CN104789076A - Multifunctional anti-glaring transparent coating material as well as preparation method and application thereof - Google Patents
Multifunctional anti-glaring transparent coating material as well as preparation method and application thereof Download PDFInfo
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- CN104789076A CN104789076A CN201510175973.3A CN201510175973A CN104789076A CN 104789076 A CN104789076 A CN 104789076A CN 201510175973 A CN201510175973 A CN 201510175973A CN 104789076 A CN104789076 A CN 104789076A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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Abstract
The invention provides a multifunctional anti-glaring transparent coating material which is formed by mixing organic-inorganic hybrid resin and rare earth silicate fluorescence powder. The invention further provides a preparation method for the multifunctional anti-glaring transparent coating material. The multifunctional anti-glaring transparent coating material can be used for coating a screen protection film base material, and a transparent functionally gradient thin film can be quickly formed; the multifunctional anti-glaring transparent coating material is particularly applicable to a PET base material, can improve the hardness of the base material and the visible light transmittance, and further has the anti-fingerprint, fluorescent falsification-preventing, ultraviolet-resistant and anti-glaring functions.
Description
Technical field
The present invention relates to multi-functional anti-glare transparent coating material and its preparation method and application.
Background technology
Along with the raising gradually of people's living standard; the electric touch screen such as mobile phone, panel computer equipment is more and more universal; and the resolving power of electronic product is more and more higher; color is also distinct all the more true to nature, and screen size is comparatively large, and brings a lot " face " problem thus; drawn as easily scraped, mirror is anti-more obvious etc. has had a strong impact on the attractive in appearance of screen and has used; its screen protecting film arisen at the historic moment also emerges in an endless stream, and of a great variety, quality is uneven.
At present, the screen protector on market mainly contains PP material, PVC material and PET material three kinds.The pad pasting of PP material is softer, and visible light transmissivity is lower, and anti-scratch, anti-wear effect are poor, dust protection only, so substantially " forgotten " by human consumer now.PVC material pad pasting is soft but easily paste, but pad pasting itself is very thick, and therefore light transmission is general, and if pad pasting of tearing, mobile phone screen then can leave cull, be difficult to process.The pad pasting of PET material has higher light transmission, does not have cull after tearing, and is also not easy to occur the small bubbles in the middle of pad pasting; But, the hardness of this pad pasting is low, reflectance is high, user can be caused not see word on screen, even eyes can be injured, the illuminance of mobile phone screen itself is just very low under normal circumstances, stick the fatigue that one deck pad pasting can increase eyes, also easily leave the vestige such as fingerprint and oil stain from the teeth outwards simultaneously.Therefore, how improving the fastness to rubbing of display screen, transparence, anti-glare and uvioresistant performance, is coatings art technical problem in the urgent need to address.In addition, the counterfeit and shoddy goods on market are many, and harmful competition is unfavorable for the protection of product and develops further, and it is necessary for increasing product self anti-counterfeiting function.
Summary of the invention
The object of the present invention is to provide a kind of multi-functional anti-glare transparent coating material and preparation method thereof; this coated material can be coated on screen protector film base material; pass through ultra-violet curing; transparent gradient function film can be formed fast; be particularly useful in PET base material; base material hardness, visible light transmissivity can be improved, also there is anti-fingerprint, fluorescence falsification preventing, uvioresistant and anti-glare performance.
For achieving the above object, the invention provides a kind of multi-functional anti-glare transparent coating material, mixed by organic-inorganic hybrid resin and rare earth silicate fluorescent powder;
Described organic-inorganic hybrid resin is made up of organosilicon-acrylic copolymer and silanol hydrolyzate;
Consisting of of described rare earth silicate fluorescent powder:
The SiO of 60 ~ 80 weight parts
2,
The B of 5 ~ 15 weight parts
2o
3,
CaO and the BaO mixture of 3 ~ 10 weight parts,
The K of 12 ~ 20 weight parts
2o and Na
2o mixture,
The Yb of 0.01 ~ 0.1 weight part
2o
3,
The Er of 0.01 ~ 0.1 weight part
2o
3;
The grain diameter characteristic of described rare earth silicate fluorescent powder is 0.5 ~ 5 μm.
Preferably, described organic-inorganic hybrid resin is obtained by following component:
12 parts by weight of methylmethacrylate,
7 weight part γ-(methacryloxypropyl) propyl trimethoxy silicane (KH570 silane coupling agent),
25 parts by weight of ethanol solvents,
0.1 weight part benzoyl peroxide (BPO initiator),
The tetraethoxy that 28 weight parts are hydrolyzed in advance.
The present invention also provides a kind of preparation method of multi-functional anti-glare transparent coating material, comprises the steps:
1) 12 parts by weight of methylmethacrylate, 7 weight part γ-(methacryloxypropyl) propyl trimethoxy silicane (KH570 silane coupling agent), 25 parts by weight of ethanol solvents and 0.1 weight part benzoyl peroxide (BPO initiator) is got, add reactor to mix, in 60 ~ 80 DEG C of confined reactions 4 hours;
2) in reaction system, add tetraethoxy (TEOS) solution that 28 weight parts are hydrolyzed in advance, continue reaction 2 hours in 40 ~ 60 DEG C, obtained organic-inorganic hybrid resin;
3) in reaction system, rare earth silicate fluorescent powder is added again, Ball milling, obtained coated material;
Wherein,
The add-on of described rare earth silicate fluorescent powder is 1.0% ~ 10% of the weight of organic-inorganic hybrid resin;
Consisting of of described rare earth silicate fluorescent powder:
The SiO of 60 ~ 80 weight parts
2,
The B of 5 ~ 15 weight parts
2o
3,
CaO and the BaO mixture of 3 ~ 10 weight parts,
The K of 12 ~ 20 weight parts
2o and Na
2o mixture,
The Yb of 0.01 ~ 0.1 weight part
2o
3,
The Er of 0.01 ~ 0.1 weight part
2o
3;
The grain diameter characteristic of described rare earth silicate fluorescent powder is 0.5 ~ 5 μm.
The present invention also provides the application of above-mentioned multi-functional anti-glare transparent coating material, by coating material application on screen protector film base material, base material solidify to form transparent gradient function film.
Preferably, the build of described coated material is 5 ~ 10 μm.
Preferably, the mode of described coating is the coating of line rod, and the mode of described solidification is ultra-violet curing, and described base material is PET section.
Advantage of the present invention and beneficial effect are: provide a kind of multi-functional anti-glare transparent coating material and preparation method thereof; this coated material can be coated on screen protector film base material; pass through ultra-violet curing; transparent gradient function film can be formed fast; be particularly useful in PET base material; base material hardness, visible light transmissivity can be improved, also there is anti-fingerprint, fluorescence falsification preventing, uvioresistant and anti-glare performance.
Rare earth silicate fluorescent powder in coated material of the present invention comprises inorganic spherical particle fillers (as SiO
2, B
2o
3deng), the particle diameter of ball packing is 0.5 ~ 5 μm, and through Ball milling, the film formed after coated material is solidified, visible light transmissivity can reach 91%, and the blank sample of the anti-numeric ratio of mirror declines about 5%, has anti-glare performance.
Rare earth silicate fluorescent powder in coated material of the present invention comprises fluorescence falsification preventing material (as Yb
2o
3, Er
2o
3deng), the film formed after coated material is solidified, both can absorb ultraviolet, can send visible ray again under infrared ray excited, can not only play fluorescence falsification preventing, uvioresistant effect, human body can also be protected with radioprotective.
The film formed after coated material solidification of the present invention, water contact angle is 92 °, and visible light transmissivity is 91%, under the good prerequisite of guarantee film transparence, improves the anti-fingerprint performance of film.
The film formed after coated material solidification of the present invention, have the hardness of 4H, anti-zoned ability is strong, has stronger screen protection ability.
Accompanying drawing explanation
Fig. 1 is visible light transmissivity collection of illustrative plates;
Fig. 2 is specular reflectance collection of illustrative plates.
Embodiment
Below in conjunction with drawings and Examples, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
The technical scheme that the present invention specifically implements is:
The invention provides a kind of multi-functional anti-glare transparent coating material, mixed by organic-inorganic hybrid resin and rare earth silicate fluorescent powder;
Described organic-inorganic hybrid resin is made up of organosilicon-acrylic copolymer and silanol hydrolyzate;
Consisting of of described rare earth silicate fluorescent powder:
The SiO of 60 ~ 80 weight parts
2,
The B of 5 ~ 15 weight parts
2o
3,
CaO and the BaO mixture of 3 ~ 10 weight parts,
The K of 12 ~ 20 weight parts
2o and Na
2o mixture,
The Yb of 0.01 ~ 0.1 weight part
2o
3,
The Er of 0.01 ~ 0.1 weight part
2o
3;
The grain diameter characteristic of described rare earth silicate fluorescent powder is 0.5 ~ 5 μm;
Described organic-inorganic hybrid resin is obtained by following component:
12 parts by weight of methylmethacrylate,
7 weight part γ-(methacryloxypropyl) propyl trimethoxy silicane (KH570 silane coupling agent),
25 parts by weight of ethanol solvents,
0.1 weight part benzoyl peroxide (BPO initiator),
The tetraethoxy that 28 weight parts are hydrolyzed in advance.
The present invention also provides a kind of preparation method of multi-functional anti-glare transparent coating material, comprises the steps:
1) 12 parts by weight of methylmethacrylate, 7 weight part γ-(methacryloxypropyl) propyl trimethoxy silicane (KH570 silane coupling agent), 25 parts by weight of ethanol solvents and 0.1 weight part benzoyl peroxide (BPO initiator) is got, add reactor to mix, in 60 ~ 80 DEG C of confined reactions 4 hours;
2) in reaction system, add tetraethoxy (TEOS) solution that 28 weight parts are hydrolyzed in advance, continue reaction 2 hours in 40 ~ 60 DEG C, obtained organic-inorganic hybrid resin;
3) in reaction system, rare earth silicate fluorescent powder is added again, Ball milling, obtained coated material;
Wherein,
The add-on of described rare earth silicate fluorescent powder is 1.0% ~ 10% of the weight of organic-inorganic hybrid resin;
Consisting of of described rare earth silicate fluorescent powder:
The SiO of 60 ~ 80 weight parts
2,
The B of 5 ~ 15 weight parts
2o
3,
CaO and the BaO mixture of 3 ~ 10 weight parts,
The K of 12 ~ 20 weight parts
2o and Na
2o mixture,
The Yb of 0.01 ~ 0.1 weight part
2o
3,
The Er of 0.01 ~ 0.1 weight part
2o
3;
The grain diameter characteristic of described rare earth silicate fluorescent powder is 0.5 ~ 5 μm.
In a preferred embodiment, the consisting of of described rare earth silicate fluorescent powder:
The SiO of 60 weight parts
2,
The B of 5 weight parts
2o
3,
CaO and the BaO mixture of 3 weight parts,
The K of 12 weight parts
2o and Na
2o mixture,
The Yb of 0.01 weight part
2o
3,
The Er of 0.01 weight part
2o
3.
In another preferred embodiment, the consisting of of described rare earth silicate fluorescent powder:
The SiO of 80 weight parts
2,
The B of 15 weight parts
2o
3,
CaO and the BaO mixture of 10 weight parts,
The K of 20 weight parts
2o and Na
2o mixture,
The Yb of 0.1 weight part
2o
3,
The Er of 0.1 weight part
2o
3.
In yet another preferred embodiment, the consisting of of described rare earth silicate fluorescent powder:
The SiO of 70 weight parts
2,
The B of 10 weight parts
2o
3,
CaO and the BaO mixture of 7 weight parts,
The K of 16 weight parts
2o and Na
2o mixture,
The Yb of 0.05 weight part
2o
3,
The Er of 0.05 weight part
2o
3.
Coating material application of the present invention (coating method can be the coating of line rod) is in screen protector PET base material; pass through ultra-violet curing; the gradient function film that quick formation is transparent; build is 5 ~ 10 μm; base material hardness, visible light transmissivity can be improved, also there is anti-fingerprint, fluorescence falsification preventing, uvioresistant and anti-glare performance.
The visible light transmissivity collection of illustrative plates of screen protector and common PET screen protector that Tu is covered with coated material of the present invention contrasts as shown in Figure 1, and in figure, A is the screen protector that Tu is covered with coated material of the present invention, and B is common PET screen protector.
The specular reflectance collection of illustrative plates of screen protector and common PET screen protector that Tu is covered with coated material of the present invention contrasts as shown in Figure 2, and in figure, A is the screen protector that Tu is covered with coated material of the present invention, and B is common PET screen protector.
The water contact angle of common PET screen protector is 79.5 °, and the water contact angle that Tu is covered with the screen protector of coated material of the present invention is 92 °.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (6)
1. multi-functional anti-glare transparent coating material, is characterized in that, is mixed by organic-inorganic hybrid resin and rare earth silicate fluorescent powder;
Described organic-inorganic hybrid resin is made up of organosilicon-acrylic copolymer and silanol hydrolyzate;
Consisting of of described rare earth silicate fluorescent powder:
The SiO of 60 ~ 80 weight parts
2,
The B of 5 ~ 15 weight parts
2o
3,
CaO and the BaO mixture of 3 ~ 10 weight parts,
The K of 12 ~ 20 weight parts
2o and Na
2o mixture,
The Yb of 0.01 ~ 0.1 weight part
2o
3,
The Er of 0.01 ~ 0.1 weight part
2o
3;
The grain diameter characteristic of described rare earth silicate fluorescent powder is 0.5 ~ 5 μm.
2. multi-functional anti-glare transparent coating material according to claim 1, it is characterized in that, described organic-inorganic hybrid resin is obtained by following component:
12 parts by weight of methylmethacrylate,
7 weight part γ-(methacryloxypropyl) propyl trimethoxy silicane,
25 parts by weight of ethanol solvents,
0.1 weight part benzoyl peroxide,
The tetraethoxy that 28 weight parts are hydrolyzed in advance.
3. the preparation method of multi-functional anti-glare transparent coating material, is characterized in that, comprise the steps:
1) 12 parts by weight of methylmethacrylate, 7 weight part γ-(methacryloxypropyl) propyl trimethoxy silicane, 25 parts by weight of ethanol solvents and 0.1 weight part benzoyl peroxide is got, add reactor to mix, in 60 ~ 80 DEG C of confined reactions 4 hours;
2) in reaction system, add the teos solution that 28 weight parts are hydrolyzed in advance, continue reaction 2 hours in 40 ~ 60 DEG C, obtained organic-inorganic hybrid resin;
3) in reaction system, rare earth silicate fluorescent powder is added again, Ball milling, obtained coated material;
Wherein,
The add-on of described rare earth silicate fluorescent powder is 1.0% ~ 10% of the weight of organic-inorganic hybrid resin;
Consisting of of described rare earth silicate fluorescent powder:
The SiO of 60 ~ 80 weight parts
2,
The B of 5 ~ 15 weight parts
2o
3,
CaO and the BaO mixture of 3 ~ 10 weight parts,
The K of 12 ~ 20 weight parts
2o and Na
2o mixture,
The Yb of 0.01 ~ 0.1 weight part
2o
3,
The Er of 0.01 ~ 0.1 weight part
2o
3;
The grain diameter characteristic of described rare earth silicate fluorescent powder is 0.5 ~ 5 μm.
4. the application of the multi-functional anti-glare transparent coating material according to any one of claim 1-3, is characterized in that, by coating material application on screen protector film base material, base material solidify to form transparent gradient function film.
5. the application of multi-functional anti-glare transparent coating material according to claim 4, is characterized in that, the build of described coated material is 5 ~ 10 μm.
6. the application of multi-functional anti-glare transparent coating material according to claim 5, is characterized in that, the mode of described coating is the coating of line rod, and the mode of described solidification is ultra-violet curing, and described base material is PET section.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113409678A (en) * | 2021-07-23 | 2021-09-17 | 上海东蕴实业有限公司 | Novel fluorescent label material |
Citations (5)
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---|---|---|---|---|
CN86101410A (en) * | 1985-04-01 | 1986-10-15 | Ppg工业公司 | Non-glare coated glass |
CN1634784A (en) * | 2003-12-31 | 2005-07-06 | 中国科学院西安光学精密机械研究所 | Erbium Ytterbium codoped multi-component oxide glass monomode fiber core glass and method for preparing monomode fiber |
CN101299073A (en) * | 2008-07-02 | 2008-11-05 | 中国乐凯胶片集团公司 | Anti-fouling anti-dazzle film |
CN101362917A (en) * | 2008-09-19 | 2009-02-11 | 浙江大学 | Organic/inorganic hybrid nanometer porous anti-reflection coating |
CN102548922A (en) * | 2009-09-15 | 2012-07-04 | 康宁股份有限公司 | Glass and display having anti-glare properties |
-
2015
- 2015-04-15 CN CN201510175973.3A patent/CN104789076A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN86101410A (en) * | 1985-04-01 | 1986-10-15 | Ppg工业公司 | Non-glare coated glass |
CN1634784A (en) * | 2003-12-31 | 2005-07-06 | 中国科学院西安光学精密机械研究所 | Erbium Ytterbium codoped multi-component oxide glass monomode fiber core glass and method for preparing monomode fiber |
CN101299073A (en) * | 2008-07-02 | 2008-11-05 | 中国乐凯胶片集团公司 | Anti-fouling anti-dazzle film |
CN101362917A (en) * | 2008-09-19 | 2009-02-11 | 浙江大学 | Organic/inorganic hybrid nanometer porous anti-reflection coating |
CN102548922A (en) * | 2009-09-15 | 2012-07-04 | 康宁股份有限公司 | Glass and display having anti-glare properties |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113409678A (en) * | 2021-07-23 | 2021-09-17 | 上海东蕴实业有限公司 | Novel fluorescent label material |
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