CN104783412A - Resin fastener with reflecting colorful effect and manufacturing method - Google Patents
Resin fastener with reflecting colorful effect and manufacturing method Download PDFInfo
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- CN104783412A CN104783412A CN201510221185.3A CN201510221185A CN104783412A CN 104783412 A CN104783412 A CN 104783412A CN 201510221185 A CN201510221185 A CN 201510221185A CN 104783412 A CN104783412 A CN 104783412A
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- button
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Abstract
The invention discloses a resin fastener with the reflecting colorful effect and a manufacturing method. The base material of the fastener is an unsaturated polyester resin material, and a vacuum electroplated layer with the reflecting colorful effect is attached to the surface of the fastener through the total vacuum electroplating technology. According to the manufacturing method, a specific metal material is motivated through strong current ions through a vacuum electroplating machine, and the metal material is freely scattered and deposited on the surface of the fastener. The unsaturated resin serves as the base material to make the resin fastener, the metal material and the photosensitive material are attached to the fastener according to a certain technology through vacuum coating equipment, and the surface of the fastener has the special reflecting colorful effect.
Description
Technical field
The present invention discloses a kind of resin button and preparation method thereof, particularly a kind of resin button and preparation method with reflective seven color effects.
Background technology
Resin button is thing common during people live, often be used to the fastening of clothes, along with making rapid progress of Garment Industry, it requires that button surface has more change, particularly the doing things creatively of gloss and color aspect, carrys out the demand of satisfied different characteristic clothes.Because the resin button glossiness of traditional material is inadequate, and color effects is more single, and when processing vacuum plating, due to the restriction of the series of problems such as pre-treatment, fixture, button process of surface treatment well can not be combined with vacuum seven colour TV depositing process and produce the stable resin button with reflective seven color effects.
How developing one can steady production, the button with reflective seven color effects can be met again, can meet again simultaneously and use prerequisite Functional Requirement on clothes, as the button preparation method that Washing, dry-cleaning color fastness and steam ironing etc. require, become problem demanding prompt solution in industry.
Summary of the invention
Not there is for the above-mentioned button of the prior art mentioned the shortcoming of reflective seven color effects, the invention provides a kind of new resin button with reflective seven color effects and preparation method, it adopts specific unsaturated polyester resin as base material, through button surface Hardening Treatment, button surface is made to have the vacuum electric coating of reflective seven color effects by the attachment of vacuum coating process, preparation method is for making it freely disperse through strong ion excitation specific metal material by vacuum coating machine and being attached to button surface, thus make the button produced have reflective seven color effects.
The technical scheme that the present invention solves the employing of its technical problem is: a kind of button with metal reflective seven color effect, button base material adopt account for percentage by weight be 97%-98% unsaturated polyester resin and account for the decentralized pigment that percentage by weight is 2%-3%, button substrate surface is provided with the coat of metal, is provided with optical film outside the coat of metal.
Have a preparation method for the button of metal reflective seven color effect described above, method comprises the steps:
(1) plated film pre-treatment is carried out to button substrate surface;
(2) to the process of button overlay coating, comprising:
A, carry out the bottoming of Vacuum Deposition zirconium metal level;
B, the color rete of Vacuum Deposition seven is carried out to button surface.
The technical scheme that the present invention solves the employing of its technical problem further comprises:
Described zirconium metal layer thickness is 25 μm ~ 35 μm;
The described color thicknesses of layers of vacuum seven is 35 μm ~ 55 μm.
Described plated film pre-treatment comprises following step:
(1), ultrasonic washing, in supersonic wave cleaning machine, add organic cleaning solvent, Ultrasonic Cleaning carried out 30 minutes to it;
(2), surface Hardening Treatment, by surface clean totally and the FC-320 forced fluid of the button of drying after dust-free workshop spraying dilution, place after 10 minutes after spraying evenly, put into baking oven, design temperature 120 DEG C, toast 150 minutes, naturally cool to room temperature.
FC-320 forced fluid after described dilution adopts the forced fluid of FC-320 to mix rear formation with industrial grade ethanol by 1:4.
The invention has the beneficial effects as follows: the present invention adopts unsaturated polyester resin button, select special pre-treating technology, use rational button coating clamp and the color filming equipment of specific vacuum seven, make button surface by the attached obtained resin button with reflective seven color effects of vacuum electroplating technology.
Detailed description of the invention
The present embodiment is the preferred embodiment for the present invention, and other its principles all are identical with the present embodiment or approximate with basic structure, all within scope.
The present invention mainly protects a kind of resin button with reflective seven color effects, the base material of resin button comprise account for percentage by weight be 97% ~ 98% unsaturated polyester resin (supplier is Zhejiang Milky Way resin Co., Ltd, unsaturated polyester resin model is 988 resins) and account for decentralized pigment (the Guangzhou Pan Yang Chemical Co., Ltd. that percentage by weight is 2% ~ 3%, pigment model: R-930, D-195, DR-0191, TR-187), button substrate surface is provided with the coat of metal, the thickness of the coat of metal is 25 μm ~ 35 μm, optical film is provided with outside the coat of metal, thicknesses of layers is 35 μm ~ 55 μm.
The present invention protects a kind of preparation method of resin button simultaneously, specifically comprises the steps:
1, carry out pre-treating technology to resin button substrate surface, in the present embodiment, pre-treatment mainly comprises Ultrasonic Cleaning and coating intensive treatment two parts, and concrete operation step is as follows:
(1) Ultrasonic Cleaning, in the present embodiment, the model that Ultrasonic Cleaning machine adopts Shenzhen Jun Chida ultrasonic equipment Co., Ltd to produce is JCD-1024 single groove ultrasonic cleaning machine, ultrasonic cleaning agent is the model that Dongguan City Xin Wei trade Co., Ltd produces is RC1120 organic cleaning solvent, during cleaning, button base material is placed in cleaning machine, Ultrasonic Cleaning is carried out 30 minutes (± 5 minutes) to it.
(2) clear water washes twice, first time water rinse employing city water rinse 1 minute, second time rinsing adopts pure water, and (pure water is also known as deionized water, the water referring to meet standards for drinking water quality is former water, by electric dialyzator method, ion-exchanger method, hyperfiltration, the way of distillation and other suitable processing methods, obtained is sealed in container, and not containing any additive, water white transparency, water capable of direct drinking, also pure substance (chemically) can be called, use in test more, again because being the method such as to distill to make, therefore also known as distilled water) rinsing 1 minute.
(3) dehydration and oven dry, its main method of operating: the button of rinsed clean is put into dewaterer and dewater two minutes, remains without water droplet to button surface, and then button is put into baking oven, adopt 60 DEG C (± 5 DEG C) air-dry 30 ~ 50 minutes.
(4) surface Hardening Treatment, by the button that surface clean is totally also dried, smooth is placed on web plate (length of half tone and wide about 80cm, mesh aperture on web plate about 0.4 ~ 0.6cm, Mesh distance is 0.1cm) on, spacing 0.5cm put by button, FC-320 forced fluid (mix by 1:3-1:4 with industrial grade ethanol with the forced fluid that the model that Van Gogh, Shenzhen Chemical Industry Science Co., Ltd produces is FC-320, after mixing, density is about 0.84g/l) after dust-free workshop spraying dilution.Place after 10 ~ 15 minutes after spraying evenly, put into baking oven, design temperature 120 DEG C ± 1 DEG C, toast 150 minutes ± 5 minutes, naturally cool to room temperature, observe button surface whether light and with or without dirty point, as being then certified products without bright and dirty point.
2, the color plated film of vacuum seven is carried out to the resin button after pre-treatment, the main operating procedure of the color plated film of vacuum seven comprises the metal level bottoming of Vacuum Deposition zirconium and the color rete two parts of Vacuum Deposition seven, and concrete operation step is as follows:
(1), start shooting, cool cycles hydraulic pressure is shown as 0.3Pa, and air pressure inside is shown as 0.6Pa, and diffusion pump temperature is adjusted to 185 DEG C.
(2), vacuumize, open workpiece plate, voltage is adjusted to 30V, vacuum meter is set as 7.0 × 10
-2pa.
(3), melt, when vacuum reaches 1.5 × 10
-2during Pa, J3 indicator lamp is bright, and when occurring reporting to the police for 3 times, clicks and start melt (adopting Beijing Zhong Jinyan Science and Technology Ltd., high-purity zirconium and high purity titanium silicon alloy, purity 4N-5N);
(4), at the bottom of plating zirconium, vacuum reaches setting value 7.0 × 10
-2pa, opens high pressure 9KV, and when adjustment electric current is to 100A, manual adjustments facula position, makes hot spot cover the product needing plated film completely.Strengthen to send a telegraph again and flow to 300A, click and start plated film, continuous firing stops for 5 minutes, completes the bottoming of zirconium metal level.Thickness of coating is at 25 μm ~ 35 μm.
(5) seven color effect retes, are plated, work rest speed setting is 30r/min, regulates current strength scope at 200-350A, excites titanium silicon mixed material, produce the particle of 400-650nm wavelength, the higher wavelength exciting raw material to produce of current strength is larger, different according to wavelength, and (450nm is blue to the color different colours particle of formation, 520nm is yellow green, 560nm is orange, and 630nm is red), click and start plated film.
(6), regulation depth, different according to required color depth, continuous vacuum plated film 1 ~ 1.5 hour, the time, longer color was darker, and color situation of change inside observing by external clear glass window, reach the color of needs, thicknesses of layers is at 35 μm ~ 55 μm.
(7), cooling shut down, when color reaches the color of needs, release vacuum, closes excitation current, when temperature is down to room temperature, takes out the button after plated film and carries out color and to judge and physicochemical property is tested.
In the present invention, carrying out to button the equipment that plated film uses is vertical vacuum electroplating machine, and supplier is Zhenhua vacuum machine Co., Ltd, model: GX-1350A optical coating system.
In the present invention, the resin button produced not only has reflective seven color color changeable effects, by physical properties tests such as the dry-cleaning of the professional standards such as ISO, AATCC, GB, 3 special washings, steam ironings, and every green technology requirement to be met especially.Compared with the color coating process of conventional vacuum seven, not only there is very big breakthrough brightness and color and luster aspect, and physical test has very large lifting, and three special washings and dry-cleaning are not faded nondiscolouring.The present invention mainly contains following adjustment to the pre-treatment of vacuum seven color plated film:
1, whole process all operates at dust-free workshop;
2, special Ultrasonic Cleaning is done to button surface and dispel greasy dirt;
3, coating surface intensive treatment (surface spraying FC-320 forced fluid also toasts 90 minutes at 120 DEG C) is increased to the adhesive force of vacuum coating;
4, customize special coating clamp, fix for all size button;
5, plating zirconium layer bottoming, 7.0 × 10
-2under Pa vacuum, setting 9KV high pressure, when adjustment electric current is to 100A, manual adjustments facula position, makes hot spot cover completely and needs coated product, then increasing is sent a telegraph and flow to 300A, and continuous firing completes the bottoming of zirconium metal level for 5 minutes.
6, regulate plated film current strength (between 200-350A), excite titanium silicon mixed material, produce the particle of 400-650nm wavelength, be attached to button surface and produce blue, yellowish green, orange, that redness four kinds is different color.
The button that the present invention produces has reflective seven color effects, can also meet the physical and chemical property test of each side simultaneously, have wide market prospects, meet development and the environmental requirement of apparel industry.
Claims (5)
1. there is a button for metal reflective seven color effect, it is characterized in that: described button base material comprises the decentralized pigment of 97%-98% unsaturated polyester resin and 2%-3%, and button surface is provided with the coat of metal, is provided with optical film outside the coat of metal.
2. the button with metal reflective seven color effect according to claim 1, is characterized in that: described metal layer thickness is between 25 μm ~ 35 μm.
3. there is a preparation method for the button of metal reflective seven color effect as claimed in claim 1 or 2, it is characterized in that: described method comprises the steps:
(1) intensive treatment before plated film is carried out to button surface;
(2) bottoming of Vacuum Deposition zirconium metal level is carried out to button surface;
(3) the color rete of Vacuum Deposition seven is carried out to button surface.
4. preparation method according to claim 3, is characterized in that: described plated film pre-treatment comprises following two steps:
(1) ultrasonic washing, dispels button surface solid particle and greasy dirt, adds cleaning agent in ultrasonic container, washs 30 minutes, and with clear water rinsing 2 times, puts into baking box 60 DEG C of low-temperature air-dryings;
(2) button surface Hardening Treatment, strengthen the adhesion on coating and button surface, adopt the forced fluid FC-320 of Van Gogh chemical engineering of materials Co., Ltd, be diluted to density 0.84g/l with industrial alcohol, button surface is sprayed on, 120 DEG C of oven for baking 150 minutes under dustfree environment.
5. preparation method according to claim 3, is characterized in that: the described color film of Vacuum Deposition seven comprises following steps:
(1), start shooting, cool cycles hydraulic pressure is shown as 0.3Pa, and air pressure inside is shown as 0.6Pa, and diffusion pump temperature is adjusted to 185 DEG C;
(2), open workpiece plate and be adjusted to 30V, vacuum meter is set as 7.0*10-2Pa;
(3), when vacuum is extracted into 1.5*10-2Pa, J3 indicator lamp lamp is bright, and reports to the police 3 times, can start melt;
(4), vacuum reaches 7.0*10-2Pa, and to opening high pressure 9KV, when being 100A to electric current, manual adjustments facula position, makes hot spot cover the product needing plated film completely, and high current, to 300A, starts at the bottom of continuous firing 5 minutes plating zirconiums;
(5), setting work rest rotating speed is 30r/min, regulates current strength (200-350A) to excite titanium, silicon raw material, produces the particle of 400-650nm wavelength, different according to wavelength, (450nm is blue to the color difference of formation, and 520nm is yellow green, 560nm is orange, and 630nm is red)
(6) different according to required color depth, continuous vacuum plated film 1-1.5 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510221185.3A CN104783412A (en) | 2015-04-30 | 2015-04-30 | Resin fastener with reflecting colorful effect and manufacturing method |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510221185.3A CN104783412A (en) | 2015-04-30 | 2015-04-30 | Resin fastener with reflecting colorful effect and manufacturing method |
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| CN104783412A true CN104783412A (en) | 2015-07-22 |
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| CN201510221185.3A Pending CN104783412A (en) | 2015-04-30 | 2015-04-30 | Resin fastener with reflecting colorful effect and manufacturing method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109674150A (en) * | 2018-12-07 | 2019-04-26 | 宁波克震服饰科技有限公司 | A kind of button with reflection alarming function |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3365478B2 (en) * | 1997-06-10 | 2003-01-14 | テイコク株式会社 | Accessories provided with a reflective material such as a reflective button and a method of manufacturing the same |
| CN1448277A (en) * | 2002-03-29 | 2003-10-15 | 荧茂科技股份有限公司 | Method of making multiplayer film color for electronic product display screen |
| CN102715711A (en) * | 2012-03-27 | 2012-10-10 | 嘉善县大舜奔马钮扣服饰厂 | Resin-dropped button and production process thereof |
| CN103876398A (en) * | 2014-04-22 | 2014-06-25 | 深圳市联星服装辅料有限公司 | Zipper with metal effect and laser effect and manufacturing method |
| CN104532195A (en) * | 2014-12-30 | 2015-04-22 | 深圳市联星服装辅料有限公司 | Nylon zipper with reflective colorful effect and manufacture method |
-
2015
- 2015-04-30 CN CN201510221185.3A patent/CN104783412A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3365478B2 (en) * | 1997-06-10 | 2003-01-14 | テイコク株式会社 | Accessories provided with a reflective material such as a reflective button and a method of manufacturing the same |
| CN1448277A (en) * | 2002-03-29 | 2003-10-15 | 荧茂科技股份有限公司 | Method of making multiplayer film color for electronic product display screen |
| CN102715711A (en) * | 2012-03-27 | 2012-10-10 | 嘉善县大舜奔马钮扣服饰厂 | Resin-dropped button and production process thereof |
| CN103876398A (en) * | 2014-04-22 | 2014-06-25 | 深圳市联星服装辅料有限公司 | Zipper with metal effect and laser effect and manufacturing method |
| CN104532195A (en) * | 2014-12-30 | 2015-04-22 | 深圳市联星服装辅料有限公司 | Nylon zipper with reflective colorful effect and manufacture method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109674150A (en) * | 2018-12-07 | 2019-04-26 | 宁波克震服饰科技有限公司 | A kind of button with reflection alarming function |
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Application publication date: 20150722 |