CN104892995A - Antibacterial type full degradable film and preparation method thereof - Google Patents

Abstract

The invention discloses an antibacterial type full degradable film characterized by comprising the following raw material by weight: 6-10 parts of beta cyclodextrin, 40-60 parts of corn starch, 20-30 parts of polyvinyl alcohol, 3-5 parts of cetostearyl alcohol, 15-25 parts of glycerin, 0.3-0.5 part of tea saponin, 3-6 parts of ethyl orthosilicate, 0.3-0.5 part of wintergreen oil, 0.5-1 part ofeucalyptus oil, 2-4 parts of polyethylene glycol (peg), and 1-2 parts of sodium stearate. The antibacterial type full degradable film has good antibacterial effect, can effectively protect human health, has good mechanical properties and resistance to water, and good degradation performance, and is low in price, green and environmentally friendly.

Description

A kind of antimicrobial form whole degrading film and preparation method thereof

Technical field

The present invention relates to thin film materials art, be specifically related to a kind of antimicrobial form whole degrading film and preparation method thereof.

Background technology

In recent years, the cry of improving the ecological environment grows to even greater heights.China is as a packaging big country, and the usage quantity of plastic packing product is huge, and waste plastic is difficult to degraded, residual formation " white pollution " in the environment, the living environment of the serious threat mankind.Therefore, development environment friendly, nontoxic, free of contamination all biological degradation type film substitutes Traditional Packing film becomes inexorable trend.

PVA is a kind of broad-spectrum high molecular polymer, containing a large amount of hydroxyls in molecule, has powerful magnetism, have good barrier, strong adherence, snappiness, glossiness, smoothness, oil-proofness and organic solvent resistance between its adjacent molecule.PVA is easy to biological degradation, and hypotoxicity is non-stimulated, cheap and easy to get, is the very promising degradable plastics body material of one.But the water tolerance of PVA and mechanical property poor, limit the application of PVA base plastics film.

Summary of the invention

The object of this invention is to provide a kind of antimicrobial form whole degrading film, can effective kill bacteria, protection HUMAN HEALTH, good mechanical properties, has good water tolerance simultaneously, cheap, environmental protection.

The present invention is achieved by the following technical solutions:

A kind of antimicrobial form whole degrading film, it is obtained by the raw material of following weight parts:

Beta-cyclodextrin 6-10, W-Gum 40-60, polyvinyl alcohol 20-30, cetostearyl alcohol 3-5, glycerine 15-25, tea saponin 0.3-0.5, tetraethoxy 3-6, wintergreen oil 0.3-0.5, eucalyptus oil 0.5-1, polyoxyethylene glycol 2-4, sodium stearate 1-2.

A preparation method for antimicrobial form whole degrading film, it comprises the following steps:

(1) add dehydrated alcohol by solid-liquid weight ratio 1:1-1:2 after being mixed with W-Gum by beta-cyclodextrin, then add wintergreen oil and eucalyptus oil supersound process 15-30min, filter and drying, obtain mixed powder;

(2) mixed powder obtained in (1) and polyoxyethylene glycol to be added jointly in the mixed solution of ethanol in proper amount/water/ammoniacal liquor and ultrasonic disperse 10-15min, obtain suspension, described ammonia concn is 25-26%, the weight ratio=1:2:5 of ammoniacal liquor, distilled water and ethanol in described ethanol/water/ammonia water mixture;

(3) ethanol/tetraethoxy mixed solution is slowly dripped in the suspension obtained in (2), in 50-60 DEG C of abundant stirring reaction 4-6h, also dry with absolute ethanol washing after filtration, obtain modified powder; Weight ratio=the 1:1 of ethanol and tetraethoxy in described ethanol/tetraethoxy mixed solution;

(4) modified powder obtained in (3) is mixed with polyvinyl alcohol, tea saponin, cetostearyl alcohol and sodium stearate, 0.5-1h is stirred prior to 70-80 DEG C, add glycerine 100-120 DEG C again and stir 0.5-1h, finally add twin screw extruder extruding pelletization, obtain film pellet;

(5) the film pellet blowing obtained in (4) is made film, to obtain final product.

Advantage of the present invention is:

Using beta-cyclodextrin and W-Gum as base-material; by the composite modified base-material of silica sphere to increase the intensity of base-material; introduce polyoxyethylene glycol simultaneously and carry out the interface compatibility that surface modification improves base-material and polyvinyl alcohol; effectively improve the mechanical property of matrix material; and by the embedding to effective constituent; the whole degrading film obtained is made not only to have good antibacterial effect; available protecting HUMAN HEALTH; there is good intensity, tensile property and water tolerance simultaneously; degradation property is good; cheap, environmental protection.

Embodiment

Non-limiting examples of the present invention is as follows:

A kind of antimicrobial form whole degrading film, is prepared from by the component raw material of following weight (kg):

Beta-cyclodextrin 8, W-Gum 50, polyvinyl alcohol 25, cetostearyl alcohol 4, glycerine 20, tea saponin 0.4, tetraethoxy 4, wintergreen oil 0.4, eucalyptus oil 0.8, polyoxyethylene glycol 3, sodium stearate 1.5.

The preparation method of antimicrobial form whole degrading film comprises the following steps:

(1) add dehydrated alcohol by solid-liquid weight ratio 1:1 after being mixed with W-Gum by beta-cyclodextrin, then add wintergreen oil and eucalyptus oil supersound process 15min, filter and drying, obtain mixed powder;

(2) mixed powder obtained in (1) and polyoxyethylene glycol to be added jointly in the mixed solution of ethanol in proper amount/water/ammoniacal liquor and ultrasonic disperse 15min, obtain suspension, described ammonia concn is 26%, the weight ratio=1:2:5 of ammoniacal liquor, distilled water and ethanol in described ethanol/water/ammonia water mixture;

(3) ethanol/tetraethoxy mixed solution is slowly dripped in the suspension obtained in (2), in 60 DEG C of abundant stirring reaction 4h, also dry with absolute ethanol washing after filtration, obtain modified powder; Weight ratio=the 1:1 of ethanol and tetraethoxy in described ethanol/tetraethoxy mixed solution;

(4) modified powder obtained in (3) is mixed with polyvinyl alcohol, tea saponin, cetostearyl alcohol and sodium stearate, stir 0.5h prior to 80 DEG C, then add glycerine 120 DEG C stirring 0.5h, finally add twin screw extruder extruding pelletization, obtain film pellet;

(5) the film pellet blowing obtained in (4) is made film, to obtain final product.

Above-mentioned obtained film performance test result is as follows:

Tensile strength (MPa): 24.5;

Breaking tenacity (MPa): 35.2;

Wet tenacity (MPa): 19.6;

60d degradation rate: >=30%.

Claims (2)

1. an antimicrobial form whole degrading film, is characterized in that, it is obtained by the raw material of following weight parts:

Beta-cyclodextrin 6-10, W-Gum 40-60, polyvinyl alcohol 20-30, cetostearyl alcohol 3-5, glycerine 15-25, tea saponin 0.3-0.5, tetraethoxy 3-6, wintergreen oil 0.3-0.5, eucalyptus oil 0.5-1, polyoxyethylene glycol 2-4, sodium stearate 1-2.

2. the preparation method of a kind of antimicrobial form whole degrading film according to claim 1, is characterized in that, comprise the following steps:

(1) add dehydrated alcohol by solid-liquid weight ratio 1:1-1:2 after being mixed with W-Gum by beta-cyclodextrin, then add wintergreen oil and eucalyptus oil supersound process 15-30min, filter and drying, obtain mixed powder;

(2) mixed powder obtained in (1) and polyoxyethylene glycol to be added jointly in the mixed solution of ethanol in proper amount/water/ammoniacal liquor and ultrasonic disperse 10-15min, obtain suspension, described ammonia concn is 25-26%, the weight ratio=1:2:5 of ammoniacal liquor, distilled water and ethanol in described ethanol/water/ammonia water mixture;

(3) ethanol/tetraethoxy mixed solution is slowly dripped in the suspension obtained in (2), in 50-60 DEG C of abundant stirring reaction 4-6h, also dry with absolute ethanol washing after filtration, obtain modified powder; Weight ratio=the 1:1 of ethanol and tetraethoxy in described ethanol/tetraethoxy mixed solution;

(4) modified powder obtained in (3) is mixed with polyvinyl alcohol, tea saponin, cetostearyl alcohol and sodium stearate, 0.5-1h is stirred prior to 70-80 DEG C, add glycerine 100-120 DEG C again and stir 0.5-1h, finally add twin screw extruder extruding pelletization, obtain film pellet;

(5) the film pellet blowing obtained in (4) is made film, to obtain final product.