CN1047572C - Chlorine dioxide generator - Google Patents
Chlorine dioxide generator Download PDFInfo
- Publication number
- CN1047572C CN1047572C CN97105713A CN97105713A CN1047572C CN 1047572 C CN1047572 C CN 1047572C CN 97105713 A CN97105713 A CN 97105713A CN 97105713 A CN97105713 A CN 97105713A CN 1047572 C CN1047572 C CN 1047572C
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- CN
- China
- Prior art keywords
- reaction chamber
- chamber
- agitator
- reaction
- retort
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 17
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 53
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 238000007600 charging Methods 0.000 claims description 6
- 230000036632 reaction speed Effects 0.000 claims description 2
- 239000012295 chemical reaction liquid Substances 0.000 abstract 1
- 238000005192 partition Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000003014 ion exchange membrane Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000003434 inspiratory effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000009711 regulatory function Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The invention discloses a chlorine dioxide generating device. Two raw material tanks (1a) and (1b) are communicated with a reaction chamber (4) in a reaction tank (17) through two feeding pipes (13a) and (13b) which are respectively connected with regulating valves (3a) and (3b), a partition plate (16) is arranged at the lower part of the inner cavity of the reaction tank (17) to ensure that the reaction chamber (4) is formed above the inner cavity of the reaction tank and a stirrer chamber (18) is formed below the inner cavity of the reaction tank, a stirrer (10) is arranged in the stirrer chamber (18) and a stirring rod (8) is positioned in the reaction chamber (4), a safety valve (5) and a one-way valve (6) are communicated on the outer wall of the upper part of the reaction chamber (4), a reaction liquid discharge port (9) is arranged on the outer wall of the bottom part of the reaction chamber, and a product outlet (7) communicated with a jet pump (11) is arranged on the outer wall of the reaction chamber, so that the device has the advantages of simple structure, high content of chlorine dioxide in the generated gas.
Description
The present invention relates to a kind of chemical reaction equipment, be specially a kind of chlorine dioxide generating device.
At present, existing chlorine dioxide generating device can be divided into electrolytic process and chemical method chlorine dioxide generating unit two big classes substantially in the society, the patent No. be 2069863U U.S. Patent Publication a kind of electrolysis chlorine dioxide generating unit, it is to adopt the electrolytic chlorination sodium solution to produce dioxide peroxide, chlorine, foul smell, mixed gass such as hydrogen peroxide, its electrolyzer adopts rare metal to do the moon, positive electrode, and tank room is divided into cathode compartment and anolyte compartment with ion-exchange membrane, though this device can realize producing the task of dioxide peroxide, but its auxiliary facility is many, investment is big, the current consumption height, the ion-exchange membrane lifetime is short, maintenance difficult, in the aerogenesis chlorine dioxide component content low be its unsurmountable defective.Plate tower chlorine dioxide generating device commonly used in industrial production is a kind of typical chemical method chlorine dioxide generating unit, this device is formed by imitating layer column plate and auxiliary facility, complex manufacturing process, bulky, investment is high, speed of reaction is slow, feed stock conversion is low, to react not exclusively be its unsurmountable defective.
Task of the present invention is to provide a kind of simple in structure, low cost of manufacture, speed of reaction is fast, feed stock conversion is high, the high novel chlorine dioxide generating device of dioxide peroxide component content in the aerogenesis.
Technical scheme of the present invention is that the inner chamber of retort is divided into top is that reaction chamber, bottom are two spaces up and down of agitator chamber to the division board by being arranged at retort bottom, but at the indoor device that whisks that is provided with of agitator with rotating speed regulatory function, and the stirring rod that makes its agitator is inserted in the reaction chamber inner chamber, change the rotating speed of stirring rod by the rotating speed that changes agitator, in order to the stirring velocity of change to raw material in the reaction chamber, thereby realization changes the task of raw material reaction speed.Upper end in retort is provided with opening for feed, this opening for feed is connected with the supply pipe that is connected with variable valve of inserting the head tank intracavity bottom, be provided with the reaction solution relief outlet that is provided with control valve with its intracavity inter-connection in the bottom of reaction chamber, be respectively arranged with safety valve and check valve with its intracavity inter-connection on the top of reaction chamber, the outer wall of reaction chamber is provided with products export, and is connected with jet-pump by escape pipe.
Accompanying drawing has provided specific embodiments of the invention.
Embodiment shown in below inciting somebody to action with reference to the accompanying drawings is described as follows concrete structure of the present invention:
In the accompanying drawings, be head tank (1a) and (1b), be charging opening (2a) and (2b), (3a) be variable valve (3b), (4) are reaction chamber, (5) be safety valve, (6) be check valve, (7) are products export, and (8) are stirring rod, (9) be the reaction solution relief outlet, (10) be agitator, (11) are jet-pump, and (12) are vapor pipe, be supply pipe (13a) and (13b), be opening for feed (14a) and (14b), (15) are escape pipe, and (16) are division board, (17) be retort, (18) are the agitator chamber.
With reference to the accompanying drawings, insert supply pipe (13a) and (13b) respectively by being respectively arranged with charging opening (2a) and two head tanks (1a) (2b) and top (1b) at an upper portion thereof, and make its supply pipe (13a) and port (13b) be in head tank (1a) and (1b) bottom in the inner chamber respectively, supply pipe (13a) and (13b) respectively by variable valve (3a) and (3b) back be arranged at two the reaction chamber chargings (14a) on the reaction chamber (4) and (14b) be connected, be provided with division board (16) in retort (17) inner chamber bottom, make and form two spaces up and down in its retort (17) inner chamber, the inner chamber that is the retort (17) of division board (16) top forms reaction chamber (4), the inner chamber of the retort (17) of its division board (16) below forms agitator chamber (18), in agitator chamber (18), be provided with agitator (10), and be in the reaction chamber (4) after making stirring rod (8) on its agitator (10) by division board (16), the outer wall of reaction chamber (4) bottom is provided with and reaction solution relief outlet (9) its intracavity inter-connection and that control valve control is arranged, the outer wall on reaction chamber (4) top is provided with the safety valve (5) of its intracavity inter-connection and has the check valve (6) of vapor pipe (12), the outer wall of reaction chamber (4) is provided with the products export (7) that is connected with escape pipe (15) one ends, escape pipe
(15) the other end is connected with jet-pump (11).
Below will be described as follows working process of the present invention with reference to the accompanying drawings:
Use when of the present invention, at first dioxide peroxide is produced raw material insert head tank ((1a) and (1b) in, open variable valve (3a) and (3b) and jet-pump (11) and agitator (10), at this moment jet-pump (10) produces negative pressure from interior air-breathing the making of reaction chamber (4) in it, under the suction function in reaction chamber, head tank (1a) and (1b) in raw material through supply pipe (13a) and (13b) and variable valve (3a) and (3b) enter in the reaction chamber (4), under the turning effort of stirring rod (8), make raw material thorough mixing and reaction produce dioxide peroxide, this dioxide peroxide is siphoned away to send into by jet-pump through product outlet (7) and escape pipe (15) in the effect of jet-pump (11) and makes use, thereby finishes working process of the present invention.Variable valve (3a) and effect (3b) set among the present invention are in order to regulate the input of control raw material, to adapt to different demands.The effect of set safety valve (5) and check valve (6) is that inspiratory capacity deficiency when jet-pump (11) is when causing pressure in the reaction chamber (4) to be higher than external atmosphere pressure among the present invention; reaction chamber (4) pressure inside will be opened, be eliminated to check valve (6) automatically; when the pressure in the reaction chamber (4) is increased to certain value; safety valve (5) and check valve (6) will start simultaneously, to realize the task of interlock protection.
The present invention has following evident characteristic, and the one, because overall structure is simple, so have manufacturing cost Low, be suitable for the characteristics that popularize; The 2nd, owing to adopted the scheme that raw material is stirred, so tool The speed that responds is fast, feed stock conversion height, the high characteristics of chlorine dioxide component content in the aerogenesis; The 3rd, by In having adopted control valve (3a) and (3b) scheme of control raw material charging, can adapt to not so have The characteristics of needs that have the applying unit of different demand tolerance with the time; The 4th, owing to adopted safety valve With the scheme of check valve duplicate protection, so have characteristics safe and reliable to operation.
In sum, can effectively realize task of the present invention, for society provides a kind of simple in structure, system Cause low, reaction rate is fast, feed stock conversion is high, high novel of chlorine dioxide component content in the aerogenesis Chlorine dioxide generating device.
Claims (2)
1, chlorine dioxide generating device, comprise head tank (1a) and (1b), charging opening (2a) and (2b), variable valve (3a) and (3b), reaction chamber (4), safety valve (5), check valve (6), products export (7), stirring rod (8), reaction solution relief outlet (9), agitator (10), jet-pump (11), vapor pipe (12), supply pipe (13a) and (13b), opening for feed (14a) and (14b), escape pipe (15), division board (16), retort (17), agitator chamber (18), it is characterized in that inserting supply pipe (13a) and (13b) respectively by being respectively arranged with charging opening (2a) and two head tanks (1a) (2b) and top (1b) at an upper portion thereof, and make its supply pipe (13a) and port (13b) be in head tank (1a) and (1b) bottom in the inner chamber respectively, supply pipe (13a) and (13b) respectively by variable valve (3a) and (3b) back be arranged at two the reaction chamber opening for feeds (14a) on the reaction chamber (4) and (14b) be connected, be provided with division board (16) in retort (17) inner chamber bottom, make and form two spaces up and down in its retort (17) inner chamber, the inner chamber that is the retort (17) of division board (16) top forms reaction chamber (4), the inner chamber of the retort (17) of its division board (16) below forms agitator chamber (18), in agitator chamber (18), be provided with agitator (10), and be in the reaction chamber (4) after making stirring rod (8) on its agitator (10) by division board (16), the outer wall of reaction chamber (4) bottom is provided with and reaction solution discharge (9) its intracavity inter-connection and that control valve control is arranged, the outer wall on reaction chamber (4) top is provided with the safety valve (5) of its intracavity inter-connection and has the check valve (6) of vapor pipe (12), the outer wall of reaction chamber (4) is provided with the products export (7) that is connected with escape pipe (15) one ends, and the other end of escape pipe (15) is connected with jet-pump (11).
2, chlorine dioxide generating device according to claim 1, it is characterized in that said agitator (10) is for having the adjustable agitator of rotating speed, and pass through to change the stirring velocity of the rotating speed change of stirring rod (8), thereby realize changing the task of raw material reaction speed to the interior raw material of reaction chamber (4).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97105713A CN1047572C (en) | 1997-03-10 | 1997-03-10 | Chlorine dioxide generator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97105713A CN1047572C (en) | 1997-03-10 | 1997-03-10 | Chlorine dioxide generator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1164507A CN1164507A (en) | 1997-11-12 |
| CN1047572C true CN1047572C (en) | 1999-12-22 |
Family
ID=5168022
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97105713A Expired - Fee Related CN1047572C (en) | 1997-03-10 | 1997-03-10 | Chlorine dioxide generator |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1047572C (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2168856Y (en) * | 1993-10-16 | 1994-06-15 | 中国人民解放军环境科学研究中心成都军区研究所 | High pure chlorine dioxide generator |
| CN2169622Y (en) * | 1993-01-12 | 1994-06-22 | 大连理工大学 | Automatically controlled ClO2 generating system |
| CN2214411Y (en) * | 1995-01-27 | 1995-12-06 | 田俊文 | Chlorine dioxide disinfectant generator |
| CN1114632A (en) * | 1994-07-08 | 1996-01-10 | 南京理工大学 | Method for preparation of chlorine dioxide and generator thereof |
| CN1138554A (en) * | 1995-06-20 | 1996-12-25 | 王鸣琴 | Prodn. plant and technique of stabitity ClO2 |
-
1997
- 1997-03-10 CN CN97105713A patent/CN1047572C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2169622Y (en) * | 1993-01-12 | 1994-06-22 | 大连理工大学 | Automatically controlled ClO2 generating system |
| CN2168856Y (en) * | 1993-10-16 | 1994-06-15 | 中国人民解放军环境科学研究中心成都军区研究所 | High pure chlorine dioxide generator |
| CN1114632A (en) * | 1994-07-08 | 1996-01-10 | 南京理工大学 | Method for preparation of chlorine dioxide and generator thereof |
| CN2214411Y (en) * | 1995-01-27 | 1995-12-06 | 田俊文 | Chlorine dioxide disinfectant generator |
| CN1138554A (en) * | 1995-06-20 | 1996-12-25 | 王鸣琴 | Prodn. plant and technique of stabitity ClO2 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1164507A (en) | 1997-11-12 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANDONG SHANDA RUITE ENVIRONMENTAL PROTECTION TE Free format text: FORMER OWNER: LIANG HUA Effective date: 20060512 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20060512 Address after: 250061, No. ten, No. 69, Ji'nan, Shandong Patentee after: Shandong great environmental protection technology Co., Ltd. Address before: 257055 No. 107, Qingzhou Road, Dongying, Shandong Patentee before: Liang Hua |
|
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |