CN104861601B - Edible oil removing towel and preparation method thereof - Google Patents

Edible oil removing towel and preparation method thereof Download PDF

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Publication number
CN104861601B
CN104861601B CN201510249024.5A CN201510249024A CN104861601B CN 104861601 B CN104861601 B CN 104861601B CN 201510249024 A CN201510249024 A CN 201510249024A CN 104861601 B CN104861601 B CN 104861601B
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Prior art keywords
oil removing
main body
solvent
removing towel
bio
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CN104861601A (en
Inventor
陈利红
李洪文
曹栋梁
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KINWIN PLASTIC INDUSTRIAL Co.,Ltd.
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ZHEJIANG KINLEAD INNOVATIVE MATERIALS Co Ltd
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Abstract

The present invention relates to a kind of edible oil removing towel and preparation method thereof, belong to the technical field of daily living article, have the nontoxic material main body of several micropore including surface configuration.The present invention eats oil removing towel, can easily remove the oil on soup class surface and leave behind soup, people can be helped to reduce the absorption for oils and fats.

Description

Edible oil removing towel and preparation method thereof
Technical field
The present invention relates to a kind of edible oil removing towel and preparation method thereof, belong to the technical field of daily living article.
Background technology
In life, oils and fats overstock problem is serious now, and the oils and fats of Excess free enthalpy endangers the healthy of people.Daily life In work, people often stew meat soup, and Boiled fish etc., due to personal habits, health, the difference of living condition, a lot of people practise It is used to only to eat soup and does not likes one layer of oils and fats above, but this layer of oil is difficult to again remove.
Summary of the invention
For above-mentioned problems of the prior art, the present invention provides a kind of edible oil removing towel and preparation method thereof, should Edible oil removing towel can conveniently remove oils and fats unnecessary in family life.
For reaching above-mentioned purpose, the technical solution adopted in the present invention is:
A kind of edible oil removing towel, has the nontoxic material main body of several micropore including surface configuration.Sized by micropore consistent Hole, it is also possible to sized by inconsistent hole, it is also possible to sized by inconsistent and irregular hole.
As the further setting of such scheme, described micropore to the internal extension of nontoxic material main body, is formed from outside to inside Microchannel.
Described nontoxic material main body be internally provided with a containing cavity, containing cavity connects with all microchannels, or hold Put chamber to connect with part microchannel.
The containing cavity being internally provided with more than one quantity of described nontoxic material main body, a containing cavity and one micro-logical Road connects, or a containing cavity connects with the microchannel of more than one quantity.
The specification of edible oil removing towel is preferably: a length of 150mm, width is 150mm, and thickness is 6mm.
Described nontoxic material main body is degradable non-poisonous material main body, or nontoxic material main body is degradable, renewable Nontoxic material main body.
The present invention eats oil removing towel, can be selected for the bio-based macromolecular materials such as polylactic acid, cellulose, starch plastic and makes.
The micropore that the present invention eats on oil removing towel is formed by the way of foaming, and concrete grammar has physical blowing method and chemistry Foaming two kinds.Physical blowing method be raw material is dissolved in gas (or liquid) afterwards gasify formation micropore, or by material dissolution in Separate out after solvent and form micropore, dissolve soluble constituent simultaneously and form abscess.Chemical blowing process is CBA decomposes Or other chemical reactions produce gas, raw material melt is made to form micropore.
The present invention eats oil removing towel, and two kinds of different physical blowing methods can be used to be prepared, and first kind of way specifically walks Suddenly it is:
(1) feed intake: dry bio-based macromolecular material is put in double screw extruder by feeding system;
(2) extrusion plasticizing: by double screw extruder by the mixing plasticizing of bio-based melt polymer material, temperature is 160- 200℃;
(3) supercritical carbon dioxide is injected: utilize supercritical carbon dioxide gas injection system to inject in double screw extruder Supercritical carbon dioxide, more than 7%, (injection rate refers in mass fraction, and double screw extruder the injection rate of carbon dioxide The extrusion capacity contrast of raw material.As: when in double screw extruder, the extrusion capacity of raw material is 100 grams, then the injection rate of carbon dioxide It is more than 7 grams), injection pressure is at more than 10MPa;
(4) high pressure extrusion: the head pressure of double screw extruder controls at more than 70MPa;
(5) foaming: after the head of double screw extruder is extruded, forms finished product.
The second way concretely comprises the following steps:
(1) material dissolution: dry bio-based macromolecular material is dissolved in solvent orange 2 A, and controls bio-based macromolecule The concentration of material is 0.05-0.15g/mL;Any during wherein solvent orange 2 A is chloroform, dichloromethane, dioxane, acetone A kind of;
(2) solvent B is added: be slowly added dropwise the solvent B of insoluble bio-based macromolecular material, bio-based macromolecular material meeting Separate out along with the increase of solvent B addition;Any one during wherein solvent B is dehydrated alcohol, hexane, ether;
(3) molding: precipitation solid phase is collected in mould;
(4) it is dried: remove residual solvent by blast heating, obtain finished product.
The edible oil removing towel formed by both physical blowing methods is to have nanometer and the material of micron order micropore, and it is at sky In gas, the contact angle to water is more than 100 °, and the contact angle to oil is 0 ° in atmosphere.
The present invention eats oil removing towel, and what employing chemical blowing process was prepared specifically comprises the following steps that
(1) feed intake: dry bio-based macromolecular material and CBA are put into twin screw by feeding system In extruder;Wherein, any during CBA is sodium bicarbonate, azodicarbonamide, sodium carbonate-citric acid foaming system A kind of;The addition of CBA be the 3-30%(of institute's substance gross mass i.e., when bio-based macromolecular material and chemistry When the interpolation gross mass of foaming agent is 100 grams, CBA accounts for 3-30 gram);
(2) extrusion plasticizing: by double screw extruder by the mixing plasticizing of bio-based melt polymer material, temperature is 140- 270℃;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
The edible oil removing towel formed by this chemical blowing process is to have nanometer and the material of micron order micropore, and it is in atmosphere The contact angle of water is more than 100 °, and the contact angle to oil is 0 ° in atmosphere.
Bio-based macromolecular material (such as polylactic acid, cellulose, starch plastic) possesses plant origin and biodegradable two Big characteristic, compared with common petroleum based high molecular, bio-based macromolecule typically can reduce the petroleum resource consumption of 30-50%, reduces People's dependence to petroleum resources.Bio-based macromolecule derives from biomass simultaneously, and discarded goods can be with organic waste one Play compost treatment, ultimately re-enter biological cycle.Based on bio-based these good characteristics high molecular, it is made into hydrophobic Lipophile foaming poromerics, for removing oils and fats unnecessary in family life.
The present invention eats oil removing towel, can easily remove the oil on soup class surface and leave behind soup, can help people reduce for The absorption of oils and fats.In addition, the present invention is also applied to other aspect oil removings of family life, and high-efficient simple is quick.
Below in conjunction with the drawings and specific embodiments, the invention will be further described.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the sectional structure schematic diagram of the present invention;
Fig. 3 is the sectional structure schematic diagram of another structure of the present invention.
Detailed description of the invention
As it is shown in figure 1, the present invention eats oil removing towel, there is the nontoxic material main body 1 of several micropore 2 including surface configuration.Micro- Hole consistent sized by hole 2, it is also possible to sized by inconsistent hole, it is also possible to sized by inconsistent and irregular hole.
For improving oil absorbency, the micropore 2 of the present invention to the internal extension of nontoxic material main body 1, forms microchannel from outside to inside 3, as shown in Figure 2 and Figure 3.
For further improving oil absorbency, the design of the present invention is: be internally provided with one in nontoxic material main body 1 Individual containing cavity 4, containing cavity 4 connects (such as Fig. 2) with all microchannels 3, or containing cavity 4 connects with part microchannel 3.
For further improving oil absorbency, another design of the present invention is: arrange in the inside of nontoxic material main body 1 Have the containing cavity 4 of more than one quantity, a containing cavity 4 to connect with a microchannel 3, or a containing cavity 4 and one with The microchannel 3 of upper quantity connects (such as Fig. 3).
The present invention eats the length of oil removing towel and is preferably 150mm, and width is preferably 150mm, and thickness is preferably 6mm.
It is degradable non-poisonous material main body that the present invention eats the nontoxic material main body 1 of oil removing towel, or nontoxic material main body 1 For degradable, renewable nontoxic material main body.
Below by specific embodiment, the invention will be further described, but the present invention is not limited by following example Fixed.
Embodiment 1
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry polylactic acid is put in double screw extruder by feeding system;
(2) extrusion plasticizing: polylactic acid melting mixing being plastified by double screw extruder, temperature is 185 DEG C;
(3) supercritical carbon dioxide is injected: utilize supercritical carbon dioxide gas injection system to inject in double screw extruder Supercritical carbon dioxide, the injection rate of carbon dioxide is more than 7%, and injection pressure is at more than 10MPa;
(4) high pressure extrusion: the head pressure of double screw extruder controls at more than 70MPa;
(5) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 2
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry polylactic acid is put in double screw extruder by feeding system;
(2) extrusion plasticizing: polylactic acid melting mixing being plastified by double screw extruder, temperature is 160 DEG C;
(3) supercritical carbon dioxide is injected: utilize supercritical carbon dioxide gas injection system to inject in double screw extruder Supercritical carbon dioxide, the injection rate of carbon dioxide is more than 7%, and injection pressure is at more than 10MPa;
(4) high pressure extrusion: the head pressure of double screw extruder controls at more than 70MPa;
(5) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 3
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry polylactic acid is put in double screw extruder by feeding system;
(2) extrusion plasticizing: polylactic acid melting mixing being plastified by double screw extruder, temperature is 200 DEG C;
(3) supercritical carbon dioxide is injected: utilize supercritical carbon dioxide gas injection system to inject in double screw extruder Supercritical carbon dioxide, the injection rate of carbon dioxide is more than 7%, and injection pressure is at more than 10MPa;
(4) high pressure extrusion: the head pressure of double screw extruder controls at more than 70MPa;
(5) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 4
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) material dissolution: dry polylactic acid is dissolved in solvent orange 2 A, and control the concentration of bio-based macromolecular material For 0.1g/mL;Wherein solvent orange 2 A is chloroform;
(2) solvent B is added: being slowly added dropwise the solvent B of insoluble polylactic acid, polylactic acid can be along with the increasing of solvent B addition Add and separate out;Wherein solvent B is dehydrated alcohol;
(3) molding: precipitation solid phase is collected in mould;
(4) it is dried: remove residual solvent by blast heating, obtain finished product.
Embodiment 5
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) material dissolution: dry polylactic acid is dissolved in solvent orange 2 A, and control the concentration of bio-based macromolecular material For 0.05g/mL;Wherein solvent orange 2 A is dichloromethane;
(2) solvent B is added: being slowly added dropwise the solvent B of insoluble polylactic acid, polylactic acid can be along with the increasing of solvent B addition Add and separate out;Wherein solvent B is hexane;
(3) molding: precipitation solid phase is collected in mould;
(4) it is dried: remove residual solvent by blast heating, obtain finished product.
Embodiment 6
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) material dissolution: dry polylactic acid is dissolved in solvent orange 2 A, and control the concentration of bio-based macromolecular material For 0.15g/mL;Wherein solvent orange 2 A is acetone;
(2) solvent B is added: being slowly added dropwise the solvent B of insoluble polylactic acid, polylactic acid can be along with the increasing of solvent B addition Add and separate out;Wherein solvent B is ether;
(3) molding: precipitation solid phase is collected in mould;
(4) it is dried: remove residual solvent by blast heating, obtain finished product.
Embodiment 7
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry polylactic acid and CBA are put in double screw extruder by feeding system;Its In, CBA is sodium bicarbonate;The addition of CBA is the 3% of institute's substance gross mass;
(2) extrusion plasticizing: polylactic acid melting mixing being plastified by double screw extruder, temperature is 185 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 8
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry polylactic acid and CBA are put in double screw extruder by feeding system;Its In, CBA is azodicarbonamide;The addition of CBA is the 16% of institute's substance gross mass;
(2) extrusion plasticizing: polylactic acid melting mixing being plastified by double screw extruder, temperature is 190 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 9
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry polylactic acid and CBA are put in double screw extruder by feeding system;Its In, CBA is sodium carbonate-citric acid foaming system;The addition of CBA is institute's substance gross mass 30%;
(2) extrusion plasticizing: polylactic acid melting mixing being plastified by double screw extruder, temperature is 180 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 10
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: by dry cellulose acetate (acetyl content 37%~42%) and CBA by feeding intake be System is put in double screw extruder;Wherein, CBA is sodium carbonate-citric acid foaming system;Adding of CBA Dosage is the 3% of institute's substance gross mass;
(2) extrusion plasticizing: cellulose acetate melting mixing being plastified by double screw extruder, temperature is 240 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 11
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: by dry cellulose acetate (acetyl content 37%~42%) and CBA by feeding intake be System is put in double screw extruder;Wherein, CBA is azodicarbonamide;The addition of CBA is by being added Add the 15% of material gross mass;
(2) extrusion plasticizing: cellulose acetate melting mixing being plastified by double screw extruder, temperature is 200 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 12
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: by dry cellulose acetate (acetyl content 37%~42%) and CBA by feeding intake be System is put in double screw extruder;Wherein, CBA is sodium bicarbonate;The addition of CBA is institute's additive The 30% of matter gross mass;
(2) extrusion plasticizing: cellulose acetate melting mixing being plastified by double screw extruder, temperature is 270 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 13
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry modified starch plastics and CBA are put into twin-screw extrusion by feeding system In machine;Wherein, CBA is sodium carbonate-citric acid foaming system;The addition of CBA is that institute's substance is total The 3% of quality;
(2) extrusion plasticizing: modified starch plastics melting mixing being plastified by double screw extruder, temperature is 160 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 14
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry modified starch plastics and CBA are put into twin-screw extrusion by feeding system In machine;Wherein, CBA is azodicarbonamide;The addition of CBA is the 18% of institute's substance gross mass;
(2) extrusion plasticizing: modified starch plastics melting mixing being plastified by double screw extruder, temperature is 140 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Embodiment 15
The present invention eats the preparation method of oil removing towel, comprises the following steps:
(1) feed intake: dry modified starch plastics and CBA are put into twin-screw extrusion by feeding system In machine;Wherein, CBA is sodium bicarbonate;The addition of CBA is the 30% of institute's substance gross mass;
(2) extrusion plasticizing: modified starch plastics melting mixing being plastified by double screw extruder, temperature is 200 DEG C;
(3) foaming: after the head of double screw extruder is extruded, forms finished product.
Above-described embodiment is only used for illustrating the inventive concept of the present invention, rather than the restriction to rights protection of the present invention, All changes utilizing this design that the present invention carries out unsubstantiality, all should fall into protection scope of the present invention.

Claims (6)

1. an edible oil removing towel, it is characterised in that: include that surface configuration has the nontoxic material main body of several micropore;
Its preparation method comprises the following steps:
(1) material dissolution: dry bio-based macromolecular material is dissolved in solvent orange 2 A, and controls bio-based macromolecular material Concentration be 0.05-0.15g/mL;Any one during wherein solvent orange 2 A is chloroform, dichloromethane, dioxane, acetone;
(2) adding solvent B: be slowly added dropwise the solvent B of insoluble bio-based macromolecular material, bio-based macromolecular material can be along with The increase of solvent B addition and separate out;Any one during wherein solvent B is dehydrated alcohol, hexane, ether;
(3) molding: precipitation solid phase is collected in mould;
(4) it is dried: remove residual solvent by blast heating, obtain finished product;
Described bio-based macromolecular material is any one in polylactic acid, cellulose, starch plastic.
2. edible oil removing towel as claimed in claim 1, it is characterised in that: described micropore is from outside to inside in nontoxic material main body Portion extends, and forms microchannel.
3. oil removing towel as claimed in claim 2 edible, it is characterised in that: described nontoxic material main body be internally provided with one Containing cavity, containing cavity connects with all microchannels, or containing cavity connects with part microchannel.
4. oil removing towel as claimed in claim 2 edible, it is characterised in that: described nontoxic material main body be internally provided with one The containing cavity of above quantity, a containing cavity and the connection of microchannel, or containing cavity and more than one quantity is micro- Channel connection.
5. edible oil removing towel as claimed in claim 1, it is characterised in that: a length of 150mm of edible oil removing towel, width is 150mm, thickness is 6mm.
6. edible oil removing towel as claimed in claim 1, it is characterised in that: described nontoxic material main body is degradable non-poisonous base material Body, or nontoxic material main body is degradable, renewable nontoxic material main body.
CN201510249024.5A 2015-05-14 2015-05-14 Edible oil removing towel and preparation method thereof Active CN104861601B (en)

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CN104861601B true CN104861601B (en) 2016-08-24

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112076498A (en) * 2019-06-13 2020-12-15 马子涵 Food oil absorption material based on cellulose-based material and preparation method and application thereof

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* Cited by examiner, † Cited by third party
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CN101386703B (en) * 2008-11-05 2011-06-29 江苏科技大学 Polylactic acid/thermoplastic starch foam and producing method thereof
US20120061867A1 (en) * 2010-09-10 2012-03-15 Playtex Products Llc Polymer pellets containing supercritical fluid and methods of making and using
CN102816418A (en) * 2012-09-06 2012-12-12 南京航空航天大学 Blended foam material based on polycaprolactone (PCL) and modified polylactic acid (PLA) and preparation method thereof
CN103772927A (en) * 2014-01-15 2014-05-07 南通烟滤嘴有限责任公司 Biodegradable porous foaming material and preparation method thereof
CN104592543B (en) * 2015-02-02 2017-11-07 四川大学 Porous polymer material with structure of double peak holes and preparation method thereof

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Effective date of registration: 20200326

Address after: No.106, Tieshan East Road, Dalian Economic and Technological Development Zone, Dalian, Liaoning 116600

Patentee after: KINWIN PLASTIC INDUSTRIAL Co.,Ltd.

Address before: 312000 mirror Road No. 889, East Industrial District, Zhejiang, Shaoxing

Patentee before: ZHEJIANG KINLEAD INNOVATIVE MATERIALS Co.,Ltd.

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