CN104804526A - UV curing adhesive printing ink - Google Patents
UV curing adhesive printing ink Download PDFInfo
- Publication number
- CN104804526A CN104804526A CN201510196438.6A CN201510196438A CN104804526A CN 104804526 A CN104804526 A CN 104804526A CN 201510196438 A CN201510196438 A CN 201510196438A CN 104804526 A CN104804526 A CN 104804526A
- Authority
- CN
- China
- Prior art keywords
- parts
- printing ink
- offset printing
- modified epoxy
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Abstract
The invention discloses UV (Ultraviolet) curing adhesive printing ink which comprises the following components in parts by weight: 20-30 parts of urethane acrylate, 25-35 parts of modified epoxy resin, 1-10 parts of polyvinylpyrrolidone, 10-20 parts of polyether acrylate, 2-8 parts of a photoinitiator, 1-5 parts of a dispersing agent, 3-7 parts of a de-foaming agent, 2-6 parts of a pigment and 5-15 parts of a filler. The UV curing adhesive printing ink prepared by the invention is quick in curing speed, good in dispersibility, high in bonding strength, suitable for offset printing and free from solvent volatilization and pollution, conforms to the environmental protection requirements and is suitable for the printing fields of food and drug packaging and the like.
Description
Technical field
The present invention relates to ink area, particularly relate to a kind of UV cured offset printing ink.
Background technology
Along with the high speed development of packages printing industry, ink industry is also correspondingly grown up fast, wherein the flexographic ink advantage that has traditional ink incomparable, is widely applied to the fields such as tobacco bale, Jiu Bao, cosmetic package, drug packaging or pressure-sensitive adhesive trade mark.
At present, printing industry generally uses solvent type ink to carry out film print production, but containing a large amount of volatile organic solvent in such ink, the gas volatilized during use enters people's cognition and causes serious harm to liver and neural system, enters in air and also can cause very large harm to environment.
Ultraviolet light polymerization (UV) flexographic ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can different-energy be produced, the monomer polymerization in different ink vehicle is become polymkeric substance, so the look film of UV flexographic ink has good machinery and chemical property.
But UV flexographic ink is in the market owing to taking into account pigment wettability, and multiselect unsaturated polyester resin is as matrix resin, and curing speed is slow.And flexographic ink contains heavy metal, there is great harm to human body and environment.
Summary of the invention
The object of the invention is to the deficiency overcoming the existence of above-mentioned prior art, the UV cured offset printing ink that a kind of environment-protecting asepsis, curing speed are fast, cohesive force is strong is provided.
For achieving the above object, the present invention is achieved by the following technical solutions:
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 20 ~ 30 parts, modified epoxy 25 ~ 35 parts, polyvinylpyrrolidone 1 ~ 10 part, polyether acrylate 10 ~ 20 parts, light trigger 2 ~ 8 parts, dispersion agent 1 ~ 5 part, defoamer 3 ~ 7 parts, pigment 2 ~ 6 parts, filler 5 ~ 15 parts.
Preferably, described modified epoxy is the mixture of one or more in acrylic modified epoxy resin, silane-modified epoxy resin, polyurethane modified epoxy resin.
Preferably, described light trigger is the mixture of one or more in benzophenone, 2,4 dihydroxyl benzophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones.
Preferably, described dispersion agent is the mixture of one or more in stearic acid, Sodium dodecylbenzene sulfonate, quaternary ammonium compound.
Preferably, described pigment is the mixture of one or more in monoazo, tetrazo, benzimidazolone.
Preferably, described filler is the mixture of one or more in calcium carbonate, talcum powder, wilkinite.
Beneficial effect of the present invention:
Compared with prior art, UV cured offset printing ink prepared by the present invention, curing speed is fast, good dispersity, cohesive force strong, is applicable to offset printing, and solvent-free volatilization, pollution-free, meet environmental requirement, be applicable to the print field such as food, drug packaging.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art and understand the present invention further, but not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, some distortion and improvement can also be made.These all belong to protection scope of the present invention.
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 20 ~ 30 parts, modified epoxy 25 ~ 35 parts, polyvinylpyrrolidone 1 ~ 10 part, polyether acrylate 10 ~ 20 parts, light trigger 2 ~ 8 parts, dispersion agent 1 ~ 5 part, defoamer 3 ~ 7 parts, pigment 2 ~ 6 parts, filler 5 ~ 15 parts.
UV cured offset printing ink prepared by the present invention, has the advantages such as environment-protecting asepsis, curing speed is fast, cohesive force is strong.
Embodiment 1
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 20 parts, acrylic modified epoxy resin 35 parts, polyvinylpyrrolidone 10 parts, polyether acrylate 10 parts, benzophenone 2 parts, stearic acid 5 parts, defoamer 3 parts, monoazo 6 parts, 5 parts, calcium carbonate.
Embodiment 2
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 30 parts, silane-modified epoxy resin 25 parts, polyvinylpyrrolidone 1 part, polyether acrylate 20 parts, 2,4 dihydroxyl benzophenone 8 parts, Sodium dodecylbenzene sulfonate 1 part, defoamer 7 parts, tetrazo 2 parts, talcum powder 15 parts.
Embodiment 3
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 25 parts, polyurethane modified epoxy resin 30 parts, polyvinylpyrrolidone 5 parts, polyether acrylate 15 parts, alpha-hydroxyalkyl benzophenone 5 parts, quaternary ammonium compound 3 parts, defoamer 6 parts, benzimidazolone 4 parts, wilkinite 10 parts.
Embodiment 4
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 22 parts, silane-modified epoxy resin 26 parts, polyvinylpyrrolidone 2 parts, polyether acrylate 12 parts, α-amine alkyl phenones 3 parts, Sodium dodecylbenzene sulfonate 2, defoamer 4 parts, tetrazo 3 parts, talcum powder 6 parts.
Embodiment 5
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 28 parts, polyurethane modified epoxy resin 33 parts, polyvinylpyrrolidone 9 parts, polyether acrylate 18 parts, alpha-hydroxyalkyl benzophenone 7 parts, quaternary ammonium compound 4 parts, defoamer 6 parts, benzimidazolone 5 parts, wilkinite 13 parts.
Embodiment 6
A kind of UV cured offset printing ink, meter comprises following component by weight: urethane acrylate 20 parts, acrylic modified epoxy resin 26 parts, polyvinylpyrrolidone 10 parts, polyether acrylate 15 parts, α-amine alkyl phenones 3 parts, stearic acid 3 parts, defoamer 7 parts, monoazo 4 parts, 12 parts, calcium carbonate.
Performance test
Basic mechanical design feature of the present invention is as shown in table 1:
Table 1
As seen from Table 1, UV cured offset printing ink prepared by the present invention, has the advantages such as environment-protecting asepsis, curing speed is fast, cohesive force is strong.
Above specific embodiments of the invention are described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (6)
1. a UV cured offset printing ink, it is characterized in that, meter comprises following component by weight: urethane acrylate 20 ~ 30 parts, modified epoxy 25 ~ 35 parts, polyvinylpyrrolidone 1 ~ 10 part, polyether acrylate 10 ~ 20 parts, light trigger 2 ~ 8 parts, dispersion agent 1 ~ 5 part, defoamer 3 ~ 7 parts, pigment 2 ~ 6 parts, filler 5 ~ 15 parts.
2. UV cured offset printing ink according to claim 1, is characterized in that: described modified epoxy is the mixture of one or more in acrylic modified epoxy resin, silane-modified epoxy resin, polyurethane modified epoxy resin.
3. UV cured offset printing ink according to claim 1, is characterized in that: described light trigger is the mixture of one or more in benzophenone, 2,4 dihydroxyl benzophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones.
4. UV cured offset printing ink according to claim 1, is characterized in that: described dispersion agent is the mixture of one or more in stearic acid, Sodium dodecylbenzene sulfonate, quaternary ammonium compound.
5. UV cured offset printing ink according to claim 1, is characterized in that: described pigment is the mixture of one or more in monoazo, tetrazo, benzimidazolone.
6. UV cured offset printing ink according to claim 1, is characterized in that: described filler is the mixture of one or more in calcium carbonate, talcum powder, wilkinite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510196438.6A CN104804526A (en) | 2015-04-22 | 2015-04-22 | UV curing adhesive printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510196438.6A CN104804526A (en) | 2015-04-22 | 2015-04-22 | UV curing adhesive printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104804526A true CN104804526A (en) | 2015-07-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510196438.6A Pending CN104804526A (en) | 2015-04-22 | 2015-04-22 | UV curing adhesive printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104804526A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106046921A (en) * | 2016-07-28 | 2016-10-26 | 南宁东印时代广告有限公司 | Printing ink and preparation method thereof |
| CN106147375A (en) * | 2016-07-28 | 2016-11-23 | 南宁东印时代广告有限公司 | A kind of ink and preparation method thereof |
| WO2017069729A1 (en) * | 2015-10-19 | 2017-04-27 | Hewlett-Packard Development Company, L.P. | Ultraviolet (uv) curable inkjet ink compositions |
| CN109466195A (en) * | 2018-11-26 | 2019-03-15 | 安徽同和包装制品有限公司 | A kind of environmental protection and energy saving packing box printing technology |
| CN109929321A (en) * | 2019-03-22 | 2019-06-25 | 广州益峰尖纸制品有限公司 | Offset litho printing ink and its preparation process |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642307A (en) * | 2013-11-19 | 2014-03-19 | 张家港市威迪森油墨有限公司 | Three-dimension printing ink |
-
2015
- 2015-04-22 CN CN201510196438.6A patent/CN104804526A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642307A (en) * | 2013-11-19 | 2014-03-19 | 张家港市威迪森油墨有限公司 | Three-dimension printing ink |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017069729A1 (en) * | 2015-10-19 | 2017-04-27 | Hewlett-Packard Development Company, L.P. | Ultraviolet (uv) curable inkjet ink compositions |
| US10590293B2 (en) | 2015-10-19 | 2020-03-17 | Hewlett-Packard Development Company, L.P. | Ultraviolet (UV) curable inkjet ink compositions |
| CN106046921A (en) * | 2016-07-28 | 2016-10-26 | 南宁东印时代广告有限公司 | Printing ink and preparation method thereof |
| CN106147375A (en) * | 2016-07-28 | 2016-11-23 | 南宁东印时代广告有限公司 | A kind of ink and preparation method thereof |
| CN109466195A (en) * | 2018-11-26 | 2019-03-15 | 安徽同和包装制品有限公司 | A kind of environmental protection and energy saving packing box printing technology |
| CN109929321A (en) * | 2019-03-22 | 2019-06-25 | 广州益峰尖纸制品有限公司 | Offset litho printing ink and its preparation process |
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Application publication date: 20150729 |
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