CN104788995A - Dispersed royal blue dye composition, dye product and application of dye product - Google Patents
Dispersed royal blue dye composition, dye product and application of dye product Download PDFInfo
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- CN104788995A CN104788995A CN201510114169.4A CN201510114169A CN104788995A CN 104788995 A CN104788995 A CN 104788995A CN 201510114169 A CN201510114169 A CN 201510114169A CN 104788995 A CN104788995 A CN 104788995A
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- sapphire blue
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Abstract
The invention discloses a dispersed royal blue dye composition, a dye product and an application of the dye product. The dispersed royal blue dye composition comprises 1-99mass% of a component A and 1-99mass% of a component B, wherein the component A is selected from a dye monomer compound with the structure represented by formula (I), and the component B is a dye monomer compound with the structure represented by formula (II). The dispersed royal blue dye product mainly contains the dispersed royal blue dye composition in claim 1 and an assistant according to a weight ratio of the assistant to the dispersed dye composition of 0.2-5:1. When the dispersed royal blue dye product is applied in printing and dyeing of hydrophobic fibrous materials especially terylene-spandex blend fabrics, various fastnesses are excellent, and especially the washing fastness is prominent.
Description
Technical field
The invention belongs to dispersed dye preparation field, particularly relate to and be a kind ofly suitable for the hydrophobic fiber material especially sapphire blue dye composite of dispersion of terylene and blended fabric dyeing and stamp and goods thereof.
Background technology
" three is high " staining technique is all emphasis of research to all kinds of textile product, comprises current mass-produced polyester/cellulosic fibre polycomponent product, so-called " three is high " staining technique, i.e. high colour-fast rate, high enhancing and high color fastness.The dark heavy colour dyestuff high for lifting force often causes fastness to decline for reducing thermophoresis phenomenon, nowadays for the dispersed dye that the various performance of exploitation is more excellent adopt dispersed dye compound synergic technology usually.
Summary of the invention
For solving the problem, the invention provides and a kind ofly disperse sapphire blue dye composite, the sapphire blue dye preparations of dispersion obtained by said composition and application thereof, the sapphire blue dye preparations of this dispersion, be applied to hydrophobic fiber material particularly polyester fibre/spandex BLENDED FABRIC printing and dyeing time, every fastness is excellent, and particularly washing fastness is given prominence to.
The technical solution used in the present invention is:
Disperse sapphire blue dye composite, comprise component A and B component, wherein component A is for structure is such as formula the dye monomer compound shown in (I), B component is for structure is such as formula the dye monomer compound shown in (II), based on described component A and B component, the massfraction of component A is 1 ~ 99%, and the massfraction of B component is 1 ~ 99%;
Further, the sapphire blue dye composite of dispersion of the present invention, is made up of component A and B component, and based on described component A and B component, the massfraction of component A is 1 ~ 99%, and preferred 30-99%, is more preferably 55-95%; The massfraction of B component is 1 ~ 99%, and preferred 1-70%, is more preferably 5-45%.
Disperse sapphire blue dye preparations, it is mainly containing, for example the sapphire blue dye composite of the dispersion described in claim l and auxiliary agent, and the ratio of the weight of auxiliary agent and disperse dye composition is 0.2 ~ 5:1.
Described auxiliary agent is selected from one of following or wherein two or more mixtures: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalene sulfonic acidformaldehyde condensation product, benzyl naphthalene sulfonic formaldehyde condensation compound, sodium lignosulfonate.
The sapphire blue dye preparations of described dispersion is that the sapphire blue dye composite of dispersion of 1:0.2 ~ 5 and auxiliary agent form by weight ratio, sapphire blue dye composite is wherein disperseed to be made up of component A and B component, based on component A and B component, the mass percentage of component A is 30 ~ 99%, and the mass percentage of B component is 1 ~ 70%.
The preparation method of the sapphire blue dye preparations of dispersion of the present invention is as follows: by the dye monomer compound (former dyestuff) represented by component A and B component by after the mixing of above-mentioned proportioning, under the existence of auxiliary agent, water or other wetting agent, carry out corpusculed with the pulverizer such as sand mill or shredder; Also mix with above-mentioned ratio after the dye monomer compound represented by component A and B component can being carried out corpusculed process with the pulverizer such as sand mill or shredder respectively under the existence of auxiliary agent, water or other wetting agent in addition.The sapphire blue dye composite of dispersion of the present invention, aqueous with can be after sand mill or shredder grinding, can be powdery, particulate state after spraying dry.This well known to a person skilled in the art preparation method.
Formula of the present invention (I), the former dyestuff shown in formula (II), can adopt mode well known in the art to synthesize, and also can adopt commercially available prod (C.I.DISPERSE BLUE354, C.I.DISPERSE BLUE367).
Present invention also offers the sapphire blue dye preparations of described dispersion hydrophobic fiber material especially wash/spandex dyeing in application.
The sapphire blue dye preparations of dispersion that the sapphire blue dye composite of dispersion of the present invention is made, particularly wash/dyeing of spandex and stamp for hydrophobic material fiber, coloured light is gorgeous, and synchronous dye uptake is good, and lifting force is good, is applicable to deep colour dyeing, and washing fastness is given prominence to.
Specific embodiments
Below in conjunction with specific embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
Embodiment 1-15
According to continuous data shown in following table l, by former dyestuff, the auxiliary agent of the dispersed dye shown in formula (I), (II), add water fully mixing, carries out grinding distribution, then carry out drying, obtain disperseing sapphire blue dye preparations with sand mill.
Table l unit: (gram)
Comparative example l ~ 4:
By the l as a comparison case of embodiment 4 disclosed in CN103740136A.
By EXAMPLE l disclosed in CN103408968A, embodiment 4 as a comparison case 2,3;
By EXAMPLE l disclosed in CN102732061A as a comparison case 4.
Dyeing Example 16:
Take the dispersed dye goods of 1.5 grams of embodiment 1-15, comparative example l ~ 4, be dispersed in 500 ml waters separately, mix with the water of 60 milliliters after drawing 20 milliliters, pH to 4.5 is adjusted with acetic acid, put people's 2 grams of polyester fibre/spandex fabrics, be warming up to 70 DEG C, continue with about 2 DEG C/min gradient increased temperature to 130 DEG C, insulation dyeing 45 minutes.Then be cooled to about 80 DEG C and use hot water wash 10min, dry; Employing standard ISO 105-X12, AATCC61-2A, ISO105-P01 test its rub resistance, water-fastness, color fastness to sublimation respectively, the results are shown in Table 2.
Table 2 unit: level
Test result shows: sapphire blue dispersion dye product application provided by the invention is in water-repellent fabrics, and particularly during polyester fibre/spandex BLENDED FABRIC, every fastness properties is excellent, is suitable as high-grade dyestuff.
Claims (7)
1. the sapphire blue dye composite of dispersion, it is characterized in that: comprise component A and B component, wherein component A is for structure is such as formula the dye monomer compound shown in (I), B component is for structure is such as formula the dye monomer compound shown in (II), based on described component A and B component, the massfraction of component A is 1 ~ 99%, and the massfraction of B component is 1 ~ 99%;
2. the sapphire blue dye composite of the dispersion according to claim l, it is characterized in that: the sapphire blue dye composite of described dispersion is made up of component A and B component, based on described component A and B component, the massfraction of component A is 30-99%, and the massfraction of B component is 1-70%.
3. the sapphire blue dye composite of dispersion according to claim 1 and 2, is characterized in that: the massfraction of component A is 55-95%, and the massfraction of B component is 5-45%.
4. disperse a sapphire blue dye preparations, it is characterized in that: it is mainly containing, for example the sapphire blue dye composite of the dispersion described in claim l and auxiliary agent, and the ratio of the weight of auxiliary agent and disperse dye composition is 0.2 ~ 5:1.
5. the sapphire blue dye preparations of dispersion according to claim 4, is characterized in that: described auxiliary agent is selected from one of following or wherein two or more mixtures: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalene sulfonic acidformaldehyde condensation product, benzyl naphthalene sulfonic formaldehyde condensation compound, sodium lignosulfonate.
6. the sapphire blue dye preparations of dispersion according to claim 5, it is characterized in that: the sapphire blue dye preparations of described dispersion is that the sapphire blue dye composite of dispersion of 1:0.2 ~ 5 and auxiliary agent form by weight ratio, sapphire blue dye composite is wherein disperseed to be made up of component A and B component, based on component A and B component, the mass percentage of component A is 30 ~ 99%, and the mass percentage of B component is 1 ~ 70%.
7. the application of the sapphire blue dye preparations of dispersion as claimed in claim 4 in hydrophobic fiber material printing and dyeing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510114169.4A CN104788995B (en) | 2015-03-16 | 2015-03-16 | Dispersed royal blue dye composition, dye product and application of dye product |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510114169.4A CN104788995B (en) | 2015-03-16 | 2015-03-16 | Dispersed royal blue dye composition, dye product and application of dye product |
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| CN104788995A true CN104788995A (en) | 2015-07-22 |
| CN104788995B CN104788995B (en) | 2017-05-24 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| US5591833A (en) * | 1990-06-28 | 1997-01-07 | Milliken Research Corporation | Colorants and intermediates therefor having branched poly(oxyalkylene)moieties, and their manufacture |
| WO2009013122A2 (en) * | 2007-07-20 | 2009-01-29 | Huntsman Advanced Materials (Switzerland) Gmbh | Azo dyes |
| CN102952415A (en) * | 2012-11-02 | 2013-03-06 | 杭州福莱蒽特精细化工有限公司 | Composite sapphire blue dispersion dye |
| CN104119697A (en) * | 2014-06-30 | 2014-10-29 | 浙江龙盛集团股份有限公司 | Disperse sapphire blue dye composition, dye product and application of dye product |
-
2015
- 2015-03-16 CN CN201510114169.4A patent/CN104788995B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5591833A (en) * | 1990-06-28 | 1997-01-07 | Milliken Research Corporation | Colorants and intermediates therefor having branched poly(oxyalkylene)moieties, and their manufacture |
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| WO2009013122A2 (en) * | 2007-07-20 | 2009-01-29 | Huntsman Advanced Materials (Switzerland) Gmbh | Azo dyes |
| CN102952415A (en) * | 2012-11-02 | 2013-03-06 | 杭州福莱蒽特精细化工有限公司 | Composite sapphire blue dispersion dye |
| CN104119697A (en) * | 2014-06-30 | 2014-10-29 | 浙江龙盛集团股份有限公司 | Disperse sapphire blue dye composition, dye product and application of dye product |
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| CN104788995B (en) | 2017-05-24 |
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