CN104891960B - A kind of method with ceramic tile waste material as raw material and through embedding SINTERING PRODUCTION haydite - Google Patents

A kind of method with ceramic tile waste material as raw material and through embedding SINTERING PRODUCTION haydite Download PDF

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Publication number
CN104891960B
CN104891960B CN201510244701.4A CN201510244701A CN104891960B CN 104891960 B CN104891960 B CN 104891960B CN 201510244701 A CN201510244701 A CN 201510244701A CN 104891960 B CN104891960 B CN 104891960B
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China
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haydite
ceramic tile
embedding
filler
raw
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CN104891960A (en
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李成峰
逯鹏
韩勇勇
丁锐
姚奇恒
刘俊成
袁东峰
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Shandong University of Technology
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Shandong University of Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Compositions Of Oxide Ceramics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A kind of method with ceramic tile waste material as raw material and through embedding SINTERING PRODUCTION haydite, belongs to ceramic particle technology field.It is characterized in that being first according to quality preparation raw material: 10 ~ 20% tile polished wastes, 22 ~ 32% green compact of ceramic tile waste materials, 18% tile edge material, 20% Laiyang soil, 10% green coke jewel, 10% feldspar, 0 ~ 0.8% carborundum, add water ball milling and manufacture raw haydite or the raw haydite of powder manufacture obtained after drying by slip with the slip spraying ground after 2 hours;Mix with embedding filler after crossing sieve classification, sinter 15 minutes through 1170 C, screen out embedding filler after cooling down with stove, be i.e. able to the haydite that ceramic tile waste material is raw material.Wherein ceramic tile waste material consumption is big, embedding filler select magnesia with quartz with mass ratio as 0:1 ~ the material grain that mixes of 0.2:1, burn till and after sieving, embed the repeatable utilization of filler, the haydite good dispersion of gained, epigranular and density controllable.

Description

A kind of method with ceramic tile waste material as raw material and through embedding SINTERING PRODUCTION haydite
Technical field
A kind of method with ceramic tile waste material as raw material and through embedding SINTERING PRODUCTION haydite, belongs to ceramic particle technology field.
Background technology
In existing ceramic particle technology, raw material typically uses the natural materials such as clay class, expanded perlite or argillaceous rock, raw The haydite produced is widely used in fields such as filling, support column carrier and function carriers.But along with the day by day scarcity of natural resources, Developing the technology producing haydite for raw material with Mining tailings or industry accessory substance to become more and more important, the ceramic tile such as building tile industry gives up Material is annual produces about 10,000,000 tons, and only tile polished waste just produces about 1,700,000 tons every year.Tile polished waste foam performance is superior, As patent CN1377859 discloses the side utilizing waste ceramic mud as a raw material produced by ceramic polished brick production line to produce haydite Method, i.e. adds give up mud and coal of raw material as additive, utilizes and be molded roller prilling, use rotary kiln sintered, cooled To ceramic product.Patent CN1468827A discloses the pitchers of generation during Production of Ceramics and, as base-material, adds proper proportion Binding material and expanded material, utilize the rotary kiln sintered method forming haydite.In these haydite producing technologies, rich in raw material Containing SiO2And solvent composition, such as Na2O、K2O and MgO etc., the frit reaction that haydite surface occurs when high temperature burns till makes haydite Smooth surface, the haydite good fluidity burnt till, but the firing process difficulty regulation and control when burning till, temperature is high, time length can ensure sintering Fully, easily stick together between haydite and haydite, cause the haydite heterogeneity in terms of Size Distribution produced, after mechanical grading There is breakage on grain surface, and haydite water absorption rate, mechanical property and military service performance are had adverse influence.Using filler to embed sintering process can The reaction being greatly reduced between haydite and haydite, but the high-temperature reactivity on haydite surface then easily reacts with filler, therefore, Haydite with ceramic tile waste material as raw material produces and need to adjust raw material and the formula of sintering filler, prevent haydite adhesion at high temperature with Ensure the integrality burning till haydite surface.
Summary of the invention
Deficiency based on above-mentioned technology, it is an object of the invention to provide a kind of with ceramic tile waste material as raw material and through embedding sintering The method producing haydite, its technical scheme comprises the following steps:
(1) dispensing is carried out according to mass ratio: tile polished waste 10 ~ 20%, green compact of ceramic tile waste material 22 ~ 32%, tile edge material 18%, Laiyang soil 20%, green coke jewel 10%, feldspar 10%, carborundum 0 ~ 0.8%, adds according still further to the ratio that ratio of water to material is 80:100 Water, with the rotating speed ball milling 2 hours of 400 rpms on planetary ball mill after mixing with material;
(2) the slip mist projection granulating that step (1) is ground, or the slip that step (1) is ground under 130 C be dried 1 After hour broken, by pelletizer or manual mode granulation, the residue on sieve obtained after sieving i.e. is made a living haydite;
(3) the raw haydite prepared through step (2) is mixed with the ratio of 0:1 ~ 0.4:1, under 1170 C with embedding filler Burnt till through 15 minutes, after cooling down with stove, embedding filler is screened out and is i.e. able to the haydite that ceramic tile waste material is raw material.
Wherein, the adjustable density burning till haydite of change of tile polished waste and carborundum content in step (1).Step (3) in magnesia with quartz using mass ratio as 0:1 ~ the material grain that mix of 0.2:1 is as embedding filler.For improving bag in step (3) The efficiency of the sieving technology burying filler and burn till gained haydite, embedding filler is 2:1 ~ 10:1 with the fineness ratio of haydite.
Having the beneficial effects that of the technical program:
1. the raw material selected by haydite is the polishing slag of polished glazed tile, green compact of ceramic tile waste material and tile edge material, this skill Art belongs to the exploitation of resource circulation utilization technology, can effectively help to solve waste material and stack the environmental problem brought;
2. the raw material sources selected by haydite are extensive, low price, and production method is simple, beneficially industrial applications;
3. embedding filler burns till after mixing with raw haydite, can effectively limit between haydite and embed filler and haydite Between reaction, ensure the distribution of haydite granularity, surface smoothness and the uniformity of chemical constituent;
4. the granularity difference between embedding filler and haydite can improve the efficiency of batch mixing and separating technology, the quartz screened out Grain can reuse, and the utilization ratio of raw material is significantly increased;
5. the chemical composition of haydite and production technology controllable, and then the particle diameter of haydite, proportion and sphericity can be regulated, Ensure the mechanical property of haydite, structural behaviour and the realization of mobile performance.
Detailed description of the invention
Embodiment 1:
(1) carry out dispensing according to mass ratio: tile polished waste 10.2%, green compact of ceramic tile waste material 31%, tile edge material 18%, Laiyang soil 20%, green coke jewel 10%, feldspar 10%, carborundum 0.8%, add water according to the ratio that ratio of water to material is 80:100, mixed with material With the rotating speed ball milling 2 hours of 400 rpms on planetary ball mill after conjunction;
(2) the slip Spray granulation method granulation that will grind through step (1), takes tailing between-40 mesh ~+60 mesh sieves Thing is made a living haydite;
(3) with the quartzy pellet of-100 mesh for embedding filler with the raw haydite prepared through step (2) according to mass ratio for 1: After the ratio mixing of 0.2, burnt till through 15 minutes under 1170 C, after cooling down with stove, quartz-grain material screen is given up except being i.e. able to ceramic tile Material is the haydite of raw material.
Embodiment 2:
(1) dispensing is carried out according to mass ratio: tile polished waste 20%, green compact of ceramic tile waste material 22%, tile edge material 18%, Lay Sun soil 20%, green coke jewel 10%, feldspar 10%, add water according to the ratio that ratio of water to material is 80:100, at planetary ball mill after mixing with material With the rotating speed ball milling 2 hours of 400 rpms on machine;
Crush after (2) slip step (1) ground is dried 1 hour under 130 C and by manual mode granulation, take- Residue on sieve between 40 mesh ~+60 mesh sieves is made a living haydite;
(3) the material grain mixed using mass ratio for 0.2:1 with the magnesia of-100 mesh and the quartz of-100 mesh is filled out as embedding Material, after being mixed according to the ratio that mass ratio is 1:0.2 with the raw haydite prepared through step (2) by embedding filler, under 1170 C Burnt till through 15 minutes, after cooling down with stove, embedding filler is screened out and is i.e. able to the haydite that ceramic tile waste material is raw material.

Claims (1)

1. the method with ceramic tile waste material as raw material and through embedding SINTERING PRODUCTION haydite, it is characterised in that real by following steps Existing:
Step 1. carries out dispensing according to mass ratio: tile polished waste 10 ~ 20%, green compact of ceramic tile waste material 22 ~ 32%, tile edge material 18%, Laiyang soil 20%, green coke jewel 10%, feldspar 10%, carborundum 0 ~ 0.8%, adds according still further to the ratio that ratio of water to material is 80:100 Water, with the rotating speed ball milling 2 hours of 400 rpms on planetary ball mill after mixing with material;
The slip mist projection granulating that step 2. will grind through step 1, or the slip ground through step 1 is dried 1 under 130 C After hour broken and by pelletizer or manual mode granulation, take residue on sieve after sieving and make a living haydite;
The raw haydite prepared through step 2 is mixed with the ratio of 0:1 ~ 0.4:1 by step 3. with embedding filler, wherein wraps Bury filler be magnesia with quartz with mass ratio as 0:1 ~ the material grain that mix of 0.2:1, raw haydite with the fineness ratio embedding filler is 2:1 ~ 10:1, burnt till through 15 minutes under 1170 C, after cooling down with stove, embedding filler screened out i.e. to be able to ceramic tile waste material be raw material Haydite.
CN201510244701.4A 2015-05-14 2015-05-14 A kind of method with ceramic tile waste material as raw material and through embedding SINTERING PRODUCTION haydite Expired - Fee Related CN104891960B (en)

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CN105513904A (en) * 2015-12-16 2016-04-20 娄底市安地亚斯电子陶瓷有限公司 Processing technology for ceramic fuse tube of DC fuse installation element
CN106396696B (en) * 2016-08-26 2019-03-15 山东金璞新材料有限公司 The preparation method of mullite spherical shape aggregate enhancing refractory material
CN110606728A (en) * 2019-09-21 2019-12-24 河南祥盛陶粒有限公司 Light microporous ceramsite sand and preparation process thereof
CN114614132A (en) * 2022-03-08 2022-06-10 宜宾光原锂电材料有限公司 Waste lithium battery discharging method

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