CN104831216A - Ni-Co-Mo-Mn nanocoating material and preparation method thereof - Google Patents

Abstract

The invention relates to a Ni-Co-Mo-Mn nanocoating material and a preparation method thereof. The Ni-Co-Mo-Mn material comprises the following components in parts by mass: 43-67 parts of Ni, 11-24 parts of Co, 12 parts of Mo, 12 parts of Mn, 1 part of WC, and 0.11-0.59 part of trace elements, wherein the trace elements comprise Gr, W, Al, Cu and Zn. The preparation method comprises the following steps: preparing Ni-Co-Mo-Mn nanospheres by adopting a gas atomization method; and then mixing the prepared nanospheres with Gr, W, Al, Cu and Zn to prepare nanopowder by adopting an active agent protection method. The Ni-Co-Mo-Mn nanocoating material provided by the invention has the appearance of spherical particles and has the advantages of uniform distribution, complete particles and relatively good tissue structure and relatively good macro-performance. A Ni-Co-Mo-Mn nanocoating prepared from the Ni-Co-Mo-Mn nanocoating material provided by the invention has the hardness of HRC44, and has certain hardness and wear resistance and relatively high bonding strength and grabbing force.

Description

A kind of Ni-Co-Mo-Mn nano-coating material and preparation method thereof

Technical field

The present invention relates to technical field of hot, is a kind of Ni-Co-Mo-Mn nano-coating material and preparation method thereof specifically.

Background technology

Thermospray is a kind of surface strengthening technology, is the important component part of surface engineering technology, is the new technology project that China's emphasis is promoted always.It utilizes certain thermal source (as electric arc, plasma spraying or combustion flame etc.) that Powdered or thread metal or non-metallic material are heated to melting or semi-melting state, then stay itself or pressurized air to be ejected into pretreated matrix surface with certain speed by flame, deposit and form a kind of technology with the top coat of various function.Thermospray refers to a series of process, in these processes, trickle and dispersion metal or nonmetallic coated material, with one fusing or semi-molten state, deposit to a kind of through preparation matrix surface, form certain spray deposited layer.It utilizes certain thermal source (as electric arc, plasma spraying or combustion flame etc.) that Powdered or thread metal or non-metallic material are heated to melting or semi-melting state, then be ejected into pretreated matrix surface by flame stream itself or pressurized air with certain speed, deposit and form a kind of technology with the top coat of various function.

The outstanding feature of hot-spraying techniques makes it apply great potential.These features are mainly manifested in: 1. Surface Engineering and being combined in design of material of multiple matrix material have obvious advantage; 2. the chemical composition of material can be adjusted easily; 3. the matrix material of special construction performance can be had by dynamic formation; 4. the compound of multiple material and multiple technologies can obtain excellent performance.Therefore the research of thermal spraying material is the deciding factor of 21 century thermospray development, is also the driving of hot-spraying techniques development.

But along with improving constantly engineering mechanical device performance requriements, improving and development of hot-spraying techniques, the application of hot-spraying techniques is limited to the development of thermal spraying material and processing unit.

The material bond strength that traditional spraying technology uses is poor, void content is high, wear no resistance.Novel hot spray material needs to make up these defects, and adopt new technology, novel method, new formula is obtained has high rigidity, high-wearing feature, high corrosion resistance, heterogeneous microstructure is even, and the excellent material of comprehensive mechanical property becomes the urgent demand of people.

Summary of the invention

Poor in order to solve conventional coatings wear resistance, the problems such as hardness is lower, the invention provides a kind of Ni-Co-Mo-Mn nano-coating material and preparation method thereof.

Technical problem to be solved by this invention realizes by the following technical solutions:

A kind of Ni-Co-Mo-Mn nano-coating material, the mass fraction of its component and each component is that Ni accounts for 43-67 part, Co accounts for 11-24 part, Mo accounts for 12 parts, Mn accounts for 12 parts, WC accounts for 1 part, trace element accounts for 0.11-0.59 part, described WC adds as additive, can improve material hardness.

Be mixed into by Ni in nano coating and can improve physical strength, the alloy of Ni and steel is used for manufacturing machine and bears larger pressure, withstands shocks and the part of reciprocal loaded portion, as turbine blade, bent axle, connecting rod etc.

It is the important source material of producing refractory alloy, Wimet, anti-corrosion alloy, magneticalloy and various cobalt salt that the physics of Co, chemical property determine it.Cobalt base alloy or cobalt-containing alloy steel are used as the heat-resistant part of various high loading and the important meals material of nuclear industry in the blade of gas turbine, impeller, conduit, jet engine, rocket engine, the parts of guided missile and chemical industry equipment.As binding agent, Co can ensure that Wimet has certain toughness.

The pure metal of Mo is silvery white, very hard.A small amount of Mo is added among nano coating, coating can be made hardening.

Described trace element is Gr, W, Al, Cu, Zn.Gr and Graphene, Graphene (Graphene) is a kind of Two-dimensional Carbon material, is the general designation of single-layer graphene, bilayer graphene and few layer graphene.Graphene is thin, the hardest nano material in known world.

Below 225 DEG C, Zn can form layer protecting film on nano coating surface, prevents nano coating oxidized.

A preparation method for Ni-Co-Mo-Mn nano-coating material, comprises the following steps:

(1) aerosolization legal system is adopted to obtain the nanometer ball of Ni-Co-Mo-Mn;

(2) mixing of promoting agent protection method Gr, W, Al, Cu, Zn is adopted by nanometer ball obtained in step (1) to obtain nanometer powder.

The invention has the beneficial effects as follows: pattern of the present invention is spherical particle, be evenly distributed, particle is complete, there is good weave construction and good macro property.The hardness of the Ni-Co-Mo-Mn nano coating that the present invention makes can reach HRC44, has certain hardness and wear resistance, and bonding strength, grasping force are higher, and density can reach 7.684g/cm ³, coating thickness can reach 5 millimeters, and density is well 0.79, and over-all properties is better than conventional washcoat material, and hardness is high, wear resistance is good has very large progress compared with conventional alloys material.

Accompanying drawing explanation

Below in conjunction with drawings and Examples, the present invention is further described.

Fig. 1 is the present invention's weave construction under a scanning electron microscope and crystal morphology.

Embodiment

The technique means realized to make the present invention and creation characteristic are easy to understand, and set forth further below to the present invention.

Embodiment one

A kind of Ni-Co-Mo-Mn nano-coating material, the mass fraction of its component and each component is that Ni accounts for 43 parts, Co accounts for 11 parts, Mo accounts for 12 parts, Mn accounts for 12 parts, WC accounts for 1 part, trace element accounts for 0.11 part.

Described trace element is Gr, W, Al, Cu, Zn.

A preparation method for Ni-Co-Mo-Mn nano-coating material, comprises the following steps:

(1) aerosolization legal system is adopted to obtain the nanometer ball of Ni-Co-Mo-Mn;

(2) mixing of promoting agent protection method Gr, W, Al, Cu, Zn is adopted by nanometer ball obtained in step (1) to obtain nanometer powder.

Embodiment two

A kind of Ni-Co-Mo-Mn nano-coating material, the mass fraction of its component and each component is that Ni accounts for 48 parts, Co accounts for 17 parts, Mo accounts for 12 parts, Mn accounts for 12 parts, WC accounts for 1 part, trace element accounts for 0.26 part.

Described trace element is Gr, W, Al, Cu, Zn.

A preparation method for Ni-Co-Mo-Mn nano-coating material, with embodiment one.

Embodiment three

A kind of Ni-Co-Mo-Mn nano-coating material, the mass fraction of its component and each component is that Ni accounts for 58 parts, Co accounts for 19 parts, Mo accounts for 12 parts, Mn accounts for 12 parts, WC accounts for 1 part, trace element accounts for 0.37 part.

Described trace element is Gr, W, Al, Cu, Zn.

A preparation method for Ni-Co-Mo-Mn nano-coating material, with embodiment one.

Embodiment four

A kind of Ni-Co-Mo-Mn nano-coating material, the mass fraction of its component and each component is that Ni accounts for 67 parts, Co accounts for 24 parts, Mo accounts for 12 parts, Mn accounts for 12 parts, WC accounts for 1 part, trace element accounts for 0.59 part.

Described trace element is Gr, W, Al, Cu, Zn.

A preparation method for Ni-Co-Mo-Mn nano-coating material, with embodiment one.

Composition graphs 1, adopt supersonic spray coating technology obtained Ni-Co-Mo-Mn nano coating on the rod class workpiece being matrix with 20Co steel, the matrix with described coating and bonding strength, microhardness, void content and the abrasive wear resistance contrast and experiment without the matrix of described coating are in table 1:

The performance comparison experimental result of table 1Ni-Co-Mo-Mn nano coating and 20Co steel matrix:

Experimental group is numbered	Porosity (AREA%)	Bonding strength (MPa)	Microhardness (HV)
				1	0.557	75.4	678
2	0.456	74.9	689
				3	0.747	68.8	789
4	0.477	75.4	874
				Mean value	0.559	73.6	758
Comparative group	0.789	54.3	595

Adopt supersonic spray coating technology obtained Ni-Co-Mo-Mn coating on the rod class workpiece being matrix with 20Co steel, the abrasion loss contrast and experiment of the matrix with described coating and the matrix without described coating is in table 2:

The abrasion loss contrast and experiment of table 2 Ni-Co-Mo-Mn nano coating and 20Co steel matrix:

Experimental group is numbered	Before wearing and tearing (g)	After wearing and tearing (g)	Abrasion loss (g)
				1	73.5858	73.5788	0.0070
2	73.5854	73.5782	0.0072
				3	73.2356	73.2291	0.0065
4	73.7965	73.7901	0.0064
				Comparative group	73.1363	73.1285	0.0078

From table 1 and table 2, the excellent combination property of Ni-Co-Mo-Mn nano coating, wear resistance is good.

The present invention is applicable to supersonic spray coating, available spraying steel have: SKD61,4Cr5MoSiV1, Cr12MoV, Cr12,4Cr5W2VSi, 8Cr3 etc., also can spray some to the higher workpiece of hardness requirement or tool steel surface process, to improve workpiece surface hardness and wear resistance.

More than show and describe ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; the just principle of the present invention described in above-described embodiment and specification sheets; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.

Claims (2)

1. a Ni-Co-Mo-Mn nano-coating material, is characterized in that: the mass fraction of its component and each component is that Ni accounts for 43-67 part, Co accounts for 11-24 part, Mo accounts for 12 parts, Mn accounts for 12 parts, WC accounts for 1 part, trace element accounts for 0.11-0.59 part;

Described trace element is Gr, W, Al, Cu, Zn.

2. a preparation method for Ni-Co-Mo-Mn nano-coating material, is characterized in that: comprise the following steps:

(1) aerosolization legal system is first adopted to obtain the nanometer ball of Ni-Co-Mo-Mn;

(2) mixing of promoting agent protection method Gr, W, Al, Cu, Zn is adopted by nanometer ball obtained in step (1) to obtain nanometer powder.