CN104844963B - A kind of high durable magnetic circle - Google Patents

A kind of high durable magnetic circle Download PDF

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Publication number
CN104844963B
CN104844963B CN201510227799.2A CN201510227799A CN104844963B CN 104844963 B CN104844963 B CN 104844963B CN 201510227799 A CN201510227799 A CN 201510227799A CN 104844963 B CN104844963 B CN 104844963B
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CN
China
Prior art keywords
rubber layer
pvc
metal ring
containing ferrite
ferrite material
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CN201510227799.2A
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Chinese (zh)
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CN104844963A (en
Inventor
申国栋
孙方先
张启慧
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Hangzhou Wo Guan Automobile Component Co Ltd
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Hangzhou Wo Guan Automobile Component Co Ltd
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Priority to CN201510227799.2A priority Critical patent/CN104844963B/en
Publication of CN104844963A publication Critical patent/CN104844963A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

Patent of the present invention discloses a kind of high durable magnetic circle, the magnetic circle includes modification rubber layer and metal ring framework containing Ferrite Material, the modification rubber layer containing Ferrite Material is by being wrapped on metal ring framework after high temperature vulcanized, transmitting can be continued after the described modification rubber layer activation containing Ferrite Material perpendicular to rubber layer N/S extremely alternate signals, the modification rubber layer containing Ferrite Material includes the raw material of following percentage by weight:5 8% PVC/NBR rubber-plastics materials, 82 90% ferromagnetic oxide powder, 3 6% pvc materials, 1 2% dispersant, 0.5 1% age resistor, 0.2 0.5% accelerator, 0.2 0.5% vulcanizing agent patent of the present invention mainly solves the poor problem of magnetic circle ozone resistance, resistance to ag(e)ing, oil resistant and chemical resistance using NBR as base material, substantially improves its tensile strength, stress at definite elongation, tear resistance, weatherability and anti-flammability.

Description

A kind of high durable magnetic circle
Technical field
The present invention relates to a kind of high durable magnetic circle.
Background technology
Magnetic circle is main by metal ring framework, and the rubber layer containing Ferrite Material annular in shape, rubber layer is wrapped in skeleton On, most of to be exposed in air, magnetic circle majority is installed on automobile bearing or hub, meeting after rubber layer activation The lasting extremely alternate signals of N/S of transmitting, the base material that usual rubber layer is used is NBR rubber, and the weatherability of NBR rubber is poor, And automobile bearing produces substantial amounts of heat in load and rotation at a high speed, magnetic circle is set to need good resistance to elevated temperatures, by In automobile bearing it is generally necessary to ensure that 300,000 kilometers of the examination of road occur without problem, ozone resistance needs to improve, it is impossible to reach automobile Bearing or the high performance requirement of hub.
The effect of high-weatherability magnetic circle:
The external diameter of matched inner ring can be reduced, cost is reduced, reduce weight, reduction car deadweight, oil consumption is reduced, save The energy;Greater area of persistent signal can be obtained.
The content of the invention
Present invention aim to address magnetic circle ozone resistance, resistance to ag(e)ing, oil resistant and the chemically-resistant by base material of NBR Medicine poor performance problem, substantially improves its tensile strength, stress at definite elongation, tear resistance, weatherability and anti-flammability, can obtain more The persistent signal of large area, can reduce the external diameter of matched inner ring, reduce cost, save the energy.
To achieve these goals, the present invention is adopted the following technical scheme that:
A kind of high durable magnetic circle, the magnetic circle includes modification rubber layer and quoit bone containing Ferrite Material Frame, the modification rubber layer containing Ferrite Material is by being wrapped on metal ring framework after high temperature vulcanized, described iron content Transmitting can be continued after the modification rubber layer activation of ferrite perpendicular to rubber layer N/S extremely alternate signals, it is characterised in that:
The modification rubber layer containing Ferrite Material includes the raw material of following percentage by weight:
5-8% PVC/NBR rubber-plastics materials,
82-90% ferromagnetic oxide powder,
3-6% pvc materials,
1-2% dispersant,
0.5-1% age resistor,
0.2-0.5% accelerator,
0.2-0.5% vulcanizing agents;
The preparation technology of the modification rubber layer containing Ferrite Material is as follows:
1) treated ferromagnetic oxide powder, pvc material and PVC/NBR rubber-plastics materials, are added to banbury together It is interior;
2) start banbury banburying 4-5 minutes, add dispersant, age resistor and vulcanizing agent;
3) continue to start banbury banburying, banbury displays temperature is checked, when temperature to be shown reaches 95-100 degrees Celsius Stop banburying, take out semi-finished product and radiating of making thinner;
4) semi-finished product are taken out and are divided into several pieces, on a mill it is thin it is logical after add the accelerator of respective component, turn over Uniform aftershaping slice is refined, now temperature is no more than 90 degrees Celsius.
The metal ring framework is class T-shape metal ring framework, and the vertical portion of the class T-shape metal ring framework is dress With internal diameter.
The modification rubber layer containing Ferrite Material is wrapped on metal ring framework in a ring.
PVC/NBR=30/70 in the PVC/NBR rubber-plastics materials.
The pvc material has high weatherability.
The beneficial effects of the invention are as follows:
1) present invention by dispersant ferromagnetic oxide powder is uniformly dispersed in rubber layer, it is ensured that transmission signal it is steady Qualitative and uniformity
2) present invention improves the weatherability of rubber layer by adding weather resistant materials, improves life of product and reliability;
3) PVC/NBR rubber-plastics materials of the invention have advantages below:
1. the oil resistivity and cross linkable of resistance to ozone and rubber are significantly improved;
2. improve and draw high intensity, stress at definite elongation, tear resistance, heat resistance and flame resistance;
3. the performances such as oil resistant, resistance to fuel oil and chemical-resistant resistance are improved;
4. extrusion, drawability are improved, while sizing material is difficult autovulcanization;
5. bin stability is enhanced;
4) present invention substitutes existing powder metallurgy or SPCC punching press teeth by including modified rubber layer on metal ring framework Circle, reduces own wt, and then reduces finished weight, and reduction vehicle deadweight reduces oil consumption, saves the energy.
Brief description of the drawings
Fig. 1 is high durable magnetic coil structures schematic diagram.
Wherein:1. metal ring framework;2. it is modified rubber layer;3. assemble internal diameter.
Embodiment
In order that product technology means produced by the invention and reached purpose are easy to understand with effect, with reference to figure 1 is specifically illustrating, and this patent is expanded on further.
As shown in Figure 1:
A kind of high durable magnetic circle, the magnetic circle includes modification rubber layer 2 and quoit bone containing Ferrite Material Frame 1, the modification rubber layer 2 containing Ferrite Material is by being wrapped on metal ring framework 1 after high temperature vulcanized, and described contains The modification rubber layer 2 of Ferrite Material can continue transmitting perpendicular to rubber layer N/S extremely alternate signals after activating.
The modification rubber layer containing Ferrite Material includes the raw material of following percentage by weight:
6% PVC/NBR rubber-plastics materials,
86% ferromagnetic oxide powder,
5% pvc material,
1.5% dispersant,
0.8% age resistor,
0.4% accelerator,
0.3% vulcanizing agent;
The preparation technology of the modification rubber layer containing Ferrite Material is as follows:
1) treated ferromagnetic oxide powder, pvc material and PVC/NBR rubber-plastics materials, are added to banbury together It is interior;
2) start banbury banburying 4-5 minutes, add dispersant, age resistor and vulcanizing agent;
3) continue to start banbury banburying, banbury displays temperature is checked, when temperature to be shown reaches 95-100 degrees Celsius Stop banburying, take out semi-finished product and radiating of making thinner;
4) semi-finished product are taken out and are divided into several pieces, on a mill it is thin it is logical after add the accelerator of respective component, turn over Uniform aftershaping slice is refined, now temperature is no more than 90 degrees Celsius.
The metal ring framework 1 is class T-shape metal ring framework, and the vertical portion of the class T-shape metal ring framework is Assemble internal diameter 3.
The modification rubber layer 2 containing Ferrite Material is wrapped on metal ring framework 1 in a ring.
PVC/NBR=30/70 in the PVC/NBR rubber-plastics materials.
The pvc material has high weatherability.

Claims (1)

1. a kind of high durable magnetic circle, the magnetic circle includes modification rubber layer and metal ring framework containing Ferrite Material, The modification rubber layer containing Ferrite Material is by being wrapped on metal ring framework after high temperature vulcanized, and described contains ferrite Transmitting can be continued after the modification rubber layer activation of material perpendicular to rubber layer N/S extremely alternate signals, it is characterised in that:
The modification rubber layer containing Ferrite Material includes the raw material of following percentage by weight:
5-8% PVC/NBR rubber-plastics materials,
82-90% ferromagnetic oxide powder,
3-6% pvc materials,
1-2% dispersant,
0.5-1% age resistor,
0.2-0.5% accelerator,
0.2-0.5% vulcanizing agents;
The preparation technology of the modification rubber layer containing Ferrite Material is as follows:
1), treated ferromagnetic oxide powder, pvc material and PVC/NBR rubber-plastics materials are added in banbury together;
2) start banbury banburying 4-5 minutes, add dispersant, age resistor and vulcanizing agent;
3) continue to start banbury banburying, check banbury displays temperature, temperature to be shown stops when reaching 95-100 degrees Celsius Banburying, takes out semi-finished product and radiating of making thinner;
4) semi-finished product are taken out and are divided into several pieces, on a mill it is thin it is logical after add the accelerator of respective component, turn refining Even aftershaping slice, now temperature is no more than 90 degrees Celsius;
The metal ring framework is class T-shape metal ring framework, and the vertical portion of the class T-shape metal ring framework is in assembling Footpath;The modification rubber layer containing Ferrite Material is wrapped on metal ring framework in a ring;In the PVC/NBR rubber-plastics materials PVC/NBR=30/70;The pvc material has high weatherability.
CN201510227799.2A 2015-05-06 2015-05-06 A kind of high durable magnetic circle Active CN104844963B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510227799.2A CN104844963B (en) 2015-05-06 2015-05-06 A kind of high durable magnetic circle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510227799.2A CN104844963B (en) 2015-05-06 2015-05-06 A kind of high durable magnetic circle

Publications (2)

Publication Number Publication Date
CN104844963A CN104844963A (en) 2015-08-19
CN104844963B true CN104844963B (en) 2017-11-07

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001041162A1 (en) * 1999-11-30 2001-06-07 Uchiyama Manufacturing Corp. Magnetic rubber composition for encoder
CN102136332B (en) * 2010-12-13 2013-05-08 北矿磁材科技股份有限公司 Permanent magnet ferrite material for injection molding and manufacture method thereof
CN102875854B (en) * 2012-09-20 2014-05-07 吴江市天源塑胶有限公司 High-intensity magnetic rubber
CN204228180U (en) * 2014-11-27 2015-03-25 杭州沃冠汽车零部件有限公司 A kind of Novel framework magnetic circle

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Denomination of invention: A high weather resistant magnetic ring

Effective date of registration: 20210913

Granted publication date: 20171107

Pledgee: Zhejiang Xiaoshan Rural Commercial Bank Co.,Ltd. Development Zone sub branch

Pledgor: HANGZHOU WOGUAN AUTO PARTS Co.,Ltd.

Registration number: Y2021330001537