CN104841393A - Adsorption filtering agent capable of efficiently adsorbing hydrogen sulfide and preparation method thereof - Google Patents
Adsorption filtering agent capable of efficiently adsorbing hydrogen sulfide and preparation method thereof Download PDFInfo
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- CN104841393A CN104841393A CN201510190044.XA CN201510190044A CN104841393A CN 104841393 A CN104841393 A CN 104841393A CN 201510190044 A CN201510190044 A CN 201510190044A CN 104841393 A CN104841393 A CN 104841393A
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Abstract
The invention discloses an adsorption filtering agent capable of efficiently adsorbing hydrogen sulfide. The invention is characterized in that the adsorption filtering agent is prepared from the following raw materials, by weight, 15-25 parts of brucite, 50-60 parts of wheat straw, 20-30 parts of ox bone, 3.8-6.2 parts of nanometer titanium dioxide, 0.5-0.8 part of cetyl trimethyl ammonium bromide, 1-3 parts of urea, 5-8 parts of steel fiber, 6-10 parts of a vinyl acetate-acrylic emulsion, 0.2-0.4 part of potassium polyacrylate, 0.9-1.1 parts of guar gum and a proper amount of water. According to the invention, wheat straw and ox bone are used as raw materials, and brucite and the like are used in cooperation. Through a physical and chemical modification method, nanometer titanium dioxide is loaded on the surface of the adsorption filtering agent so as to decompose organic pollutants into carbon dioxide and oxygen and prolong service life of the adsorption filtering agent. The prepared adsorption filtering agent has advantages of rough and hard surface, large specific surface area, high porosity, good adsorption filtering performance and low cost. By spraying the adsorption filtering agent onto a filter material, hydrogen sulfide gas can be adsorbed efficiently and flue gas can be purified.
Description
Technical field
The present invention relates to absorption filter agent field of material technology, be specifically related to a kind of can the absorption filter agent and preparation method thereof of efficient adsorption hydrogen sulfide.
Background technology
Along with the fast development of process of industrialization, air quality problems is increasingly serious, especially the healthy of people in nationwide haze serious threat in recent years, the side effect brought thus is also day by day serious, wherein arch-criminal is exactly the flue dust of the discharge such as kiln head and tail, furnace of calcium carbide, ferro-alloy furnace of the industries such as domestic building materials, chemical industry, metallurgy, and cleaner the most frequently used is at present exactly sack cleaner.Sack cleaner is a kind of dry type dust filtration device, after filtrate uses a period of time, due to effects such as sieving, collision, delay, diffusion, electrostatic, one deck dust has been gathered on filter bag surface, this layer of dust is called bonding layer, and in motion process after this, bonding layer has become the main filtration layer of filtrate, rely on the effect of bonding layer, the filtrate that mesh is larger also can obtain higher filter efficiency.But the utilization of bonding layer is abundant not in real-world operation process, cause that dust removing effects is low, the consequences such as erosion corrosion situation is serious after filtrate Long-Time Service, the absorption filter agent being badly in need of a kind of efficient function diversification is sprayed on filter material surface and is used as bonding layer use before deduster is started working, both can improve the dust removing effects of deduster, the harmful exhaust that absorption is fallen to discharge can also have been filtered.
Summary of the invention
Object of the present invention be just to provide a kind of can the absorption filter agent and preparation method thereof of efficient adsorption hydrogen sulfide, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of can the absorption filter agent of efficient adsorption hydrogen sulfide, it is characterized in that, be made up of the raw material of following weight portion: shepardite 15-25, wheat stalk 50-60, ox bone 20-30, nano titanium oxide 3.8-6.2, softex kw 0.5-0.8, urea 1-3, steel fibre 5-8, acrylate and vinyl acetate emulsion 6-10, polyacrylic acid potassium 0.2-0.4, guar gum 0.9-1.1, suitable quantity of water.
Described a kind of can the preparation method of absorption filter agent of efficient adsorption hydrogen sulfide, it is characterized in that comprising the following steps:
(1) steel fibre is pulverized 120-180 mesh sieve and added nano titanium oxide, acrylate and vinyl acetate emulsion, guar gum agitation grinding 1-2 hour, at 150-180 DEG C, dry obtained modified nano-titanium dioxide;
(2) wheat stalk, ox bone are dried pulverizing and stirred and evenly mixed in 420-560 DEG C of high-temperature calcination process 2-4 hour, cooling is pulverized to drop in high mixer and is added modified nano-titanium dioxide in 180-210 DEG C of mix and blend 30-50 minute;
(3) added water to be stirred to by urea and dissolve completely, add step (2) material stirring 10-20 minute, be warming up to 80-120 DEG C and continue to stir 30-40 minute, then add shepardite and other residual components dispersion grinding 2-3 hour, granulation is dried, discharging.
The present invention has following beneficial effect: the present invention adopts wheat stalk, ox bone are raw material and are equipped with shepardite etc., by physical and chemical modified method, nano titanium oxide is carried on absorption filter agent surface, organic pollution can be decomposed into carbon dioxide and oxygen, extend absorption filter agent service life, obtained absorption filter agent rough surface is hard, specific area is large, porosity is high, Adsorption Filtration Properties is good, cost is low, be sprayed on all right efficient adsorption hydrogen sulfide gas on filtrate, purifying smoke.
Detailed description of the invention
Described a kind of can the absorption filter agent of efficient adsorption hydrogen sulfide, it is characterized in that, be made up of the raw material of following weight portion: shepardite 22, wheat stalk 57, ox bone 26, nano titanium oxide 4.8, softex kw 0.7, urea 1, steel fibre 6, acrylate and vinyl acetate emulsion 7, polyacrylic acid potassium 0.3, guar gum 1.1, suitable quantity of water.
Preparation method comprises the following steps:
(1) steel fibre is pulverized 120-180 mesh sieve and added nano titanium oxide, acrylate and vinyl acetate emulsion, guar gum agitation grinding 1-2 hour, at 150-180 DEG C, dry obtained modified nano-titanium dioxide;
(2) wheat stalk, ox bone are dried pulverizing and stirred and evenly mixed in 420-560 DEG C of high-temperature calcination process 2-4 hour, cooling is pulverized to drop in high mixer and is added modified nano-titanium dioxide in 180-210 DEG C of mix and blend 30-50 minute;
(3) added water to be stirred to by urea and dissolve completely, add step (2) material stirring 10-20 minute, be warming up to 80-120 DEG C and continue to stir 30-40 minute, then add shepardite and other residual components dispersion grinding 2-3 hour, granulation is dried, discharging.
The specific area of the absorption filter agent using the present invention to produce is 388 ㎡/g, is 97.3% to the filter of hydrogen sulfide.
Claims (2)
1. one kind can the absorption filter agent of efficient adsorption hydrogen sulfide, it is characterized in that, be made up of the raw material of following weight portion: shepardite 15-25, wheat stalk 50-60, ox bone 20-30, nano titanium oxide 3.8-6.2, softex kw 0.5-0.8, urea 1-3, steel fibre 5-8, acrylate and vinyl acetate emulsion 6-10, polyacrylic acid potassium 0.2-0.4, guar gum 0.9-1.1, suitable quantity of water.
2. according to claim 1 a kind of can the preparation method of absorption filter agent of efficient adsorption hydrogen sulfide, it is characterized in that comprising the following steps:
(1) steel fibre is pulverized 120-180 mesh sieve and added nano titanium oxide, acrylate and vinyl acetate emulsion, guar gum agitation grinding 1-2 hour, at 150-180 DEG C, dry obtained modified nano-titanium dioxide;
(2) wheat stalk, ox bone are dried pulverizing and stirred and evenly mixed in 420-560 DEG C of high-temperature calcination process 2-4 hour, cooling is pulverized to drop in high mixer and is added modified nano-titanium dioxide in 180-210 DEG C of mix and blend 30-50 minute;
(3) added water to be stirred to by urea and dissolve completely, add step (2) material stirring 10-20 minute, be warming up to 80-120 DEG C and continue to stir 30-40 minute, then add shepardite and other residual components dispersion grinding 2-3 hour, granulation is dried, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510190044.XA CN104841393A (en) | 2015-04-21 | 2015-04-21 | Adsorption filtering agent capable of efficiently adsorbing hydrogen sulfide and preparation method thereof |
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| CN201510190044.XA CN104841393A (en) | 2015-04-21 | 2015-04-21 | Adsorption filtering agent capable of efficiently adsorbing hydrogen sulfide and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105920941A (en) * | 2016-06-19 | 2016-09-07 | 山东玉皇粮油食品有限公司 | Novel environment-friendly dust collector |
| CN105944452A (en) * | 2016-06-20 | 2016-09-21 | 杭州富阳飞博科技有限公司 | Modified glass fiber dust-removing material |
| CN105964058A (en) * | 2016-06-28 | 2016-09-28 | 安徽国能亿盛环保科技有限公司 | Filter material for treating industrial waste water and preparation method of filter material |
| CN106166436A (en) * | 2016-08-17 | 2016-11-30 | 保护伞环保科技成都有限公司 | A kind of composite air purifying agent |
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| CN102114405A (en) * | 2009-12-30 | 2011-07-06 | 中国石油化工股份有限公司 | Desulfurizing and adsorption agent containing titanium, preparation method and application thereof |
| CN103736389A (en) * | 2013-12-12 | 2014-04-23 | 芜湖中路实业有限责任公司 | Flue gas denitration desulfurizer and preparation method thereof |
| CN103736451A (en) * | 2013-12-12 | 2014-04-23 | 芜湖中路实业有限责任公司 | Nanometer titanium dioxide desulfurizer and preparation method thereof |
| CN104475051A (en) * | 2014-11-13 | 2015-04-01 | 安徽凤凰滤清器股份有限公司 | Mixed desulfurization dedusting particles having bactericidal effect and preparation method thereof |
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2015
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102114405A (en) * | 2009-12-30 | 2011-07-06 | 中国石油化工股份有限公司 | Desulfurizing and adsorption agent containing titanium, preparation method and application thereof |
| CN103736389A (en) * | 2013-12-12 | 2014-04-23 | 芜湖中路实业有限责任公司 | Flue gas denitration desulfurizer and preparation method thereof |
| CN103736451A (en) * | 2013-12-12 | 2014-04-23 | 芜湖中路实业有限责任公司 | Nanometer titanium dioxide desulfurizer and preparation method thereof |
| CN104475051A (en) * | 2014-11-13 | 2015-04-01 | 安徽凤凰滤清器股份有限公司 | Mixed desulfurization dedusting particles having bactericidal effect and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105920941A (en) * | 2016-06-19 | 2016-09-07 | 山东玉皇粮油食品有限公司 | Novel environment-friendly dust collector |
| CN105920941B (en) * | 2016-06-19 | 2017-12-29 | 山东玉皇粮油食品有限公司 | A kind of Environmental-protecting dust-removing device |
| CN105944452A (en) * | 2016-06-20 | 2016-09-21 | 杭州富阳飞博科技有限公司 | Modified glass fiber dust-removing material |
| CN105944452B (en) * | 2016-06-20 | 2018-01-23 | 中山市锐星新材料科技有限公司 | A kind of modified glass-fiber dedusting material |
| CN105964058A (en) * | 2016-06-28 | 2016-09-28 | 安徽国能亿盛环保科技有限公司 | Filter material for treating industrial waste water and preparation method of filter material |
| CN106166436A (en) * | 2016-08-17 | 2016-11-30 | 保护伞环保科技成都有限公司 | A kind of composite air purifying agent |
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Application publication date: 20150819 |
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