Background technology
Concrete, as the material that consumption is maximum in the world at present, has irreplaceable effect in engineering.And concrete technology is systems engineering, from proportion design, stirring, transport, build, vibrating to maintenance links is closely connected, any one link goes wrong all to produce concrete quality and have a strong impact on.Concrete precuring is the important step that concrete quality ensures, if the improper concrete drying shrinkage that will cause of precuring causes cracking, surface dehydration makes aquation deficiency affect concrete strength and weather resistance, the excessive generation that also will speed up crack of internal-external temperature difference.Therefore, the guarantee of effective concrete pouring way to construction quality seems very necessary.
Concrete curing method conventional in current engineering: cotton-wadded quilt moisture-heat preservation cladding process, pad pasting method of curing, geotextile wrap watering method and automatic spray method.These methods are time-consuming, take a lot of work and produce serious water resource waste.Therefore, carry out maintenance with effective curing compound and develop into important maintenance means.Cement concrete curing agent is that one is sprayed or painting way, forms the material of the continuous fluid-tight curing in airtight condition film of one deck at cement concrete surface.
Current curing compound is divided into organic type and the large class of inorganic type two.Organic type curing agent refers to that macromolecule material film molecule aggregation after moisture drying evaporation becomes fluid-tight polymer thin film to cover cement concrete surface, stops the evaporation of moisture content, reaches the effect of moisturizing, mainly comprise: resene, latex class and emulsion class.Resene is usually containing volatile solvent, and contaminate environment is also detrimental to health; Latex type curing agent exists that cost is high, maintenance terminates rear film forming and is difficult to remove, affect the problems such as successive projects progress; Emulsion class advantage is comparatively obvious, but also there is the problems such as coating thickness is little, film forming compactness is poor, unit mass spray area is little.Inorganic type curing agent is mainly silicate solutions class, reduces the speed of water evaporates by strengthening dense surface, but it can not film forming, and water retention is not enough.
Chinese patent CN 103253985 B discloses a kind of composite cement curing compound and preparation method thereof, although film forming is fine and close, good water-retaining property, use epoxy resin is as coating, and cleaning is complicated.
Chinese patent CN103058544 B discloses a kind of Concrete Double component curing agent, owing to adopting two component film forming, must carry out twice spraying, will increase hand spray expense.
Chinese patent CN 102976652 B discloses emulsion curing agent of a kind of high water retention and preparation method thereof.Although what adopt is nucleocapsid structure, owing to being solid core shell structure, not there is effect of heat insulation, and high expensive.
In sum, although current curing compound kind is a lot, water-retentivity also meets the requirements, and does not generally possess heat-proof quality, causes coating amount comparatively large and makes cost higher.
Summary of the invention
The object of this invention is to provide a kind of moisturizing insulating cement curing compound simultaneously with good humidity-holding effect and effect of heat insulation and preparation method thereof.
Described a kind of moisturizing insulating cement curing compound, its consisting of by mass percentage: nucleocapsid hollow polymer particle 30% ~ 60%, emulsion stabilizer 1% ~ 2%, film coalescence aid 2% ~ 8%, flow agent 0 ~ 5%, surplus is water.
Described nucleocapsid hollow polymer particle can be the one in nucleocapsid hollow polystyrene particle, nucleocapsid hollow polystyrene-divinylbenzene particles, the hollow poly methyl methacrylate particle of nucleocapsid, the hollow polyvinyl chloride particles of nucleocapsid etc.
Described emulsion stabilizer can be the one in liquid barium zinc stabilizer, liquid calcium zinc stabilizer etc.
Described film coalescence aid can be the strong solvent of ether alcohol class superpolymer, as: the one during propandiol butyl ether, 1-Methoxy-2-propyl acetate, No. 200 solvent oils, ethylene glycol, alcohol ester ten are second-class.
Described flow agent can be polyurethanes flow agent or acrylic acid or the like flow agent etc.
The preparation method of described a kind of moisturizing insulating cement curing compound, comprises the following steps:
1) air kernel emulsion is prepared
In water, add pore forming material, emulsifying agent and suds-stabilizing agent, stir and form foam kernel, make generation foam bubbles can in water stable suspersion, obtain air kernel emulsion;
In step 1) in, described pore forming material can select the one in rosin, sodium lauryl sulphate, trimethyl-glycine etc., and the add-on of pore forming material can be 0.5% ~ 5% of air kernel emulsion total mass;
Described emulsifying agent can select anionic emulsifier or nonionic emulsifying agent; Described anionic emulsifier can select the one in sodium stearate, oleate soap, lauric acid soap, rosinol soap, Sodium dodecylbenzene sulfonate, two dodecylphenyl ether sodium disulfonate, sulfonated lignin, sodium methylene diisopropyl naphthalene sulfonate, potassium methylene diisopropyl naphthalene sulphonate, sulfuric acid etc.; The add-on of described emulsifying agent can be 1% ~ 10% of air kernel emulsion total mass;
Described suds-stabilizing agent can be silicone resin polyethers emulsion class suds-stabilizing agent or nonionogenic tenside; Described suds-stabilizing agent add-on can be 0.5% ~ 8% of air kernel emulsion total mass;
The speed of described stirring can be 200 ~ 2000r/min, and the temperature of stirring can be 50 ~ 80 DEG C; The bubble diameter of described foam bubbles reaches a μm level.
2) internal layer nucleocapsid hollow polymer grain emulsion is prepared
Hard monomer is added in air kernel emulsion, hard monomer is made to be gathered on the liquid-gas interface of foam, adding water soluble starter again and carry out letex polymerization, and add step 1) described suds-stabilizing agent prevents lather collapse, obtains internal layer nucleocapsid hollow polymer grain emulsion;
In step 2) in, described hard monomer can be the one in vinylbenzene, styrene-divinylbenzene, methyl methacrylate, vinylchlorid etc., and the add-on of hard monomer can be 5 ~ 30% of air kernel emulsion total mass; Described water soluble starter can be the one in ammonium persulphate, Potassium Persulphate, persulphate, sulphite etc., and water soluble starter mass concentration can be 0.5 ~ 3%, and the add-on of water soluble starter can be 0.5% ~ 5% of air kernel emulsion total mass; The add-on of described suds-stabilizing agent can be 0.5% ~ 5% of air kernel emulsion total mass.
3) the nucleocapsid hollow polymer grain emulsion of preparation containing outer soft shell
In step 2) add hydrophilic soft monomer, through being polymerized the nucleocapsid hollow polymer grain emulsion obtained containing outer soft shell in the internal layer nucleocapsid hollow polymer grain emulsion that obtains;
In step 3) in, described hydrophilic soft monomer can be containing the one in acrylic acid or the like mix monomer, alkene acid amides etc.; The described one can selected containing acrylic acid or the like mix monomer in vinylformic acid, butyl acrylate methyl esters, methyl methacrylate etc., the add-on of hydrophilic soft monomer can be 10% ~ 45% of internal layer nucleocapsid hollow polymer grain emulsion total mass; Adding in hydrophilic soft monomer, can add the water soluble starter that mass concentration is 0.5% ~ 3%, water soluble starter add-on can be 0.5% ~ 5% of internal layer nucleocapsid hollow polymer grain emulsion total mass; Can step 1 be added) described in emulsifying agent, emulsifying agent add-on can be 1% ~ 10% of internal layer nucleocapsid hollow polymer grain emulsion total mass; The solid content of the described nucleocapsid hollow polymer grain emulsion containing outer soft shell can be 30% ~ 60%.
4) in the nucleocapsid hollow polymer grain emulsion containing outer soft shell, add emulsion stabilizer, film coalescence aid and flow agent, obtain moisturizing insulating cement curing compound.
In step 4) in, described emulsion stabilizer can be liquid barium zinc stabilizer or liquid calcium zinc stabilizer, and emulsion stabilizer add-on can be 1% ~ 2% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell; Described film coalescence aid can be the strong solvent of ether alcohol class superpolymer, the strong solvent of ether alcohol class superpolymer can be propandiol butyl ether, 1-Methoxy-2-propyl acetate, No. 200 solvent oils, ethylene glycol, alcohol ester ten second-class in one; The add-on of film coalescence aid can be 2% ~ 8% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell; Described flow agent can be polyurethanes flow agent or acrylic acid or the like flow agent, and the nucleocapsid hollow polymer grain emulsion total mass that the add-on of flow agent can be containing outer soft shell is 0 ~ 5%.
Compared with the prior art, beneficial effect of the present invention is as follows:
The mechanism of preparation method of the present invention is: the polymer beads emulsion preparing hollow structure with emulsion polymerization, the feature that polymer beads in polymer beads emulsion possesses is: hollow ball-shape body, kernel is air, and housing internal layer is polymer beads, skin is wetting ability flexible polymer.Final obtained emulsion (moisturizing insulating cement curing compound) is made up of this auxiliary agent such as nucleocapsid hollow polymer particle and emulsifying agent, stablizer, film coalescence aid and water.
Moisturizing insulating cement curing compound of the present invention, has following outstanding advantages:
1, letex polymerization has high humidity-holding effect, and water retention reaches more than 90%.
2, wetting ability flexible polymer can produce good bounding force with concrete surface, make coating not easily peeling come off.
3, the kernel of hollow structure is by reduction ambient temperature on the impact of concrete hydrating, not only improves early strength, and: hot weather construction reduces external high temperature dehydration; Winter low temperature construction can reduce the outer cold concrete surface that causes of heat in concrete and ftracture (being particularly suitable for the mass concrete construction such as dam, bridge pier).
4, while, the polymer beads of hollow structure, decreases the consumption of polymkeric substance when same thickness and area, and cost will be made to reduce by more than 20% ~ 80%.
5, easy to use, substantially identical with other curing compounds, the modes such as spraying, spreading, spraying, brushing can be adopted in the even application of cement concrete surface, and suggestion brushing consumption is 100g ~ 200g/ ㎡.
6, curing agent is particle hollow spherulite suspensoid, and conjunctiva forms micron openings film, has larger thermal resistance, has incubation and thermal insulation function; Hollow spherulite can reduce raw material consumption, good economy performance, wide coverage, and efficiency is high, and cost performance is high; Curing agent is in dry, water-bearing concreae surface flotation, and a covering surfaces can reduce curing agent consumption; Outer layer copolymer softness is conducive to the complete raising water retaining efficiency of conjunctiva; Outer layer copolymer hydrophilic being conducive to, in the stable absorption of alkaline concrete surface, improves the compactness of curing film, improves water retention.
Embodiment
Embodiment 1
A kind of moisturizing insulating cement curing compound described in the present embodiment 1, its composition is by mass percentage: the hollow soft monomer of nucleocapsid is 40%, and emulsion stabilizer is 2%, and film coalescence aid is 3%, and flow agent is 2%, Yu Weishui.
The composition of described nucleocapsid hollow polymer particle is nucleocapsid hollow polystyrene particle; The composition of described emulsion stabilizer is liquid barium zinc stabilizer; The composition of described film coalescence aid can be the strong solvent of propandiol butyl ether; The composition of described flow agent is polyurethanes flow agent;
A kind of preparation method of moisturizing insulating cement curing compound described in the present embodiment 1, comprises the following steps:
1) air kernel emulsion is prepared
Pore forming material rosin, emulsifying agent oleate soap and silicone resin polyethers emulsion class suds-stabilizing agent is added in water; The add-on of pore forming material rosin, emulsifying agent oleate soap and silicone resin polyethers emulsion class suds-stabilizing agent is respectively 1.5%, 5% and 1% of air kernel emulsion total mass; Then in water with the speed violent stirring of 1500r/min, form foam kernel, temperature during stirring is 60 DEG C.Obtain air kernel emulsion thus.Controlling the bubble diameter of foam bubbles is a μm level, and can in water stable suspersion.
2) internal layer nucleocapsid hollow polymer grain emulsion is prepared
Hard monomer vinylbenzene is added in air kernel emulsion, hard monomer is made to be gathered on the liquid-gas interface of foam, adding water soluble starter again and carry out letex polymerization, and add step 1) described suds-stabilizing agent prevents lather collapse, obtains internal layer nucleocapsid hollow polymer grain emulsion.
The cinnamic add-on of described hard monomer is 15% of air kernel emulsion total mass; Described water soluble starter is ammonium persulphate, and water soluble starter mass concentration is 2%, and the add-on of water soluble starter is 3% of air kernel emulsion total mass, and described suds-stabilizing agent add-on is 1% of air kernel emulsion total mass.
3) the nucleocapsid hollow polymer grain emulsion of preparation containing outer soft shell
In step 2) progressively drip hydrophilic soft monomeric acrylic, through being polymerized the nucleocapsid hollow polymer grain emulsion obtained containing outer soft shell in the internal layer nucleocapsid hollow polymer grain emulsion that obtains.
In dropping hydrophilic soft monomeric acrylic process, add the water soluble starter that mass concentration is 2%, water soluble starter add-on is 1% of internal layer nucleocapsid hollow polymer grain emulsion total mass; Add step 1) described in emulsifying agent oleate soap, by mass percentage, emulsifying agent oleate soap add-on is 2.5% of internal layer nucleocapsid hollow polymer grain emulsion total mass.
The add-on of described hydrophilic soft monomeric acrylic is 18% of internal layer nucleocapsid hollow polymer grain emulsion total mass; The solid content of the nucleocapsid hollow polymer grain emulsion containing outer soft shell is 40%.
4) in the nucleocapsid hollow polymer grain emulsion containing outer soft shell, add the auxiliary agents such as emulsion stabilizer, film coalescence aid and flow agent, and mix, obtain described a kind of moisturizing insulating cement curing compound.
Described emulsion stabilizer is liquid barium zinc stabilizer, and emulsion stabilizer add-on is 1.5% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell; Described film coalescence aid is propandiol butyl ether, and the add-on of film coalescence aid is 5% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell; Described flow agent is polyurethanes flow agent, and the add-on of flow agent is 2% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell.
The present embodiment 1 is according to the effective water retention of curing agent in People's Republic of China's building material industry standard " cement concrete curing agent " (JC901-2002) and compressive strength rate testing method, the effective water retention obtained after tested is 94%, 7d compressive strength rate is 112%, 28d compressive strength rate is 109%.Meet acceptable end product index request.
Embodiment 2
A kind of moisturizing insulating cement curing compound described in the present embodiment 2, its composition is by mass percentage: the hollow soft monomer of nucleocapsid is 30%, and emulsion stabilizer is 2%, and film coalescence aid is 2%, and flow agent is 1%, Yu Weishui.
The composition of described nucleocapsid hollow polymer particle is the hollow polyvinyl chloride particles of nucleocapsid; The composition of described emulsion stabilizer is liquid calcium zinc stabilizer; The composition of described film coalescence aid can be the strong solvent of alcohol ester 12; The composition of described flow agent is polyurethanes flow agent;
Described in the present embodiment 2, a kind of preparation method of moisturizing insulating cement curing compound, comprises the following steps.
1) air kernel emulsion is prepared
Pore forming material rosin, emulsifying agent oleate soap and silicone resin polyethers emulsion class suds-stabilizing agent is added in water; The add-on of pore forming material rosin, emulsifying agent oleate soap and silicone resin polyethers emulsion class suds-stabilizing agent is respectively 1.5%, 4% and 1% of air kernel emulsion total mass; Then in water with the speed violent stirring of 1400r/min, form foam kernel, temperature during stirring is 60 DEG C.Obtain air kernel emulsion thus.Controlling the bubble diameter of foam bubbles is a μm level, and can in water stable suspersion.
2) internal layer nucleocapsid hollow polymer grain emulsion is prepared
Hard monomer vinylchlorid is added in air kernel emulsion, hard monomer is made to be gathered on the liquid-gas interface of foam, adding water soluble starter again and carry out letex polymerization, and add step 1) described suds-stabilizing agent prevents lather collapse, obtains internal layer nucleocapsid hollow polymer grain emulsion.
The cinnamic add-on of described hard monomer is 15% of air kernel emulsion total mass; Described water soluble starter is ammonium persulphate, and water soluble starter mass concentration is 1%, and the add-on of water soluble starter is 2.5% of air kernel emulsion total mass, and the add-on of described suds-stabilizing agent is 1% of air kernel emulsion total mass.
3) the nucleocapsid hollow polymer grain emulsion of preparation containing outer soft shell
In step 2) progressively drip hydrophilic soft monomeric acrylic, through being polymerized the nucleocapsid hollow polymer grain emulsion obtained containing outer soft shell in the internal layer nucleocapsid hollow polymer grain emulsion that obtains.
In dropping hydrophilic soft monomeric acrylic process, add the water soluble starter that mass concentration is 2%, add-on is 1% of internal layer nucleocapsid hollow polymer grain emulsion total mass; Add step 1) described in emulsifying agent oleate soap, the add-on of emulsifying agent oleate soap is 2.0% of internal layer nucleocapsid hollow polymer grain emulsion total mass.
The add-on of described hydrophilic soft monomeric acrylic is 16% of internal layer nucleocapsid hollow polymer grain emulsion total mass; The solid content of the described nucleocapsid hollow polymer grain emulsion containing outer soft shell is 30%.
4) in the nucleocapsid hollow polymer grain emulsion containing outer soft shell, add the auxiliary agents such as emulsion stabilizer, film coalescence aid and flow agent, and mix, obtain described a kind of moisturizing insulating cement curing compound.
Described emulsion stabilizer is liquid calcium zinc stabilizer, and emulsion stabilizer add-on is 2% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell; Described film coalescence aid is alcohol ester 12, and the add-on of film coalescence aid is 2% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell; Described flow agent is polyurethanes flow agent, and the add-on of flow agent is the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell is 1%.
The present embodiment 2 is according to the effective water retention of curing agent in People's Republic of China's building material industry standard " cement concrete curing agent " (JC901-2002) and compressive strength rate testing method, the effective water retention obtained after tested is 85%, 7d compressive strength rate is 96%, 28d compressive strength rate is 101%.Meet salable product index request.
Embodiment 3
A kind of moisturizing insulating cement curing compound described in the present embodiment 3, its composition is by mass percentage: the hollow soft monomer of nucleocapsid is 50%, and emulsion stabilizer is 1.5%, and film coalescence aid is 3.5%, and flow agent is 2.5%, Yu Weishui.
Described nucleocapsid hollow polymer particle is the hollow poly methyl methacrylate particle of nucleocapsid; Described emulsion stabilizer is liquid barium zinc stabilizer; Described film coalescence aid is the strong solvent of propandiol butyl ether; Described flow agent is acrylic acid class flow agent.
A kind of preparation method of moisturizing insulating cement curing compound described in the present embodiment 3, comprises the following steps:
1) air kernel emulsion is prepared
Pore forming material rosin, emulsifying agent oleate soap and silicone resin polyethers emulsion class suds-stabilizing agent is added in water; The add-on of pore forming material rosin, emulsifying agent oleate soap and silicone resin polyethers emulsion class suds-stabilizing agent is respectively 1.9%, 4% and 1.5% of air kernel emulsion total mass; Then in water with the speed violent stirring of 1700r/min, form foam kernel, temperature during stirring is 65 DEG C.Obtain air kernel emulsion thus.Controlling the bubble diameter of foam bubbles is a μm level, and can in water stable suspersion.
2) internal layer nucleocapsid hollow polymer grain emulsion is prepared
Hard monomer methyl methacrylate is added in air kernel emulsion, hard monomer is made to be gathered on the liquid-gas interface of foam, adding water soluble starter again and carry out letex polymerization, and add step 1) described suds-stabilizing agent prevents lather collapse, obtains internal layer nucleocapsid hollow polymer grain emulsion.
The cinnamic add-on of described hard monomer is 15% of air kernel emulsion total mass; Described water soluble starter is ammonium persulphate, and water soluble starter mass concentration is 1%, and the add-on of water soluble starter is 2.2% of air kernel emulsion total mass, and suds-stabilizing agent add-on is 0.8% of air kernel emulsion total mass.
3) the nucleocapsid hollow polymer grain emulsion of preparation containing outer soft shell
In step 2) progressively drip hydrophilic soft monomeric acrylic, through being polymerized the nucleocapsid hollow polymer grain emulsion obtained containing outer soft shell in the internal layer nucleocapsid hollow polymer grain emulsion that obtains.
In dropping hydrophilic soft monomeric acrylic process, add the water soluble starter that mass concentration is 2%, the add-on of water soluble starter be internal layer nucleocapsid hollow polymer grain emulsion total mass be 1%; Add step 1) described in emulsifying agent oleate soap, the add-on of emulsifying agent oleate soap is 2.0% of internal layer nucleocapsid hollow polymer grain emulsion total mass.
The add-on of described hydrophilic soft monomeric acrylic is 24% of internal layer nucleocapsid hollow polymer grain emulsion total mass; The solid content of the described nucleocapsid hollow polymer grain emulsion containing outer soft shell is 50%.
4) in the nucleocapsid hollow polymer grain emulsion containing outer soft shell, add the auxiliary agents such as emulsion stabilizer, film coalescence aid and flow agent, and mix, obtain described a kind of moisturizing insulating cement curing compound.
Described emulsion stabilizer is liquid barium zinc stabilizer, and emulsion stabilizer add-on is 1.5%; Described film coalescence aid is propandiol butyl ether, and the add-on of film coalescence aid is 3.5% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell; Described flow agent is acrylic acid or the like flow agent, and the add-on of flow agent is 2.5% of the nucleocapsid hollow polymer grain emulsion total mass containing outer soft shell.
The present embodiment 3 is according to the effective water retention of curing agent in People's Republic of China's building material industry standard " cement concrete curing agent " (JC901-2002) and compressive strength rate testing method, the effective water retention obtained after tested is 97%, 7d compressive strength rate is 105%, 28d compressive strength rate is 110%.Meet acceptable end product index request.
Embodiment 4
A kind of moisturizing insulating cement curing compound described in the present embodiment 4, its composition is by mass percentage: the hollow soft monomer of nucleocapsid is 55%, and emulsion stabilizer is 2.0%, and film coalescence aid is 3.5%, and flow agent is 2.9%, Yu Weishui.
The composition of described nucleocapsid hollow polymer particle is the hollow poly methyl methacrylate particle of nucleocapsid; The composition of described emulsion stabilizer is liquid barium zinc stabilizer; The composition of described film coalescence aid can be the strong solvent of propandiol butyl ether; The composition of described flow agent is acrylic acid class flow agent;
Described in the present embodiment 4, a kind of preparation method of moisturizing insulating cement curing compound, identical with embodiment 3.
The present embodiment 4 is according to the effective water retention of curing agent in People's Republic of China's building material industry standard " cement concrete curing agent " (JC901-2002) and compressive strength rate testing method, the effective water retention obtained after tested is 98%, 7d compressive strength rate is 107%, 28d compressive strength rate is 113%.Meet acceptable end product index request.