CN104862534A - Nickel-based alloy and preparation method and application thereof - Google Patents
Nickel-based alloy and preparation method and application thereof Download PDFInfo
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Abstract
The invention discloses nickel-based alloy and a preparation method and application thereof, and relates to the technical field of anti-corrosion materials. The nickel-based alloy and the preparation method and application thereof aim to solve the problem that an existing Inconel-625 material or a Hastelloy C-276 material causes poor corrosion resistance of supercritical equipment in an acidic oxidizing medium where various ions coexist. The nickel-based alloy comprises, by mass, 15-28% of Cr, 4-13% of Mo, 0.5-1.5% of Ti, 1-4% of Cu, 6-15% of Fe, 0-0.03% of C, 0-0.5% of microelements and the balance Ni. According to the preparation method of the nickel-based alloy, Ni, Cr, Mo and Fe are mixed and melted under a vacuum condition till being clarified, then refining is carried out, after refining is finished, Ti and the microelements are added and evenly stirred, desulfuration is carried out, and finally casting molding is carried out to obtain the nickel-based alloy. The nickel-based alloy can be used in the supercritical equipment as a corrosion-resistant material.
Description
Technical field
The present invention relates to corrosion resistant material technical field, particularly relate to a kind of nickel-base alloy and its preparation method and application.
Background technology
At present, along with various countries are to the attention of environmental protection, also higher requirement is proposed accordingly to the process of trade effluent, municipal effluent.Supercritical water oxidation method treatment technology utilizes supercritical water as medium, under high-temperature and high-pressure conditions, organism oxygen contained in waste water or sewage resolved into the simply nontoxic micromolecular compound such as water, carbonic acid gas.Because supercritical water oxidation method treatment technology almost reaches 100% to organism clearance rate contained in waste water or sewage, and be fully oxidized at full closeding state organism, non-secondary pollution, therefore, technique is subject to people's attention day by day.
Supercritical water oxidation method treatment technology carries out under high temperature, condition of high voltage, requires high especially to the corrosion resisting property of overcritical equipment.In addition, owing to containing the materials such as various salts in some waste water or sewage, after the water in overcritical equipment reaches super critical point, salts substances contained in waste water or sewage is under the existence of dissolved oxygen, corrosion can be produced to overcritical equipment, therefore, need to carry out anti-corrosive treatment to overcritical equipment, to improve the corrosion resistance nature of overcritical equipment.
In order to improve the resistance to corrosion of overcritical equipment, Inconel-625 material or Hastelloy C-276 material is usually adopted to carry out corrosion-resistance treatment to the interchanger of overcritical equipment and reactor; Wherein, Inconel-625 material has outstanding anti-crevice corrosion ability, and has good processibility and weldability, and cracking sensitivity after welding.Hastelloy C-276 material main moisture-proof chlorine, various oxidisability muriate, chlorate solution, sulfuric acid and oxidisability salt, all have good corrosion resisting property in low temperature and middle thermohaline acid.But research finds, Inconel-625 material or Hastelloy C-276 material are in different kinds of ions and in the acidic oxidation medium deposited, often occur multiple corrosion phenomenon, causes the resistance to corrosion of overcritical equipment poor.
Summary of the invention
The object of the present invention is to provide a kind of nickel-base alloy and its preparation method and application, in the acidic oxidation medium deposited, the problem of the resistance to corrosion difference of overcritical equipment is caused to solve existing Inconel-625 material or Hastelloy C-276 material in different kinds of ions.
To achieve these goals, the invention provides following technical scheme:
A kind of nickel-base alloy, in massfraction, comprise the Cr that massfraction is 15%-28%, massfraction is the Mo of 4%-13%, and massfraction is the Ti of 0.5%-1.5%, and massfraction is the Cu of 1%-4%, massfraction is the Fe of 6%-15%, massfraction is be greater than the C that 0 is less than or equal to 0.03%, and massfraction is the trace element of 0-0.5%, and surplus is Ni.
Preferably, described nickel-base alloy comprises the Cr that massfraction is 17.5%-25%, massfraction is the Mo of 4%-10%, massfraction is the Ti of 0.55%-1.0%, massfraction is the Cu of 2%-3.5%, and massfraction is the Fe of 7%-14%, and massfraction is be greater than the C that 0 is less than or equal to 0.02%, massfraction is the trace element of 0-0.3%, and surplus is Ni.
Preferably, described nickel-base alloy comprises the Cr that massfraction is 16.8%-24.5%, massfraction is the Mo of 5.8%-10.5%, massfraction is the Ti of 0.6%-1.0%, massfraction is the Cu of 2%-3%, and massfraction is that the massfraction of the Fe of 7%-13%, C is less than or equal to 0.01% for being greater than 0, the massfraction of trace element is 0-0.3%, and surplus is Ni.
Preferably, described nickel-base alloy comprises the Cr that massfraction is 16%-20%, massfraction is the Mo of 5%-10%, massfraction is the Ti of 0.6%-1.0%, massfraction is the Cu of 2%-4%, and massfraction is the Fe of 7.5%-12.5%, and massfraction is be greater than the C that 0 is less than or equal to 0.01%, massfraction is the trace element of 0-0.5%, and surplus is Ni.
Preferably, described trace element comprises one or more in W, Al, Mn, V, Nb, Co, B.
Preferably, in described nickel-base alloy,
The massfraction of described W is less than or equal to 0.5% for being greater than 0; And/or
The massfraction of described Al is greater than 0 and is less than or equal to 0.4%; And/or
The massfraction of described Mn is greater than 0 and is less than or equal to 0.4%; And/or
The massfraction of described V is greater than 0 and is less than or equal to 0.4%; And/or
The massfraction of described Nb is greater than 0 and is less than or equal to 0.5%; And/or
The massfraction of described Co is greater than 0 and is less than or equal to 0.3%; And/or
The massfraction of described B is greater than 0 and is less than or equal to 0.006%.
Present invention also offers a kind of preparation method of nickel-base alloy, comprise the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu and trace element respectively, wherein, be calculated in mass percent, the massfraction of Cr is 15%-28%, the mass percent of the mass percent of Mo to be the mass percent of 4%-13%, Ti be 0.5%-1.5%, Cu is 1%-4%, the mass percent of Fe is 6%-15%, and the mass percent of trace element is 0-0.5%; The mass percent of the C substituted in Ni, Cr, Mo, Fe, Ti, Cu and trace element is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, by Ni, Cr, Mo, Fe under vacuum mixed melting until change clear, obtaining clearly after molten metal bath;
Step 3, clear to describedization after molten metal bath carry out refining, cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains;
Step 4, in the described refining liquid of shallow freezing conjunctiva, be blown into protective gas, then that described refining liquid is melted is homogeneous in heating, adds Ti, Cu and trace element and stirs, obtaining aluminium alloy;
Step 5, in aluminium alloy, add sweetening agent, then vacuumize, be incubated under vacuum with the desulfurization of alloy liquid, last casting, obtains nickel-base alloy.
Preferably, during described step 3 refining, refining temperature is 1450 DEG C-1500 DEG C, and refining time is 17 minutes-23 minutes, in step 5, before adding sweetening agent, controls the temperature of aluminium alloy at 1380-1390 DEG C.
Present invention also offers a kind of described nickel-base alloy as the application of corrosion resistant material in overcritical equipment.
Compared with prior art, the present invention has following beneficial effect:
Nickel-base alloy of the present invention comprises the Cr that massfraction is 15%-28%, also containing massfraction be the Mo of 4%-13%, the massfraction Ti that is 0.5%-1.5%, the massfraction Cu that is 1%-4%, massfraction be the Fe of 6%-15%, under this content, Cr in nickel-base alloy can cause austenitic matrix lattice distortion, reduce sosoloid stacking fault energy, solution strengthening effect is served to austenitic matrix simultaneously, make the intensity of the austenite sosoloid in nickel-base alloy high; And the Cr in nickel-base alloy can form fine and close passive state Cr when high temperature
2o
3type oxide film, makes nickel-base alloy have good anti-oxidant and hot corrosion resistance under the high temperature conditions; Mo in nickel-base alloy has good erosion resistance to sour environment, makes nickel-base alloy have good erosion resistance in the supercritical water of acidic conditions; And Ti is the component forming strengthening phase in nickel-base alloy, wherein a part of Ti enters in the γ sosoloid of nickel-base alloy, solution strengthening effect is served to nickel-base alloy, in addition some Ti enter nickel-base alloy γ ' mutually in, with to nickel-base alloy precipitation strength, the intensity of nickel-base alloy is further enhanced; In addition, Cu significantly can improve the corrosion resisting property of Ni in non-oxidizing acid and the stability of counter stress corrosion, and, because nickel-base alloy provided by the invention belongs to Ni-Cr-Fe system alloy, Cu wherein containing 1%-4% can produce ageing strengthening effect, thus improves the intensity of nickel-base alloy.
Known by analyzing above, the present invention is by the optimization to chemical composition each in nickel-base alloy, make nickel-base alloy can not only have good erosion resistance in Oxidant, but also there is preferably intensity, good erosion resistance can be kept in acid condition, make nickel-base alloy in different kinds of ions and in the acidic oxidation medium deposited, corrosion speed reduces greatly, thus when ensure that nickel-base alloy provided by the invention is applied to overcritical equipment as corrosion resistant material, improve the resistance to corrosion of overcritical equipment, enable overcritical equipment safe handling.
Embodiment
The invention provides a kind of nickel-base alloy, its chemical composition comprise Ni, Cr, Mo, Ti, Cu, Fe, for regulating the trace element of described nickel-base alloy performance, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe and trace element; And in massfraction, in nickel-base alloy, the massfraction of Cr is 15%-28%, the massfraction of Mo is 4%-13%, the massfraction of Ti is 0.5%-1.5%, the massfraction of the massfraction of Cu to be the massfraction of 1%-4%, Fe be 6%-15%, C is less than or equal to 0.03% for being greater than 0, the massfraction of trace element is 0-0.5%, and surplus is Ni.
Of the present invention by being optimized combination to each chemical composition in nickel-base alloy, control the content of each chemical composition simultaneously, solve existing Inconel-625 material or Hastelloy C-276 material in different kinds of ions and in the acidic oxidation medium deposited, cause the resistance to corrosion of overcritical equipment poor, concrete reason is as follows:
The present invention take Ni as matrix element, Ni can dissolve many alloying elements and carry out alloying, and still keep the stability of austenite phase, make to add wherein after other alloying elements carry out alloying, can be formed with austenite is the nickel-base alloy of matrix.
In nickel-base alloy provided by the invention, contained Cr can cause austenitic matrix lattice distortion, reduces sosoloid stacking fault energy, serves solution strengthening effect simultaneously, make the intensity of the austenite sosoloid in nickel-base alloy high to austenitic matrix.
In nickel-base alloy provided by the invention, contained Cr can improve the solidity to corrosion of Ni under the high temperature conditions in Oxidant, and Oxidant comprises oxidizing acid, oxidative acidic salt or oxidisability basic salt, but is not limited only to this.Fine and close passive state Cr can be formed during Cr high temperature wherein
2o
3type oxide film, nickel-base alloy is made to have good anti-oxidant and hot corrosion resistance under the high temperature conditions, and there is good anti-oxidant and hot corrosion resistance under the high temperature conditions therefore due to nickel-base alloy, nickel-base alloy provided by the invention can be applied in overcritical equipment as corrosion resistant material, to improve the corrosion resistance of overcritical equipment.
The present invention is by control Cr content, the rotproofness of nickel-base alloy is improved, and, in different environments, improve the corrosion proof critical Cr content of Ni-Cr alloy different, therefore, the factor will considered when determining Cr content also comprises the interaction of Ni, Cr two kinds of elements, process is very complicated, just can not determine simply by limited number of time experiment.
In nickel-base alloy provided by the invention, Mo has good erosion resistance to sour environment, can improve nickel-base alloy in acid condition, the erosion resistance under especially hydrochloric condition of supercritical water.
In nickel-base alloy provided by the invention, Ti can form the component of strengthening phase in nickel-base alloy, part Ti enters the γ sosoloid of nickel-base alloy, play solution strengthening effect to nickel-base alloy, partial-titanium atom enters the γ ' phase in nickel-base alloy, carries out precipitation strength to nickel-base alloy.
Cu containing 1%-4% in nickel-base alloy provided by the invention, because nickel-base alloy provided by the invention belongs to Ni-Cr-Fe system alloy, therefore, Cu significantly can improve the corrosion resisting property of Ni in non-oxidizing acid and the stability of counter stress corrosion, ageing strengthening effect can be produced, thus improve the intensity of nickel-base alloy.
Also use the Fe of advantage of lower cost in nickel-base alloy provided by the invention, reduce nickel-base alloy cost.
Known by analyzing above, the present invention is by the optimization to chemical composition each in nickel-base alloy, make nickel-base alloy can not only have good erosion resistance in Oxidant in high temperature environments, but also there is preferably intensity, good erosion resistance can be kept in acid condition, make nickel-base alloy in different kinds of ions and in the acidic oxidation medium deposited, corrosion speed reduces greatly, thus when ensure that nickel-base alloy provided by the invention is applied to overcritical equipment as corrosion resistant material, overcritical equipment can safe handling.Meanwhile, the present invention, by carrying out considered critical to the add-on of each chemical composition, makes that each chemical composition is maximized has given play to synergy, thus improves intensity and the corrosion resistance nature of nickel-base alloy.
In order to improve the physical strength of nickel-base alloy, nickel-base alloy of the present invention comprises the Cr that massfraction is 17.5%-25%, massfraction is the Mo of 4%-10%, massfraction is the Ti of 0.55%-1.0%, massfraction is the Cu of 2%-3.5%, and massfraction is the Fe of 7%-14%, and massfraction is be greater than the C that 0 is less than or equal to 0.02%, massfraction is the trace element of 0-0.3%, and surplus is Ni.
In order to maintain the stable phase in nickel-base alloy, nickel-base alloy of the present invention comprises the Cr that massfraction is 16.8%-24.5%, massfraction is the Mo of 5.8%-10.5%, massfraction is the Ti of 0.6%-1.0%, massfraction is the Cu of 2%-3%, and massfraction is that the massfraction of the Fe of 7%-13%, C is less than or equal to 0.01% for being greater than 0, the massfraction of trace element is 0-0.3%, and surplus is Ni.
In order to reduce costs further, nickel-base alloy of the present invention comprises the Cr that massfraction is 16%-20%, massfraction is the Mo of 5%-10%, massfraction is the Ti of 0.6%-1.0%, massfraction is the Cu of 2%-4%, and massfraction is the Fe of 7.5%-12.5%, and massfraction is be greater than the C that 0 is less than or equal to 0.01%, massfraction is the trace element of 0-0.5%, and surplus is Ni.
When the mass percent of nickel-base alloy medium trace element provided by the invention gets 0, namely trace element is not added in nickel-base alloy, now, in massfraction, in nickel-base alloy, the massfraction of Cr is 15%-28%, the massfraction of Mo is 4%-13%, the massfraction of the massfraction of Ti to be the massfraction of 0.5%-1.5%, Cu be 1%-4%, Fe is 6%-15%, the massfraction of C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The mass percent of nickel-base alloy medium trace element provided by the invention is greater than 0 when being less than or equal to 0.5%, namely trace element is contained in nickel-base alloy, now in massfraction, in nickel-base alloy, the massfraction of Cr is 15%-28%, the massfraction of Mo is 4%-13%, the massfraction of Ti is 0.5%-1.5%, the massfraction of Cu is 1%-4%, the massfraction of Fe is 6%-15%, the massfraction of C is less than or equal to 0.03% for being greater than 0, the massfraction of trace element is greater than 0 and is less than or equal to 0.5%, and surplus is Ni.
Further, trace element comprises one or more in W, Al, Mn, V, Nb, Co, B.
In nickel-base alloy, W is for increasing the thermostability of nickel-base alloy and wear resistance, and its massfraction is less than or equal to 0.5% for being greater than 0, is preferably greater than 0 and is less than or equal to 0.3%, is preferably greater than 0 further and is less than or equal to 0.1%; And/or
Al plays solution strengthening and precipitation strength effect to nickel-base alloy, and its massfraction is greater than 0 and is less than or equal to 0.4%, is preferably greater than 0 and is less than 0.2%, is preferably greater than 0 further and is less than or equal to 0.1%; And/or
Mn is used for the tissue stablizing austenitic matrix in nickel-base alloy, and increase the hardening capacity of nickel-base alloy, its massfraction is greater than 0 and is less than or equal to 0.4%, is preferably greater than 0 and is less than or equal to 0.3%, is preferably greater than 0 further and is less than or equal to 0.15%; And/or
V is used for tissue and the grain fineness number of refinement nickel-base alloy, and its massfraction is greater than 0 and is less than or equal to 0.4%, is preferably greater than 0 and is less than or equal to 0.35%, is preferably greater than 0 further and is less than or equal to 0.1%; And/or
Nb is for improving the impelling strength of nickel-base alloy or strengthening resistant to hydrogen performance, and its massfraction is greater than 0 and is less than or equal to 0.5%, is preferably greater than 0 and is less than or equal to 0.4%, is preferably greater than 0 further and is less than or equal to 0.1%; And/or
Co is for improving the tensile strength of nickel-base alloy, and its massfraction is greater than 0 and is less than or equal to 0.3%, is preferably greater than 0 and is less than or equal to 0.2%, is preferably greater than 0 further and is less than or equal to 0.1%; And/or
B is for improving the grain-boundary strengthening of nickel-base alloy, and its massfraction is greater than 0 and is less than or equal to 0.006%.
Some performance variation that these trace elements bring nickel-base alloy are all relevant with the characteristic of himself, repeat no more.
Although there is the inevitable C introduced in nickel-base alloy provided by the invention, and C can destroy the erosion resistance of nickel-base alloy under acidic conditions in nickel-base alloy, belong to the unwanted component to nickel-base alloy, but be not, C cannot introduce, in nickel-base alloy, when C massfraction for be greater than 0 be less than or equal to 0.03% time, the intensity of nickel-base alloy can be improved.
It should be noted that, the C that will inevitably inevitably introduce in nickel-base alloy provided by the invention, the size of its introduction volume is by regulating the amount of Ni, Cr, Mo, Ti, Cu, Fe and trace element to control, therefore, in nickel-base alloy provided by the invention each chemical composition mass percent between be also exist to be mutually related, be not elective.
Present invention also offers a kind of preparation method of above-mentioned nickel-base alloy, comprise the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu and trace element respectively, wherein, be calculated in mass percent, the massfraction of Cr is 15%-28%, the mass percent of the mass percent of Mo to be the mass percent of 4%-13%, Ti be 0.5%-1.5%, Cu is 1%-4%, the mass percent of Fe is 6%-15%, and the mass percent of trace element is 0-0.5%; The mass percent of C inevitable substituted in Ni, Cr, Mo, Fe, Ti, Cu and trace element is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, by Ni, Cr, Mo, Fe under vacuum mixed melting until change clear, obtaining clearly after molten metal bath;
Step 3, clear to describedization after molten metal bath carry out refining, cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains;
Step 4, in the described refining liquid of shallow freezing conjunctiva, be blown into protective gas, then that described refining liquid is melted is homogeneous in heating, adds Ti, Cu and trace element and stirs, obtaining aluminium alloy;
Step 5, in aluminium alloy, add sweetening agent, then vacuumize, be incubated under vacuum with the desulfurization of alloy liquid, last casting, obtains nickel-base alloy.
The preparation of nickel-base alloy completes in vacuum induction furnace, but is not limited only to vacuum induction furnace.
To prepare nickel-base alloy in vacuum induction furnace, in step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize, then by controlling power transmission power, Ni, Cr, Mo, Fe being melted under vacuum, obtaining molten metal bath; Then power transmission power is increased, until molten metal liquefaction is clear, the molten metal bath after obtaining is clear.
Preferably, during vacuum condition, vacuum tightness is less than 10Pa, such as 9.9Pa, 8Pa, 6Pa, 4Pa, 2Pa, 1Pa, and certainly for avoiding oxidation, vacuum tightness is the bigger the better.And to control power transmission power be to make Ni, Cr, Mo, Fe melt, can select according to actual needs.
In step 3, to change clear after molten metal bath carry out refining, cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, during refining, refining temperature is 1450 DEG C-1500 DEG C, and refining time is 17 minutes-23 minutes; Refining temperature realizes controlling by adjustment power transmission power; Entering the refining later stage, gas clean-up, making vacuum tightness be not more than 1Pa, preferably, reaching refining time one half, gas clean-up, making vacuum tightness be not more than 1Pa, to reduce oxygen level.
In step 4, protective gas is preferably argon gas or nitrogen; Its effect makes the refining liquid of shallow freezing conjunctiva be in protective gas atmosphere, anti-oxidation.The object of heating makes refining liquid fusing homogeneous, and its Heating temperature is 1480 DEG C-1490 DEG C, and same Heating temperature also realizes controlling by adjustment power transmission power.
In step 5, before adding sweetening agent, the temperature of aluminium alloy is controlled at 1380-1390 DEG C, the temperature of aluminium alloy also makes to be controlled by adjustment power transmission power, and sweetening agent is reducing metal, as Mg, Al etc., but not only in this, can also substitute with other sweetening agents; In addition, during vacuum condition desulfurization, vacuum tightness is less than 5Pa, exists to avoid oxygen; And desulfurization time at least 10 minutes, the sulphur in aluminium alloy is removed as far as possible.
Be described in detail nickel-base alloy provided by the invention and preparation method thereof below, following examples are only explanation of the invention, instead of limit.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment one:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 16.8%, the massfraction of the massfraction of Mo to be the massfraction of 4.0%, Ti be 0.8%, Cu is 3.3%, the massfraction of Fe is that the massfraction of 7.9%, C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu respectively, wherein, be calculated in mass percent, the mass percent of the massfraction of Cr to be the mass percent of 16.8%, Mo be 4.0%, Ti is 0.8%, the mass percent of Cu is 3.3%, the mass percent of Fe is 7.9%, and surplus is that the mass percent of C inevitable substituted in Ni, Ni, Cr, Mo, Fe, Ti, Cu is greater than 0 and is less than or equal to 0.03%;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 10Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 10Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1500 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 17 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1480 DEG C, that refining liquid is melted is homogeneous, adds Ti and Cu and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1380 DEG C, then adds Mg, then vacuumize, make vacuum tightness be less than 3Pa, to be less than under the vacuum condition of 3Pa desulfurization in vacuum tightness 10 minutes, last casting, obtains nickel-base alloy.
Embodiment two:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 17.5%, the massfraction of the massfraction of Mo to be the massfraction of 6.7%, Ti be 1.1%, Cu is 4.0%, the massfraction of Fe is that the massfraction of 13.3%, C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu respectively, wherein, be calculated in mass percent, the mass percent of the massfraction of Cr to be the mass percent of 17.5%, Mo be 6.7%, Ti is 1.1%, the mass percent of Cu is 4.0%, the mass percent of Fe is that the mass percent of C inevitable substituted in 13.3%, Ni, Cr, Mo, Fe, Ti, Cu is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 10Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 10Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1450 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 23 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 0.5Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1490 DEG C, that refining liquid is melted is homogeneous, adds Ti and Cu and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1390 DEG C, then adds Al, then vacuumize, make vacuum tightness be less than 5Pa, to be less than under the vacuum condition of 5Pa desulfurization in vacuum tightness 10 minutes, last casting, obtains nickel-base alloy.
Embodiment three:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 21.3%, the massfraction of the massfraction of Mo to be the massfraction of 9.1%, Ti be 0.6%, Cu is 1.7%, the massfraction of Fe is that the massfraction of 12.5%, C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu respectively, wherein, be calculated in mass percent, the mass percent of the massfraction of Cr to be the mass percent of 21.3%, Mo be 9.1%, Ti is 0.6%, the mass percent of Cu is 1.7%, the mass percent of Fe is that the mass percent of C inevitable substituted in 12.5%, Ni, Cr, Mo, Fe, Ti, Cu is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 6Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 6Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1470 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 20 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1486 DEG C, that refining liquid is melted is homogeneous, adds Ti and Cu and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1384 DEG C, then adds Al, then vacuumize, make vacuum tightness be less than 1Pa, to be less than under the vacuum condition of 1Pa desulfurization in vacuum tightness 12 minutes, last casting, obtains nickel-base alloy.
Embodiment four:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 24.5%, the massfraction of the massfraction of Mo to be the massfraction of 5.8%, Ti be 0.5%, Cu is 2.6%, the massfraction of Fe is that the massfraction of 15.0%, C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu respectively, wherein, be calculated in mass percent, the mass percent of the massfraction of Cr to be the mass percent of 24.5%, Mo be 5.8%, Ti is 0.5%, the mass percent of Cu is 2.6%, the mass percent of Fe is that the mass percent of C inevitable substituted in 15.0%, Ni, Cr, Mo, Fe, Ti, Cu is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 6Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 6Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1480 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 21 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti and Cu and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1380 DEG C, then adds Mg, then vacuumize, make vacuum tightness be less than 1Pa, to be less than under the vacuum condition of 1Pa desulfurization in vacuum tightness 12 minutes, last casting, obtains nickel-base alloy.
Embodiment five:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 26.7%, the massfraction of the massfraction of Mo to be the massfraction of 13.0%, Ti be 1.4%, Cu is 1.0%, the massfraction of Fe is that the massfraction of 6.0%, C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu respectively, wherein, be calculated in mass percent, the mass percent of the massfraction of Cr to be the mass percent of 26.7%, Mo be 13.0%, Ti is 1.4%, the mass percent of Cu is 1.0%, the mass percent of Fe is that the mass percent of C inevitable substituted in 6.0%, Ni, Cr, Mo, Fe, Ti, Cu is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 8Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 8Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1500 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 18 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 0.4Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into nitrogen, being then heated to 1489 DEG C, that refining liquid is melted is homogeneous, adds Ti and Cu and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1390 DEG C, then adds Al, then vacuumize, make vacuum tightness be less than 1Pa, to be less than under the vacuum condition of 1Pa desulfurization in vacuum tightness 17 minutes, last casting, obtains nickel-base alloy.
Embodiment six:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 28.0%, the massfraction of the massfraction of Mo to be the massfraction of 10.5%, Ti be 0.9%, Cu is 2.9%, the massfraction of Fe is that the massfraction of 7.5%, C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu respectively, wherein, be calculated in mass percent, the mass percent of the massfraction of Cr to be the mass percent of 28.0%, Mo be 10.5%, Ti is 0.9%, the mass percent of Cu is 2.9%, the mass percent of the C that mass percent is 7.5%, Ni, Cr, Mo, Fe, Ti, Cu are inevitable substituted into of Fe is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 10Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 10Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1450 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 23 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti and Cu and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1385 DEG C, then adds Mg, then vacuumize, make vacuum tightness be less than 5Pa, to be less than under the vacuum condition of 5Pa desulfurization in vacuum tightness 12 minutes, last casting, obtains nickel-base alloy.
Embodiment seven:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 23.2%, the massfraction of the massfraction of Mo to be the massfraction of 7.9%, Ti be 1.5%, Cu is 1.3%, the massfraction of Fe is that the massfraction of 9.4%, C is less than or equal to 0.03% for being greater than 0, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu respectively, wherein, be calculated in mass percent, the mass percent of the massfraction of Cr to be the mass percent of 23.2%, Mo be 7.9%, Ti is 1.5%, the mass percent of Cu is 1.3%, the mass percent of Fe is that the mass percent of C inevitable substituted in 9.4%, Ni, Cr, Mo, Fe, Ti, Cu is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 10Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 10Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1450 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 23 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti and Cu and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1390 DEG C, then adds Al, then vacuumize, make vacuum tightness be less than 5Pa, to be less than under the vacuum condition of 5Pa desulfurization in vacuum tightness 17 minutes, last casting, obtains nickel-base alloy.
Embodiment eight:
The C that the nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, W and introduced by Ni, Cr, Mo, Ti, Cu, Fe, W; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 15%, the massfraction of the massfraction of Mo to be the massfraction of 5%, Ti be 0.55%, Cu is 2%, the massfraction of Fe is 13%, the massfraction of C is 0.5% for being greater than 0 massfraction being less than or equal to 0.02%, W, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu and W respectively, wherein, be calculated in mass percent, the massfraction of Cr is the mass percent of 15%, Mo is 5%, the mass percent of Ti is 0.55%, the massfraction of the mass percent of Cu to be the mass percent of 2%, Fe be 13%, W is 0.5%, surplus is that the mass percent of C inevitable substituted in Ni, Ni, Cr, Mo, Fe, Ti, Cu and W is greater than 0 and is less than or equal to 0.02%;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 10Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 10Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1450 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 23 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into nitrogen, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti, Cu and W and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1380 DEG C, then adds Mg, then vacuumize, make vacuum tightness be less than 5Pa, to be less than under the vacuum condition of 5Pa desulfurization in vacuum tightness 17 minutes, last casting, obtains nickel-base alloy.
The mass percent of the W in the present embodiment can also be 0.1% or 0.3%, it should be noted that, just illustrates herein, is not limit.
Embodiment nine:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, Al, Mn, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe, Al, Mn; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 20%, the massfraction of the massfraction of Mo to be the massfraction of 10%, Ti be 1.0%, Cu is 3.5%, the massfraction of Fe is 14%, the massfraction of C is for being greater than the massfraction 0.1% that 0 massfraction being less than or equal to 0.03%, Al is 0.4%, Mn; Surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu, Al, Mn respectively, wherein, be calculated in mass percent, the massfraction of Cr is 28.0%, the massfraction of Mo is 10%, the massfraction of the massfraction of Ti to be the massfraction of 1.0%, Cu be 3.5%, Fe is 14%, the massfraction of Al is 0.4%, the massfraction 0.1% of Mn, surplus is that the mass percent of C inevitable substituted in Ni, Ni, Cr, Mo, Fe, Ti, Cu, Al, Mn is greater than 0 and is less than or equal to 0.01%;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 10Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 10Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1450 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 20 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti, Cu, Al and Mn and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1380 DEG C, then adds Al, then vacuumize, make vacuum tightness be less than 5Pa, to be less than under the vacuum condition of 5Pa desulfurization in vacuum tightness 12 minutes, last casting, obtains nickel-base alloy.
In the present embodiment, the mass percent of Al can also be 0.2%, and now the mass percent of Mn is 0.3%; It should be noted that, just illustrate herein, is not limit.
Embodiment ten:
The C that the nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, B and introduced by Ni, Cr, Mo, Ti, Cu, Fe, B; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 25%, the massfraction of Mo is 5.8%, the massfraction of the massfraction of Ti to be the massfraction of 0.8%, Cu be 3%, Fe is 15.0%, the massfraction of C is 0.006% for being greater than 0 massfraction being less than or equal to 0.02%, B.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Ti, Cu, Fe, B respectively, wherein, be calculated in mass percent, the massfraction of Cr is the massfraction of 25%, Mo is 5.8%, the massfraction of Ti is 0.8%, the massfraction of the massfraction of Cu to be the massfraction of 3%, Fe be 15.0%, B is 0.006%, surplus is that the massfraction of C inevitable substituted in Ni, Ni, Cr, Mo, Fe, Ti, Cu, B is greater than 0 and is less than or equal to 0.02%;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 6Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 6Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1480 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 21 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into nitrogen, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti, Cu and B and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1380 DEG C, then adds Mg, then vacuumize, make vacuum tightness be less than 1Pa, to be less than under the vacuum condition of 1Pa desulfurization in vacuum tightness 12 minutes, last casting, obtains nickel-base alloy.
Embodiment 11:
The C that the nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, V, Nb, Co and introduced by Ni, Cr, Mo, Ti, Cu, Fe, V, Nb, Co; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is the massfraction of 15%, Mo is 7.9%, the massfraction of Ti is 1.5%, the massfraction of the massfraction of Cu to be the massfraction of 1.3%, Fe be 9.4%, C is less than or equal to 0.03% for being greater than 0, the massfraction of V is 0.1%, the massfraction of Nb is the massfraction of 0.1%, Co is 0.3%, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu, V, Nb, Co respectively; Wherein, be calculated in mass percent, the massfraction of the massfraction of Cr to be the massfraction of 15%, Mo be 7.9%, Ti is 1.5%, the massfraction of Cu is 1.3%, the massfraction of the massfraction of Fe to be the massfraction of 9.4%, V be 0.1%, Nb is 0.1%, the massfraction of Co is 0.3%, and surplus is Ni; The mass percent of C inevitable substituted in Ni, Cr, Mo, Fe, Ti, Cu, V, Nb, Co is greater than 0 and is less than or equal to 0.03%;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 10Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 10Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1450 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 17 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti, Cu, V, Nb and Co and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1386 DEG C, then adds Mg, then vacuumize, make vacuum tightness be less than 5Pa, to be less than under the vacuum condition of 5Pa desulfurization in vacuum tightness 17 minutes, last casting, obtains nickel-base alloy.
The massfraction of the V in the present embodiment also can be 0.2%, and the massfraction that the massfraction of Nb is 0.1%, Co is 0.2%, it should be noted that, just illustrates herein, is not limit.
Embodiment 12:
The nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, V, and the C introduced by Ni, Cr, Mo, Ti, Cu, Fe, V; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 24.5%, the massfraction of the massfraction of Mo to be the massfraction of 5.8%, Ti be 0.5%, Cu is 3%, the massfraction of Fe is 14.0%, the massfraction of C is 0.4% for being greater than 0 massfraction being less than or equal to 0.03%, V, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu, V respectively; Wherein, be calculated in mass percent, the massfraction of the massfraction of the massfraction of Cr to be the massfraction of 24.5%, Mo be 5.8%, Ti to be the massfraction of 0.5%, Cu be 3%, Fe is the massfraction of 14.0%, V is 0.4%, and surplus is Ni; The mass percent of C inevitable substituted in Ni, Cr, Mo, Fe, Ti, Cu, V is greater than 0 and is less than or equal to 0.03%;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 6Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 6Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1480 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 21 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti, Cu and V and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1380 DEG C, then adds Al, then vacuumize, make vacuum tightness be less than 1Pa, to be less than under the vacuum condition of 1Pa desulfurization in vacuum tightness 12 minutes, last casting, obtains nickel-base alloy.
V in the present embodiment can also replace with Co, and the massfraction of Co is 0.2% or 0.1%, it should be noted that, just illustrates herein, is not limit.
Embodiment 13:
The C that the nickel-base alloy that the present embodiment provides comprises Ni, Cr, Mo, Ti, Cu, Fe, Nb and introduced by Ni, Cr, Mo, Ti, Cu, Fe, Nb; Wherein, in massfraction, in described nickel-base alloy, the massfraction of Cr is 24%, the massfraction of the massfraction of Mo to be the massfraction of 5.8%, Ti be 0.5%, Cu is 2.6%, the massfraction of Fe is 15.0%, the massfraction of C is 0.5% for being greater than 0 massfraction being less than or equal to 0.03%, Nb, and surplus is Ni.
The preparation method of the nickel-base alloy that the present embodiment provides comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu, Nb respectively; Wherein, be calculated in mass percent, in described nickel-base alloy, the massfraction of Cr is 24%, the massfraction of the massfraction of Mo to be the massfraction of 5.8%, Ti be 0.5%, Cu is 2.6%, the massfraction of Fe is the massfraction of 15.0%, Nb is 0.5%, and surplus is Ni; The mass percent of C inevitable substituted in Ni, Cr, Mo, Fe, Ti, Cu, Nb is greater than 0 and is less than or equal to 0.03%;
Step 2, Ni, Cr, Mo, Fe are added in vacuum induction furnace, vacuumize and make vacuum tightness be less than 6Pa, being then 30KW by controlling power transmission power, being incubated 10 minutes, to make Ni, Cr, Mn, Fe melt under the vacuum condition being less than 6Pa, obtain molten metal bath; Then increase power transmission power to 50KW, be incubated until molten metal liquefaction is clear, the molten metal bath after obtaining is clear;
Step 3, utilizing infrared radiation detection apparatus to detect furnace temperature, is 1480 DEG C to control refining temperature, then start to change clear after molten metal bath carry out refining, refining time is 21 minutes, and cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains; Wherein, reaching refining time one half, gas clean-up, vacuum tightness is made to be not more than 1Pa;
Step 4, in the refining liquid of shallow freezing conjunctiva, be blown into argon gas, being then heated to 1485 DEG C, that refining liquid is melted is homogeneous, adds Ti, Cu and Nb and stirs, obtaining aluminium alloy;
Step 5, the temperature of aluminium alloy is down to 1380 DEG C, then adds Mg, then vacuumize, make vacuum tightness be less than 1Pa, to be less than under the vacuum condition of 1Pa desulfurization in vacuum tightness 12 minutes, last casting, obtains nickel-base alloy.
The mass percent of the Nb in the present embodiment can also be 0.4%, it should be noted that, just illustrates herein, is not limit.
From nickel-base alloy prepared by above-described embodiment one to embodiment 13, randomly draw 8 samples, then following anti-corrosion test carried out to these 8 samples and Inconel-625 material, Hastelloy C-276 material:
Test one
At 300 DEG C, 23MPa, pH value is under the environment of 6, utilizes the mixed aqueous solution being added with hydrogen peroxide to carry out 500h hanging test to following six kinds of alloys respectively; Six kinds of alloys are respectively nickel-base alloy prepared by Inconel-625 material, Hastelloy C-276 material, the nickel-base alloy of embodiment one, the nickel-base alloy of embodiment three, the nickel-base alloy of embodiment four and embodiment six; Wherein, in mixed aqueous solution, solute is Na
2sO
4, Na
3pO
4and NaCl; Na
2sO
4concentration be 2.0g/L, Na
3pO
4concentration be the concentration of 0.5g/L, NaCl be 1.0g/L, acting as of hydrogen peroxide provides oxygen, and its mass concentration is 2%.
As calculated, at 300 DEG C, each alloy annual erosion rate (mm/yr) is as shown in table 1:
Each alloy annual erosion rate result at 300 DEG C, table 1
Test two
450 DEG C, 23MPa, pH value is under the environment of 6, utilizes the mixed aqueous solution being added with hydrogen peroxide to carry out 500h hanging test to following six kinds of alloys respectively; Six kinds of alloys are respectively the obtained nickel-base alloy of the obtained nickel-base alloy of the obtained nickel-base alloy of Inconel-625 material, Hastelloy C-276 material, embodiment two, embodiment five, embodiment seven and the obtained nickel-base alloy of embodiment ten; Wherein, in mixed aqueous solution, solute is Na
2sO
4, Na
3pO
4and NaCl; Na
2sO
4concentration be 2.0g/L, Na
3pO
4concentration be the concentration of 0.5g/L, NaCl be 1.0g/L, acting as of hydrogen peroxide provides oxygen, and its mass concentration is 2%.
As calculated, in such circumstances, at 450 DEG C, the annual erosion rate (mm/yr) of each alloy is as follows:
Each alloy annual erosion rate result at 450 DEG C, table 2
Because the corrosive effect contrast tested under two conditions is more obvious, so the anti-corrosion test data in Selection experiment two are further analyzed; For corrosion resisting alloy prepared by the embodiment two of testing in two, analytical results shows: the corrosion thickness of Inconel-625 material is 4.0 μm, the corrosion thickness of Hastelloy C-276 material is 7.8 μm, the corrosion thickness of nickel-base alloy prepared by embodiment two is 1.97 μm, therefore, the nickel-base alloy that embodiment two provides is relative to Inconel-625 material and Hastelloy C-276 material, its corrosion thickness is little, and compactness extent is better than Inconel-625 material and Hastelloy C-276 material.
To sum up, can find out, in the acidic oxidation medium that the nickel-base alloy that this programme obtains exists in different kinds of ions, its erosion rate reduces greatly relative to Hastelloy C-276 material and Inconel-625 material, therefore, in nickel-base alloy prepared by the present invention acidic oxidation medium when different kinds of ions exists, there is good resistance to corrosion, can be applied in overcritical equipment.
The above; be only the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, is anyly familiar with those skilled in the art in the technical scope that the present invention discloses; change can be expected easily or replace, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of described claim.
Claims (9)
1. a nickel-base alloy, it is characterized in that, in massfraction, comprise the Cr that massfraction is 15%-28%, massfraction is the Mo of 4%-13%, massfraction is the Ti of 0.5%-1.5%, massfraction is the Cu of 1%-4%, and massfraction is the Fe of 6%-15%, and massfraction is be greater than the C that 0 is less than or equal to 0.03%, massfraction is the trace element of 0-0.5%, and surplus is Ni.
2. nickel-base alloy according to claim 1, it is characterized in that, described nickel-base alloy comprises the Cr that massfraction is 17.5%-25%, massfraction is the Mo of 4%-10%, and massfraction is the Ti of 0.55%-1.0%, and massfraction is the Cu of 2%-3.5%, massfraction is the Fe of 7%-14%, massfraction is be greater than the C that 0 is less than or equal to 0.02%, and massfraction is the trace element of 0-0.3%, and surplus is Ni.
3. nickel-base alloy according to claim 1, it is characterized in that, described nickel-base alloy comprises the Cr that massfraction is 16.8%-24.5%, massfraction is the Mo of 5.8%-10.5%, and massfraction is the Ti of 0.6%-1.0%, and massfraction is the Cu of 2%-3%, massfraction is the Fe of 7%-13%, the massfraction of C is less than or equal to 0.01% for being greater than 0, and the massfraction of trace element is 0-0.3%, and surplus is Ni.
4. nickel-base alloy according to claim 1, it is characterized in that, described nickel-base alloy comprises the Cr that massfraction is 16%-20%, massfraction is the Mo of 5%-10%, and massfraction is the Ti of 0.6%-1.0%, and massfraction is the Cu of 2%-4%, massfraction is the Fe of 7.5%-12.5%, massfraction is be greater than the C that 0 is less than or equal to 0.01%, and massfraction is the trace element of 0-0.5%, and surplus is Ni.
5., according to the nickel-base alloy in claim 1-4 described in any one, it is characterized in that, described trace element comprise in W, Al, Mn, V, Nb, Co, B one or more.
6. nickel-base alloy according to claim 5, is characterized in that, in described nickel-base alloy,
The massfraction of described W is less than or equal to 0.5% for being greater than 0; And/or
The massfraction of described Al is greater than 0 and is less than or equal to 0.4%; And/or
The massfraction of described Mn is greater than 0 and is less than or equal to 0.4%; And/or
The massfraction of described V is greater than 0 and is less than or equal to 0.4%; And/or
The massfraction of described Nb is greater than 0 and is less than or equal to 0.5%; And/or
The massfraction of described Co is greater than 0 and is less than or equal to 0.3%; And/or
The massfraction of described B is greater than 0 and is less than or equal to 0.006%.
7. a preparation method for nickel-base alloy, is characterized in that, comprises the following steps:
Step one, take Ni, Cr, Mo, Fe, Ti, Cu and trace element respectively, wherein, be calculated in mass percent, the massfraction of Cr is 15%-28%, the mass percent of the mass percent of Mo to be the mass percent of 4%-13%, Ti be 0.5%-1.5%, Cu is 1%-4%, the mass percent of Fe is 6%-15%, and the mass percent of trace element is 0-0.5%; The mass percent of the C substituted in Ni, Cr, Mo, Fe, Ti, Cu and trace element is greater than 0 and is less than or equal to 0.03%, and surplus is Ni;
Step 2, by Ni, Cr, Mo, Fe under vacuum mixed melting until change clear, obtaining clearly after molten metal bath;
Step 3, clear to describedization after molten metal bath carry out refining, cooling after refining completes is until the refining liquid shallow freezing conjunctiva that obtains;
Step 4, in the described refining liquid of shallow freezing conjunctiva, be blown into protective gas, then that described refining liquid is melted is homogeneous in heating, adds Ti, Cu and trace element and stirs, obtaining aluminium alloy;
Step 5, in aluminium alloy, add sweetening agent, then vacuumize, be incubated under vacuum with the desulfurization of alloy liquid, last casting, obtains nickel-base alloy.
8. the preparation method of nickel-base alloy according to claim 7, is characterized in that, during described step 3 refining, refining temperature is 1450 DEG C-1500 DEG C, and refining time is 17 minutes-23 minutes, in step 5, before adding sweetening agent, the temperature of aluminium alloy is controlled at 1380-1390 DEG C.
9. the nickel-base alloy in a claim 1-6 described in any one is as the application of corrosion resistant material in overcritical equipment.
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