CN104861534A - Nano bamboo carbon PTT enhanced master batch - Google Patents
Nano bamboo carbon PTT enhanced master batch Download PDFInfo
- Publication number
- CN104861534A CN104861534A CN201410546388.5A CN201410546388A CN104861534A CN 104861534 A CN104861534 A CN 104861534A CN 201410546388 A CN201410546388 A CN 201410546388A CN 104861534 A CN104861534 A CN 104861534A
- Authority
- CN
- China
- Prior art keywords
- nano
- bamboo carbon
- master batch
- ptt
- strengthens
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a nano bamboo carbon PTT enhanced master batch. The nano bamboo carbon PTT enhanced master batch comprises the following ingredients, by weight, 15%-50% of PTT resins, 10%-30% of glass fibers, 15%-40% of nano bamboo carbon, 10%-25% of ACR, 3%-8% of compatibilizers, 2%-5% of heat resistant agents and 0.5%-3% of dispersants. The beneficial effects are that the enhanced master batch has functions of no pollution, high dispersion, high intensity, and strong adsorption, sterilization, deodorizing, purifying and anti ultraviolet functions, when 5%-15% of the enhanced master batch is added in PTT production, good sterilization, toughening, reinforcing and anti-ultraviolet modification effects are achieved, the heat resistance, processing properties and appearance quality of the material are raised obviously, the production cost is lowered, and the production efficiency is raised.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of nano-bamboo carbon PTT strengthens master batch.
Background technology
Poly(Trimethylene Terephthalate) (PTT) is by terephthalic acid and 1, ammediol polycondensation and the new polyester macromolecular material of obtained one after polyethylene terephthalate (PET) and polybutylene terephthalate (PBT), and PTT is more excellent than PET and PBT in mechanical characteristics, weathering resistance, heat-resistant aging and resistance to hydrolysis.The fields such as fiber, film, engineering plastics are widely used in because PTT has excellent over-all properties.But PTT is used alone exists the defect that notched Izod impact strength is low, notch sensitivity is large, will greatly limit the application of PTT in every field.
Summary of the invention
The object of the present invention is to provide a kind of good dispersity, intensity high and have concurrently sterilization, uvioresistant function nano-bamboo carbon PTT strengthen master batch.
The technical solution adopted for the present invention to solve the technical problems is: a kind of nano-bamboo carbon PTT strengthens master batch, and its component by mass percent proportioning is: PTT resin 15% ~ 50%, glass fibre 10% ~ 30%, nano-bamboo carbon 15% ~ 40%, ACR 10% ~ 25%, expanding material 3% ~ 8%, heat-resistant agent 2% ~ 5%, dispersion agent 0.5% ~ 3%.
Described PTT resin is Poly(Trimethylene Terephthalate).
Described glass fibre be surface through silane coupler modified process and mean diameter at the alkali-free short glass fiber of 8 ~ 15 μm.
Described nano-bamboo carbon be surface through nano-titanium dioxide modified process and particle diameter at the nano-bamboo carbon of 20 ~ 80nm.
Described ACR has the toughness reinforcing Methylacrylate-Acrylate Copolymer of nucleocapsid structure.
Described expanding material is ethylene-ethylacrylate-glycidyl methacrylate triblock copolymer (E-MA-GMA).
Described heat-resistant agent is bismaleimides or N-phenylmaleimide.
Described lubricant is modification ethylene bis-fatty acid amides (TAF).
The preparation method that above-mentioned a kind of nano-bamboo carbon PTT strengthens master batch is: take each component by weight ratio, and by PTT resin, nano-bamboo carbon, ACR, expanding material, heat-resistant agent and dispersion agent add in high-speed mixer and mix 3 ~ 15 minutes, after fully mixing, discharging adds the main spout of twin screw extruder, add from the side spout of twin screw extruder the glass fibre taken by weight ratio simultaneously, by twin screw extruder melting mixing 1 ~ 2 minute, screw speed controls at 150 ~ 600r/min, processing temperature is 210 DEG C ~ 280 DEG C scopes, then extruding pelletization, and it is dry, packaging, obtain the present invention.
The invention has the beneficial effects as follows, the present invention has pollution-free, high dispersive, high strength and has the functions such as powerful absorption, sterilization, deodorizing, purification, uvioresistant, when producing PTT and adding 5% ~ 15%, to there is good sterilization, toughness reinforcing, reinforcement, uvioresistant modified effect, but also the resistance toheat of material, processing characteristics and visual appearance can be significantly improved, also reduce production cost simultaneously, enhance productivity.
Embodiment
Technical scheme of the present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1:
A kind of nano-bamboo carbon PTT strengthens master batch, its component by mass percent proportioning is: PTT resin 28%, glass fibre 20%, nano-bamboo carbon 25%, ACR 15%, E-MA-GMA 6%, bismaleimides 3.5%, TAF 2.5%, described glass fibre be surface through silane coupler modified process and mean diameter at the alkali-free short glass fiber of 8 ~ 15 μm, described nano-bamboo carbon be surface through nano-titanium dioxide modified process and particle diameter at the nano-bamboo carbon of 20 ~ 80nm.
Preparation method: take each component by weight ratio, and by PTT resin, nano-bamboo carbon, ACR, E-MA-GMA, bismaleimides and TAF add in high-speed mixer and mix 3 ~ 15 minutes, after fully mixing, discharging adds the main spout of twin screw extruder, add from the side spout of twin screw extruder the glass fibre taken by weight ratio simultaneously, by twin screw extruder melting mixing 1 ~ 2 minute, screw speed controls at 150 ~ 600r/min, processing temperature is 210 DEG C ~ 280 DEG C scopes, then extruding pelletization, and it is dry, packaging, obtain a kind of nano-bamboo carbon PTT of the present invention and strengthen master batch.
Embodiment 2:
A kind of nano-bamboo carbon PTT strengthens master batch, its component by mass percent proportioning is: PTT resin 20%, glass fibre 30%, nano-bamboo carbon 15%, ACR 25%, E-MA-GMA 5%, N-phenylmaleimide 2%, TAF 3%, described glass fibre be surface through silane coupler modified process and mean diameter at the alkali-free short glass fiber of 8 ~ 15 μm, described nano-bamboo carbon be surface through nano-titanium dioxide modified process and particle diameter at the nano-bamboo carbon of 20 ~ 80nm.
Preparation method: take each component by weight ratio, and by PTT resin, nano-bamboo carbon, ACR, E-MA-GMA, N-phenylmaleimide and TAF add in high-speed mixer and mix 3 ~ 15 minutes, after fully mixing, discharging adds the main spout of twin screw extruder, add from the side spout of twin screw extruder the glass fibre taken by weight ratio simultaneously, by twin screw extruder melting mixing 1 ~ 2 minute, screw speed controls at 150 ~ 600r/min, processing temperature is 210 DEG C ~ 280 DEG C scopes, then extruding pelletization, and it is dry, packaging, obtain a kind of nano-bamboo carbon PTT of the present invention and strengthen master batch.
Claims (7)
1. a nano-bamboo carbon PTT strengthens master batch, it is characterized in that, its component by mass percent proportioning is: PTT resin 15% ~ 50%, glass fibre 10% ~ 30%, nano-bamboo carbon 15% ~ 40%, ACR 10% ~ 25%, expanding material 3% ~ 8%, heat-resistant agent 2% ~ 5%, dispersion agent 0.5% ~ 3%.
2. a kind of nano-bamboo carbon PTT according to claim 1 strengthens master batch, it is characterized in that, described glass fibre be surface through silane coupler modified process and mean diameter at the alkali-free short glass fiber of 8 ~ 15 μm.
3. a kind of nano-bamboo carbon PTT according to claim 1 strengthens master batch, it is characterized in that, described nano-bamboo carbon be surface through nano-titanium dioxide modified process and particle diameter at the nano-bamboo carbon of 20 ~ 80nm.
4. a kind of nano-bamboo carbon PTT according to claim 1 strengthens master batch, and it is characterized in that, described expanding material is ethylene-ethylacrylate-glycidyl methacrylate triblock copolymer.
5. a kind of nano-bamboo carbon PTT according to claim 1 strengthens master batch, and it is characterized in that, described heat-resistant agent is bismaleimides or N-phenylmaleimide.
6. a kind of nano-bamboo carbon PTT according to claim 1 strengthens master batch, and it is characterized in that, described lubricant is modification ethylene bis-fatty acid amides.
7. a kind of nano-bamboo carbon PTT according to claim 1 strengthens the preparation method of master batch, it is characterized in that, comprise the following steps: take each component by weight ratio, and by PTT resin, nano-bamboo carbon, ACR, expanding material, heat-resistant agent and dispersion agent add in high-speed mixer and mix 3 ~ 15 minutes, after fully mixing, discharging adds the main spout of twin screw extruder, add from the side spout of twin screw extruder the glass fibre taken by weight ratio simultaneously, by twin screw extruder melting mixing 1 ~ 2 minute, screw speed controls at 150 ~ 600r/min, processing temperature is 210 DEG C ~ 280 DEG C scopes, then extruding pelletization, and it is dry, packaging, obtain the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410546388.5A CN104861534A (en) | 2014-10-16 | 2014-10-16 | Nano bamboo carbon PTT enhanced master batch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410546388.5A CN104861534A (en) | 2014-10-16 | 2014-10-16 | Nano bamboo carbon PTT enhanced master batch |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104861534A true CN104861534A (en) | 2015-08-26 |
Family
ID=53907744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410546388.5A Pending CN104861534A (en) | 2014-10-16 | 2014-10-16 | Nano bamboo carbon PTT enhanced master batch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104861534A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108211765A (en) * | 2017-12-11 | 2018-06-29 | 赵耀祥 | A kind of bamboo carbon packet with fresh air and preparation method thereof |
| CN108244762A (en) * | 2017-12-11 | 2018-07-06 | 赵耀祥 | A kind of bamboo carbon insole |
-
2014
- 2014-10-16 CN CN201410546388.5A patent/CN104861534A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108211765A (en) * | 2017-12-11 | 2018-06-29 | 赵耀祥 | A kind of bamboo carbon packet with fresh air and preparation method thereof |
| CN108244762A (en) * | 2017-12-11 | 2018-07-06 | 赵耀祥 | A kind of bamboo carbon insole |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105385124B (en) | Carbon fiber reinforced polylactic acid 3D printing material and preparation method thereof | |
| CN106589578A (en) | High-performance jute fiber reinforced polypropylene composite and preparation method thereof | |
| CN107033456B (en) | One kind is based on POSS organic-inorganic hybrid nanometer compatilizer and its preparation and application | |
| CN103450530A (en) | Nanoparticle composite material | |
| CN102311616B (en) | Carbon-fiber-reinforced polyester composite material and preparation method thereof | |
| CN102516662B (en) | Polypropylene composite material with high strength and high heat resistance and its preparation method | |
| CN106188842A (en) | The preparation method of polypropylene/bamboo granule/ultra micro bamboo charcoal composite material | |
| CN104861534A (en) | Nano bamboo carbon PTT enhanced master batch | |
| CN104341741A (en) | High performance low cost PET (polyethylene terephthalate)/PBT (polybutylene terephthalate) alloy and preparation method | |
| CN106433053B (en) | A kind of method for preparing poly-lactic acid material and the poly-lactic acid material prepared by this method | |
| CN108148368A (en) | A kind of full-biodegradable polylactic acid base resin material | |
| CN105273239A (en) | Cellulose diacetate composite material and preparation method thereof | |
| CN104845083A (en) | High-temperature resistant strengthened modified PET/PTT/PETG composite material | |
| CN105802068A (en) | PVC (polyvinyl chloride) nano-plastics and preparation method thereof | |
| CN104845234A (en) | PTT functional black masterbatch | |
| CN104861576A (en) | Polytrimethylene terephthalate toughening weather-proof master batch | |
| CN104845208A (en) | High-ductility and high-strength PTT composition | |
| CN104845325A (en) | Glass-fiber reinforced PC/PTT alloy material | |
| CN104845244A (en) | Carbon fiber reinforced and nano-bamboo carbon antibacterial PTT functional masterbatch | |
| CN108676376A (en) | A kind of modified plastics and preparation method thereof | |
| CN104845258A (en) | Glass fiber reinforced aging resistant PET/PTT alloy and preparation method thereof | |
| CN104194327A (en) | Enhanced micro-transparent nylon material and preparation method thereof | |
| CN104861510A (en) | Low-warping high-strength high-impact modified PTT/PETG composite material | |
| CN103756267A (en) | Fiber-reinforced ABS/PBT (Acrylonitrile Butadiene Styrene)/(Poly Butylece Terephthalate) alloy and preparation method thereof | |
| CN104845337A (en) | Reinforced and modified PC/PTT alloy and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150826 |