CN104851773A - Ion deflection transmission apparatus and mass spectrometer using same - Google Patents
Ion deflection transmission apparatus and mass spectrometer using same Download PDFInfo
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- CN104851773A CN104851773A CN201510276312.XA CN201510276312A CN104851773A CN 104851773 A CN104851773 A CN 104851773A CN 201510276312 A CN201510276312 A CN 201510276312A CN 104851773 A CN104851773 A CN 104851773A
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Abstract
An ion deflection transmission apparatus comprises an ion accelerator, deflectors and an ion decelerator. The deflectors comprise an ion electrostatic lens and one or more guide devices arranged in the ion electrostatic lens. The ion accelerator and the ion decelerator are arranged at a front part and a rear part of the deflectors respectively. Before ions enter the electrostatic lens, the ions firstly pass through the accelerator to obtain kinetic energy. When the ions leave the electrostatic lens, the ions pass through the decelerator to regain initial kinetic energy. Under the action of the guide devices in the electrostatic lens, the forced direction of the ions is the electric field direction; an incidence ion beam is parallel to an emission ion beam; and photons and neutral particles are free of action of an electric field force to do linear movement and cannot pass through the deflection transmission apparatus. The invention also discloses a mass spectrometer using the same ion deflection transmission apparatus. The invention has the following advantages that the ion transmission efficiency is high; the photons and neutral particles are effectively prevented from entering a next channel while positive ions are deflected; and the miniaturization of the instrument is facilitated.
Description
Technical field
The present invention relates to mass spectrometer, particularly relate to the ion transport device in mass spectrometer, cation can be made to be deflected through and block electrons, photon and neutral particle.
Background technology
Mass spectrometer is a kind of instrument measuring ion mass-to-charge ratio, and the ion produced by ion source arrives mass analyzer through overshoot transmitting device, signal detected, to obtain the information of mass-to-charge ratio after selecting matter by detector.The effect of ion deflecting transmitting device has two, and one is that two is that block electrons, neutral particle and photon are to improve the final signal to noise ratio of instrument at difference vacuum cavity transmission ion.
In current mass spectrometer, the implementation of ion deflecting transmitting device is mainly divided into three kinds, and one is cylinder baffle-type, and one is normal deflection formula, also has one to be off-axis conveying type.In the ion deflecting transmitting device of cylinder baffle-type, circular baffle plate is put at tubular ion lens center.Ion, when scioptics, is subject to the effect of electric field force, and first outwards disperse, to walk around baffle plate, more again focus on, fly out deflection transmitting device.And for photon and neutral particle, due to not by the effect of electric field force, then directly to strike on baffle plate and kinetic energy loss, cannot ion deflecting transmitting device be passed through.This kind of mode structural design is simple, but ion transmission efficiency is low.The structure that typical cylinder baffle-type ion deflecting transmitting device has Perkin-Elmer company to use on its Elan series ICP-MS.
For normal deflection mode, its main operation principle is, ion is by a deflecting electric field region, be subject to the effect of electric field force and depart from the original direction of motion, and finally deflect 90 ° when outgoing, and photon and neutral ion be not by electric field force effect, flies along former road.Although this mode structure is simple, because ion transfer path is right angle, be unfavorable for the miniaturization of instrument.The quadrupole ion deflector that typical normal deflection formula ion deflecting transmitting device has Extrel company to produce and the deflection structure that Varian company adopts on its ICP-MS product.
Off-axis transmission means refers to that ion transfer fore-and-aft direction is constant, but transmission path can offset to some extent.This mode can be realized by off-axis guide bar, and ion is travelled forward along off-axis guide bar under the constraint of rf electric field; Or adopt the electrostatic lens of given shape and direct voltage, ion does off-axis motion under this electric field.
In addition, for basic electrostatic lens, it has focussing force to ion beam, focuses on similar with optical lens to light beam.And optical lens can deflect the light beam from axle, similar electrostatic lens also has deflecting action for the light beam from axle.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of efficiency of transmission high and is conducive to the ion deflecting transmitting device of the miniaturization of instrument and uses the mass spectrometer of this ion deflecting transmitting device.
The present invention proposes a kind of mode; the off-axis transmission of ion can be realized; its basic structure is ion electrostatic lens; show through software emulation; for carry out deflecting in ion electrostatic lens from axle ion beam; the initial kinetic energy of ion has a great impact deflection effect, and kinetic energy cannot pass through electrostatic lens slightly lower than the ion of desirable kinetic energy, and the slightly high ion motion trace of kinetic energy has larger departing from.
The present invention solves the problems of the technologies described above by the following technical programs: a kind of ion deflecting transmitting device, comprise ion accelerator, deflector, ion decelerator, described deflector comprises ion electrostatic lens and is arranged on one or more guide in ion electrostatic lens, ion accelerator and ion decelerator are separately positioned on the front and back of deflector, before ion enters electrostatic lens, first through accelerator, obtain kinetic energy, this kinetic energy is greater than ion initial kinetic energy several times, after ion leaves electrostatic lens, again through decelerator, initial kinetic energy is returned to through slowing down, under the electric field action of the guide in electrostatic lens, the Impact direction of ion is direction of an electric field, and incident ion bundle is parallel with outgoing ion beam, make ion according to the orbiting motion of setting, realize off-axis transmission.When ion moves in electrostatic lens, its kinetic energy is mainly from accelerator but not initial kinetic energy, and therefore initial kinetic energy is little on the impact of its movement locus.Under electric field action, guide changes ion motion trace by changing Electric Field Distribution, and electronics is subject to opposition at accelerating region and is ejected, and photon and neutral particle then do not move along a straight line by electric field force effect, cannot through this deflection transmitting device.
As scheme concrete further, described ion accelerator comprises one or more battery lead plate, each battery lead plate comprises at least one hole, use intermediate ion through the transmission of this at least one hole, described deflector comprises one or more electrostatic lens, use intermediate ion through each electrostatic lens, described ion decelerator comprises one or more battery lead plate, each battery lead plate comprises at least one hole, use intermediate ion through the transmission of this at least one hole, and kinetic energy is lost in decelerator, one or more guide is comprised in each electrostatic lens, intermediate ion is used to transmit through the direction of an electric field produced along guide during each electrostatic lens.
Preferred:
The some or all of shape of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is circular, ellipse, triangle, rectangle, square, polygon, cylindrical or taper, or the combination of these shapes; And/or
Described ion accelerator electrodes plate and/or the some or all of of described ion decelerator battery lead plate have circular, ellipse, triangle, rectangle, square or polygonal hole; And/or
The some or all of shape of described electrostatic lens is roughly cylindrical, elliptical cylinder-shape, triangle cylindricality, four side column shapes, Polygonal column shape or taper, or the combination of these shapes; And/or
The some or all of shape of described guide is circular, ellipse, triangle, rectangle, square, polygon or crescent, or the combination of these shapes; And/or
The some or all of of described guide has circular, ellipse, triangle, rectangle, square or polygonal hole.
Preferred:
The some or all of overall diameter of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate or yardstick are the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
Some or all of interior diameter or the yardstick of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate are selected from by the hole in the group that the following is formed: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 5.0mm; (iii) 5.0mm ~ 20.0mm; And/or
The some or all of thickness of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is the group that the following is formed: (i) is less than or equal to 0.1mm; (ii) 0.1mm ~ 1.0mm; (iii) 1.0mm ~ 10.0mm; And/or
The some or all of overall diameter of described electrostatic lens or yardstick are the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
The some or all of length of described electrostatic lens is the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
The some or all of thickness of described electrostatic lens is the group that the following is formed: (i) is less than or equal to 0.1mm; (ii) 0.1mm ~ 1.0mm; (iii) 1.0mm ~ 10.0mm; And/or
The some or all of overall diameter of described guide or yardstick are the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
The some or all of interior diameter of described guide or yardstick are the group that the following is formed: (i) is less than or equal to 5.0mm; (ii) 5.0mm ~ 20.0mm; (iii) 20.0mm ~ 50.0mm; And/or
The some or all of thickness of described guide is the group that the following is formed: (i) is less than or equal to 0.1mm; (ii) 0.1mm ~ 1.0mm; (iii) 1.0mm ~ 10.0mm.
Preferred:
The some or all of distance between plates of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is from the group formed for the following: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm; And/or
The distance of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate and deflector is the group that the following is formed: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm; And/or
The some or all of distance between plates of described guide is from the group formed for the following: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm; And/or
The some or all of relative angle of described guide is the group that the following is formed: (i) 0 ° ~ 30 °; (ii) 30 ° ~ 90 °; (iii) 90 ° ~ 180 °; And/or
Described guide is positioned at electrostatic lens, and the distance of its distance electrostatic lens opening is the group that the following is formed: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm.
Preferred:
The some or all of voltage of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is the group that the following is formed: (i) is lower than equaling-100V; (ii)-100V ~-50V; (iii)-50V ~ 0V; (iv) 0V ~ 50V; (v) 50V ~ 100V; And/or
The some or all of voltage of described electrostatic lens is the group that the following is formed: (i) is lower than equaling-100V; (ii)-100V ~-50V; (iii)-50V ~ 0V; (iv) 0V ~ 50V; (v) 50V ~ 100V; And/or
The some or all of voltage of described guide is the group that the following is formed: (i) is lower than equaling-100V; (ii)-100V ~-50V; (iii)-50V ~ 0V; (iv) 0V ~ 50V; (v) 50V ~ 100V.
Preferred:
The some or all of material of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is the group that the following is formed: (i) stainless steel; (ii) copper; (iii) aluminium; (iv) nickel; (v) silver; (vi) gold; (vii) molybdenum and (v) platinum; And/or
The some or all of material of described electrostatic lens is the group that the following is formed: (i) stainless steel; (ii) copper; (iii) aluminium; (iv) nickel; (v) silver; (vi) gold; (vii) molybdenum and (v) platinum; And/or
The some or all of material of described guide is the group that the following is formed: (i) stainless steel; (ii) copper; (iii) aluminium; (iv) nickel; (v) silver; (vi) gold; (vii) molybdenum and (v) platinum.
The invention also discloses a kind of mass spectrometer using described ion deflecting transmitting device, described ion deflecting transmitting device is applicable to meet mass spectrometer described below:
Some or all of vacuum environment during instrument work is the group that the following is formed: (i) is lower than equaling 10
-5pa; (ii) 10
-5~ 10
-4pa; (iii) 10
-4~ 10
-3pa; (iii) 10
-3~ 10
-2pa; (iv) 10
-2~ 10
-1pa; (iv) 10
-1~ 1Pa; And/or
The type ion source of instrument is selected from the group be made up of the following: (i) electron spray ionisation (" ESI ") ion source; (ii) atmospheric pressure photoionization (" APPI ") ion source; (iii) Atmosphere Pressure Chemical Ionization (APCI) (" APCI ") ion source; (iv) substance assistant laser desorpted ionized (" MALDI ") ion source; (v) laser desorption ionisation (" LDI ") ion source; (vi) atmospheric pressure ionization (" API ") ion source; (vii) desorption ionization (" DIOS ") ion source on silicon; (viii) electron bombardment (" EI ") ion source; (ix) chemi-ionization (" CI ") ion source; (x) field ionization (FI) (" FI ") ion source; (xi) field desorption (" FD ") ion source; (xii) inductively coupled plasma (" ICP ") ion source; (xiii) fast electronics bombardment (" FAB ") ion source; (xiv) liquid secondary ion mass spectroscopy (" LSIMS ") ion source; And (xv) desorption electrospray ionization (" DESI ") ion source; And/or
C the mass analyzer partly or completely of () instrument is selected from the group be made up of the following: (i) level Four bar mass analyzer; (ii) 2D or linear four-electrode quality analyzer; (iii) Borrow or 3D four-electrode quality analyzer; (iv) Peng Ning catcher mass analyzer; (v) ion trap mass analyzer; (vi) magnetic sector mass analyzer; (vii) ion cyclotron resonance (" ICR ") mass analyzer; (viii) Fourier Transform Ion cyclotron Resonance (" FTICR ") mass analyzer; (ix) electrostatic or orbitrap mass analyser; And (x) time of flight mass analyzer.
The present invention has the following advantages compared to existing technology:
1, use ion deflecting transmitting device of the present invention, ion transmission efficiency is high and do not affect by the initial kinetic energy of ion, while deflection cation, effectively stops that photon and neutral particle enter in next passage, the signal to noise ratio of raising mass spectrometer.
2, incident ion bundle is parallel with outgoing ion beam, is conducive to the miniaturization of instrument.
3, all electrode structures can be processed by common metal, can have various ways in shape, and processing is simple, and cost is low.
4, use direct voltage, voltage swing requires low.
5, can be used for, in all kinds of mass spectrometer and relevant ion transfer equipment, being with a wide range of applications.
Accompanying drawing explanation
Fig. 1 is the schematic cross-section of the ion deflecting transmitting device of the embodiment of the present invention 1.
Fig. 2 is the stereogram of the ion deflecting transmitting device of the embodiment of the present invention 1.
Fig. 3 is the ion motion trace analogous diagram of embodiment 1.
Fig. 4 is the schematic cross-section of the ion deflecting transmitting device of the embodiment of the present invention 2.
Fig. 5 is the stereogram of the ion deflecting transmitting device of the embodiment of the present invention 2.
Fig. 6 is the ion motion trace analogous diagram of embodiment 2.
Number in the figure: 1,2,10,20-ion accelerator electrodes plate, 3,30,50,60-deflector, 4,5,40,70-guide, 6,7,80,90-ion decelerator battery lead plate
Embodiment
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the accompanying drawing in the embodiment of the present invention, technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1:
In Fig. 1 institute diagram, by battery lead plate 1 and 2 constituent particle accelerator, wherein the voltage of battery lead plate 1 is-30V, and the voltage of battery lead plate 2 is-90V.Ion, through the aperture in the middle of battery lead plate 1 and 2, enters deflector.Deflector comprises an electrostatic lens 3, and guide 4 and 5 is contained in the inside.The voltage of electrostatic lens 3 and guide 4 and 5 is-6V.After deflector, ion enters into decelerator, is made up of battery lead plate 6 and 7, and its voltage is respectively-110V and-20V.
Battery lead plate 1,2 is taper, and wherein the taper hole diameter of battery lead plate 1 is 5mm, height 19mm, and bottom external diameter is 20mm, bottom thickness 2mm, and thickness is less gradually to top the end of from, is 0 at taper hole place thickness; The taper hole diameter of battery lead plate 2 is 5mm, height 19mm, and bottom external diameter is 16mm, bottom thickness 1.88mm, and thickness is less gradually to top the end of from, is 0 at taper hole place thickness.Battery lead plate 6,7 is circular sheet with hole, and diameter is 24mm, and thickness is 1mm, and the diameter of centre bore is 10mm.Electrostatic lens 3 is round tube shape, external diameter 34mm, internal diameter 30mm, long 40mm.Guide 4 and 5 is crescent, and in it, outer radius is 15mm, and summit width is 4mm, and thickness is 5mm.The axis of acceleration/deceleration device battery lead plate, electrostatic lens, guide all at same plane, and is parallel to each other.Bottom battery lead plate 1,2, and the distance between battery lead plate 6,7 is 5mm, and battery lead plate 2 is also 5mm to electrostatic lens and battery lead plate 6 to the distance of electrostatic lens.The inwall of electrostatic lens 3 is close in the periphery of guide 4,5, and the relative angle of two guides is 180 °.Guide 4 is apart from electrostatic lens entrance 6mm, and the distance of guide 4,5 is 11mm.Battery lead plate 1,2 and battery lead plate 6,7 are symmetrical, and its axis and electrostatic lens axial line distance are 5mm.
In Fig. 3 institute diagram, mass number is 100, and kinetic energy is that the tape unit positive charge ion of 8eV obtains acceleration by battery lead plate 1,2, enters in electrostatic lens 3, deflects.Ion after deflection passes from the aperture at battery lead plate 6 and 7 center.The kinetic energy that ion leaves when deflecting transmitting device is consistent with initial kinetic energy.Meanwhile, emulation shows, for same ion deflecting transmitting device, have identical initial kinetic energy and the different ion of mass number, its movement locus is consistent.
Embodiment 2:
In Fig. 4 institute diagram, by battery lead plate 10 and 20 constituent particle accelerator, wherein the voltage of battery lead plate 10 is 0V, and the voltage of battery lead plate 20 is-50V.Ion, through the aperture in the middle of battery lead plate 10 and 20, enters deflector.Deflector comprises 3 electrostatic lens 30,50,60, containing guide 40 inside electrostatic lens 30, containing guide 70 inside electrostatic lens 60.The voltage of electrostatic lens 30 and guide 40 is 0.3V, and the voltage of electrostatic lens 50 is-11V, and the voltage of electrostatic lens 60 and guide 70 is 1.1V.After deflector, ion enters into decelerator, and be made up of battery lead plate 80 and 90, its voltage is respectively-20V and 0V.
Battery lead plate 10,20,80,90 is circular sheet with hole, diameter 16mm, and thickness is 1mm, and the diameter of centre bore is 6mm.Electrostatic lens 30 and 60 is round tube shape, external diameter 24mm, internal diameter 20mm, long 30mm; Electrostatic lens 50 is also round tube shape, external diameter 12mm, internal diameter 10mm, long 10mm.Guide 40 and 70 is annular, and its external diameter is 20mm, and internal diameter is 14mm, thick 3mm.The axis of acceleration/deceleration device battery lead plate, electrostatic lens, guide all at same plane, and is parallel to each other.Battery lead plate 10,20, and the distance between battery lead plate 80,90 is 4mm; Battery lead plate 20 is all 4mm to the distance of electrostatic lens 30, battery lead plate 80 to the distance of electrostatic lens 60, electrostatic lens 30 to the distance of electrostatic lens 50, electrostatic lens 50 to the distance of electrostatic lens 60.The inwall of electrostatic lens 30,60 is close in the periphery of guide 40,70.Guide 40,70 distance electrostatic lens 30,60 entrance 13.5mm.Electrostatic lens 30 axis is than battery lead plate 10,20 axis height 4mm, and electrostatic lens 50 axis is than electrostatic lens 30 axis height 7.12mm, and electrostatic lens 60 axis is than electrostatic lens 50 axis height 7.12mm, and battery lead plate 80,90 axis is than electrostatic lens 6 axis height 4mm.
In Fig. 6 institute diagram, mass number is 100, and kinetic energy is that the tape unit positive charge ion of 8eV obtains acceleration by battery lead plate 10,20, enter in electrostatic lens 30, deflect, enter electrostatic lens 50, enter electrostatic lens 60 again to deflect, finally pass from the aperture at battery lead plate 80 and 90 center.The kinetic energy that ion leaves when deflecting transmitting device is consistent with initial kinetic energy.Meanwhile, emulation shows, for same ion deflecting transmitting device, have identical initial kinetic energy and the different ion of mass number, its movement locus is consistent.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (9)
1. an ion deflecting transmitting device, it is characterized in that: comprise ion accelerator, deflector, ion decelerator, described deflector comprises ion electrostatic lens and is arranged on one or more guide of ion electrostatic lens, ion accelerator and ion decelerator are separately positioned on the front and back of deflector, before ion enters electrostatic lens, first through accelerator, obtain kinetic energy, after ion leaves electrostatic lens, again through decelerator, initial kinetic energy is returned to through slowing down, under the electric field action of the guide in electrostatic lens, the Impact direction of ion is direction of an electric field, and incident ion bundle is parallel with outgoing ion beam, photon and neutral particle then do not move along a straight line by electric field force effect, cannot through this deflection transmitting device.
2. a kind of ion deflecting transmitting device as claimed in claim 1, it is characterized in that: described ion accelerator comprises one or more battery lead plate, each battery lead plate comprises at least one hole, use intermediate ion through the transmission of this at least one hole, described deflector comprises one or more electrostatic lens, use intermediate ion through each electrostatic lens, described ion decelerator comprises one or more battery lead plate, each battery lead plate comprises at least one hole, use intermediate ion through the transmission of this at least one hole, and kinetic energy is lost in decelerator, one or more guide is comprised in each electrostatic lens, intermediate ion is used to transmit through the direction of an electric field produced along guide during each electrostatic lens.
3. a kind of ion deflecting transmitting device as claimed in claim 2, it is characterized in that: the some or all of shape of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is circular, ellipse, triangle, rectangle, square, polygon, cylindrical or taper, or the combination of these shapes; And/or
Described ion accelerator electrodes plate and/or the some or all of of described ion decelerator battery lead plate have circular, ellipse, triangle, rectangle, square or polygonal hole; And/or
The some or all of shape of described electrostatic lens is roughly cylindrical, elliptical cylinder-shape, triangle cylindricality, four side column shapes, Polygonal column shape or taper, or the combination of these shapes; And/or
The some or all of shape of described guide is circular, ellipse, triangle, rectangle, square, polygon or crescent, or the combination of these shapes; And/or
The some or all of of described guide has circular, ellipse, triangle, rectangle, square or polygonal hole.
4. a kind of ion deflecting transmitting device as claimed in claim 2, is characterized in that: the some or all of overall diameter of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate or yardstick are the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
Some or all of interior diameter or the yardstick of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate are selected from by the hole in the group that the following is formed: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 5.0mm; (iii) 5.0mm ~ 20.0mm; And/or
The some or all of thickness of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is the group that the following is formed: (i) is less than or equal to 0.1mm; (ii) 0.1mm ~ 1.0mm; (iii) 1.0mm ~ 10.0mm; And/or
The some or all of overall diameter of described electrostatic lens or yardstick are the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
The some or all of length of described electrostatic lens is the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
The some or all of thickness of described electrostatic lens is the group that the following is formed: (i) is less than or equal to 0.1mm; (ii) 0.1mm ~ 1.0mm; (iii) 1.0mm ~ 10.0mm; And/or
The some or all of overall diameter of described guide or yardstick are the group that the following is formed: (i) 5.0mm ~ 10.0mm; (ii) 10.0mm ~ 50.0mm; (iii) 50.0mm is more than or equal to; And/or
The some or all of interior diameter of described guide or yardstick are the group that the following is formed: (i) is less than or equal to 5.0mm; (ii) 5.0mm ~ 20.0mm; (iii) 20.0mm ~ 50.0mm; And/or
The some or all of thickness of described guide is the group that the following is formed: (i) is less than or equal to 0.1mm; (ii) 0.1mm ~ 1.0mm; (iii) 1.0mm ~ 10.0mm.
5. a kind of ion deflecting transmitting device as claimed in claim 2, is characterized in that: the some or all of distance between plates of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is from the group formed for the following: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm; And/or
The distance of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate and deflector is the group that the following is formed: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm; And/or
The some or all of distance between plates of described guide is from the group formed for the following: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm; And/or
The some or all of relative angle of described guide is the group that the following is formed: (i) 0 ° ~ 30 °; (ii) 30 ° ~ 90 °; (iii) 90 ° ~ 180 °; And/or
Described guide is positioned at electrostatic lens, and the distance of its distance electrostatic lens opening is the group that the following is formed: (i) is less than or equal to 1.0mm; (ii) 1.0mm ~ 10.0mm; (iii) 10.0mm ~ 50.0mm.
6. a kind of ion deflecting transmitting device as claimed in claim 2, is characterized in that: the some or all of voltage of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is the group that the following is formed: (i) is lower than equaling-100V; (ii)-100V ~-50V; (iii)-50V ~ 0V; (iv) 0V ~ 50V; (v) 50V ~ 100V; And/or
The some or all of voltage of described electrostatic lens is the group that the following is formed: (i) is lower than equaling-100V; (ii)-100V ~-50V; (iii)-50V ~ 0V; (iv) 0V ~ 50V; (v) 50V ~ 100V; And/or
The some or all of voltage of described guide is the group that the following is formed: (i) is lower than equaling-100V; (ii)-100V ~-50V; (iii)-50V ~ 0V; (iv) 0V ~ 50V; (v) 50V ~ 100V.
7. a kind of ion deflecting transmitting device as claimed in claim 2, is characterized in that: the some or all of material of described ion accelerator electrodes plate and/or described ion decelerator battery lead plate is the group that the following is formed: (i) stainless steel; (ii) copper; (iii) aluminium; (iv) nickel; (v) silver; (vi) gold; (vii) molybdenum and (v) platinum; And/or
The some or all of material of described electrostatic lens is the group that the following is formed: (i) stainless steel; (ii) copper; (iii) aluminium; (iv) nickel; (v) silver; (vi) gold; (vii) molybdenum and (v) platinum; And/or
The some or all of material of described guide is the group that the following is formed: (i) stainless steel; (ii) copper; (iii) aluminium; (iv) nickel; (v) silver; (vi) gold; (vii) molybdenum and (v) platinum.
8. one kind uses the mass spectrometer of ion deflecting transmitting device as described in any one of claim 1 to 7.
9. a mass spectrometer as claimed in claim 8, is characterized in that:
Some or all of vacuum environment during mass spectrometer work is the group that the following is formed: (i) is lower than equaling 10
-5pa; (ii) 10
-5~ 10
-4pa; (iii) 10
-4~ 10
-3pa; (iii) 10
-3~ 10
-2pa; (iv) 10
-2~ 10
-1pa; (iv) 10
-1~ 1Pa; And/or
The type ion source of instrument is selected from the group be made up of the following: (i) electron spray ionisation (" ESI ") ion source; (ii) atmospheric pressure photoionization (" APPI ") ion source; (iii) Atmosphere Pressure Chemical Ionization (APCI) (" APCI ") ion source; (iv) substance assistant laser desorpted ionized (" MALDI ") ion source; (v) laser desorption ionisation (" LDI ") ion source; (vi) atmospheric pressure ionization (" API ") ion source; (vii) desorption ionization (" DIOS ") ion source on silicon; (viii) electron bombardment (" EI ") ion source; (ix) chemi-ionization (" CI ") ion source; (x) field ionization (FI) (" FI ") ion source; (xi) field desorption (" FD ") ion source; (xii) inductively coupled plasma (" ICP ") ion source; (xiii) fast electronics bombardment (" FAB ") ion source; (xiv) liquid secondary ion mass spectroscopy (" LSIMS ") ion source; And (xv) desorption electrospray ionization (" DESI ") ion source; And/or
C the mass analyzer partly or completely of () instrument is selected from the group be made up of the following: (i) level Four bar mass analyzer; (ii) 2D or linear four-electrode quality analyzer; (iii) Borrow or 3D four-electrode quality analyzer; (iv) Peng Ning catcher mass analyzer; (v) ion trap mass analyzer; (vi) magnetic sector mass analyzer; (vii) ion cyclotron resonance (" ICR ") mass analyzer; (viii) Fourier Transform Ion cyclotron Resonance (" FTICR ") mass analyzer; (ix) electrostatic or orbitrap mass analyser; And (x) time of flight mass analyzer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510276312.XA CN104851773A (en) | 2015-05-26 | 2015-05-26 | Ion deflection transmission apparatus and mass spectrometer using same |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510276312.XA CN104851773A (en) | 2015-05-26 | 2015-05-26 | Ion deflection transmission apparatus and mass spectrometer using same |
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| CN104851773A true CN104851773A (en) | 2015-08-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510276312.XA Pending CN104851773A (en) | 2015-05-26 | 2015-05-26 | Ion deflection transmission apparatus and mass spectrometer using same |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110504152A (en) * | 2018-05-17 | 2019-11-26 | 塞莫费雪科学（不来梅）有限公司 | Ion guide |
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| US5559337A (en) * | 1993-09-10 | 1996-09-24 | Seiko Instruments Inc. | Plasma ion source mass analyzing apparatus |
| US5481107A (en) * | 1993-09-20 | 1996-01-02 | Hitachi, Ltd. | Mass spectrometer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110504152A (en) * | 2018-05-17 | 2019-11-26 | 塞莫费雪科学（不来梅）有限公司 | Ion guide |
| CN110504152B (en) * | 2018-05-17 | 2022-04-29 | 塞莫费雪科学（不来梅）有限公司 | Ion guide |
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Application publication date: 20150819 |