CN104775129A - Rapid acid pickling device and method for cold-rolled steel strip - Google Patents

Rapid acid pickling device and method for cold-rolled steel strip Download PDF

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Publication number
CN104775129A
CN104775129A CN201510218912.0A CN201510218912A CN104775129A CN 104775129 A CN104775129 A CN 104775129A CN 201510218912 A CN201510218912 A CN 201510218912A CN 104775129 A CN104775129 A CN 104775129A
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pickling
liquid
acid pickling
pickling tank
tank
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CN104775129B (en
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陈海林
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Wisdri Engineering and Research Incorporation Ltd
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Wisdri Engineering and Research Incorporation Ltd
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Abstract

The invention provides a rapid acid pickling device and method for a cold-rolled steel strip. The device comprises an acid pickling tank, a tank cover and an acid pickling circulation system. The two sides of the tank cover are connected with a hydraulic system, overflow channels are formed in two ends of the acid pickling tank, liquid return holes are formed in the bottoms of the overflow channels, and liquid inlet holes are formed in the two side walls of the acid pickling tank. The acid pickling circulation system comprises a liquid storage tank, a liquid inlet pipe and a liquid return pipe, a circulation pump is arranged on the side, connected with the liquid storage tank, of the liquid inlet pipe, the other side of the liquid inlet pipe is connected with spraying pipes, the spraying pipes enter the acid pickling tank through the liquid inlet holes, the two ends of the liquid return pipe are connected with the liquid return holes respectively, and the middle of the liquid return pipe is connected with the liquid storage tank. The rapid acid pickling device further comprises an ultrasonic device which comprises ultrasonic generators and transducers which are evenly arranged on the top of the tank cover at intervals, and the transducers and the ultrasonic generators are connected through cables. By means of the rapid acid pickling device and method, the acid pickling speed can be increased, the acid pickling process is easier to control, and meanwhile the production cost is low.

Description

A kind of fast acid cleaning device of cold rolled strip and method
Technical field
The invention belongs to the technical field that cold rolled strip is clean, particularly relate to a kind of fast acid cleaning device and method of cold rolled strip.
Background technology
Hot-rolled sheet (cold rolling raw material) in hot rolling, batch, cool and all can produce iron scale in transportation, these iron scales can affect the operation such as rolling, annealing of postorder, therefore hot-rolled sheet enter rolling last as to carry out pickling obtain clean surface.
Current hot rolled silicon steel sheet in coil acid cleaning process many employings shallow slot turbulence acid dip technique, uses hydrochloric acid as pickling medium.In cold-rolling pickling process section, there is a series of chemistry and physical action in the iron scale on hydrochloric acid and hot-rolled sheet surface, makes it come off from surface of steel plate, dissolves, thus obtain the surface cleaned.Shallow slot turbulence acid dip acid solution flow direction is also with steel direction contrary, and in acid tank, sprays acid solution by nozzle, thus accelerates acid solution flowing, realizes turbulent flow, pickling speed is accelerated.Acid cleaning process is acid solution and the scale on surface process at belt steel surface generation chemical reaction in fact, and chemical reaction rate is by reactant and the impact of producing thing velocity of diffusion, turbulence acid dip process acid solution is fast with the relative movement of band steel, reactant hydrogen ion, chlorion etc. diffuse to the surface soon, and reaction product iron ion, ferrous ion are fast to solution diffusion, the essence of visible turbulence acid dip accelerates belt steel surface reactant and product ion diffusion, thus accelerate chemical reaction and improve pickling speed.
Summary of the invention
The object of patented technology of the present invention is the fast acid cleaning device and the method that provide a kind of cold rolled strip, by arranging ultrasonic unit on conventional turbulent flow acid cleaning process basis, accelerates the pickling speed of cold rolled strip.
The present invention solves the problems of the technologies described above adopted technical scheme: a kind of fast acid cleaning device of cold rolled strip, comprise pickling tank, groove lid and the pickling recycle system, described groove lid both sides are connected with hydraulic efficiency system, the two ends of described pickling tank are also provided with overflow groove, described isopipe root has hole for back flow, two side has inlet opening with pickling tank, the described pickling recycle system comprises container for storing liquid, liquid-inlet pipe and liquid returning tube, the side that described liquid-inlet pipe is connected with described container for storing liquid is provided with recycle pump, opposite side is connected with jet pipe respectively, described jet pipe enters in pickling tank by inlet opening, described liquid returning tube two ends are connected with described hole for back flow respectively, be connected with container for storing liquid in the middle part of liquid returning tube, it is characterized in that, also comprise ultrasonic unit, described ultrasonic unit comprises ultrasonic generator and transverter, described transverter uniform intervals is located at the top of described groove lid, described transverter is connected by cable with ultrasonic generator.
By such scheme, the outer wall of described pickling tank lays ultrasonic absorption film.
By such scheme, described groove lid is made up of steel plate, and the both sides top groove of groove lid two side bottom and described pickling tank forms water-lute, is provided with gap bottom the two ends of groove lid with top, pickling tank two ends.
The fast acid cleaning device of above-mentioned a kind of cold rolled strip is adopted to carry out the method for strip pickling, it is characterized in that: cold rolled strip enters described pickling tank vertically, pickle solution in described container for storing liquid enters in described liquid-inlet pipe at the flows by action of described recycle pump, by described jet pipe ejection, pickling is carried out to cold rolled strip again, start described ultrasonic generator, electrical signal is launched to described transverter, transverter is driven to launch ultrasonic wave to pickling tank, pickle solution produces cavitation effect, dirt on cold rolled strip is peeled off, also pickling chemical reaction velocity can be made to accelerate, cold rolling more quickly by pickling, described overflow groove is entered when pickle solution overflows pickling tank, liquid returning tube is entered by described hole for back flow, finally be back in container for storing liquid and recycle.
The invention has the beneficial effects as follows: the fast acid cleaning device and the method that 1, provide a kind of cold rolled strip, conventional turbulent flow acid cleaning process basis adds ultrasonic technique, accelerate pickling speed, save the use of acid solution, thus save production cost; 2, because ultrasonic intensity regulates reaction fast, therefore better can prevent overpickling, owe the appearance of the defects such as pickling, make the pickling controllability of cold rolled strip high; 3, ultrasonic wave can play the effect improving pickling speed of response, and acid solution heating unit therefore can not be used to heat pickle solution, reduces equipment investment cost.
Accompanying drawing explanation
Fig. 1 is the front view of one embodiment of the invention.
Fig. 2 is the side-view of one embodiment of the invention.
Wherein: 1. pickling tank, 2. groove lid, 3. overflow groove, 4. container for storing liquid, 5. liquid-inlet pipe, 6. liquid returning tube, 7. recycle pump, 8. jet pipe, 9. ultrasonic generator, 10. transverter.
Embodiment
For understanding the present invention better, below in conjunction with drawings and Examples, the invention will be further described.
As shown in Figure 1-2, a kind of fast acid cleaning device of cold rolled strip, comprise pickling tank 1, groove lid 2 and the pickling recycle system, groove lid is made up of steel plate, the both sides top groove of its two side bottom and pickling tank forms water-lute, is provided with gap, cold rolled strip is passed therethrough bottom the two ends of groove lid with top, pickling tank two ends, groove lid both sides are connected with hydraulic efficiency system, by hydraulic efficiency system automatic vertical unlocking; Pickling tank is welded by certain thickness stainless-steel sheet, inner line with rubber, acid corrosion-resistant, anti-corrosion brick is laid on bottom pickling tank and both sides, prevents acid solution from corroding pickling tank, and heat-insulation and heat-preservation, the two ends of pickling tank are also provided with overflow groove 3, collect and backflow for pickling, isopipe root has hole for back flow, and two side has inlet opening with pickling tank; The pickling recycle system comprises container for storing liquid 4, liquid-inlet pipe 5 and liquid returning tube 6, the side that liquid-inlet pipe is connected with container for storing liquid is provided with recycle pump 7, opposite side is connected with jet pipe 8 respectively, jet pipe enters in pickling tank by inlet opening, liquid returning tube two ends are connected with hole for back flow respectively, be connected with container for storing liquid in the middle part of liquid returning tube, recovered acid washing lotion reuses; Also comprise ultrasonic unit, ultrasonic unit comprises ultrasonic generator 9 and transverter 10, and transverter uniform intervals is located at the top of groove lid, and it is connected by cable with ultrasonic generator; The outer wall of pickling tank lays ultrasonic absorption film, prevents ultrasonic wave to the injury of human body.
This device is adopted to carry out being with the method for the quick pickling of steel, cold rolled strip enters pickling tank 1 vertically, pickle solution in container for storing liquid 4 enters in liquid-inlet pipe 5 at the flows by action of recycle pump 7, sprayed by jet pipe 8 again and pickling is carried out to cold rolled strip, start ultrasonic generator 9, electrical signal is launched to transverter 10, transverter is driven to launch ultrasonic wave to pickling tank, pickle solution produces cavitation effect, dirt on cold rolled strip is peeled off, also pickling chemical reaction velocity can be made to accelerate, cold rolling more quickly by pickling, overflow groove 3 is entered when pickle solution overflows pickling tank, liquid returning tube 6 is entered by hole for back flow, finally be back in container for storing liquid and recycle.
When there is ultrasonic wave in acid solution, liquid generation ultrasonic vibration will be made, in the circulation that liquid internal increases for pressure instantaneous reduction, when pressure reduces suddenly, acid solution inside can form the little hole of many vacuum, the gas be dissolved in acid solution can be inhaled in hole and form small bubbles, but after small bubbles are formed, pressure increases suddenly and oppressed, there is time generation shockwave, these shockwave occur in belt steel surface makes effects on surface iron scale produce shock action on the one hand, the stripping of accelerating oxidation iron, promote that stirring action is played on surface on the other hand, accelerate belt steel surface pickling reaction reactant and product ion diffusion, thus greatly promote the carrying out of pickling.
By hyperacoustic cavitation effect principle, accelerate the mobility of acid solution, make belt steel surface acid solution change liquid speed to accelerate, thus accelerate pickling chemical reaction velocity, reduce the use of current pickle solution, improve whole unit speed further, because ultrasonic intensity regulates reaction fast, therefore better can prevent overpickling, owe the appearance of the defects such as pickling, make acid washing method controllability of the present invention high.

Claims (4)

1. the fast acid cleaning device of a cold rolled strip, comprise pickling tank, groove lid and the pickling recycle system, described groove lid both sides are connected with hydraulic efficiency system, the two ends of described pickling tank are also provided with overflow groove, described isopipe root has hole for back flow, two side has inlet opening with pickling tank, the described pickling recycle system comprises container for storing liquid, liquid-inlet pipe and liquid returning tube, the side that described liquid-inlet pipe is connected with described container for storing liquid is provided with recycle pump, opposite side is connected with jet pipe respectively, described jet pipe enters in pickling tank by inlet opening, described liquid returning tube two ends are connected with described hole for back flow respectively, be connected with container for storing liquid in the middle part of liquid returning tube, it is characterized in that, also comprise ultrasonic unit, described ultrasonic unit comprises ultrasonic generator and transverter, described transverter uniform intervals is located at the top of described groove lid, described transverter is connected by cable with ultrasonic generator.
2. the fast acid cleaning device of a kind of cold rolled strip according to claim 1, is characterized in that, the outer wall of described pickling tank lays ultrasonic absorption film.
3. the fast acid cleaning device of a kind of cold rolled strip according to claim 2, it is characterized in that, described groove lid is made up of steel plate, and the both sides top groove of groove lid two side bottom and described pickling tank forms water-lute, is provided with gap bottom the two ends of groove lid with top, pickling tank two ends.
4. adopt the fast acid cleaning device of the described a kind of cold rolled strip of one of the claims to carry out the method for pickling, it is characterized in that: cold rolled strip enters described pickling tank vertically, pickle solution in described container for storing liquid enters in described liquid-inlet pipe at the flows by action of described recycle pump, by described jet pipe ejection, pickling is carried out to cold rolled strip again, start described ultrasonic generator, electrical signal is launched to described transverter, transverter is driven to launch ultrasonic wave to pickling tank, pickle solution produces cavitation effect, dirt on cold rolled strip is peeled off, also pickling chemical reaction velocity can be made to accelerate, cold rolling more quickly by pickling, described overflow groove is entered when pickle solution overflows pickling tank, liquid returning tube is entered by described hole for back flow, finally be back in container for storing liquid and recycle.
CN201510218912.0A 2015-04-29 2015-04-29 A kind of quick acid dip pickle and method of cold-strip steel Active CN104775129B (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106011902A (en) * 2016-07-06 2016-10-12 湖北大帆金属制品有限公司 Pickling tank
CN107520261A (en) * 2017-09-26 2017-12-29 德清县荣昌冷轧带钢有限公司 A kind of novel all-in-one cold rolled strip steel production device
CN108914035A (en) * 2018-09-03 2018-11-30 德清县欣琪电子有限公司 A kind of copper covered steel wire tinning stack of double-station
CN109082619A (en) * 2018-09-03 2018-12-25 德清县欣琪电子有限公司 A kind of tinning stack of copper covered steel wire
CN109161830A (en) * 2018-09-03 2019-01-08 德清县欣琪电子有限公司 A kind of adjustable copper covered steel wire double-station tinning stack
CN109295407A (en) * 2018-09-03 2019-02-01 德清县欣琪电子有限公司 A kind of adjustable copper covered steel wire tinning stack
CN109536980A (en) * 2019-01-23 2019-03-29 陈欣洁 A kind of strip pickling recycle unit
CN110420922A (en) * 2019-08-27 2019-11-08 中冶南方工程技术有限公司 Sparge pipe, energy-saving type cleaning device and band processing system
CN111235586A (en) * 2020-02-28 2020-06-05 马鞍山钢铁股份有限公司 Low acid consumption environment-friendly pickling acid mist pumping and discharging system
CN111607800A (en) * 2020-06-24 2020-09-01 江苏苏讯新材料科技有限公司 Stainless steel strip hydrochloric acid pickling circulation system and method thereof
CN112144064A (en) * 2020-09-16 2020-12-29 熊家豪 Cold-rolled strip steel manufacturing process

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CN2307008Y (en) * 1997-08-21 1999-02-10 鞍山钢铁集团公司 Continuous strip steel pickling shallow slot using hydrochloric acid
JP2009173980A (en) * 2008-01-23 2009-08-06 Jfe Steel Corp Recovery, regeneration, and supply method of acid solution in annealing-pickling equipment, acid-pickling tank, and pickling equipment for steel strip
CN201659108U (en) * 2010-03-01 2010-12-01 王兆谦 Ultrasonic cleaning machine
CN202199544U (en) * 2011-07-26 2012-04-25 张家港华裕有色金属材料有限公司 Ultrasonic wave cleaner for titanium and titanium alloy pipe
CN203284471U (en) * 2013-05-27 2013-11-13 攀钢集团攀枝花钢钒有限公司 Shallow-slot pickling device
CN204234411U (en) * 2014-09-25 2015-04-01 杭州华光焊接新材料股份有限公司 A kind of welding wire continuous ultrasonic cleaning equipment
CN204676164U (en) * 2015-04-29 2015-09-30 中冶南方工程技术有限公司 A kind of fast acid cleaning device of cold rolled strip

Patent Citations (7)

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Publication number Priority date Publication date Assignee Title
CN2307008Y (en) * 1997-08-21 1999-02-10 鞍山钢铁集团公司 Continuous strip steel pickling shallow slot using hydrochloric acid
JP2009173980A (en) * 2008-01-23 2009-08-06 Jfe Steel Corp Recovery, regeneration, and supply method of acid solution in annealing-pickling equipment, acid-pickling tank, and pickling equipment for steel strip
CN201659108U (en) * 2010-03-01 2010-12-01 王兆谦 Ultrasonic cleaning machine
CN202199544U (en) * 2011-07-26 2012-04-25 张家港华裕有色金属材料有限公司 Ultrasonic wave cleaner for titanium and titanium alloy pipe
CN203284471U (en) * 2013-05-27 2013-11-13 攀钢集团攀枝花钢钒有限公司 Shallow-slot pickling device
CN204234411U (en) * 2014-09-25 2015-04-01 杭州华光焊接新材料股份有限公司 A kind of welding wire continuous ultrasonic cleaning equipment
CN204676164U (en) * 2015-04-29 2015-09-30 中冶南方工程技术有限公司 A kind of fast acid cleaning device of cold rolled strip

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106011902A (en) * 2016-07-06 2016-10-12 湖北大帆金属制品有限公司 Pickling tank
CN107520261A (en) * 2017-09-26 2017-12-29 德清县荣昌冷轧带钢有限公司 A kind of novel all-in-one cold rolled strip steel production device
CN108914035A (en) * 2018-09-03 2018-11-30 德清县欣琪电子有限公司 A kind of copper covered steel wire tinning stack of double-station
CN109082619A (en) * 2018-09-03 2018-12-25 德清县欣琪电子有限公司 A kind of tinning stack of copper covered steel wire
CN109161830A (en) * 2018-09-03 2019-01-08 德清县欣琪电子有限公司 A kind of adjustable copper covered steel wire double-station tinning stack
CN109295407A (en) * 2018-09-03 2019-02-01 德清县欣琪电子有限公司 A kind of adjustable copper covered steel wire tinning stack
CN109536980A (en) * 2019-01-23 2019-03-29 陈欣洁 A kind of strip pickling recycle unit
CN110420922A (en) * 2019-08-27 2019-11-08 中冶南方工程技术有限公司 Sparge pipe, energy-saving type cleaning device and band processing system
CN111235586A (en) * 2020-02-28 2020-06-05 马鞍山钢铁股份有限公司 Low acid consumption environment-friendly pickling acid mist pumping and discharging system
CN111607800A (en) * 2020-06-24 2020-09-01 江苏苏讯新材料科技有限公司 Stainless steel strip hydrochloric acid pickling circulation system and method thereof
CN112144064A (en) * 2020-09-16 2020-12-29 熊家豪 Cold-rolled strip steel manufacturing process
CN112144064B (en) * 2020-09-16 2021-07-13 惠民万顺节能新材料有限公司 Cold-rolled strip steel manufacturing process

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