CN104779410A - Reforming hydrogen production fuel cell power generation module without hydrogen purification device - Google Patents
Reforming hydrogen production fuel cell power generation module without hydrogen purification device Download PDFInfo
- Publication number
- CN104779410A CN104779410A CN201510219661.8A CN201510219661A CN104779410A CN 104779410 A CN104779410 A CN 104779410A CN 201510219661 A CN201510219661 A CN 201510219661A CN 104779410 A CN104779410 A CN 104779410A
- Authority
- CN
- China
- Prior art keywords
- fuel cell
- hydrogen production
- power generation
- generation module
- proton exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000001257 hydrogen Substances 0.000 title claims abstract description 65
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 65
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 63
- 239000000446 fuel Substances 0.000 title claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 35
- 238000010248 power generation Methods 0.000 title claims abstract description 20
- 238000000746 purification Methods 0.000 title claims abstract description 14
- 238000002407 reforming Methods 0.000 title abstract 8
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000006243 chemical reaction Methods 0.000 claims description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 12
- 239000003054 catalyst Substances 0.000 abstract description 9
- 229910052697 platinum Inorganic materials 0.000 abstract description 6
- 239000012528 membrane Substances 0.000 abstract 3
- 208000001408 Carbon monoxide poisoning Diseases 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000006057 reforming reaction Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
The invention discloses a reforming hydrogen production fuel cell power generation module without a hydrogen purification device. The reforming hydrogen production fuel cell power generation module without the hydrogen purification device comprises a methanol water reforming hydrogen production machine (1) and a high-temperature proton exchange membrane fuel cell (2) which are connected with each other, and the hydrogen purification device is not arranged between the methanol water reforming hydrogen production machine (1) and the high-temperature proton exchange membrane fuel cell (2). According to the reforming hydrogen production fuel cell power generation module without the hydrogen purification device, the hydrogen purification device is omitted, the use cost of porpezite is reduced, and meanwhile carbon monoxide poisoning caused by a platinum catalyst is avoided by adopting the high-temperature proton exchange membrane fuel cell; The reforming hydrogen production fuel cell power generation module without the hydrogen purification device is mainly applied to the field of reforming hydrogen production fuel cell power generation.
Description
Technical field
The present invention relates to reformation hydrogen production fuel cell power generation field, particularly relate to a kind of reformation hydrogen production fuel cell power generation module of no hydrogen purifying plant.
Background technology
Current fuel cell has strict requirement to the content of carbon monoxide in hydrogen, General Requirements is less than 100ppm, preferably be less than 10ppm, particularly utilize the on-the-spot reforming reaction of methanol-water to generate hydrogen, all need to be provided with hydrogen purification device, otherwise easily cause fuel-cell catalyst poisoning, and hydrogen purification device needs to use porpezite, porpezite is expensive, thus causes reformation hydrogen production fuel cell cost high, thus cannot widely apply.At low temperatures, the catalyst meeting anthracemia in fuel cell, causes fuel battery service life to shorten.Therefore designing a kind of cost low and can avoid the reformation hydrogen production fuel cell power generation module of catalyst anthracemia, is also the technical problem being badly in need of at present solving.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of reformation hydrogen production fuel cell power generation module of no hydrogen purifying plant is provided, this module is by cancelling hydrogen purification device, reduce porpezite use cost, simultaneously by adopting high temperature proton exchange film fuel cell, avoid platinum catalyst anthracemia.
The present invention is the technical scheme that its technical problem of solution is taked: a kind of reformation hydrogen production fuel cell power generation module of no hydrogen purifying plant, comprise methanol-water reformation hydrogen production device, high temperature proton exchange film fuel cell, described methanol-water reformation hydrogen production device is connected with described high temperature proton exchange film fuel cell, does not arrange hydrogen purification device between described methanol-water reformation hydrogen production device and described high temperature proton exchange film fuel cell.
Further, described high temperature proton exchange film fuel cell is reaction temperature is 125 ° C to 170 ° C high temperature proton exchange film fuel cell.
Further, the reformation hydrogen production fuel cell power generation module of described a kind of no hydrogen purifying plant also comprises power transfer module, and described power transfer module is connected with described high temperature proton exchange film fuel cell.
Further, the reformation hydrogen production fuel cell power generation module of described a kind of no hydrogen purifying plant also comprises rack, and described methanol-water reformation hydrogen production device, high temperature proton exchange film fuel cell, power transfer module are arranged on interior of equipment cabinet.
Further, described power transfer module is DC/DC power transfer module.
The operation principle of the technical program is, methanol-water reformation hydrogen production device produces hydrogen-rich gas, hydrogen-rich gas enters high temperature proton exchange film fuel cell, hydrogen reacts in high temperature pile, generating electric energy, carbon monoxide is under 125 ° C to 170 ° C high temperature action, inoperative to the catalyst platinum in pile, and catalyst platinum keeps not poisoning.Institute's electrogenesis can convert power supply needed for use to through power transfer module.
The invention has the beneficial effects as follows: eliminate hydrogen purification device, reduce porpezite use cost, adopt high temperature proton exchange film fuel cell simultaneously, avoid platinum catalyst anthracemia.
Accompanying drawing explanation
Fig. 1 is the structure chart of reformation hydrogen production fuel cell power generation module of the present invention.
The implication marked in figure: 1. methanol-water reformation hydrogen production device, 2. high temperature proton exchange film fuel cell, 3. power transfer module, 4. rack.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
In embodiment illustrated in fig. 1, methanol-water reformation hydrogen production device (1) is connected with high temperature proton exchange film fuel cell (2), power transfer module (3) is connected with high temperature proton exchange film fuel cell (2), and it is inner that methanol-water reformation hydrogen production device (1), high temperature proton exchange film fuel cell (2), power transfer module (3) are all arranged on rack (4).
In the embodiment of the present invention, high temperature proton exchange film fuel cell (2) for reaction temperature be 125 ° C to 170 ° C high temperature proton exchange film fuel cell.
In the embodiment of the present invention, power transfer module (3) is DC/DC power transfer module.
The invention has the beneficial effects as follows: eliminate hydrogen purification device, reduce porpezite use cost, adopt high temperature proton exchange film fuel cell simultaneously, avoid platinum catalyst anthracemia.
The above is only the description of the preferred embodiment of the present invention; should be understood that the finiteness due to literal expression; and objectively there is unlimited concrete structure; for this area those skilled in the art; under the premise without departing from the principles of the invention; can also make some improvement, these improvement also should be considered as the scope of protection of the invention.
Claims (5)
1. the reformation hydrogen production fuel cell power generation module of a no hydrogen purifying plant, it is characterized in that: comprise methanol-water reformation hydrogen production device, high temperature proton exchange film fuel cell, described methanol-water reformation hydrogen production device is connected with described high temperature proton exchange film fuel cell, does not arrange hydrogen purification device between described methanol-water reformation hydrogen production device and described high temperature proton exchange film fuel cell.
2. the reformation hydrogen production fuel cell power generation module of a kind of no hydrogen purifying plant according to claim 1, is characterized in that: described high temperature proton exchange film fuel cell is reaction temperature is 125 ° C to 170 ° C high temperature proton exchange film fuel cell.
3. the reformation hydrogen production fuel cell power generation module of a kind of no hydrogen purifying plant according to claim 1, it is characterized in that: also comprise power transfer module, described power transfer module is connected with described high temperature proton exchange film fuel cell.
4. the reformation hydrogen production fuel cell power generation module of a kind of no hydrogen purifying plant according to claim 1, it is characterized in that: also comprise rack, described methanol-water reformation hydrogen production device, high temperature proton exchange film fuel cell, power transfer module are arranged on interior of equipment cabinet.
5. the reformation hydrogen production fuel cell power generation module of a kind of no hydrogen purifying plant according to claim 3, is characterized in that: described power transfer module is DC/DC power transfer module.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510219661.8A CN104779410A (en) | 2015-05-04 | 2015-05-04 | Reforming hydrogen production fuel cell power generation module without hydrogen purification device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510219661.8A CN104779410A (en) | 2015-05-04 | 2015-05-04 | Reforming hydrogen production fuel cell power generation module without hydrogen purification device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104779410A true CN104779410A (en) | 2015-07-15 |
Family
ID=53620751
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510219661.8A Pending CN104779410A (en) | 2015-05-04 | 2015-05-04 | Reforming hydrogen production fuel cell power generation module without hydrogen purification device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104779410A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108206289A (en) * | 2016-12-19 | 2018-06-26 | 中氢新能技术有限公司 | One kind prepares fuel cell based on first alcohol and water reformation |
| CN108206291A (en) * | 2016-12-19 | 2018-06-26 | 中氢新能技术有限公司 | A kind of silence vehicular power plant |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101106200A (en) * | 2006-07-11 | 2008-01-16 | 株式会社东芝 | Hydrogen generation device, a fuel cell system, and an analysis system |
| CN101540410A (en) * | 2009-04-29 | 2009-09-23 | 华南理工大学 | Natural gas hydrogen preparation and proton-exchange film fuel cell integrated generation method and device thereof |
| CN204230987U (en) * | 2014-12-15 | 2015-03-25 | 深圳市荥阳堂投资发展有限公司 | A kind of electric hybrid power supply device |
| CN204279132U (en) * | 2014-12-15 | 2015-04-22 | 深圳市荥阳堂投资发展有限公司 | A kind of reformation hydrogen production fuel cell electric vehicle |
| CN204516849U (en) * | 2015-05-04 | 2015-07-29 | 深圳伊腾得新能源有限公司 | A kind of reformation hydrogen production fuel cell power generation module of no hydrogen purifying plant |
-
2015
- 2015-05-04 CN CN201510219661.8A patent/CN104779410A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101106200A (en) * | 2006-07-11 | 2008-01-16 | 株式会社东芝 | Hydrogen generation device, a fuel cell system, and an analysis system |
| CN101540410A (en) * | 2009-04-29 | 2009-09-23 | 华南理工大学 | Natural gas hydrogen preparation and proton-exchange film fuel cell integrated generation method and device thereof |
| CN204230987U (en) * | 2014-12-15 | 2015-03-25 | 深圳市荥阳堂投资发展有限公司 | A kind of electric hybrid power supply device |
| CN204279132U (en) * | 2014-12-15 | 2015-04-22 | 深圳市荥阳堂投资发展有限公司 | A kind of reformation hydrogen production fuel cell electric vehicle |
| CN204516849U (en) * | 2015-05-04 | 2015-07-29 | 深圳伊腾得新能源有限公司 | A kind of reformation hydrogen production fuel cell power generation module of no hydrogen purifying plant |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108206289A (en) * | 2016-12-19 | 2018-06-26 | 中氢新能技术有限公司 | One kind prepares fuel cell based on first alcohol and water reformation |
| CN108206291A (en) * | 2016-12-19 | 2018-06-26 | 中氢新能技术有限公司 | A kind of silence vehicular power plant |
| CN108206289B (en) * | 2016-12-19 | 2021-08-03 | 中氢新能技术有限公司 | Fuel cell prepared based on methanol and water reforming |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160706 Address after: 518103 Guangdong city of Shenzhen province Baoan District Fuyong Funing street high tech Park Building 8 Building A room Applicant after: SHENZHEN YITENGDI NEW ENERGY Co.,Ltd. Address before: 518103 Guangdong city of Shenzhen province Baoan District Fuyong Funing street high tech Park Building 8 Building A room Applicant before: SHENZHEN YITENGDE NEW ENERGY CO.,LTD. |
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| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150715 |
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| WD01 | Invention patent application deemed withdrawn after publication |