part; Ethene 10-20 part; PEG3-7 part; N-butyl acrylate 5-15 part; Nano silicon 2-8 part; Glycidyl methacrylate 6-14 part; Oxidation inhibitor 0.2-0.4 part; Nano barium sulfate 4-6 part; PVA15-25 part; Talcum powder is 35-45 part; UV light absorber 0.2-0.8 part; POM is 20-30 part; PA6 is 2-4 part; Decabromodiphynly oxide 8-12 part; HDPE is 25-35 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described PET Beer Bottle is as follows: PET100 part; Ethene 15 parts; PEG5 part; N-butyl acrylate 10 parts; Nano silicon 5 parts; Glycidyl methacrylate 10 parts; 0.3 part, oxidation inhibitor; Nano barium sulfate 5 parts; PVA20 part; Talcum powder is 40 parts; UV light absorber 0.5 part; POM is 25 parts; PA6 is 3 parts; Decabromodiphynly oxide 10 parts; HDPE is 30 parts.
As a preferred technical solution of the present invention: described oxidation inhibitor adopts antioxidant 1010 or anti-oxidant DLTP.
As a preferred technical solution of the present invention: described UV light absorber adopts UV-P or UV-531.
As a preferred technical solution of the present invention: the preparation method of described PET Beer Bottle, comprises the steps:
The first step: take PET according to parts by weight proportioning, ethene, PEG, n-butyl acrylate, nano silicon, glycidyl methacrylate, oxidation inhibitor, nano barium sulfate, PVA, talcum powder, UV light absorber, POM, PA6 be, decabromodiphynly oxide and HDPE;
Second step: PET, ethene, PEG, n-butyl acrylate and nano silicon are dropped in reactor and is heated to 60-70 DEG C, stir 15-35min, stirring velocity 200-300r/min;
3rd step: add surplus stock, be warming up to 80-90 DEG C, stirs 30-60min, stirring velocity 200-400r/min;
4th step: mixed material is dropped into extrusion moulding in forcing machine, barrel temperature, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 200 DEG C and 215 DEG C.
beneficial effect:
A kind of PET Beer Bottle of the present invention and preparation method thereof adopts above technical scheme compared with prior art, has following technique effect: 1, product cantilever beam impact strength 1200-1400J/m, Vicat softening point 180-200 DEG C; 2, tensile strength 50-70MPa, flexural strength 70-90MPa; 3, transmittance 80-90%, oxygen-barrier property improves 3 times than PET; 4, appearance colorless glossy clear, the widespread production not division of history into periods can replace current material.
Embodiment
embodiment 1:
PET100 part is taken according to parts by weight proportioning; Ethene 5 parts; PEG2 part; N-butyl acrylate 1 part; Nano silicon 1 part; Glycidyl methacrylate 4 parts; Anti-oxidant DLTP 0.1 part; Nano barium sulfate 3 parts; PVA10 part; Talcum powder is 30 parts; UV-P0.1 part; POM is 15 parts; PA6 is 1 part; Decabromodiphynly oxide 5 parts; HDPE is 20 parts.
PET, ethene, PEG, n-butyl acrylate and nano silicon are dropped in reactor and is heated to 60 DEG C, stir 15min, stirring velocity 200r/min, add surplus stock, be warming up to 80 DEG C, stir 30min, stirring velocity 200r/min.
Mixed material is dropped into extrusion moulding in forcing machine, barrel temperature, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 200 DEG C and 215 DEG C.
Product cantilever beam impact strength 1200J/m, Vicat softening point 180 DEG C; Tensile strength 50MPa, flexural strength 70MPa; Transmittance 80%, oxygen-barrier property improves 3 times than PET.
embodiment 2:
PET100 part is taken according to parts by weight proportioning; Ethene 25 parts; PEG8 part; N-butyl acrylate 20 parts; Nano silicon 10 parts; Glycidyl methacrylate 16 parts; Anti-oxidant DLTP 0.5 part; Nano barium sulfate 7 parts; PVA30 part; Talcum powder is 50 parts; UV-P1 part; POM is 35 parts; PA6 is 5 parts; Decabromodiphynly oxide 15 parts; HDPE is 40 parts.
PET, ethene, PEG, n-butyl acrylate and nano silicon are dropped in reactor and is heated to 70 DEG C, stir 35min, stirring velocity 300r/min, add surplus stock, be warming up to 90 DEG C, stir 60min, stirring velocity 400r/min.
Mixed material is dropped into extrusion moulding in forcing machine, barrel temperature, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 200 DEG C and 215 DEG C.
Product cantilever beam impact strength 1250J/m, Vicat softening point 185 DEG C; Tensile strength 55MPa, flexural strength 75MPa; Transmittance 82%, oxygen-barrier property improves 3 times than PET.
embodiment 3:
PET100 part is taken according to parts by weight proportioning; Ethene 10 parts; PEG3 part; N-butyl acrylate 5 parts; Nano silicon 2 parts; Glycidyl methacrylate 6 parts; Antioxidant 1010 is 0.2 part; Nano barium sulfate 4 parts; PVA15 part; Talcum powder is 35 parts; UV-P0.2 part; POM is 20 parts; PA6 is 2 parts; Decabromodiphynly oxide 8 parts; HDPE is 25 parts.
PET, ethene, PEG, n-butyl acrylate and nano silicon are dropped in reactor and is heated to 60 DEG C, stir 15min, stirring velocity 200r/min, add surplus stock, be warming up to 80 DEG C, stir 30min, stirring velocity 200r/min.
Mixed material is dropped into extrusion moulding in forcing machine, barrel temperature, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 200 DEG C and 215 DEG C.
Product cantilever beam impact strength 1300J/m, Vicat softening point 190 DEG C; Tensile strength 60MPa, flexural strength 80MPa; Transmittance 85%, oxygen-barrier property improves 3 times than PET.
embodiment 4:
PET100 part is taken according to parts by weight proportioning; Ethene 20 parts; PEG7 part; N-butyl acrylate 15 parts; Nano silicon 8 parts; Glycidyl methacrylate 14 parts; Antioxidant 1010 is 0.4 part; Nano barium sulfate 6 parts; PVA25 part; Talcum powder is 45 parts; UV-531 is 0.8 part; POM is 30 parts; PA6 is 4 parts; Decabromodiphynly oxide 12 parts; HDPE is 35 parts.
PET, ethene, PEG, n-butyl acrylate and nano silicon are dropped in reactor and is heated to 70 DEG C, stir 35min, stirring velocity 300r/min, add surplus stock, be warming up to 90 DEG C, stir 60min, stirring velocity 400r/min.
Mixed material is dropped into extrusion moulding in forcing machine, barrel temperature, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 200 DEG C and 215 DEG C.
Product cantilever beam impact strength 1350J/m, Vicat softening point 195 DEG C; Tensile strength 65MPa, flexural strength 85MPa; Transmittance 88%, oxygen-barrier property improves 3 times than PET.
embodiment 5:
PET100 part is taken according to parts by weight proportioning; Ethene 15 parts; PEG5 part; N-butyl acrylate 10 parts; Nano silicon 5 parts; Glycidyl methacrylate 10 parts; Antioxidant 1010 is 0.3 part; Nano barium sulfate 5 parts; PVA20 part; Talcum powder is 40 parts; UV-531 is 0.5 part; POM is 25 parts; PA6 is 3 parts; Decabromodiphynly oxide 10 parts; HDPE is 30 parts.
PET, ethene, PEG, n-butyl acrylate and nano silicon are dropped in reactor and is heated to 65 DEG C, stir 25min, stirring velocity 250r/min, add surplus stock, be warming up to 85 DEG C, stir 45min, stirring velocity 300r/min.
Mixed material is dropped into extrusion moulding in forcing machine, barrel temperature, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 200 DEG C and 215 DEG C.
Product cantilever beam impact strength 1400J/m, Vicat softening point 200 DEG C; Tensile strength 70MPa, flexural strength 90MPa; Transmittance 90%, oxygen-barrier property improves 3 times than PET.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth content of the present invention, instead of restriction, and any change therefore in the implication suitable with claims of the present invention and scope, all should think to be included in the scope of claims.
Claims (6)
1. a PET Beer Bottle, is characterized in that the raw materials by weight portion proportioning of described PET Beer Bottle is as follows: PET100 part; Ethene 5-25 part; PEG2-8 part; N-butyl acrylate 1-20 part; Nano silicon 1-10 part; Glycidyl methacrylate 4-16 part; Oxidation inhibitor 0.1-0.5 part; Nano barium sulfate 3-7 part; PVA10-30 part; Talcum powder is 30-50 part; UV light absorber 0.1-1 part; POM is 15-35 part; PA6 is 1-5 part; Decabromodiphynly oxide 5-15 part; HDPE is 20-40 part.
2. a kind of PET Beer Bottle according to claim 1, proportioning is as follows by weight: PET100 part to it is characterized in that described PET beer bottle material; Ethene 10-20 part; PEG3-7 part; N-butyl acrylate 5-15 part; Nano silicon 2-8 part; Glycidyl methacrylate 6-14 part; Oxidation inhibitor 0.2-0.4 part; Nano barium sulfate 4-6 part; PVA15-25 part; Talcum powder is 35-45 part; UV light absorber 0.2-0.8 part; POM is 20-30 part; PA6 is 2-4 part; Decabromodiphynly oxide 8-12 part; HDPE is 25-35 part.
3. a kind of PET Beer Bottle according to claim 1, is characterized in that the raw materials by weight portion proportioning of described PET Beer Bottle is as follows: PET100 part; Ethene 15 parts; PEG5 part; N-butyl acrylate 10 parts; Nano silicon 5 parts; Glycidyl methacrylate 10 parts; 0.3 part, oxidation inhibitor; Nano barium sulfate 5 parts; PVA20 part; Talcum powder is 40 parts; UV light absorber 0.5 part; POM is 25 parts; PA6 is 3 parts; Decabromodiphynly oxide 10 parts; HDPE is 30 parts.
4. a kind of PET Beer Bottle according to claim 1, is characterized in that: described oxidation inhibitor adopts antioxidant 1010 or anti-oxidant DLTP.
5. a kind of PET Beer Bottle according to claim 1, is characterized in that: described UV light absorber adopts UV-P or UV-531.
6. a preparation method for PET Beer Bottle described in claim 1, is characterized in that, comprise the steps:
The first step: take PET according to parts by weight proportioning, ethene, PEG, n-butyl acrylate, nano silicon, glycidyl methacrylate, oxidation inhibitor, nano barium sulfate, PVA, talcum powder, UV light absorber, POM, PA6 be, decabromodiphynly oxide and HDPE;
Second step: PET, ethene, PEG, n-butyl acrylate and nano silicon are dropped in reactor and is heated to 60-70 DEG C, stir 15-35min, stirring velocity 200-300r/min;
3rd step: add surplus stock, be warming up to 80-90 DEG C, stirs 30-60min, stirring velocity 200-400r/min;
4th step: mixed material is dropped into extrusion moulding in forcing machine, barrel temperature, 170 DEG C, 180 DEG C, 190 DEG C, 190 DEG C, 200 DEG C and 215 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510134010.9A CN104893259A (en) | 2015-03-26 | 2015-03-26 | PET beer bottle and preparation method therefor |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510134010.9A CN104893259A (en) | 2015-03-26 | 2015-03-26 | PET beer bottle and preparation method therefor |
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| CN104893259A true CN104893259A (en) | 2015-09-09 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176016A (en) * | 2015-09-22 | 2015-12-23 | 苏州博利迈新材料科技有限公司 | Reinforced and toughened PET plastic and preparation method thereof |
| CN105566867A (en) * | 2016-02-17 | 2016-05-11 | 苏州铂普乐新材料有限公司 | Antibacterial bottle embryo material |
| CN110283376A (en) * | 2019-08-05 | 2019-09-27 | 林正雄 | A kind of combined plastic alloy and the preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1817963A (en) * | 2005-12-09 | 2006-08-16 | 中国石油天然气股份有限公司 | Single-layer and transparent high-impedant composite materials terephthalate product swith polyethylene glycol |
| CN103205091A (en) * | 2012-01-11 | 2013-07-17 | 贵州省纳米材料工程中心 | Inorganic nanoparticle dispersion for high-transparency high-barrier polyester material, and preparation method thereof |
-
2015
- 2015-03-26 CN CN201510134010.9A patent/CN104893259A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1817963A (en) * | 2005-12-09 | 2006-08-16 | 中国石油天然气股份有限公司 | Single-layer and transparent high-impedant composite materials terephthalate product swith polyethylene glycol |
| CN103205091A (en) * | 2012-01-11 | 2013-07-17 | 贵州省纳米材料工程中心 | Inorganic nanoparticle dispersion for high-transparency high-barrier polyester material, and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176016A (en) * | 2015-09-22 | 2015-12-23 | 苏州博利迈新材料科技有限公司 | Reinforced and toughened PET plastic and preparation method thereof |
| CN105566867A (en) * | 2016-02-17 | 2016-05-11 | 苏州铂普乐新材料有限公司 | Antibacterial bottle embryo material |
| CN110283376A (en) * | 2019-08-05 | 2019-09-27 | 林正雄 | A kind of combined plastic alloy and the preparation method and application thereof |
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Application publication date: 20150909 |