CN104761951A - Ink-jet printing ink formula - Google Patents

Ink-jet printing ink formula Download PDF

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Publication number
CN104761951A
CN104761951A CN201510012123.1A CN201510012123A CN104761951A CN 104761951 A CN104761951 A CN 104761951A CN 201510012123 A CN201510012123 A CN 201510012123A CN 104761951 A CN104761951 A CN 104761951A
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ink
water
jet printing
total amount
base
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CN201510012123.1A
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CN104761951B (en
Inventor
刁正平
郑文军
施卫斌
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SHANGHAI CELLUDYE COLORANTS CO Ltd
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SHANGHAI CELLUDYE COLORANTS CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/32Inkjet printing inks characterised by colouring agents
    • C09D11/328Inkjet printing inks characterised by colouring agents characterised by dyes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/36Inkjet printing inks based on non-aqueous solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/38Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30Ink jet printing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Coloring (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention relates to an ink-jet printing ink formula. The ink-jet printing ink formula comprises an aqueous ink main material and an aqueous ink accessory matrial and is characterized in that the aqueous ink main material comprises, by mass, 5-9% of dye, 20-25% of diethylene glycol, 5-20% of 1,2-propylene glycol, 0-5% of caprolactam, 0-15% of 2-pyrrolidone, 5-10% of glycerin, 0-5% of PEG 600, 0.2-2% of Surfynol 465, 0.1-0.5% of Proxel GXL and the balance water. The ink-jet printing ink has good stability, does not block printing equipment, has no toxicity and no obvious peculiar smell, and can be used for nylon materials such as a nylon banner and a streamer and silk fabrics such as silk scarf and shirts.

Description

A kind of ink-jet printing ink formula
Technical field
The present invention relates to ink set, be specifically related to the acid dye ink formula for digit printing of weaving.
Background technology
The digital ink-jet printed technology of textiles has much remarkable advantage than traditional screen printing, day by day pursues in textile printing field.The advantage of weaving digit printing is mainly reflected in following several respects: printing precision is tens times of traditional screen printing, without the need to plate-making, batch flexibly, do not limit by flower pattern, both can realize single-piece to make, also can produce in enormous quantities, delivery rate is fast, in whole jet printing process, do not produce waste water simultaneously, really reach the requirement of less energy-consumption, low stain, lower noise.
Ink for digit printing of weaving mainly is divided into water-base ink and solvent-based inks, wherein water-base ink mainly comprises disperse dye ink, reactive dye ink and acid dye ink, disperse dye ink is mainly used in polyester piece good, reactive dye ink is mainly used in the fabrics such as cotton, fiber crops and viscose glue, acid dye ink is mainly used in the fabrics such as nylon, real silk and wool, as the pure silk products on market, high-grade carpet, down jackets and flag banner etc.At present, disperse dye ink and reactive dye ink develop rapidly, are widely used, technology relative maturity, also can meet the demand of some high-speed printer.But the development of acid dye ink is not and above two kinds of inks, and it technically still exists problems, and the general lower solubleness of matching stain becomes maximum bottleneck.
Summary of the invention
The object of the present invention is to provide a kind of ink-jet printing ink formula, to solve the problems of the technologies described above.
Technical problem solved by the invention can realize by the following technical solutions:
A kind of ink-jet printing ink formula, comprises water-base ink major ingredient and water-base ink auxiliary material, it is characterized in that, described water-base ink major ingredient is made up of the material of following mass percent: the dyestuff of 5%-9%, the Diethylene Glycol of 20%-30%, 5%-20% 1,2-propylene glycol, the hexanolactam of 0-5%, the 2-Pyrrolidone of 0-15%, the glycerine of 5%-10%, the Surfynol 465 of the PEG600 of 0-5%, 0.2%-2%, the Proxel GXL of 0.1%-0.5%, surplus is water.
Described water-base ink auxiliary material comprises at least one water-miscible organic solvent, at least one tensio-active agent, at least one sterilant and at least one buffer reagent.Concrete formula is mainly determined according to the requirement of surface tension, viscosity, kind of dyes and fabric types.
A kind of ink-jet printing ink formula, comprises at least one yellow water-base ink, and described yellow water-base ink is formulated and the mass percent accounting for ink total amount is 4%-8% by turmeric yellow 79 (C.I.Acid Yellow 79).
Turmeric yellow 79 preferably includes the material of following mass percent: the dyestuff of 6%, the Diethylene Glycol of 23%, 20% 1,2-propylene glycol, the glycerine of 6%, the Proxel GXL of the Surfynol 465,0.2% of 1%, surplus is water.
A kind of ink-jet printing ink formula, comprises at least one red water-base ink, and described red water-base ink is formulated and the mass percent accounting for ink total amount is 6%-10% by Xylene Red 52 (C.I.Acid Red 52).
Xylene Red 52 preferably includes the material of following mass percent: the dyestuff of 8%, the Diethylene Glycol of 25%, 20% 1,2-propylene glycol, the glycerine of 5%, the Proxel GXL of the PEG600 of 2%, the Surfynol 465,0.2% of 1%, surplus is water.
A kind of ink-jet printing ink formula, comprises at least one blue water-based ink, and described blue water-based ink is formulated and the mass percent accounting for ink total amount is 3%-7% by acid blue 260 (C.I.Acid Blue 260).
Acid blue 260 preferably includes the material of following mass percent: the dyestuff of 5%, the Diethylene Glycol of 20%, 5% 1,2-propylene glycol, the hexanolactam of 5%, the 2-Pyrrolidone of 15%, the glycerine of 10%, the PEG600 of 52%, the Proxel GXL of the Surfynol 465,0.2% of 1%, surplus is water.
A kind of ink-jet printing ink formula, comprises at least one cyan water-base ink, and described cyan water-base ink is formulated and the mass percent accounting for ink total amount is 6%-10% by acid blue 9 (C.I.Acid Blue 9).
Acid blue 9 preferably includes the material of following mass percent: the dyestuff of 9%, the Diethylene Glycol of 22%, 20% 1,2-propylene glycol, the glycerine of 8%, the Proxel GXL of the PEG600 of 3%, the Surfynol 465,0.2% of 1%, surplus is water.
A kind of ink-jet printing ink formula, comprises at least one black water ink, and described yellow water-base ink is formulated and the mass percent accounting for ink total amount is 6%-10% by Acid Black 1 94 (C.I.Acid Black 194).
Acid Black 1 94 preferably includes the material of following mass percent: the dyestuff of 7%, the Diethylene Glycol of 30%, 5% 1,2-propylene glycol, the hexanolactam of 3%, the glycerine of 10%, the PEG600 of 1%, the Proxel GXL of the Surfynol 465,0.2% of 1%, surplus is water.
A kind of ink-jet printing ink formula, containing the yellow water-base ink that and the mass percent that account for ink total amount formulated by turmeric yellow 79 (C.I.Acid Yellow 79) is 4%-8%, by Xylene Red 52 (C.I.Acid Red 52), the formulated and mass percent accounting for ink total amount is the red water-base ink of 6%-10%, by acid blue 260 (C.I.Acid Blue 260), the formulated and mass percent accounting for ink total amount is the blue water-based ink of 3%-7%, by acid blue 9 (C.I.Acid Blue 9), the formulated and mass percent accounting for ink total amount is the cyan water-base ink of 6%-10%, formulated and the mass percent accounting for ink total amount is at least four kinds in the black water ink of 6%-10% by Acid Black 1 94 (C.I.Acid Black194).
In above-mentioned formula, water is preferably ultrapure water, and dyestuff is preferably the salt-free high pure dye of ink-jet level, and Surfynol465 is preferably the tensio-active agent of US Air gasification work, and Proxel GXL is preferably the sterilant of Avecia company.
Ink-jet printing ink formula optimization water accounts for the 35%-85% of ink total amount.Water-miscible organic solvent preferably accounts for the 5%-65% of ink total amount.
Described water-miscible organic solvent mainly comprises, alcohols, ketone or ketols, ethers etc.;
Described alcoholic solvent comprises: ethylene glycol, Diethylene Glycol, propylene glycol, butyleneglycol, triglycol, n-propyl alcohol, thiodiglycol, hexylene glycol, Virahol etc.;
Described ketone or ketols solvent comprise: pimelinketone, acetone, methylethylketone, 2-Pyrrolidone, methyl-2-pyrrolidone, Pyranton etc.;
Described ether solvent comprises: ethylene glycol monomethyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, triglycol monomethyl ether, triglycol one ether etc.;
Described tensio-active agent mainly comprises: ethoxyacetylene glycol (the Surfynols series product as US Air gasification work), oxyethyl group primary alconol (the Tomadol series product as Tomah company of the U.S.), oxyethyl group secondary alcohol (the Tergitol series product as union carbide corporation of the U.S.), organo-siloxane (the Silwet series product of GE company of the U.S.), fluorine surfactant (the Zonyl series product of E.I.Du Pont Company) etc.;
Described tensio-active agent accounts for the 0.01%-5% of ink total amount, preferred 0.2%-2%;
The surface tension of described ink is about 20-70mN/m, and be preferably 30-50mN/m, viscosity is 10-30cP;
The stability of described ink is good, can not block printing device, and nontoxic, without obvious peculiar smell;
Described ink is used for nylon, real silk fabric, as goods such as nylon flag, banner and real silk scarf, shirts.
Fabric needs to carry out pre-treatment usually, and conventional pretreatment mode is: by textile pad pretreatment fluid, then extrude redundant solution by roll, and mangle expression is regulated by the pressure controlling roll; Another kind of pretreatment mode is front and back pretreatment fluid being sprayed on fabric by the mode of spraying; The liquid carrying rate of fabric controls at 20%-90%, preferred 25%-70%.
By the balancing band water yield that pretreated fabric drying to Room is depressed, the resin be retained in fabric can absorb and fixing ink when printing; On the other hand, too much cull may hinder the infiltration of ink.
Stamp can be realized by the ink-jet decorating machine of some main flows, as the Mmaki TX series printing machine of Japan and the Artistri series printing machine of Du Pont.Ink coverage density is 5-15g/m 2, specifically depending on the receptivity of required color and pre-treatment resin.PRINTED FABRIC finally carries out evaporating and washing completes.
Embodiment
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, setting forth the present invention further below.
Ink-jet printing ink, comprises the ink of at least four kinds of different colours, specific as follows: it is formulated by turmeric yellow 79 (C.I.Acid Yellow 79) that ink comprises a kind of yellow water-base ink, and the mass percentage of its dyestuff accounts for 4%-8%; It is formulated by Xylene Red 52 (C.I.Acid Red52) that ink comprises a kind of red water-base ink, and the mass percentage of its dyestuff accounts for 6%-10%; It is formulated by acid blue 260 (C.I.Acid Blue 260) that ink comprises a kind of blue water-based ink, and the mass percentage of its dyestuff accounts for 3%-7%; It is formulated by acid blue 9 (C.I.Acid Blue 9) that ink comprises a kind of cyan water-base ink, and the mass percentage of its dyestuff accounts for 6%-10%; It is formulated by Acid Black 1 94 (C.I.Acid Black 194) that ink comprises a kind of black water ink, and the mass percentage of its dyestuff accounts for 6%-10%.
Ink set at least comprises a kind of water-miscible organic solvent, and the auxiliary agent such as tensio-active agent, sterilant, buffer reagent, and specifically fills a prescription and mainly determine according to the requirement of surface tension, viscosity, kind of dyes and fabric types; The general water containing 35%-85% in acid dye ink, the water-miscible organic solvent of 5%-65%.
Water-miscible organic solvent mainly comprises, alcohols, ketone or ketols, ethers etc.; Alcoholic solvent comprises: ethylene glycol, Diethylene Glycol, propylene glycol, butyleneglycol, triglycol, n-propyl alcohol, thiodiglycol, hexylene glycol, Virahol etc.; Ketone or ketols solvent comprise: pimelinketone, acetone, methylethylketone, 2-Pyrrolidone, methyl-2-pyrrolidone, Pyranton etc.; Ether solvent comprises: ethylene glycol monomethyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, triglycol monomethyl ether, triglycol one ether etc.
Tensio-active agent mainly comprises: ethoxyacetylene glycol (the Surfynols series product as US Air gasification work), oxyethyl group primary alconol (the Tomadol series product as Tomah company of the U.S.), oxyethyl group secondary alcohol (the Tergitol series product as union carbide corporation of the U.S.), organo-siloxane (the Silwet series product of GE company of the U.S.), fluorine surfactant (the Zonyl series product of E.I.Du Pont Company) etc.
Tensio-active agent accounts for the 0.01%-5% of ink total amount, preferred 0.2%-2%; The surface tension of ink is about 20-70mN/m, and be preferably 30-50mN/m, viscosity is 10-30cP.
The stability of ink is good, can not block printing device, and nontoxic, without obvious peculiar smell; Ink is used for nylon, real silk fabric, as goods such as nylon flag, banner and real silk scarf, shirts.Fabric needs to carry out pre-treatment usually, and conventional pretreatment mode is: by textile pad pretreatment fluid, then extrude redundant solution by roll, and mangle expression is regulated by the pressure controlling roll; Another kind of pretreatment mode is front and back pretreatment fluid being sprayed on fabric by the mode of spraying; The liquid carrying rate of fabric controls at 20%-90%, preferred 25%-70%.By the balancing band water yield that pretreated fabric drying to Room is depressed, the resin be retained in fabric can absorb and fixing ink when printing; On the other hand, too much cull may hinder the infiltration of ink.Stamp can be realized by the ink-jet decorating machine of some main flows, as the Mmaki TX series printing machine of Japan and the Artistri series printing machine of Du Pont.Ink coverage density is 5-15g/m 2, specifically depending on the receptivity of required color and pre-treatment resin.PRINTED FABRIC finally carries out evaporating and washing completes.
Embodiment:
Ink is prepared according to the formula of table 1, the ink the prepared nylon leaching film of 0.22 micron filters, and wherein water is ultrapure water, and dyestuff is the salt-free high pure dye of ink-jet level, Surfynol 465 is the tensio-active agent of US Air gasification work, and Proxel GXL is the sterilant of Avecia company.
Table 1 ink set
Table 2 ink performance
Mimaki TX400 printing machine is loaded with yellow, red, blue, black four chromatic ink.With the nylon cloth of 200 Denier, through padding pretreatment fluid post-drying, then steam 15 minutes in 120 DEG C of gas after printing with digital decorating machine, finally carry out cold wash and each 10 minutes of hot water wash, dry and obtain tprinted Fabrics.
The color depth of PRINTED FABRIC is evenly full, and the color of fabric pros and cons is substantially close, and decalcomania edge does not have obvious bleeding yet; The light fastness (xenon lamp irradiates 40 hours) of PRINTED FABRIC is tested according to the testing method of ISO105-B02, and light fastness grade is in table 3.
Table 2 light fastness
More than show and describe ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.

Claims (10)

1. an ink-jet printing ink formula, comprises water-base ink major ingredient, water-base ink auxiliary material, it is characterized in that, described water-base ink major ingredient is made up of the material of following mass percent: the dyestuff of 5%-9%, the Diethylene Glycol of 20%-25%, 5%-20% 1,2-propylene glycol, the hexanolactam of 0-5%, the 2-Pyrrolidone of 0-15%, the glycerine of 5%-10%, the Surfynol 465 of the PEG600 of 0-5%, 0.2%-2%, the Proxel GXL of 0.1%-0.5%, surplus is water.
2. a kind of ink-jet printing ink formula according to claim 1, is characterized in that: described water-base ink auxiliary material comprises at least one water-miscible organic solvent, at least one tensio-active agent, at least one sterilant, at least one buffer reagent.
3. a kind of ink-jet printing ink formula according to claim 1, it is characterized in that: a kind of ink-jet printing ink formula, comprise at least one yellow water-base ink, described yellow water-base ink is formulated and the mass percent accounting for ink total amount is 4%-8% by turmeric yellow 79 (C.I.Acid Yellow 79).
4. a kind of ink-jet printing ink formula according to claim 1, it is characterized in that: a kind of ink-jet printing ink formula, comprise at least one red water-base ink, described red water-base ink is formulated and the mass percent accounting for ink total amount is 6%-10% by Xylene Red 52 (C.I.Acid Red 52).
5. a kind of ink-jet printing ink formula according to claim 1, it is characterized in that: a kind of ink-jet printing ink formula, comprise at least one blue water-based ink, described blue water-based ink is formulated and the mass percent accounting for ink total amount is 3%-7% by acid blue 260 (C.I.Acid Blue 260).
6. a kind of ink-jet printing ink formula according to claim 1, it is characterized in that: a kind of ink-jet printing ink formula, comprise at least one cyan water-base ink, described cyan water-base ink is formulated and the mass percent accounting for ink total amount is 6%-10% by acid blue 9 (C.I.Acid Blue 9).
7. a kind of ink-jet printing ink formula according to claim 1, it is characterized in that: a kind of ink-jet printing ink formula, comprise at least one black water ink, described yellow water-base ink is formulated and the mass percent accounting for ink total amount is 6%-10% by Acid Black 1 94 (C.I.Acid Black 194).
8. a kind of ink-jet printing ink formula according to claim 1, it is characterized in that: a kind of ink-jet printing ink formula, containing the yellow water-base ink that and the mass percent that account for ink total amount formulated by turmeric yellow 79 (C.I.Acid Yellow 79) is 4%-8%, by Xylene Red 52 (C.I.Acid Red 52), the formulated and mass percent accounting for ink total amount is the red water-base ink of 6%-10%, by acid blue 260 (C.I.Acid Blue 260), the formulated and mass percent accounting for ink total amount is the blue water-based ink of 3%-7%, by acid blue 9 (C.I.Acid Blue 9), the formulated and mass percent accounting for ink total amount is the cyan water-base ink of 6%-10%, formulated and the mass percent accounting for ink total amount is at least four kinds in the yellow water-base ink of 6%-10% by Acid Black 1 94 (C.I.Acid Black 194).
9. a kind of ink-jet printing ink formula according to claim 1, it is characterized in that: water is ultrapure water, dyestuff is the salt-free high pure dye of ink-jet level, and Surfynol 465 is the tensio-active agent of US Air gasification work, and Proxel GXL is the sterilant of Avecia company.
10. a kind of ink-jet printing ink formula according to claim 2, it is characterized in that: water-miscible organic solvent accounts for the 5%-65% of ink total amount, described tensio-active agent accounts for the 0.1%-5% of ink total amount.
CN201510012123.1A 2015-01-09 2015-01-09 A kind of ink-jet printing ink formula Active CN104761951B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63314285A (en) * 1987-06-16 1988-12-22 Ricoh Co Ltd Water-base ink composition
US6443569B1 (en) * 1998-07-08 2002-09-03 Ciba Specialty Chemicals Corporation Method for printing fibrous textile materials according to the ink jet printing technique
CN1451698A (en) * 2002-04-17 2003-10-29 幸伟 Water quick-drying ink for ink-jet printer
CN1478829A (en) * 2003-04-03 2004-03-03 大连思创信息材料有限公司 Multicolor composite ink used for inkjet printing machine

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63314285A (en) * 1987-06-16 1988-12-22 Ricoh Co Ltd Water-base ink composition
US6443569B1 (en) * 1998-07-08 2002-09-03 Ciba Specialty Chemicals Corporation Method for printing fibrous textile materials according to the ink jet printing technique
CN1451698A (en) * 2002-04-17 2003-10-29 幸伟 Water quick-drying ink for ink-jet printer
CN1478829A (en) * 2003-04-03 2004-03-03 大连思创信息材料有限公司 Multicolor composite ink used for inkjet printing machine

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