CN104851546A - Magnetic porous-polymer functional nanoparticle and preparation method thereof - Google Patents
Magnetic porous-polymer functional nanoparticle and preparation method thereof Download PDFInfo
- Publication number
- CN104851546A CN104851546A CN201510307145.0A CN201510307145A CN104851546A CN 104851546 A CN104851546 A CN 104851546A CN 201510307145 A CN201510307145 A CN 201510307145A CN 104851546 A CN104851546 A CN 104851546A
- Authority
- CN
- China
- Prior art keywords
- add
- preparation
- magnetic
- phenolic resins
- magnetic porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000002105 nanoparticle Substances 0.000 title abstract description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000005011 phenolic resin Substances 0.000 claims abstract description 34
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 34
- 238000005815 base catalysis Methods 0.000 claims abstract description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 44
- 239000004005 microsphere Substances 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 27
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- DKAGJZJALZXOOV-UHFFFAOYSA-N hydrate;hydrochloride Chemical compound O.Cl DKAGJZJALZXOOV-UHFFFAOYSA-N 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 238000002390 rotary evaporation Methods 0.000 claims description 5
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical class [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 4
- 235000011091 sodium acetates Nutrition 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 abstract description 9
- 239000002245 particle Substances 0.000 abstract description 9
- 229920002223 polystyrene Polymers 0.000 abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 239000002122 magnetic nanoparticle Substances 0.000 abstract description 5
- BDKLKNJTMLIAFE-UHFFFAOYSA-N 2-(3-fluorophenyl)-1,3-oxazole-4-carbaldehyde Chemical compound FC1=CC=CC(C=2OC=C(C=O)N=2)=C1 BDKLKNJTMLIAFE-UHFFFAOYSA-N 0.000 abstract description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract description 4
- 235000017281 sodium acetate Nutrition 0.000 abstract description 4
- 229940087562 sodium acetate trihydrate Drugs 0.000 abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 150000004687 hexahydrates Chemical class 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 abstract 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 abstract 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 abstract 1
- 238000004729 solvothermal method Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 9
- 239000000243 solution Substances 0.000 description 8
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 5
- 239000011805 ball Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000000703 high-speed centrifugation Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- -1 iron ion Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510307145.0A CN104851546B (en) | 2015-06-05 | 2015-06-05 | A kind of magnetic porous polymers function Nano microsphere and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510307145.0A CN104851546B (en) | 2015-06-05 | 2015-06-05 | A kind of magnetic porous polymers function Nano microsphere and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104851546A true CN104851546A (en) | 2015-08-19 |
CN104851546B CN104851546B (en) | 2017-07-11 |
Family
ID=53851129
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510307145.0A Expired - Fee Related CN104851546B (en) | 2015-06-05 | 2015-06-05 | A kind of magnetic porous polymers function Nano microsphere and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104851546B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110201613A (en) * | 2019-06-10 | 2019-09-06 | 东莞东阳光科研发有限公司 | A kind of Magnetic Polystyrene Microsphere and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012193366A (en) * | 2011-03-17 | 2012-10-11 | Xerox Corp | Solvent-type ink containing coated magnetic nanoparticle |
CN103500622A (en) * | 2013-08-30 | 2014-01-08 | 复旦大学 | Magnetism inorganic nanoparticle/ordered mesopore silica nuclear shell composite microsphere and preparing method thereof |
KR20140024586A (en) * | 2012-08-20 | 2014-03-03 | 삼성에스디아이 주식회사 | Negative active material for rechargeble lithium battery and negative electrode and rechargeble lithium battery including the same |
CN104072659A (en) * | 2014-06-26 | 2014-10-01 | 蓝星(成都)新材料有限公司 | Magnetic resin microspheres and preparation method thereof |
CN104387712A (en) * | 2014-11-03 | 2015-03-04 | 遵义医学院 | Nano composite carrier with superparamagnetism and preparation method thereof |
-
2015
- 2015-06-05 CN CN201510307145.0A patent/CN104851546B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012193366A (en) * | 2011-03-17 | 2012-10-11 | Xerox Corp | Solvent-type ink containing coated magnetic nanoparticle |
KR20140024586A (en) * | 2012-08-20 | 2014-03-03 | 삼성에스디아이 주식회사 | Negative active material for rechargeble lithium battery and negative electrode and rechargeble lithium battery including the same |
CN103500622A (en) * | 2013-08-30 | 2014-01-08 | 复旦大学 | Magnetism inorganic nanoparticle/ordered mesopore silica nuclear shell composite microsphere and preparing method thereof |
CN104072659A (en) * | 2014-06-26 | 2014-10-01 | 蓝星(成都)新材料有限公司 | Magnetic resin microspheres and preparation method thereof |
CN104387712A (en) * | 2014-11-03 | 2015-03-04 | 遵义医学院 | Nano composite carrier with superparamagnetism and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110201613A (en) * | 2019-06-10 | 2019-09-06 | 东莞东阳光科研发有限公司 | A kind of Magnetic Polystyrene Microsphere and preparation method thereof |
CN110201613B (en) * | 2019-06-10 | 2021-09-14 | 东莞东阳光科研发有限公司 | Polystyrene magnetic microsphere and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN104851546B (en) | 2017-07-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103232051B (en) | Preparation method of ultrafine porous calcium carbonate microsphere | |
CN102600778B (en) | Nanometer composite epoxy resin self-repairing microcapsule and preparation method thereof | |
CN103351016B (en) | A kind of method preparing spherulitic porous calcium carbonate particle | |
CN103588920B (en) | Novel preparation method for monodisperse porous polymer nano microcapsule | |
CN101804986B (en) | Method for preparing hollow silicon dioxide microsphere with controllable wall thickness by taking polystyrene microsphere as template | |
US20100311852A1 (en) | Preparing method for melamine-formaldehyde spheres | |
CN107993784A (en) | Magnetic-particle of different morphologies and preparation method and application | |
CN101921353A (en) | Synthesizing method of polystyrene microsphere | |
Sun et al. | Controllable preparation of magnetic polymer microspheres with different morphologies by miniemulsion polymerization | |
CN107022102B (en) | Preparation method of monodisperse mesoporous silica, nano composite foaming agent, preparation method and application | |
CN105801901A (en) | Method for preparing uniformly magnetic cellulose aerogel materials | |
CN104194003A (en) | Method for preparing black monodisperse polymer microspheres | |
CN110201613A (en) | A kind of Magnetic Polystyrene Microsphere and preparation method thereof | |
Cong et al. | Fabrication of monodisperse anisotropic silica hollow microspheres using polymeric cave particles as templates | |
Liu et al. | Facile method for large scale synthesis of magnetic inorganic–organic hybrid anisotropic Janus particles | |
CN107955191A (en) | A kind of processing method of powders of thermoplastic polymers mobility | |
CN104851546A (en) | Magnetic porous-polymer functional nanoparticle and preparation method thereof | |
Macková et al. | Magnetic hollow poly (N-isopropylacrylamide-co-N, N′-methylenebisacrylamide-co-glycidyl acrylate) particles prepared by inverse emulsion polymerization | |
CN103360529A (en) | Controllable synthetic method of micro-sized mono-disperse polystyrene microsphere | |
CN109786118A (en) | A kind of nitrogen oxygen doping carbosphere of large scale preparation size tunable and its preparation method and application | |
CN104445333A (en) | Process for producing calcium carbonate employing nano-precipitation method | |
Mao et al. | In situ polymerization of uniform poly (urea–formaldehyde) microcapsules containing paraffins under the high-speed agitation without emulsifier | |
CN110013805A (en) | A method of preparing amino resins hollow microcapsules | |
CN106749930B (en) | A kind of preparation method of the aspherical particle with surface folding | |
CN106867021B (en) | Preparation method of magnetic porous polymer microspheres |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
EXSB | Decision made by sipo to initiate substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information |
Inventor after: Dai Lizong Inventor after: Xie Honghui Inventor after: Yuan Conghui Inventor after: Mao Jie Inventor after: Xu Yiting Inventor after: Wang Shuang Inventor after: Liu Cheng Inventor after: Luo Weiang Inventor after: He Kaibin Inventor before: Dai Lizong Inventor before: Xie Honghui Inventor before: Yuan Conghui Inventor before: Mao Jie Inventor before: Xu Yiting Inventor before: Wang Shuang Inventor before: Liu Cheng Inventor before: Luo Weiang Inventor before: He Kaibin |
|
COR | Change of bibliographic data | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170711 |