CN104832230B - A kind of liquid organic-fuel Multi-purpose energy-saving combustion system and method - Google Patents

A kind of liquid organic-fuel Multi-purpose energy-saving combustion system and method Download PDF

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CN104832230B
CN104832230B CN201510225519.4A CN201510225519A CN104832230B CN 104832230 B CN104832230 B CN 104832230B CN 201510225519 A CN201510225519 A CN 201510225519A CN 104832230 B CN104832230 B CN 104832230B
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flue gas
fuel
organic
liquid organic
vaporising device
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CN104832230A (en
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张华�
巨永林
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Shanghai Jiaotong University
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Shanghai Jiaotong University
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Abstract

The present invention relates to a kind of liquid organic-fuel Multi-purpose energy-saving combustion system and method, this system includes combustion apparatus, vaporising device and flue gas condenser, organic-fuel after vaporization is burnt by combustion apparatus, and the flue gas making organic-fuel burning produce returns vaporising device and carries out waste heat recovery;Vaporising device accepts the flue gas that organic-fuel burning produces, and makes liquid organic-fuel vaporize, and the flue gas after heat exchange enters flue gas condenser and carries out the degree of depth recovery of fume afterheat;Flue gas condenser utilizes the waste heat of the flue gas that vaporising device flows out to heat relevant working medium, reduces flue-gas temperature further, it is achieved the cascade utilization of fume afterheat, and the relevant working medium after heating enters combustion apparatus simultaneously, improves efficiency of combustion.Compared with prior art, the present invention has carried out cascade utilization to fume afterheat, and the thermal efficiency of combustion apparatus is greatly improved, and while flue gas waste heat recovery, also eliminates part harmful substance contained in flue gas, reduces the discharge capacity of harmful substance.

Description

A kind of liquid organic-fuel Multi-purpose energy-saving combustion system and method
Technical field
The present invention relates to a kind of organic-fuel combustion system, especially relate to a kind of liquid organic-fuel multipurpose joint Energy combustion system and method, belong to energy field of combustion technology.
Background technology
At present, natural gas is widely used in every field as clear energy sources.Use natural gas as the energy, The consumption of coal and oil can be reduced, thus be substantially improved problem of environmental pollution;Natural gas as a kind of clean energy resource, Sulfur dioxide and dust discharge amount nearly 100% can be reduced, reduce CO2 emissions 60% and oxynitride row High-volume 50%, and contribute to reducing acid rain and formed, global greenhouse effect of releiving, fundamentally improves environmental quality. But along with the rise of Gas Prices, use natural gas the most constantly to raise as the operating cost of the equipment of fuel;By In China's natural gas reserves and product quantitative limitation, the natural gas external dependence degree of current China has reached 30%, it is contemplated that To the year two thousand twenty, the natural gas external dependence degree of China will reach 50%;And along with various places coal changes the popularization of gas project, The consumption of natural gas will be greatly increased.Country has started to that various places gas consumption has carried out planning and limits, and starts to open Dynamic natural gas peak-shaving project.
China's methanol etc. can be far below production capacity, and dropping along with coal price as the Organic substance yield of organic-fuel, Its production cost also continuous decrease;And along with the improvement of technology, oven gas produces the price of Related product the most therewith Reduce.Therefore methanol etc. is used the most day by day can to raise as the cry of the Organic substance of the organic-fuel energy as an alternative. Use at present the automobile of methanol gasoline and used methanol to carry out the burner being atomized, but due to its latent heat of vaporization relatively , therefore easily there is low warm spot when burning, thus causes ignition temperature not high enough (1100 DEG C) in height, and burning Unstable (flame-out phenomenon easily occurs), the most still cannot be carried out large-scale promotion.
Chinese patent CN 103196139A discloses a kind of smoke backflow vaporization alcohol-based fuel burner, including outside Shell, the top of shell arranges fuel channel, arranges catalytic reaction body in the enclosure, is vertically arranged flue gas and returns in shell Circulation road, smoke backflow passage passes catalytic reaction body, is provided above top cover, and bottom arranges bottom;Fuel exports The outlet section of pipe is extending upwardly to the throat of shell by the lower vertical of shell, and the inwall of shell is provided with lighter.In combustion Before material atomization, utilize the heat alcohol-based fuel that burner self produces so that the tension force of alcohol-based fuel reduces, Atomizing effect is more preferably;Smoke backflow, to gas atomization Mixed Zone, is possible not only to preheated air, improves burner and combines Close efficiency of utilization, and owing to the backflow of flue gas makes flame combustion district heat move to blending space so that fire Flame combustion zone temperature reduces, and the temperature of whole burner more tends to uniform, reduces liquid fuel due to too high fire Carbon distribution produced by flame temperature.In this patent, the waste heat for flue gas the most well processes, and causes more than flue gas The waste of heat.
Summary of the invention
Defect that the purpose of the present invention is contemplated to overcome above-mentioned prior art to exist and a kind of organic combustion of liquid is provided Material Multi-purpose energy-saving combustion system and method.The system and method for the present invention can improve organic-fuel ignition temperature, And stablizing of burning can be realized, simultaneously by the waste heat recovery to flue gas, improve the thermal efficiency of equipment, it is achieved system Energy-saving and emission-reduction.Overcome ignition temperature existing during the organic-fuels such as current methanol use not high enough (1100 DEG C), and combustion instability (flame-out phenomenon easily occurs).Thus realize using organic-fuel to substitute natural gas The purpose of the energy.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system, including:
Combustion apparatus: the organic-fuel after vaporization is burnt, and make the flue gas of organic-fuel burning generation return Vaporising device carries out waste heat recovery;
Vaporising device: accept the flue gas that organic-fuel burning produces, flue gas and liquid organic-fuel carry out heat exchange, make Liquid organic-fuel vaporizes, and the flue gas after heat exchange enters flue gas condenser and carries out the degree of depth recovery of fume afterheat;
Flue gas condenser: utilize the waste heat of the flue gas that vaporising device flows out that relevant working medium is heated, drop further Low flue-gas temperature, it is achieved the cascade utilization of fume afterheat, the relevant working medium after heating enters combustion apparatus simultaneously, carries High burning efficiency.
Described combustion apparatus includes boiler, air compressor machine or electromotor burner.
Described combustion apparatus i.e. can use organic-fuel gas as fuel, it is possible to use the fuel gas such as natural gas As fuel.When native system is as the burning of the associated fuel gas such as natural gas, vaporising device can be set as burning Standby economizer uses, thus realizes the multipurpose of system.
Described vaporising device is gas liquid exchanger.
In addition to carrying out heat exchange by flue gas and liquid organic based fuels, described vaporising device is self by hot water, steam Or electrical heating carries out heat exchange to liquid organic based fuels so that it is vaporization.This system in start-up course owing to there is no flue gas, Therefore can enter with liquid organic based fuels using the associated fuel gas such as natural gas first to carry out burning generation flue gas in advance Row heat exchange so that it is gasify or by associated heat systems such as hot water, steam or electrical heating, liquid organic based fuels carried out Heat exchange so that it is gasification, and combustion, after generating flue gas, then switches over it, thus realizes the startup of system.
Described flue gas condenser includes economizer or air preheater.
After described flue gas condenser is to flue gas heat exchange, flue-gas temperature is made to be less than its dew point temperature, water in recovered flue gas The latent heat of steam, simultaneously during flue gas condensing generates condensed water, removes and includes carbide, nitride and sulfur Compound is at interior harmful substance.
Described relevant working medium is the standby combustion air of the combustion heat or water.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion method, comprises the following steps:
Combustion step: burn the organic-fuel after vaporization, produces required energy, and organic-fuel burning produces Flue gas return vaporising device carry out flue gas waste heat recovery;
Pervaporation step: liquid organic-fuel is vaporized process by vaporising device, the organic-fuel after vaporization supplies Should give combustion apparatus, the flue gas that on the one hand vaporization institute calorific requirement produces for organic-fuel burning after vaporization, on the other hand For hot water, steam or electrical heating that vaporising device is external, owing to flue gas is after vaporising device, temperature has necessarily Decline, but still far above ambient temperature, accordingly, it would be desirable to the degree of depth that flue gas carries out waste heat reclaims.
The degree of depth of fume afterheat reclaims: flue gas condenser utilizes the waste heat of flue gas after vaporizing heat exchange to carry out relevant working medium Heating, reduces flue-gas temperature, it is achieved the cascade utilization of fume afterheat further, and the degree of depth at fume afterheat reclaims step In Zhou, after described flue gas condenser is to flue gas heat exchange, flue-gas temperature is made to be less than its dew point temperature, in recovered flue gas The latent heat of water vapour, thus the heat of recovery is greatly improved;Relevant working medium after heating enters combustion apparatus simultaneously, Owing to working medium is heated, temperature raises, thus improves the thermal efficiency of combustion apparatus, it is achieved energy-conservation purpose;With Time generate during condensed water at flue gas condensing, remove including carbide, nitride and sulfide is harmful Material, it is achieved thereby that the purpose reduced discharging.
Compared with prior art, the present invention has the following advantages and beneficial effect:
1, the multipurpose of system: the present invention is not only applicable to organic-fuel, is simultaneously applicable to the combustions such as natural gas Material gas;
2, it is used for burning after being gasified by liquid organic based fuels, ignition temperature and combustion stability can be improved;
3, fume afterheat has been carried out cascade utilization, the thermal efficiency of combustion apparatus has been greatly improved, thus realizes Energy-conservation purpose;
4, while to flue gas waste heat recovery, also eliminate part harmful substance contained in flue gas, reduced The discharge capacity of pest matter, it is achieved thereby that the purpose reduced discharging.
Accompanying drawing explanation
Fig. 1 is the liquid organic-fuel Multi-purpose energy-saving combustion system structural representation of the present invention.
Detailed description of the invention
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
Embodiment
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system, including combustion apparatus 1, vaporising device 2, flue gas Condenser 3 and include the associated pipe of flue gas pipeline, air pipe line and supply channel etc..
Organic-fuel after vaporization is burnt by combustion apparatus 1, and the flue gas making organic-fuel burning produce returns Vaporising device carries out waste heat recovery, and combustion apparatus includes boiler, air compressor machine or electromotor burner.Combustion apparatus is i.e. Organic-fuel gas can be used as fuel, it is possible to use the fuel gas such as natural gas are as fuel.Make at native system During for the burning of the associated fuel gas such as natural gas, vaporising device can be used as the economizer of combustion apparatus, thus Realize the multipurpose of system.
Vaporising device 2 is gas liquid exchanger.The flue gas 6 that vaporising device is produced by organic fuel combustion, flue gas with Liquid organic-fuel 4 carries out heat exchange, makes liquid organic-fuel 4 vaporize, and the flue gas 6 after heat exchange enters flue gas condensing Device 3 carries out the degree of depth of fume afterheat and reclaims;In addition to carrying out heat exchange by flue gas and liquid organic based fuels, vaporising device Self by hot water, steam or electrical heating, liquid organic based fuels is carried out heat exchange so that it is vaporization.
Flue gas condenser 3 includes economizer or air preheater.Flue gas condenser 3 utilizes vaporising device 2 to flow out Relevant working medium 5 is heated by the waste heat of flue gas 6, reduces flue-gas temperature further, makes flue-gas temperature be less than its dew Point temperature, the latent heat of water vapour in recovered flue gas, it is achieved the cascade utilization of fume afterheat, simultaneously being correlated with after heating Working medium enters combustion apparatus 1, improves efficiency of combustion, simultaneously during flue gas condensing generates condensed water, removes Harmful substance including carbide, nitride and sulfide.Relevant working medium be the standby combustion air of the combustion heat or Water.
This system owing to not having flue gas, therefore can use the associated fuel gas such as natural gas in start-up course in advance First carry out burning generation flue gas and carry out heat exchange with liquid organic based fuels so that it is gasify or added by hot water, steam or electricity The associated heat systems such as heat carry out heat exchange to liquid organic based fuels so that it is gasification, and combustion, after generating flue gas more right It switches over, thus realizes the startup of system.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion method, comprises the following steps:
Combustion step: burn the organic-fuel after vaporization, produces required energy, and organic-fuel burning produces Flue gas return vaporising device carry out flue gas waste heat recovery;
Pervaporation step: liquid organic-fuel is vaporized process by vaporising device, the organic-fuel after vaporization supplies Should give combustion apparatus, the flue gas that on the one hand vaporization institute calorific requirement produces for organic-fuel burning after vaporization, on the other hand For hot water, steam or electrical heating that vaporising device is external, owing to flue gas is after vaporising device, temperature has necessarily Decline, but still far above ambient temperature, accordingly, it would be desirable to the degree of depth that flue gas carries out waste heat reclaims.
The degree of depth of fume afterheat reclaims: flue gas condenser utilizes the waste heat of flue gas after vaporizing heat exchange to carry out relevant working medium Heating, reduces flue-gas temperature, it is achieved the cascade utilization of fume afterheat further, and the degree of depth at fume afterheat reclaims step In Zhou, after described flue gas condenser is to flue gas heat exchange, flue-gas temperature is made to be less than its dew point temperature, in recovered flue gas The latent heat of water vapour, thus the heat of recovery is greatly improved;Relevant working medium after heating enters combustion apparatus simultaneously, Owing to working medium is heated, temperature raises, thus improves the thermal efficiency of combustion apparatus, it is achieved energy-conservation purpose;With Time generate during condensed water at flue gas condensing, remove including carbide, nitride and sulfide is harmful Material, it is achieved thereby that the purpose reduced discharging.
The above-mentioned description to embodiment is to be understood that for ease of those skilled in the art and use to send out Bright.These embodiments obviously easily can be made various amendment by person skilled in the art, and at this The General Principle illustrated is applied in other embodiments without through performing creative labour.Therefore, the present invention does not limits In above-described embodiment, those skilled in the art are according to the announcement of the present invention, without departing from changing that scope is made Entering and revise all should be within protection scope of the present invention.

Claims (9)

1. a liquid organic-fuel Multi-purpose energy-saving combustion system, it is characterised in that including:
Combustion apparatus: the organic-fuel after vaporization is burnt, and make the flue gas of organic-fuel burning generation return Vaporising device carries out waste heat recovery;
Vaporising device: accept the flue gas that organic-fuel burning produces, flue gas and liquid organic-fuel carry out heat exchange, make Liquid organic-fuel vaporizes, and the flue gas after heat exchange enters flue gas condenser and carries out the degree of depth recovery of fume afterheat;
Flue gas condenser: utilize the waste heat of the flue gas that vaporising device flows out that relevant working medium is heated, drop further Low flue-gas temperature, it is achieved the cascade utilization of fume afterheat, the relevant working medium after heating enters combustion apparatus simultaneously, carries High burning efficiency.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system the most according to claim 1, its feature exists In, described combustion apparatus includes boiler, air compressor machine or electromotor burner.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system the most according to claim 1, its feature exists In, the fuel of described combustion apparatus includes organic-fuel or natural gas.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system the most according to claim 1, its feature exists In, described vaporising device is gas liquid exchanger.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system the most according to claim 1, its feature exists In, in addition to carrying out heat exchange by flue gas and liquid organic based fuels, described vaporising device is self by hot water, steam Or electrical heating carries out heat exchange to liquid organic based fuels so that it is vaporization.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system the most according to claim 1, its feature exists In, described flue gas condenser includes economizer or air preheater.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system the most according to claim 1, its feature exists In, after described flue gas condenser is to flue gas heat exchange, make flue-gas temperature be less than its dew point temperature, water in recovered flue gas The latent heat of steam, simultaneously during flue gas condensing generates condensed water, removes and includes carbide, nitride and sulfur Compound is at interior harmful substance.
A kind of liquid organic-fuel Multi-purpose energy-saving combustion system the most according to claim 1, its feature exists In, described relevant working medium is the standby combustion air of the combustion heat or water.
9. a liquid organic-fuel Multi-purpose energy-saving combustion method, it is characterised in that comprise the following steps:
Combustion step: burn the organic-fuel after vaporization, produces required energy, and organic-fuel burning produces Flue gas return vaporising device carry out flue gas waste heat recovery;
Pervaporation step: liquid organic-fuel is vaporized process by vaporising device, the organic-fuel after vaporization supplies Should give combustion apparatus, the flue gas that on the one hand vaporization institute calorific requirement produces for organic-fuel burning after vaporization, on the other hand For hot water, steam or electrical heating that vaporising device is external;
The degree of depth of fume afterheat reclaims: flue gas condenser utilizes the waste heat of flue gas after vaporizing heat exchange to carry out relevant working medium Heating, reduces flue-gas temperature, it is achieved the cascade utilization of fume afterheat further, and the relevant working medium after heating is entered simultaneously Enter combustion apparatus, improve efficiency of combustion, in the degree of depth recycling step of fume afterheat, described flue gas condenser pair After flue gas heat exchange, making flue-gas temperature be less than its dew point temperature, the latent heat of water vapour in recovered flue gas, simultaneously at flue gas During condensation generates condensed water, remove the harmful substance including carbide, nitride and sulfide.
CN201510225519.4A 2015-05-05 2015-05-05 A kind of liquid organic-fuel Multi-purpose energy-saving combustion system and method Active CN104832230B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06294306A (en) * 1993-04-08 1994-10-21 Mitsubishi Heavy Ind Ltd Methanol evaporating method for methanol gas burning turbine compound plant
CN2795467Y (en) * 2005-05-30 2006-07-12 闫中民 Alcohol burning device for gasoline engine
CN103485868A (en) * 2013-09-09 2014-01-01 华南理工大学 Auxiliary combustion device using tail gas waste heat to gasify alcohol

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06294306A (en) * 1993-04-08 1994-10-21 Mitsubishi Heavy Ind Ltd Methanol evaporating method for methanol gas burning turbine compound plant
CN2795467Y (en) * 2005-05-30 2006-07-12 闫中民 Alcohol burning device for gasoline engine
CN103485868A (en) * 2013-09-09 2014-01-01 华南理工大学 Auxiliary combustion device using tail gas waste heat to gasify alcohol

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