CN1048916C - Organic sulfur hydrolysis catalyst and preparation thereof - Google Patents
Organic sulfur hydrolysis catalyst and preparation thereof Download PDFInfo
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- CN1048916C CN1048916C CN95111160A CN95111160A CN1048916C CN 1048916 C CN1048916 C CN 1048916C CN 95111160 A CN95111160 A CN 95111160A CN 95111160 A CN95111160 A CN 95111160A CN 1048916 C CN1048916 C CN 1048916C
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- titanium
- hydroxide
- organic sulfur
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- 239000003054 catalyst Substances 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 125000001741 organic sulfur group Chemical group 0.000 title claims abstract description 15
- 230000007062 hydrolysis Effects 0.000 title abstract description 8
- 238000006460 hydrolysis reaction Methods 0.000 title abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims abstract description 11
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 10
- 238000005406 washing Methods 0.000 claims abstract description 9
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000011265 semifinished product Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- -1 Mei Chemical compound 0.000 claims 1
- 239000012065 filter cake Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 238000001354 calcination Methods 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006477 desulfuration reaction Methods 0.000 abstract description 2
- 230000023556 desulfurization Effects 0.000 abstract description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 abstract 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 235000019580 granularity Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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- Catalysts (AREA)
Abstract
An organic sulfur hydrolysis catalyst and a preparation method thereof. The catalyst consists of 4-20 wt% of titanium dioxide and gamma-alumina. The preparation method is that refined aluminum hydroxide and titanium hydroxide are mixed according to a proportion and then are rolled into balls for molding. Treating the semi-finished ball with a special washing solution, activating and calcining. The catalyst has good hydrolysis effect on carbonyl sulfide, carbon disulfide, mercaptan, thioether and the like, and can further convert hydrogen sulfide generated by hydrolysis into elemental sulfur for recycling. At airspeed of 1800 DEG C-1The content of COS reaches 5000 mg/m3Under the condition, the hydrolysis conversion rate is more than or equal to 90 percent, and the organic sulfur hydrolysis catalyst can be widely used for hydrolyzing organic sulfur in desulfurization devices in various industries.
Description
The invention belongs to the catalyst class, relate to organic sulfur hydrolyst and preparation method thereof.
The nineties, China introduces advanced foreign technology, builds up tens covers in succession and adopts the coke oven gas purification that ammonia decomposes and the Sulfur Recovery Unit technology combines to reclaim new technology.Wherein in the claus reaction device except that filling sulfur recovery catalyst, also must load the part organic sulfur hydrolyst, (mainly be cos, content is at 3000～5000 milligrams/meter to be used for organic sulfur with acid gas
3) be hydrolyzed into hydrogen sulfide, and further be converted into elementary sulfur.China's first cover adopts CR type sulfur recovery catalyst, the CRS-21 type organic sulfur hydrolyst of the device imported France Rhone-Poulenc production once of this new technology.From relevant documents and materials, CR type catalyst is full alumina balls, and CRS-21 type catalyst is to make with CR type catalyst soakage titanium compound.Domestic also have similar catalyst, for example LS-811 type, a LS-821 type catalyst.The same with CRS-21 type catalyst, LS-821 type catalyst is to make with LS-811 type catalyst soakage titanium compound.Restricted by manufacturing condition, CRS-21 type catalyst and LS-821 type catalyst have a common characteristic, and promptly active component titanium dioxide mainly is distributed in catalyst coating, and titanium dioxide easily runs off in the use, cause catalytic performance to descend.
Domestic have in the TG series that a class organic sulfur hydrolyst such as the Ministry of Chemical Industry's chemical fertilizer researched and developed in addition, the low temperature organic sulfur hydrolyst, and inlet cos content is at 100～200 milligrams/meter
3Organic sulfur hydrolyst (Chinese patent CN1069673A) disposal ability of Hubei Prov. Chemical Research Inst research and development is littler, only 1～5 milligram/meter of inlet cos content
3This class catalyst all is to adopt alkali metal such as alumina balls dipping sodium, potassium, is used for that Fischer-Tropsch is synthetic, the smart desulfurization of ammonia factory and other unstripped gas.
The purpose of this invention is to provide a kind of hydrolyst and the unique preparation process thereof that can handle the high level organic sulfur.This activity of such catalysts uniform component distribution is difficult for running off, and longer service life is of a specified duration.
Technical scheme of the present invention is that titanium hydroxide and the aluminium hydroxide that will refine mix, roller forming, handles with the weak acid solution cyclic washing that contains ammonia, and catalyst of the present invention is made in activated, calcining.Catalyst main active component content of titanium dioxide is 4～20% (weight), and crystalline form is a Detitanium-ore-type, and carrier is a gama-alumina.
At first refining titanium oxide.Titanium-containing compound is handled with mixing ammonium salt solution, put into centrifugal separator and dry, repeatable operation is up to qualified.The wet cake that makes is put into oven for drying, is crushed to≤0.045 millimeter (330 order), obtains the titanium hydroxide of content of titanium dioxide 〉=80% (weight).
The synthetic method of aluminium hydroxide is a lot, can be according to the working condition method production of choosing any one kind of them, granularity should≤0.045 millimeter (330 order), and the dehydration back stirs in mixer by a certain percentage with titanium hydroxide, keep 70～150 ℃ of mixed material temperature, roller forming.The weight ratio of aluminium hydroxide and titanium hydroxide is 7～15.
Preparation contains the weak acid solution (PH4～7) of ammonia in the sink that can lead to the even heating of steam, the semi-finished product ball is put into groove wash.Logical an amount of steam is kept the wash solution temperature at 70～100 ℃ in the washing process; Join the wash solution washing again after changing clear water washing, qualified up to impurity contents such as pore structure and sodium, iron.Wash solution is with preparations such as deionized water and ammonium salt, acetic acid, prepares variable concentrations according to the impure situation of semi-finished product ball, and PH is 4～7.
200～300 ℃ of activation 2～3 hours in activation furnace of titanium aluminium ball oven dry back by said process preparation place calcining kiln to calcine then, 500～600 ℃ of calcining heats, and calcination time 3～5 hours makes catalyst of the present invention.
Catalyst of the present invention is the spheric granules of 3～8 millimeters of diameters, is made up of the anatase titanium dioxide and the gama-alumina of 4～20% (weight), and impurity contents such as sodium, iron, magnesium, calcium, silicon all are lower than 0.1% (weight).This catalyst has higher specific surface area (180～300 meters/gram) and pore volume (0.4～0.6 milliliter/gram), crush strength 〉=130 newton/.
Embodiment:
The aluminium hydroxide that takes by weighing 2 kilograms of granularities and be 0.045 millimeter carries out processed, and other takes by weighing 180 gram granularities is 0.045 millimeter refining titanium hydroxide, stirs roller forming, about 80 ℃ of mixed material temperature in mixer.Wet bulb is put into polybag and was left standstill 16 hours.
Take by weighing ammonium chloride 80 gram and be dissolved in 8 liters of deionized waters, add acetic acid and transfer to PH in right amount and 5 be made into wash solution; The semi-finished product ball is put into cleaning solution, logical Steam Heating, the cleaning solution temperature maintenance is at 80～90 ℃; Change the clear water washing after one hour.It is qualified up to middle control detection to repeat aforesaid operations.
The titanium aluminium ball that washing is good is dried back 300 ℃ of activation 2 hours, and 580 ℃ of roastings got final product in 4 hours.
Catalyst of the present invention contrasts with CRS-21 type catalyst result of use under identical industrial operation condition of French Rhone-Poulenc: certain coke-oven plant uses CRS-21 type catalyst, when stopping, for the first time annual overhaul gets a little detection of active, conversion ratio less than 50%, accumulative total is used and is changed catalyst of the present invention after 2 years, used more than 2 years up till now, effect is fine always, does not find to exceed standard phenomenon.
The activity of such catalysts test is carried out in the glass reactor of 28 millimeters of internal diameters.The employing original catalyst particle size detects, 20 milliliters of loadings, and 220 ℃ of reaction temperatures are during air speed 1800
-1, normal pressure, activity is represented with the COS hydrolysis conversion.When in the unstripped gas during COS content 0.2% (volume), catalyst of the present invention is suitable with CRS-21 type catalyst activity, all 〉=90%.
Catalyst of the present invention has that reactivity is good, working strength is high and is steady The qualitative good characteristics that are difficult for inactivation. The specific area of catalyst of the present invention Greatly, pore structure is good, has hydrolysis and sulfur recovery dual-use function.
Catalyst of the present invention also can be used for sour crude oil and natural gas processing, Organic sulfur removal in various synthesis gas or the town gas preparation process.
Claims (8)
1, a kind of organic sulfur hydrolyst, it is characterized in that this catalyst is made up of gama-alumina and titanium dioxide, content of titanium dioxide is 4～20% (weight), and crystalline form is a Detitanium-ore-type, carrier is a gama-alumina, and sodium, iron, Mei, Calcium, silicone content are lower than 0.1% (weight).
2, catalyst according to claim 1 is characterized in that catalyst is the spheric granules of 3～8 millimeters of diameters, and specific area is 180～300 meters
2/ gram, pore volume is 0.4～0.6 milliliter, crush strength more than or equal to 130 newton/.
3, a kind of preparation method of organic sulfur hydrolyst according to claim 1, it is characterized in that this method mainly is made up of following steps: 1. titanium oxide is refining, ammonium salt solution is handled, centrifuge dripping with mixing with titanium-containing compound, repeated multiple times makes titanium hydroxide filter cake and the pulverizing of content of titanium dioxide greater than 80% (weight); 2. the preliminary treatment of aluminium hydroxide; 3. mix roller forming behind the aluminium hydroxide dehydration of handling well by a certain percentage with titanium hydroxide; 4. preparation contains the weak acid solution washing semi-finished product ball of ammonia, and repeated multiple times is qualified up to pore structure and impurity content; 5. 200～300 ℃ activate 2～3 hours; 6. calcined 3～5 hours for 500～600 ℃.
4, preparation method according to claim 3, when it is characterized in that refining aluminium hydroxide mixes with titanium hydroxide, its weight ratio is 7～15.
5, preparation method according to claim 3, the granularity that it is characterized in that refining aluminium hydroxide and titanium hydroxide is all smaller or equal to 0.045 millimeter (330 order).
6, preparation method according to claim 3, when it is characterized in that refining aluminium hydroxide mixes with titanium hydroxide, the temperature that keeps mixed material is at 70～150 ℃.
7, preparation method according to claim 3 is characterized in that weak acid solution PH4～7 that contain ammonia of being prepared.
8, preparation method according to claim 3, the temperature that it is characterized in that control wash solution in the washing process is at 70～100 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95111160A CN1048916C (en) | 1995-08-16 | 1995-08-16 | Organic sulfur hydrolysis catalyst and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95111160A CN1048916C (en) | 1995-08-16 | 1995-08-16 | Organic sulfur hydrolysis catalyst and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1134312A CN1134312A (en) | 1996-10-30 |
| CN1048916C true CN1048916C (en) | 2000-02-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95111160A Expired - Fee Related CN1048916C (en) | 1995-08-16 | 1995-08-16 | Organic sulfur hydrolysis catalyst and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1048916C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331596C (en) * | 2005-01-19 | 2007-08-15 | 太原理工大学 | Low-temperature hydrolyst for high concentrated organosulfur and preparation thereof |
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| CN1080584C (en) * | 1997-12-26 | 2002-03-13 | 太原理工大学 | Normal atmospheric temp. and low temp. organic sulphur hydrolyst and its prepn. |
| CN1102420C (en) * | 2000-07-11 | 2003-03-05 | 中国科学院山西煤炭化学研究所 | Hydrolytic catalyst of carbonyl sulfur and its preparing process and application |
| FR2830466B1 (en) * | 2001-10-09 | 2004-02-06 | Axens | USE OF A TI02-BASED COMPOSITION AS A CATALYST FOR REALIZING COS AND / OR HCN HYDROLYSIS IN A GASEOUS MIXTURE |
| CN101987970B (en) * | 2009-07-30 | 2014-08-20 | 中国石油化工股份有限公司 | Method for removing mercaptan from gasoline |
| CN102200179B (en) * | 2010-03-23 | 2014-03-26 | 鸿富锦精密工业（深圳）有限公司 | Speed reducing mechanism |
| US10376836B2 (en) | 2013-12-31 | 2019-08-13 | Beijing Sj Environmental Protection And New Material Co., Ltd. | Desulfurizer for conversion and absorption of high-concentration carbonyl sulfide and a desulfurizer for catalytic conversion and absorption of carbon disulfide and their preparation methods |
| CN104740981B (en) * | 2013-12-31 | 2017-10-03 | 北京三聚环保新材料股份有限公司 | A kind of carbon disulfide inversion absorption type desulfurizing agent and preparation method thereof |
| CN105032393B (en) * | 2015-07-31 | 2018-07-13 | 青岛联信催化材料有限公司 | A kind of high water/gas Sulfur Contained Raw Gas organic sulfur conversion catalyst of high pressure |
| CN106824193A (en) * | 2017-01-17 | 2017-06-13 | 福州大学化肥催化剂国家工程研究中心 | A kind of organic sulfur hydrolyst and preparation method thereof |
| CN114425315B (en) * | 2020-09-28 | 2023-10-31 | 中国石油化工股份有限公司 | Normal temperature CS 2 Hydrolysis agent and preparation method thereof |
| CN113731391A (en) * | 2021-08-27 | 2021-12-03 | 江苏朗润环保科技有限公司 | High-antioxidant low-temperature organic sulfur hydrolysis catalyst and preparation method thereof |
| CN114682241B (en) * | 2022-03-24 | 2023-08-25 | 福州大学 | Titanium dioxide-aluminum oxide composite desulfurization catalyst and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4491516A (en) * | 1983-11-22 | 1985-01-01 | Sun Refining And Marketing Company | Hydrolysis of carbonyl sulfide over alumina |
| CN1069673A (en) * | 1992-06-08 | 1993-03-10 | 湖北省化学研究所 | Normal tempreture organic sulphur hydrolysis catalyst and preparation |
| CN1095309A (en) * | 1994-02-21 | 1994-11-23 | 中国石化齐鲁石油化工公司 | Novel carbonyl sulfide hydrolysis catalyst |
-
1995
- 1995-08-16 CN CN95111160A patent/CN1048916C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4491516A (en) * | 1983-11-22 | 1985-01-01 | Sun Refining And Marketing Company | Hydrolysis of carbonyl sulfide over alumina |
| CN1069673A (en) * | 1992-06-08 | 1993-03-10 | 湖北省化学研究所 | Normal tempreture organic sulphur hydrolysis catalyst and preparation |
| CN1095309A (en) * | 1994-02-21 | 1994-11-23 | 中国石化齐鲁石油化工公司 | Novel carbonyl sulfide hydrolysis catalyst |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331596C (en) * | 2005-01-19 | 2007-08-15 | 太原理工大学 | Low-temperature hydrolyst for high concentrated organosulfur and preparation thereof |
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| Publication number | Publication date |
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| CN1134312A (en) | 1996-10-30 |
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