CN104877214A - Fluoridated plastic container - Google Patents

Abstract

The invention discloses a fluoridated plastic container which is prepared from the following components in parts by weight: 0.4-1 part of nickel hypophosphite, 1-2 parts of mannitol, 0.8-1 part of potassium pyrophosphate, 0.2-0.4 part of propanediol phenyl ether, 1-2 parts of magnesium fluoride, 2-4 parts of acetyl triethyl citrate, 0.1-0.4 part of ethylene thiourea, 2-3 parts of boric oxide, 2-4 parts of polyisodiene, 5-7 parts of fluorapatite, 0.8-1 part of bisoctyl dimethyl ammonium chloride, 1-2 parts of urea, 0.4-1 part of magnesium hydrate, 84-90 parts of high density polyethylene and 10-15 parts of a fluoridated sizing material. The plastic container disclosed by the invention is high in hardness, has good wear resistance and overall performance, is hard to age and strong in leakage resistance, and can be used for containing liquids.

Description

A kind of fluorinated plastic container

Technical field

The present invention relates generally to plastic applications, particularly relates to a kind of fluorinated plastic container.

Background technology

Plastic containers are seen everywhere in life, bucket, bottle, tank, cup etc., because it is of many uses, throw-out also gets more and more, inevitable pollution is caused to environment, the plastic containers simultaneously had need the chemical products holding different performance, and some chemical productss can cause certain erosion to plastics itself, not only have a strong impact on the purity of chemical products, also easily cause danger in various degree, some plastic containers easily distribute toxic gas under burning or hot environment, the safety of harm surrounding population, in order to improve the defect of conventional plastic container each side, therefore reasonable disposition plastic formula composition is needed, add waste-tyre rubber-powder simultaneously, make full use of Resource recovery, reduce production cost, improve the integrated quality of finished plastic containers.

Summary of the invention

The object of the invention is just to provide a kind of fluorinated plastic container.

The present invention is achieved by the following technical solutions:

A kind of fluorinated plastic container, is characterized in that what it was made up of the raw material of following weight parts:

Nickelous hypophosphite 0.4-1, N.F,USP MANNITOL 1-2, potassium pyrophosphate 0.8-1, propylene glycol phenylate 0.2-0.4, magnesium fluoride 1-2, acetyl triethyl citrate 2-4, ethylene thiourea 0.1-0.4, boron oxide 2-3, poly-different diene 2-4, fluorapatite 5-7, two octyldimethyl ammonium chloride 0.8-1, urea 1-2, magnesium hydroxide 0.4-1, high density polyethylene(HDPE) 84-90, fluoridize sizing material 10-15;

Described fluoridize that sizing material is made up of the raw material of following weight parts:

Ten difluoro heptyl propyl trimethoxy silicane 2-3, waste-tyre rubber-powder 80-90, polyoxyethylene glycol 6-8, aluminium titanates 1-2, diatomite 4-6, ethyl cellulose 16-20, tetracol phenixin 30-41, tributyl citrate 2-3, whiteruss 50-60,2-mercaptobenzothiazole 0.1-0.2;

Polyoxyethylene glycol, ethyl cellulose are mixed to join in tetracol phenixin, ultrasonic vibration 3-5 minute, obtain solution a; Joined by tributyl citrate in whiteruss, after stirring, raised temperature is 80-90 DEG C, drips above-mentioned solution a, dropwises rear insulation reaction 1-2 hour, diatomite is mixed with aluminium titanates, adds after wearing into fine powder, ageing 3-4 hour, press filtration, dry, obtain dry powder;

By waste-tyre rubber-powder, above-mentioned dry powder blend, be heated to 60-65 DEG C, add ten difluoro heptyl propyl trimethoxy silicanes, insulated and stirred 20-30 minute, raised temperature is 150-160 DEG C, add 2-mercaptobenzothiazole, be act on 4-5 minute under the microwave exposure of 2450MHz in microwave frequency, must sizing material be fluoridized.

A preparation method for fluorinated plastic container, comprises the following steps:

(1) by magnesium fluoride, fluorapatite mixing, add poly-different diene, acetyl triethyl citrate after ball milling is even, insulated and stirred 4-6 minute at 80-90 DEG C, adds urea, is stirred to normal temperature;

(2) two octyldimethyl ammonium chloride is joined in 3-4 times of water, after stirring, add N.F,USP MANNITOL, propylene glycol phenylate, boron oxide, 60-100 rev/min of dispersed with stirring 2-3 minute;

(3) each raw material after above-mentioned process is mixed with each raw material of residue, join in forcing machine, melt extrude into pipe by forcing machine;

(4) designed still importing at the little pipe of molten state in the mould of definite shape, mould has been closed, and be blown into high-pressure air simultaneously and make it according to the mould molding set, simultaneously to mold cools down sizing, then started the goods that die cavity has been shaped.

Advantage of the present invention is:

Of the present inventionly fluoridize sizing material: the present invention is by polyoxyethylene glycol, the carbon tetrachloride solution of ethyl cellulose joins in whiteruss, because tetracol phenixin is easy to spread in whiteruss, be separated, add diatomite in powder, aluminium titanates, can be formed by alcohol, Mierocrystalline cellulose, soil powder, the height mixture of aluminium titanates composition, give mixture good thermostability simultaneously, thermoplasticity, anti-old property etc., aluminium titanates can also reduce the thermal conductivity of finished product, improve resistance and high thermal resistance, then mix with waste-tyre rubber-powder and carry out microwave treatment, further increase the anti-aging and anti-caking effect of rubber powder, the ten difluoro heptyl propyl trimethoxy silicanes added can improve electrical insulating property and the resistance to medium of rubber, obtain high strength, high tenacity, resistance rubber powder,

Plastic containers hardness of the present invention is high, has good resistance to abrasion, good combination property, not easily aging, and leakage resistance is strong, may be used for taking up liquid.

Embodiment

Embodiment 1:

A kind of fluorinated plastic container, is characterized in that what it was made up of the raw material of following weight parts:

Nickelous hypophosphite 0.4, N.F,USP MANNITOL 1, potassium pyrophosphate 0.8, propylene glycol phenylate 0.4, magnesium fluoride 1, acetyl triethyl citrate 4, ethylene thiourea 0.4, boron oxide 2, poly-different diene 2, fluorapatite 5, two octyldimethyl ammonium chloride 0.8, urea 2, magnesium hydroxide 0.4, high density polyethylene(HDPE) 90, fluoridize sizing material 10;

Described fluoridize that sizing material is made up of the raw material of following weight parts:

Ten difluoro heptyl propyl trimethoxy silicanes 3, waste-tyre rubber-powder 90, polyoxyethylene glycol 8, aluminium titanates 2, diatomite 4, ethyl cellulose 20, tetracol phenixin 41, tributyl citrate 2, whiteruss 60,2-mercaptobenzothiazole 0.2;

Be mixed to join in tetracol phenixin by polyoxyethylene glycol, ethyl cellulose, ultrasonic vibration 5 minutes, obtains solution a; Joined by tributyl citrate in whiteruss, after stirring, raised temperature is 90 DEG C, drips above-mentioned solution a, dropwises rear insulation reaction 2 hours, is mixed by diatomite with aluminium titanates, add after wearing into fine powder, ageing 4 hours, press filtration, dry, obtains dry powder;

By waste-tyre rubber-powder, above-mentioned dry powder blend, be heated to 65 DEG C, add ten difluoro heptyl propyl trimethoxy silicanes, insulated and stirred 30 minutes, raised temperature is 160 DEG C, adds 2-mercaptobenzothiazole, be act on 4 minutes under the microwave exposure of 2450MHz in microwave frequency, must sizing material be fluoridized.

A preparation method for fluorinated plastic container, is characterized in that comprising the following steps:

(1) by magnesium fluoride, fluorapatite mixing, add poly-different diene, acetyl triethyl citrate after ball milling is even, at 90 DEG C, insulated and stirred 4 minutes, adds urea, is stirred to normal temperature;

(2) two octyldimethyl ammonium chloride is joined in 3 times of water, after stirring, add N.F,USP MANNITOL, propylene glycol phenylate, boron oxide, 100 revs/min of dispersed with stirring 2 minutes;

(3) each raw material after above-mentioned process is mixed with each raw material of residue, join in forcing machine, melt extrude into pipe by forcing machine;

(4) designed still importing at the little pipe of molten state in the mould of definite shape, mould has been closed, and be blown into high-pressure air simultaneously and make it according to the mould molding set, simultaneously to mold cools down sizing, then started the goods that die cavity has been shaped.

Performance test:

Tensile strength: 53MPa;

Flexural strength: 61 MPa;

Resistance to impact shock: 18.0KJ/m ².

Claims (2)

1. a fluorinated plastic container, is characterized in that what it was made up of the raw material of following weight parts:

Nickelous hypophosphite 0.4-1, N.F,USP MANNITOL 1-2, potassium pyrophosphate 0.8-1, propylene glycol phenylate 0.2-0.4, magnesium fluoride 1-2, acetyl triethyl citrate 2-4, ethylene thiourea 0.1-0.4, boron oxide 2-3, poly-different diene 2-4, fluorapatite 5-7, two octyldimethyl ammonium chloride 0.8-1, urea 1-2, magnesium hydroxide 0.4-1, high density polyethylene(HDPE) 84-90, fluoridize sizing material 10-15;

Described fluoridize that sizing material is made up of the raw material of following weight parts:

Ten difluoro heptyl propyl trimethoxy silicane 2-3, waste-tyre rubber-powder 80-90, polyoxyethylene glycol 6-8, aluminium titanates 1-2, diatomite 4-6, ethyl cellulose 16-20, tetracol phenixin 30-41, tributyl citrate 2-3, whiteruss 50-60,2-mercaptobenzothiazole 0.1-0.2;

Polyoxyethylene glycol, ethyl cellulose are mixed to join in tetracol phenixin, ultrasonic vibration 3-5 minute, obtain solution a; Joined by tributyl citrate in whiteruss, after stirring, raised temperature is 80-90 DEG C, drips above-mentioned solution a, dropwises rear insulation reaction 1-2 hour, diatomite is mixed with aluminium titanates, adds after wearing into fine powder, ageing 3-4 hour, press filtration, dry, obtain dry powder;

By waste-tyre rubber-powder, above-mentioned dry powder blend, be heated to 60-65 DEG C, add ten difluoro heptyl propyl trimethoxy silicanes, insulated and stirred 20-30 minute, raised temperature is 150-160 DEG C, add 2-mercaptobenzothiazole, be act on 4-5 minute under the microwave exposure of 2450MHz in microwave frequency, must sizing material be fluoridized.

2. a preparation method for fluorinated plastic container as claimed in claim 1, is characterized in that comprising the following steps:

(1) by magnesium fluoride, fluorapatite mixing, add poly-different diene, acetyl triethyl citrate after ball milling is even, insulated and stirred 4-6 minute at 80-90 DEG C, adds urea, is stirred to normal temperature;

(2) two octyldimethyl ammonium chloride is joined in 3-4 times of water, after stirring, add N.F,USP MANNITOL, propylene glycol phenylate, boron oxide, 60-100 rev/min of dispersed with stirring 2-3 minute;

(3) each raw material after above-mentioned process is mixed with each raw material of residue, join in forcing machine, melt extrude into pipe by forcing machine;

(4) designed still importing at the little pipe of molten state in the mould of definite shape, mould has been closed, and be blown into high-pressure air simultaneously and make it according to the mould molding set, simultaneously to mold cools down sizing, then started the goods that die cavity has been shaped.