CN104831434B - Shear-type-drafting electrostatic-spinning micron-yarn direct-spinning device and method and use thereof - Google Patents

Shear-type-drafting electrostatic-spinning micron-yarn direct-spinning device and method and use thereof Download PDF

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CN104831434B
CN104831434B CN201510225483.XA CN201510225483A CN104831434B CN 104831434 B CN104831434 B CN 104831434B CN 201510225483 A CN201510225483 A CN 201510225483A CN 104831434 B CN104831434 B CN 104831434B
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cone cylinder
micron
yarn
spinning
shower nozzle
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CN104831434A (en
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于伟东
章丽娟
刘洪玲
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Donghua University
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/12Stretch-spinning methods

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)

Abstract

The invention provides a shear-type-drafting electrostatic-spinning micron-yarn direct-spinning device and a method and use thereof. The device consists of a horn-shaped jet, a shear-drafting conical tube, a bundling and winding mechanism, a liquid injection cavity, a negative high-voltage source and a driving mechanism. According to the micron-yarn direct-spinning method, a high-polymer solution, extruded from the liquid injection cavity, is of an umbrella shape at the edge of a horn under the action of a high electric field, jetted sub-micron filaments form nano filaments on the high-speed rotating conical tube under the action of shear-drafting, the nano filaments are solidified, then, are collected by a bundler and are twisted into micron yarn, and the micron yarn is wound so as to produce yarn capable of being woven directly or after being twisted and doubled. The device is simple, effective and reasonable in structure and can be used for realizing the nano and high-strength spinning and twisted collected yarn forming of monofilaments.

Description

Shearing drawing-off Static Spinning directly spins a micron yarn feeding device, method and purposes
Technical field
The present invention relates to electrostatic spinning, electrostatic spinning and nanofiber spinning mechanical field, more particularly to a kind of electrostatic The straight spinning technique for spinning micron yarn.
Background technology
Recently as the development of nanotechnology, electrostatic spinning technique obtains fast development.At present electrostatic spinning is obtained Nanofiber yardstick mostly at submicron-scale (100~1000nm), and the real nanofiber for being less than 100nm is less.Then It is the problem that needs scholar's research how the fiber of submicron thickness to be narrowed down to into nanoscale fiber.
Electrostatic spinning fiber has an application in fields such as environment, the energy, biomedicine, photoelectricity, but the electrostatic of research at present Spinning nano fibre mainly occurs in the form of film that fiber is directly piled up or felt, is the fiber assembly of two one-dimensional disorders, serious resistance The expansion application of this material is hindered.Generally yarn can be used for tatting, knitting or braiding, but direct is to cannot be used for staple in bulk Knitting, tatting and braiding, not to mention using nanometer staple in bulk body.The thickness of simultaneously current electrostatic spinning fiber is partially thick, strong Degree is low or very low, is almost difficult to meet the requirement of utility cloth, or even cannot directly weave into cloth.Therefore, by institute into nanometer Fibre bundle is directly spun into the yarn of micron, and then is applied to woven, knitting or braiding, prepares the fabric of various structures and shape, There is provided electrostatic spinning filament strength, refinement monofilament to nano-scale and even thickness, be in Static Spinning nanotechnology urgently The problem of solution, is also the basis of nanofiber application development.Meanwhile, also there is the report of the straight yarn of some electrostatic spinnings.
As Dalton [Dalton PD, Polymer, 2005,46,611-614] etc. is collected and shape using double roudnel devices Into the micron yarn of orientations, the method prepares yarn evenness and is orientated, but fiber only has electrostatic field drawing-off, and without any machine Tool drawing-off, therefore monofilament is in submicron-scale and low intensity, fiber yarn forming thick, intensity partially is also low.Li [Chinese patents ZL201110205027.0] a kind of method and apparatus of electro-spun nanofiber yarn is disclosed, it is right using funnel reception device The tangential evacuation of tube bundle of funnel rear end, forming air-flow carries out device, but below not only without drawing-off but also without twisting winding dress Putting cannot realize continuous resultant yarn.Li [Li N, Materials Letters, 2012:245-247] etc. self-control it is a kind of equipped with a high speed The funnel type collection device of air-flow, air-flow can form multiple fiber aggregation and continuous yarn, collection funnel as power carrier Device is divided into two parts of funnel and cylinder, but high velocity air can only realize that twisting is acted on to nanofiber, continuously collect without yarn Device and final fibre bundle are without the twist.
Qin little Hong, Wu Shaohua [Chinese patent ZL201310058070.8] disclose a kind of orientation Static Spinning continuous yarn system Standby device and method, it realizes what nanofiber spinned using the rotation for being oppositely disposed and connecing both positive and negative polarity shower nozzle and metal circular target Continuous production, though the degree of orientation and yield are high, is not also present to tow drawing-off, and monofilament is partially thick, and intensity cannot improve, resultant yarn fineness Attenuating is restricted, and intensity is poor.Usman Ali [Usman Ali, The Textile Institute, 2012 (1):80-88]; He [He J, Journal of Applied Polymer Science, 2014,131 (8)];He [He J, Polymer International, 2014,63 (7):1288-1294] etc. also have correlational study, be not directed to shear drawing-off, and horn mouth is only Collect outer side spray and spin the mechanism that the sub-micron fibers rotation twisting for obtaining directly returns winding resultant yarn.Principle is with the present invention completely not Together.Qin little Hong, Wu Shaohua [Chinese patent ZL201320083418.4] disclose a kind of vortex spun yarn device, using tubaeform Conveyance conduit is connected just to spinning head and with vortex tube sprocket hole, and using eddy current effect resultant yarn is twisted, though continuously preparing nano can be connected Yarns line production efficiency is higher, but still without shearing drawing-off, then fibre orientation and intensity are not enough.
Li [Li Jie, Polymer Engineering&Science, 2013,54,1618-1624] discloses a kind of poly- Amide 6,66 copolymer filament yarn continuously static spinning methods.Fibre bundle is combined in surfactant body lotion, the fiber Jing of boundling It is wound into and just spins, then filament yarn is obtained through heating and secondary drawing-off, easy fracture need to control liquid collection for drawing-off winding Device body lotion, the scope of application has been limited.Eugene Smit [Eugene Smit, Polymer, 2005 (46):2419- 2423], Yu Hao [Chinese patent ZL201908162] also has similar research work.Its in Static Spinning process without drafting system, Both non-straight spun yarn, and fibre fineness is thick in spun yarn, low intensity and damage that big, operation is more, energy consumption is big, is undisputable fact.
To sum up, the straight spun yarn of existing Static Spinning does not produce shearing drafting method to realize the drawing-off change to electrostatic spinning Direct resultant yarn (straight to spin) technology thin and that real nano-scale and filament strength lifting can be reached.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of submicron ejected to loudspeaker shower nozzle using rotation cone cylinder Electrostatic silk realizes the straight frame structure of electrostatic and direct resultant yarn method of shearing drawing-off, fineness thinner, intensity is obtained with this higher Nano wire and the micron yarn of shaping.
In order to solve above-mentioned technical problem, the technical scheme is that a kind of shearing drawing-off Static Spinning of offer directly spins micro- Rice yarn feeding device, it is characterised in that:Including
For high polymeric solution to be carried out into the flaring shower nozzle that umbrella sprays the liquid filaments to form submicron thickness;
Drawing-off is sheared for receiving liquid filaments and it being implemented, makes liquid filaments further be refined into the cone cylinder of nano wire;
Converge and boundling twists into the collection of micron yarn for the cured nano wire for being distributed in cone cylinder and rotating to be peeled off Beam device;
For providing the fluid injection chamber of high polymeric solution to shower nozzle;
For forming negative high voltage electric field between shower nozzle and cone cylinder, so that the injection stream drawing-off sprayed from shower nozzle attenuates On the inside of the front port of cone cylinder, the negative high voltage source of the liquid filaments of umbrella distribution is formed;
For the micron yarn reel for collecting beam shaping to be taken the winding mechanism of shaping;
For driving cone cylinder to rotate at a high speed so as to shear the drive mechanism of drawing-off liquid filaments.
Preferably, the shower nozzle by the loudspeaker shower nozzle being connected with the negative high voltage source, for the ring set closing and shield and The ascending pipe being connected with the fluid injection chamber is sequentially connected composition.
Preferably, the cone cylinder is on the inside of Rotary-table or horn body, cone cylinder front port and the company at the loudspeaker shower nozzle edge Slope of the slope of line more than cone cylinder;Distance of the cone cylinder rear port away from cone cylinder front port must can guarantee that the solidification of nano wire is completed, And cone cylinder rear port fillet.
Preferably, the endoporus of the buncher is horn mouth, and buncher is engaged with the cone cylinder for rotating and completes to nano wire Twisting and boundling into micron yarn.
Preferably, the negative high voltage source is the generator of the negative high voltage that can provide 6~30kv.
Preferably, the winding mechanism include takers-in, groove drum and tube, takers-in rotate by the nano wire after solidification from Cone cylinder is stripped down, and is drawn to up to buncher by cone cylinder rear port, during rotated using cone cylinder and add nano wire boundling to be twisted For micron yarn, Jing groove drums winding and tube collection, the cheese of stable micron yarn is formed.
Preferably, the drive mechanism by contact with the cone cylinder actuating cylinder, drive actuating cylinder rotate rotary shaft, The cone cylinder smooth rotation is made in couples with actuating cylinder and central shaft connects with the loudspeaker shower nozzle central point and buncher center The coaxial support cylinder of line, the high-speed electric expreess locomotive for driving rotary shaft to rotate simultaneously adjustable speed are constituted.
Another technical scheme of the present invention there is provided above-mentioned shearing drawing-off Static Spinning and directly spin the straight of micron yarn feeding device Spinning method, it is characterised in that step is:
The first step, electrostatic spray webbing:High polymeric solution reaches loudspeaker shower nozzle and forms uniform films by fluid injection chamber Jing ascending pipe, and The edge of loudspeaker shower nozzle falls within the inner side of cone cylinder front port because of the effect division of negative high voltage electric field and drafted attenuating, and forms umbrella The liquid filaments of shape distribution;
Second step, shearing drawing-off:The liquid filaments of umbrella distribution are gripped because of the inwall by loudspeaker shower nozzle and cone cylinder, and cone cylinder is again The shearing drawing-off to liquid filaments is formed in high-speed rotation, makes liquid filaments further be refined into nano wire, and solidified in cone cylinder;
3rd step, boundling twisting:Cured nano wire is drawn from cone cylinder to peel off and is converged into buncher by takers-in Horn mouth, and twisting forms micron yarn under the rotation of cone cylinder, and Jing groove drums are wound on tube, form the micron of form stable The cheese of yarn.
Another technical scheme of the present invention there is provided above-mentioned shearing drawing-off Static Spinning and directly spin answering for micron yarn feeding device With, it is characterised in that above-mentioned shearing drawing-off Static Spinning is directly spun into micron yarn feeding device is used for the monofilament thickness of Static Spinning in nanometer Yardstick direct resultant yarn processing, or for resultant yarn thickness micro-meter scale direct resultant yarn process, or for the twist it is adjustable, The direct resultant yarn processing thinner than micro-meter scale of resultant yarn thickness.
The principle of the present invention is that the stretching of negative high voltage electric field action not merely with conventional fluidic attenuates effect, also using loudspeaker The mode that shape edge is combined with electric field forms the division filamentation of liquid film, to form the liquid filaments of submicron-scale, and here During introduce rotational shear effect and make the tow not solidified completely become thinner, higher, evenly, and while to be sheared Twisting resultant yarn is implemented in the rotation of effect to nanometer tow, and realizes to fiber nanorize in the straight spun yarn of existing Static Spinning, high-strength The solution of the difficult problem such as change and straight spun yarn.
The present invention has the advantages that:1. compared with prior art, principle innovation, not only relies on electrostatic field, And wisdom ground introduces nanorize, high strengthening and the homogenization that rotation drawing-off effect reaches electrostatic spinning;2. loudspeaker shower nozzle is adopted Combined with electrostatic field, realize film split, sub-wire;3. the rotational shear of cone cylinder, not only introduces topmost shearing drawing-off, and has Twisting effect, to achieve many things at one stroke, practical spinning mechanism simple for structure.
Description of the drawings
Fig. 1 directly spins a micron yarn feeding device structural representation for the shearing drawing-off Static Spinning that the present invention is provided;
In figure:1- shower nozzles:11- loudspeaker shower nozzles, 12- ring sets, 13- ascending pipes;2- cone cylinders:21- cone cylinder front ports, 22- cones Tube rear end mouth;3- bunchers;4- fluid injections chamber;5- negative high voltages source;6- winding mechanisms:61- takers-ins, 62- groove drums, 63- tubes;7- Drive mechanism:71- actuating cylinders, 72- rotary shafts, 73- support cylinders, 74- high-speed electric expreess locomotives;8- nanofibers:81- liquid filaments, 82- nanometers Silk, 83- micron yarns.
Specific embodiment
To become apparent the present invention, hereby with preferred embodiment, and accompanying drawing is coordinated to be described in detail below.It should be understood that These embodiments are only illustrative of the invention and is not intended to limit the scope of the invention.In addition, it is to be understood that reading the present invention After the content of instruction, those skilled in the art can make various changes or modifications to the present invention, and these equivalent form of values equally fall In the application appended claims limited range.
Fig. 1 directly spins a micron yarn feeding device structural representation, described shearing for the shearing drawing-off Static Spinning that the present invention is provided Formula drawing-off Static Spinning directly spin micron yarn feeding device by shower nozzle 1, cone cylinder 2, buncher 3, fluid injection chamber 4, negative high voltage source 5, winding mechanism 6, The grade of drive mechanism 7 is constituted.
Shower nozzle 1 includes loudspeaker shower nozzle 11, ring set 12 and the ascending pipe 13 being sequentially connected, the connection fluid injection of ascending pipe 13 chamber 4.Match somebody with somebody Put the high polymeric solutions such as PAN (polyacrylonitrile), the PVA (polyvinyl alcohol) of suitable concentration injection cylinder fluid injection chamber 4, and with 0.1~ 0.6ml/h constant flow rate Jing politef ascending pipe 13 reaches loudspeaker shower nozzle 11 and forms uniform films, arranges loudspeaker shower nozzle 11 Radius is that 0~4cm is adjustable.
One end in negative high voltage source 5 is connected on loudspeaker shower nozzle 11, it is another to terminate in the cone cylinder 2 that inwall is metallic conduction, The high pressure of 6~30kv can be provided, the voltage swing of proper security is adjusted so that loudspeaker shower nozzle 11 with cone cylinder 2 under suitable distance, Produce the high voltage electric field of high electric field drafting force;From loudspeaker shower nozzle 11 spray injection stream at the edge of loudspeaker shower nozzle 11 because of negative high voltage Electric field effect division, and drafted attenuating and fall cone cylinder 2 front port 21 inner side, formed umbrella distribution liquid filaments 81。
Liquid filaments 81 by the inwall of loudspeaker shower nozzle 11 and cone cylinder 2 because mutually being gripped, and cone cylinder 2 is in the driving of drive mechanism 7 Under cause liquid filaments 81 to be subject to drawing-off shearing force and drafted drawing-down in appropriate range of speeds high-speed rotation, be further refined into and receive The nano wire 82 of metrical scale, solidifies gradually because of the certain distance length of cone cylinder 2.
The appropriate rotating speed of takers-in 61 is set, the nano wire 82 after solidification is shelled from cone cylinder 2 by the rotary action of takers-in 61 From getting off, it is drawn to up to buncher 3 by the rear port 22 of cone cylinder 2, and the rear port 22 of cone cylinder 2 is fillet, prevents scratch nanometer Silk, is easy to peel off;During using cone cylinder 2 rotate make the boundling of nano wire 82 twisting eventually become micron yarn 83;Jing groove drums volume 62 Around collecting with tube 63, the cheese of stable micron yarn 83 is formed.
Drive mechanism 7 is made up of actuating cylinder 71, rotary shaft 72, support cylinder 73 and high-speed electric expreess locomotive 74, actuating cylinder 71 and the phase of cone cylinder 2 Contact, high-speed electric expreess locomotive 74 drives the rotation of rotary shaft 72 and adjustable speed, rotary shaft 72 to drive actuating cylinder 71 to rotate, and holds in the palm cylinder 73 with active Cylinder 71 makes in couples the smooth rotation of cone cylinder 2, and holds in the palm the central shaft of cylinder 73 with the central point of loudspeaker shower nozzle 11 and the line of centres of buncher 3 Coaxially.
Table 1 show the shearing drawing-off Static Spinning of present invention offer and directly spins micron yarn feeding device work in different embodiments Skill parameter and measured result.
In table 1, flow refers to the solution capacity amount flow through in the unit interval, and voltage refers to the voltage swing that high voltage power supply is produced, Cone cylinder slope refers to the tangent value of the angle that cone cylinder front port is formed to rear port line and horizontal line, and loudspeaker shower nozzle slope refers to loudspeaker Shower nozzle front end refers to before loudspeaker shower nozzle rear port and cone cylinder with backhaul connection and the tangent value of horizontal line angulation, draw zone slope The tangent value of end line and horizontal line angulation.
There is specific embodiment 1~12 to be to obtain different nano wires and micron yarn in electrostatic spinning device in table 1, simply Using the polymer solution of different types of debita spissitudo, different electrostatic spinning apparatus parts technological parameters, different electrostatic spinnings Method setup parameter, carries out directly being spun a micron yarn method and being prepared nano wire and micron yarn by the shearing drawing-off Static Spinning of the present invention.
Shearing drawing-off Static Spinning directly spins micron yarn feeding device and method and Static Spinning direct spinning process, and nanoscale is obtained Nano wire and submicron-scale monofilament, i.e. thus thickness be directly spun into the micron yarn of micro-meter scale, i.e. thickness in 0~500nm At 1~100 μm.Specific process parameter and measured result are shown in Table 1, and filament diameter represents the thickness index of single fiber, unit nm; Micron yarn diameter represents the thickness index of yarn, unit μm;Filament strength represents that fiber resists the index of external force damage capability, single Position cN/dtex;Yarn strength represents that yarn resists the index of external force damage capability, unit cN/tex;CV values refer to the coefficient of variation Size, is the ratio of the standard deviation with average of each technological parameter.
From the measured result (being shown in Table 1) of embodiment 1~12:The nano wire of cone cone cylinder is compared with being coarser than horn body cone cylinder As a result, the thickness of the big nano wire of cone cylinder or draw zone slope is thicker, and its main cause is that have certain shock to hinder and more early Peel off;Electrostatic pressure and the cone cylinder rotating speed of shearing drawing-off affect obvious to monofilament thickness, are that electrostatic negative high voltage is higher, electric field drawing-off is made With stronger, cone cylinder rotating speed is higher, the reason that shear action is stronger;And the intensity of nanometer monofilament with thickness result conversely, i.e. thinner Monofilament, intensity is of a relatively high.This just breaches the critical defect of original or existing electrostatic spinning, and realization is better, stronger. Its filament strength apparently higher than 1~3 times of the intensity of existing electrostatic spinning, become can direct spinning nanofiber, and monofilament Fineness also attenuates several times to an order of magnitude.It is straight to spin the thick of micron yarn due to the raising attenuated with filament strength of monofilament fineness The result of thin and intensity be it is one-to-one, i.e., it is more thin stronger.Further, since the dual drawing-off of electrostatic field and mechanical shearing and The protection that grips of cone cylinder makes the thickness coefficient of variation (CV) for being spun into nanometer monofilament become strong by only 19.0%~24.0%, than routine 50%~150% reduction at double, this make into micron yarn plucked value (CV) < 6.4%;Intensity irregularity (CV) < 5.5%, it is irregular with the intensity of existing endless tow quite even more excellent.All fineness and intensity results in embodiment 1~12 are equal It is better than existing electrostatic spinning fiber, and the direct resultant yarn of energy at double, it was demonstrated that micron yarn feeding device and method are simultaneously directly spun in the electrostatic nanometer spinning Effective and advantage.
The apparatus of the present invention of table 1 technological parameter in different embodiments and measured result

Claims (10)

1. a kind of shearing drawing-off Static Spinning directly spins a micron yarn feeding device, it is characterised in that:Including
For high polymeric solution to be carried out into the flaring shower nozzle (1) that umbrella sprays the liquid filaments (81) to form submicron thickness;
Drawing-off is sheared for receiving liquid filaments (81) and it being implemented, makes liquid filaments (81) further be refined into nano wire (82) Cone cylinder (2);
Converge and boundling twists into micron yarn for the cured nano wire (82) for being distributed in cone cylinder (2) and rotating to be peeled off (83) buncher (3);
For providing the fluid injection chamber (4) of high polymeric solution to shower nozzle (1);
For forming negative high voltage electric field between shower nozzle (1) and cone cylinder (2), so that the injection stream drawing-off sprayed from shower nozzle (1) Attenuate and fall in the front port inner side of cone cylinder (2), form the negative high voltage source (5) of the liquid filaments (81) of umbrella distribution;
For the micron yarn (83) for collecting beam shaping to be batched the winding mechanism (6) of shaping;
For driving cone cylinder (2) to rotate at a high speed so as to shear the drive mechanism (7) of drawing-off liquid filaments (81).
2. a kind of shearing drawing-off Static Spinning as claimed in claim 1 directly spins a micron yarn feeding device, it is characterised in that:The shower nozzle (1) by the loudspeaker shower nozzle (11) being connected with the negative high voltage source (5), for the ring set (12) closing and shield and with the fluid injection The ascending pipe (13) that chamber (4) is connected is sequentially connected composition.
3. a kind of shearing drawing-off Static Spinning as claimed in claim 2 directly spins a micron yarn feeding device, it is characterised in that:The cone cylinder (2) it is Rotary-table or horn body, cone cylinder (2) front port (21) inner side is big with the slope of the line at loudspeaker shower nozzle (11) edge In the slope of cone cylinder (2);Distance of cone cylinder (2) rear port (22) away from cone cylinder (2) front port (21) must can guarantee that nano wire (82) Solidification complete, and cone cylinder (2) rear port (22) is fillet.
4. a kind of shearing drawing-off Static Spinning as claimed in claim 1 directly spins a micron yarn feeding device, it is characterised in that:The boundling The endoporus of device (3) is horn mouth, and buncher (3) is engaged with the cone cylinder (2) for rotating and completes the twisting to nano wire (82) with collection Beam is into micron yarn (83).
5. a kind of shearing drawing-off Static Spinning as claimed in claim 1 directly spins a micron yarn feeding device, it is characterised in that:The negative height Potential source (5) is the generator of the negative high voltage that can provide 6~30kv.
6. a kind of shearing drawing-off Static Spinning as claimed in claim 2 directly spins a micron yarn feeding device, it is characterised in that:The winding Mechanism (6) includes takers-in (61), groove drum (62) and tube (63), takers-in (61) rotate by the nano wire (82) after solidification from Cone cylinder (2) is stripped down, and is drawn to up to buncher (3) by cone cylinder (2) rear port (22), during using cone cylinder (2) rotate make The twisting of nano wire (82) boundling becomes a micron yarn (83), and Jing groove drums (62) winding and tube (63) are collected, and form stable micron The cheese of yarn (83).
7. a kind of shearing drawing-off Static Spinning as claimed in claim 2 directly spins a micron yarn feeding device, it is characterised in that:The driving Rotary shaft (72) and master that mechanism (7) is rotated by the actuating cylinder (71), driving actuating cylinder (71) that contact with the cone cylinder (2) Dynamic cylinder (71) is in couples using making the cone cylinder (2) smooth rotation and in cone cylinder (2) central shaft and the loudspeaker shower nozzle (11) The coaxial support cylinder (73) of heart point and buncher (3) line of centres, the high-speed electric expreess locomotive for driving rotary shaft (72) rotation and adjustable speed (74) constitute.
8. a kind of employing shearing drawing-off Static Spinning as claimed in claim 6 directly spins the straight spinning method of micron yarn feeding device, and it is special Levy and be, step is:
The first step, electrostatic spray webbing:High polymeric solution reaches loudspeaker shower nozzle (11) and is formed uniformly by fluid injection chamber (4) Jing ascending pipes (13) Film, and fall within cone cylinder (2) front end because of the effect of negative high voltage electric field division and drafted attenuating at the edge of loudspeaker shower nozzle (11) The inner side of mouth (21), forms the liquid filaments (81) of umbrella distribution;
Second step, shearing drawing-off:The liquid filaments (81) of umbrella distribution are gripped because of the inwall by loudspeaker shower nozzle (11) and cone cylinder (2), And cone cylinder (2) and the shearing drawing-off to liquid filaments (81) is formed in high-speed rotation, liquid filaments (81) is further refined into and receive Rice silk (82), and the solidification in cone cylinder (2);
3rd step, boundling twisting:Cured nano wire (82) is drawn from cone cylinder (2) to peel off to converge by takers-in (61) and enters collection The horn mouth of beam device (3), and twisting forms micron yarn (83) under the rotation of cone cylinder (2), and Jing groove drums (62) are wound in tube (63) on, the cheese of the micron yarn (83) of form stable is formed.
9. a kind of application that micron yarn feeding device is directly spun using shearing drawing-off Static Spinning as claimed in claim 1, its feature is existed In:Shearing drawing-off Static Spinning as claimed in claim 1 is directly spun into micron yarn feeding device to receive for the monofilament thickness of Static Spinning The direct resultant yarn processing of metrical scale.
10. a kind of application that micron yarn feeding device is directly spun using shearing drawing-off Static Spinning as claimed in claim 1, its feature is existed In:Shearing drawing-off Static Spinning as claimed in claim 1 is directly spun into micron yarn feeding device for resultant yarn thickness in micro-meter scale Directly resultant yarn processing, or process for the direct resultant yarn that the twist is adjustable, resultant yarn thickness is thinner than micro-meter scale.
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CN110205685A (en) * 2019-05-23 2019-09-06 东华大学 Spinning self-regulation electrostatic spinning apparatus and its application method

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CN110079903B (en) * 2019-05-21 2020-10-09 江西先材纳米纤维科技有限公司 Preparation method and application of continuous long-line high-count yarn of electrospun nylon nanofiber
CN114717669B (en) * 2022-03-30 2023-05-26 南通纺织丝绸产业技术研究院 Nanofiber yarn and continuous yarn forming method thereof

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