CN1047769C - Production process for producing large specification nucleated glass plates by using tunnel kiln and shuttle kiln - Google Patents
Production process for producing large specification nucleated glass plates by using tunnel kiln and shuttle kiln Download PDFInfo
- Publication number
- CN1047769C CN1047769C CN96114107A CN96114107A CN1047769C CN 1047769 C CN1047769 C CN 1047769C CN 96114107 A CN96114107 A CN 96114107A CN 96114107 A CN96114107 A CN 96114107A CN 1047769 C CN1047769 C CN 1047769C
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- CN
- China
- Prior art keywords
- kiln
- glass
- shuttle
- present
- shuttle kiln
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
- C03C10/0045—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The present invention provides a technology for producing large-scale glass ceramic plates by using a tunnel kiln and a shuttle kiln, and provides a formula of glass ceramic, which contains MgO, Fe2Oe and Cr2O3 but contains no Zno or BaO, wherein the contents of MgO and Fe2O3 are 5 to 7%. The glass ceramic can be crystallized within a range of 1000 to 1050 DEG C, and has the advantages of good fluidity of glass metal, high crystallization rate, smooth product surface and short heat insulation time (only being 10 to 20 minutes). The present invention provides that fireproof shed plates are spliced into a mold with a size of 1000*1500mm or a larger size by using kiln cars of the tunnel kiln and the shuttle kiln; the purpose of stacking the fireproof shed plates in multiple layers can be realized; glass slag containing ingredients in the compounding range of the glass ceramic of the present invention is loaded into the mold for performing heat treatment.
Description
The present invention relates to utilize tunnel and shuttle kiln, make the production technique of large specification nucleated glass plates according to sintering process, the microcrystalline glass decorative plate of this explained hereafter can be used for the finishing on exterior wall, interior wall, cylinder and the ground of buildings.
Sintering process can be by glasswork because of technological process, and ceramic process is independently finished, so technology is more easily implemented, and becomes the main production method of present crystallizing glass sheet material.For example: the open CN1107811A of Chinese patent discloses the production technique of the roller kiln of large specification nucleated glass plates.But be subjected to the restriction of refractory materials specification, the microcrystalline glass decorative plate that surpasses 1000 * 1500mm specification can't be produced.In addition, because refractory slab moves, very easily cause the vibration deformation of microcrystal glass plate in roller kiln.
The present invention proposes a kind of MgO and Fe
2O
3Content is 5-7% and contains Cr
2O
3, do not contain the devitrified glass composition of ZnO, BaO, i.e. SiO
250-60%, Al
2O
31-5%, CaO15-20%, Na
2O 5-10%, K
2O 1-5%, MgO+Fe
2O
35-7%, Cr
2O
3The microcrystalline glass formula of 1-3% (weight percent), this glass can be in 1000-1050 ℃ of scope crystallization and glass metal good fluidity, crystallization rate is fast, the goods table is and smooth, soaking time only is 10-20 minute.The present invention proposes to utilize the kiln car of tunnel furnace and shuttle kiln, splice fire-resistant refractory slab and become to surpass 1000 * 1500mm or larger sized mould, and the realization multilayer is piled up, and inserts the glass slag charge of devitrified glass compositing range proposed by the invention in the mould, heat-treats.
Method of the present invention is made up of the following step:
(1). the preparation of glass particle (weight ratio): SiO
250-60% Al
2O
31-5% CaO 15-20%MgO+Fe
2O
35-7% K
2O 1-5% Na
2O 5-10%Cr
2O
31-3%
Found at 1450-1550 ℃, it is 1-5mm glass particle material that shrend becomes diameter;
(2). an amount of above-mentioned glass slag charge of in mould, packing into, be coated with in this mould with aluminum oxide powder slurry, on the kiln car of shuttle kiln or tunnel furnace, pile up one or more layers, in 1000-1050 ℃ scope thermal treatment 10-20 minute;
(3). the sheet material of making becomes qualified product through cutting, grinding, polishing.
Compared with prior art, there is following progressive in the present invention:
(1) the crystallization treatment temp is low, and approximately than low 50-100 ℃ of prior art, soaking time is short, lacks 40-80 minute than prior art, burns till cost and reduces greatly.
(2) utilize tunnel furnace, shuttle kiln can produce the sheet material of big specification (specification that 1000 * 1500mm is above), and planeness better (being lower than 1mm), product surface is smooth, and sintering quality is better.
(3) tunnel furnace, shuttle kiln can be realized multi-layer sintering, because the thermal treatment temperature difference that the selected prescription of the present invention allows is bigger.The qualification rate of product is higher, has reduced the sintering cost.
(4) in tunnel furnace, shuttle kiln, refractory slab is relative with the car face static, and when having avoided roller kiln to use, the vibration that friction transmission causes between refractory slab and the roller, and the product deformation that occurs.
(5) in tunnel furnace, shuttle kiln, can form mould with the refractory slab and the refractory roll of small dimension, and avoid using in the roller kiln complete big specification refractory materials flute profile mould, reduced the mould cost.
(6) in tunnel furnace, shuttle kiln, during the glass slag charge of thermal treatment the present invention proposition, can not adopt the moulding process of vibration, and only need wipe off, just can satisfy heat treated needs.
Come the present invention is further described by means of specific embodiment down, still, should be understood that the present invention is not limited to these schemes.
Embodiment 1
With 38 parts in certain steel mill's slag, 12 parts of rhombspars, 54 parts of quartz sands, 8 parts in Wingdale, 12 parts of soda ash, 4 parts of potassium bichromate, 1 part of weight of ferric oxide is mixed, and in glass melting furnace, founds into glass metal in 1450 ℃, the shrend chilling becomes the 1-5mm grain diameter, is enclosed in after the drying in the mould of assembling on the kiln car face of tunnel furnace, after the strickling, push in the kiln and fire, fired 20 minutes for 1000-1050 ℃, be cooled to room temperature, can obtain light green sheet material.Observe plate surface, planeness is better, and error is no more than 1mm, and the top layer does not have bubble, and after testing, the main crystalline phase of this material is a peridotites.
The oxide compound of this devitrified glass (weight percent) composed as follows:
SiO
2 55 Al
2O
3 5 CaO 20 Na
2O 10
K
2O 2 MgO＋Fe
2O
3 6 Cr
2O
3 2
Add up to: 100
Embodiment 2
With 30 parts in certain steel mill's slag, 10 parts of rhombspars, 64 parts of quartz sands, 10 parts in Wingdale, 14 parts of soda ash, 2 parts in chromic oxide, 1 part of weight of ferric oxide is mixed, and in glass melting furnace, founds into glass metal in 1500 ℃, the shrend chilling becomes the 1-5mm grain diameter, is enclosed in after the drying in the mould of assembling on the kiln car face of shuttle kiln, after the strickling, push in the kiln and fire, fired 20 minutes in 1020 ℃, be cooled to room temperature, can obtain light green sheet material.Observe plate surface, planeness is better, and error is no more than 1mm, and the top layer does not have bubble, and after testing, the main crystalline phase of this material is a peridotites.
The oxide compound of this devitrified glass (weight percent) composed as follows:
SiO
2 58 Al
2O
3 3 CaO 18 Na
2O 12
K
2O 1.5 MgO＋Fe
2O
3 5.6 Cr
2O
3 1.9
Add up to: 100
Obviously, the foregoing description only is that it does not limit protection scope of the present invention to giving an example that the present invention can implement, and in protection scope of the present invention, affiliated technician all can make large specification nucleated glass plates by skill system provided by the invention and composition.
Claims (3)
1. utilize tunnel furnace and shuttle kiln to produce the production technique of large specification nucleated glass plates, it is made up of the following step:
(1). the preparation of glass particle (weight percent): SiO
250-60% Al
2O
31-5% CaO 15-20%MgO+Fe
2O
35-7% K
2O 1-5% Na
2O 5-12%Cr
2O
31-3%
Found at 1450-1550 ℃, it is 1-5mm glass particle material that shrend becomes diameter;
(2). an amount of above-mentioned glass slag charge of in mould, packing into, be coated with in this mould with aluminum oxide powder slurry, on the kiln car of shuttle kiln or tunnel furnace, pile up one or more layers, in 1000-1050 ℃ scope thermal treatment 10-20 minute;
(3). the sheet material of making becomes qualified product through cutting, grinding, polishing.
2. the described technology of claim 1, described glass board material size is 1000 * 1500mm or bigger size.
3. claim 1 or 2 described technologies, the main crystalline phase of described sheet material is a peridotites.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96114107A CN1047769C (en) | 1996-12-23 | 1996-12-23 | Production process for producing large specification nucleated glass plates by using tunnel kiln and shuttle kiln |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96114107A CN1047769C (en) | 1996-12-23 | 1996-12-23 | Production process for producing large specification nucleated glass plates by using tunnel kiln and shuttle kiln |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1157270A CN1157270A (en) | 1997-08-20 |
| CN1047769C true CN1047769C (en) | 1999-12-29 |
Family
ID=5121926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96114107A Expired - Fee Related CN1047769C (en) | 1996-12-23 | 1996-12-23 | Production process for producing large specification nucleated glass plates by using tunnel kiln and shuttle kiln |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1047769C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102674695A (en) * | 2012-05-25 | 2012-09-19 | 南昌航空大学 | Method for preparing calcium-aluminum-silicon (CAS) glass ceramics by quickly sintering waste lamp tube glass |
| CN105924013B (en) * | 2016-04-25 | 2019-04-02 | 四川一名微晶科技股份有限公司 | It is raw material using the devitrified glass and production method of the production of all-electric melting calendering technology using ferrochrome waste residue |
| CN107285773A (en) * | 2017-08-01 | 2017-10-24 | 南通大明玉新材料科技有限公司 | A kind of shuttle kiln sintering process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049835A (en) * | 1989-09-02 | 1991-03-13 | 中国科学院上海硅酸盐研究所 | The manufacturing of glass-ceramic type facing material |
| CN1072398A (en) * | 1992-09-28 | 1993-05-26 | 唐山市古冶玻璃制品厂 | Nucleated glass granite dalle and production technique |
-
1996
- 1996-12-23 CN CN96114107A patent/CN1047769C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1049835A (en) * | 1989-09-02 | 1991-03-13 | 中国科学院上海硅酸盐研究所 | The manufacturing of glass-ceramic type facing material |
| CN1072398A (en) * | 1992-09-28 | 1993-05-26 | 唐山市古冶玻璃制品厂 | Nucleated glass granite dalle and production technique |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1157270A (en) | 1997-08-20 |
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