CN104746675A - Glass welded composite vacuum insulation board and production method thereof - Google Patents

Glass welded composite vacuum insulation board and production method thereof Download PDF

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Publication number
CN104746675A
CN104746675A CN201310721491.4A CN201310721491A CN104746675A CN 104746675 A CN104746675 A CN 104746675A CN 201310721491 A CN201310721491 A CN 201310721491A CN 104746675 A CN104746675 A CN 104746675A
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vacuum
vacuum chamber
composite
plate
solder
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CN201310721491.4A
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戴长虹
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Individual
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/242Slab shaped vacuum insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/10Insulation, e.g. vacuum or aerogel insulation

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  • Joining Of Glass To Other Materials (AREA)

Abstract

The invention discloses a glass welded composite vacuum insulation boardproduction method. The glass welded composite vacuum insulation board comprises a panel, core veneers and a vacuum cavity, and is characterized in that the panel is fixed on the upper outer surface of the vacuum cavity through either a welding way or a gluing way, the core veneers are placed at the inner bottom of the vacuum cavity, and the panel and/or the core veneers are used for providing additional strength to the vacuum cavity to ensure the smoothness of the vacuum cavity at barometric pressure; the vacuum cavity is a sealed cavity carrying out glass welding and sealing at constant pressure and high pressure and high temperature sealing in vacuum to low carbon steel plates, the sealing is that an extraction opening preformed in the vacuum cavity is sealed by the low temperature steel plate by virtue of a low temperature solder in a vacuum furnace according to a liquid sealing theory,, the low temperature solder comprises a low temperature metal and an alloy solder, and a support is arranged in the vacuum cavity. A production method of the composite vacuum insulation board provided by the invention is simple in process, the defects of an existing insulation board and vacuum insulated panel can be overcome, and the strength, heat insulation, sound insulation, fire resistance and decorative function can be enhanced.

Description

Composite vacuum insulating plate of glass solder and preparation method thereof
Technical field
The present invention relates to energy-saving building technology field, particularly relate to composite vacuum insulating plate of a kind of glass solder and preparation method thereof.
Background technology
Current building exterior wall heat preserving material used is divided into A level heat insulating material and B level heat insulating material, and the fireproof performance of A level heat insulating material is good, but its heat-insulating property, water resistance etc. are all lower than B level heat insulating material, and there is the problems such as price is high, complicated construction technique; B level heat insulating material has the advantages such as cost is low, good heat insulating, construction technology are ripe, but its durability is bad, heat resistance is poor, easy firing, a large amount of poison gas is not only discharged during burning, and spreading of big fire can be accelerated, so prohibit the use organic insulation material for exterior-wall heat insulation in highrise building and public building.Vacuum heat-insulating plate was applied to building heat preservation field in recent years, its major advantage be belong to A level heat insulating material, good heat insulating, thickness is thin, unit mass is light, but also have that obvious shortcoming is as low in vacuum bag poor air-tightness, puncture-resistant intensity, edge exists cold bridge, soon, easily rise bag, insulation life-span of vacuum decay is short etc.Therefore, building heat preservation needs the new A level heat insulating material researching and developing good heat insulating, long service life.
Applicant discloses a series of evacuated panel and preparation method thereof in July, 2013, although solve the contradiction and problems of the aspect such as fire prevention, insulation, application life that existing heat insulating material exists, but owing to directly metal sheet being welded together, so its edge exists obvious cold bridge, its heat-insulating property is made not reach optimum state.
Summary of the invention
technical problem to be solved by this invention is for existing building insulating board, warming plate, the defect that vacuum heat-insulating plate exists, composite vacuum insulating plate of a kind of novel glass solder and preparation method thereof is provided, the preparation method technique of the composite vacuum insulating plate of this glass solder is simple, prepared composite vacuum insulating plate can overcome existing insulating board, the deficiency of vacuum heat-insulating plate and warming plate, effectively can ensure the tightness of composite vacuum insulating plate, increase the service life, and its intensity and heat insulation can be increased, sound insulation, fireproof performance, also there is good decorative effect simultaneously.
In order to solve the problems of the technologies described above, the invention provides a kind of composite vacuum insulating plate of glass solder, comprise panel, central layer and vacuum chamber, it is characterized in that described panel is fixed on the upper surface outside described vacuum chamber by welding or bonding mode, described central layer is placed on the bottom in described vacuum chamber, described panel and or described central layer provide additional strength for described vacuum chamber, ensure vacuum chamber planarization under atmospheric pressure, described vacuum chamber welds edge sealing by low carbon steel plate at constant-pressure and high-temperature lower-glass, high temperature seals and the closed cavity of formation under vacuo, the coefficient of thermal expansion of described low carbon steel plate and described glass solder matches, described sealing utilizes solder according to hydraulic seal principle automatic-sealed in a vacuum furnace pre-extract opening on vacuum chamber, described solder comprises low-temperature metal and solder, have supporter in described vacuum chamber, above support makes separately or directly formed on vacuum chamber inwall or on central layer.
In order to solve the problems of the technologies described above, the invention provides a kind of preparation method of composite vacuum insulating plate of glass solder, it is characterized in that comprising the following steps:
The first step, make one piece of panel, one piece of central layer and two pieces of low carbon steel plates for the formation of vacuum chamber respectively according to the shape of the composite vacuum insulating plate of the glass solder of required making and size, two pieces of low carbon steel plates for the formation of vacuum chamber are carried out flanging shaping and on one piece of low carbon steel plate or and central layer on make supporter and extract opening;
Second step, first by the weld coated glass solder of the lower low carbon steel plate in two pieces of low carbon steel plates, again central layer is placed on consistency from top to bottom between two pieces of low carbon steel plates to be combined, then send in edge sealing heating furnace, by the heat fused of glass solder, cooling solidification, the edge of two pieces of low carbon steel plates is hermetic welded together; Vacuum chamber after edge sealing is joined together to form composite plate by welding or bonding mode and panel; In extract opening, place solder, composite plate is sent in vacuum drying oven, once can send into one to several piece;
3rd step, first vacuum drying oven is warming up to the temperature of bleeding, again vacuum drying oven is evacuated to below 0.1Pa, then vacuum drying oven is warming up to the temperature of sealing, solder fusing is by extract opening self-closed, with stove cooling, solder solidify rear to vacuum chamber realize tightness welding, open the composite vacuum insulating plate that vacuum drying oven obtains glass solder.
Wherein, the composite vacuum insulating plate of described glass solder comprises the various forms of sheet materials such as surface plate, curved slab, bending plate, sketch plate.
Wherein, the composite vacuum insulating plate of described glass solder has connector for installing or groove or hole etc.
Wherein, the composite vacuum insulating plate of described glass solder or the surrounding of vacuum chamber scribble fluid sealant or structure glue.
Wherein, described panel is metal sheet, ceramic wafer, glass plate, plastic plate or composite plate etc., can have decoration, overcoat above it and on the soffit of vacuum chamber, as coating, electrodeposited coating, F-C paint etc.;
Further, the preferred ultra thin plate of described panel, with weight reduction and cost;
Further, described panel can be commaterial, also can be two kinds of different materials.
Wherein, the surface of described central layer can be coated with low-radiation film, as aluminium film etc.
Wherein, described panel can connect as one with vacuum chamber before vacuumizing or in vacuum or after vacuumizing.
Wherein, described bonding employing bonding adhesive, described bonding adhesive comprises organic gel, inorganic glue and composite adhesive, is commercially available prod; Described organic gel comprises thermosetting cement, PUR etc., and preferred resistant to elevated temperatures bonding adhesive, as phenolic resins, epoxy resin, organic siliconresin etc.
Wherein, described central layer can be one to several layers;
Wherein, described vacuum chamber is the air-tight cavity be welded by a piece or two pieces of low carbon steel plates, and the C content of described low carbon steel plate is not more than 0.06%, preferred enamel low carbon steel plate, and thickness is 0.3-3mm, preferred 0.3-1mm.
Wherein, described vacuum chamber can be one to several, and when described vacuum chamber is two, upper and lower two vacuum chambers stack bonding along the diagonal dislocation of lower upper surface, make it form overlap edge, to reduce edge cold bridge impact when described composite evacuated plate is installed.
Wherein, the low carbon steel plate of described vacuum chamber can adopt mirror board, if its surface is senior finish, or its inner surface makes it have extremely low emissivity, as aluminizer etc. through process.
Wherein, the inwall of described vacuum chamber can have coating that is heat insulation, sound insulation; Can have getter in described vacuum chamber, getter is automatic activation under high temperature, high vacuum.
Wherein, described glass solder refers to and utilizes glass solder at high temperature to be welded together by two pieces of low carbon steel plates, commercially available low temperature glass solder selected by described glass solder, and its welding temperature is generally 380-480 DEG C, selects low temperature glass solder to be conducive to reducing costs, improving production capacity etc.; Described glass solder, certain pressure can be applied, namely pressure welding is carried out, with make welding and combine more solid and reliable, vacuum chamber and plate face more smooth, and can eliminate because solder thickness is uneven, vacuum chamber surface irregularity can not get supporter and evenly effectively supports and the edge sealing stress that causes; Described pressure is approximately 0.1MPa, described in the mode of exerting pressure can adopt mechanical compression, air pressure or hydraulic pressure etc.
Wherein, described extract opening can be arranged on surface or the side of vacuum chamber.
Wherein, described extract opening can directly be made in vacuum chamber punching press, also first can make extract opening and be welded on vacuum chamber again.
Wherein, described edge sealing heating furnace or vacuum drying oven are the single-unit furnaces of batch production, or the tunnel kiln that continous way is produced; The edge sealing temperature of described edge sealing heating furnace is 360-500 DEG C, is preferably 380-480 DEG C; The vacuum of described vacuum drying oven is 0.001-0.1Pa, is preferably 0.005-0.05Pa; The sealing temperature of described vacuum drying oven is 150-450 DEG C, is preferably 280-350 DEG C.
Wherein, above support can be the supporter made separately, also can be the projection directly formed on the low carbon steel plate making vacuum chamber or on central layer, as point, line etc.;
Further, when above support makes separately, be point, line or the net etc. that adopt the materials such as metal, glass, pottery, high polymer to make.
Wherein, above support has one to several layers.
Wherein, above support can directly put into described vacuum chamber, also can form one with the inwall of described vacuum chamber or central layer by punching press, roll extrusion and welding, the mode such as bonding.
The invention has the beneficial effects as follows:
The present invention replaces metal () to weld with glass solder, coefficient of thermal conductivity due to glass only has 1% of metal even less so can solve the edge cold bridge problem of evacuated panel well, because glass is different with the material of metal so the evacuated panel of glass solder has better sound insulation value; The low carbon steel plate matched with coefficient of thermal expansion and glass solder replaces conventional metal sheet, solves the Welding Problems between glass and metal; An about atmospheric pressure is applied when glass solder, glass solder is made to solidify the sizing of final vacuum chamber in using state, eliminate edge sealing stress, avoid the evacuated panel in use damage that causes because of unbalance stress of brittle glass solder, thus ensure that heat-proof quality and the application life of evacuated panel; The composite vacuum insulating plate of glass solder of the present invention forms primarily of metal material, and panel can select inorganic material or fire proofing, so have good fireproof performance; Its panel of the composite vacuum insulating plate of glass solder of the present invention can select multiple decorative panel, so have good decorative effect, does not need to do decorative layer again after installation, not only saves material and also saves manpower and time; The composite vacuum insulating plate of glass solder of the present invention is composited by multiple material, so not only thickness is thin, lightweight, and has very high mechanical strength; The composite vacuum insulating plate of glass solder of the present invention adopts normal temperature and pressure lower sealing edge, high-temperature vacuum lower sealing, its manufacture craft is simple, cost of production is low, can mechanization, automation, production in enormous quantities, product can be widely used in interior wall, exterior wall and curtain wall, the consumption that can greatly reduce material and the energy, the weight alleviating building, shortening building cycle; The composite vacuum insulating plate of glass solder of the present invention not only can be applied to new building, and the energy-conservation of existing building and outward appearance transformation can be applied to, not only can wet combining but also can be cladding, can greatly save the engineering time compared with existing heat insulating material, improve heat insulation and soundproof effect; The composite vacuum insulating plate of glass solder of the present invention can also make sketch plate, is directly used in the production of refrigerator, refrigerator-freezer, refrigerator carriage, incubator, cold store, frozen products insulated container etc.; High-temperature field can also be used for, as the Surgery therapy etc. of various body of heater.
Accompanying drawing explanation
Fig. 1 is the composite vacuum insulating plate structural representation of glass solder of the present invention.
In figure: 1. panel, 2. central layer, 3. vacuum chamber, 4. supporter, 5. extract opening, 6. solder, 7. glass solder.
Detailed description of the invention
Below adopt embodiment and accompanying drawing to describe embodiments of the present invention in detail, to the present invention, how application technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
See accompanying drawing, the composite vacuum insulating plate of glass solder is by panel 1, central layer 2, vacuum chamber 3 and supporter 4 form, panel 1 is metal sheet, ceramic wafer, glass plate, plastic plate or composite plate, the armorplate glass that preferred 3-5mm is thick, ceramic wafer, stone plate, artificial stone plate or Aluminiumplastic composite panel etc., and be pasted onto on the soffit of vacuum chamber 3 by high temperature adhesive, high temperature adhesive can select the resistant to elevated temperatures phenolic resin glue of normal temperature or hot setting, epoxide-resin glue, the organic adhesion agents such as organic siliconresin glue and polyimides and conventional inorganic adhesive or organo-mineral complexing bonding adhesive etc., central layer 2 is low carbon steel plate, ceramic wafer, glass plate, plastic plate or composite plate, the aluminium alloy plate that the armorplate glass that preferred 3-4mm is thick, 1-2mm are thick or fiber composite plate etc., the low carbon steel plate that vacuum chamber 3 is 0.3-1.0mm by thickness is welded, supporter 4 is made up of metal, pottery, glass or high polymer, and modes such as utilizing printing, print, spray, machinery lays becomes dot matrix to be distributed in vacuum chamber 3, and the bearing height of supporter 4 is advisable with 0.15-1.0mm, and the diameter of the strong point is advisable with 0.3-1.0mm, the air exhaust nozzle that extract opening 5 is directly stamped out by one piece of low carbon steel plate of vacuum chamber 3 and can form, and place solder 6 in can as tin, zinc, magnesium and low-melting alloy thereof, and solder 6 dissolves and automatically to seal extract opening 5 afterwards.The preparation method of the composite vacuum insulating plate of glass solder is as follows: the low carbon steel plate that first cutting two pieces is onesize for making vacuum chamber 3, and utilize the mode of punching press to two pieces of low carbon steel plates carry out flanging shaping and make extract opening 5; Secondly cutting one piece of glass plate is as central layer 2, and on glass plate, punching forms bleed-off passage, is printed by glass ink and forms supporter 4 on a glass, after tempering process; By the weld coated glass solder 7 of the lower low carbon steel plate in two pieces of low carbon steel plates, again central layer 2 is placed between two pieces of low carbon steel plates, two pieces of low carbon steel plate consistencies from top to bottom are combined, then send in edge sealing heating furnace, the edge sealing temperature of edge sealing heating furnace is 400-450 DEG C, by the heat fused of glass solder 7, cooling solidification, the edge of two pieces of low carbon steel plates is hermetic welded together, complete edge sealing; Again produce one piece of armorplate glass as panel 1, choose epoxide-resin glue as bonding adhesive, soffit panel 1 being pasted onto vacuum chamber 3 forms composite plate; Finally place solder, one piece or composite plate are in batch sent in vacuum drying oven, first heating make epoxy resin adhesive curing after be evacuated to below 0.1Pa again, temperature when vacuumizing preferably more than 300 DEG C, to promote the eliminating of gas in vacuum chamber 3, after vacuum reaches, be warming up to sealing temperature again, solder 6 melts extract opening 5 self-closed, lowers the temperature with stove, solder 6 solidifies final vacuum chamber 3 and realizes airtight sealing, opens the composite vacuum insulating plate that vacuum drying oven obtains glass solder; In order to protect the impact of vacuum chamber 3 and elimination heat bridge, the surrounding of vacuum chamber 3 can smear fluid sealant or structure glue; In order to protect vacuum chamber 3 and play decoration function, extract opening 5 smears fluid sealant, the upper surface of vacuum chamber 3 can brushing F-C paint.
All above-mentioned this intellectual properties of primary enforcement, not setting restriction this new product of other forms of enforcement and/or new method.Those skilled in the art will utilize this important information, and foregoing is revised, to realize similar implementation status.But all modifications or transformation belong to the right of reservation based on new product of the present invention.
The above is only preferred embodiment of the present invention, and be not restriction the present invention being made to other form, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the Equivalent embodiments of equivalent variations.But everyly do not depart from technical solution of the present invention content, any simple modification, equivalent variations and the remodeling done above embodiment according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.

Claims (10)

1. the composite vacuum insulating plate of a glass solder, comprise panel, central layer and vacuum chamber, it is characterized in that described panel is fixed on the upper surface outside described vacuum chamber by welding or bonding mode, described central layer is placed on the bottom in described vacuum chamber, described panel and or described central layer provide additional strength for described vacuum chamber, ensure vacuum chamber planarization under atmospheric pressure, described vacuum chamber welds edge sealing by low carbon steel plate at constant-pressure and high-temperature lower-glass, high temperature seals and the closed cavity of formation under vacuo, the coefficient of thermal expansion of described low carbon steel plate and described glass solder matches, described sealing utilizes solder according to hydraulic seal principle automatic-sealed in a vacuum furnace pre-extract opening on vacuum chamber, described solder comprises low-temperature metal and solder, have supporter in described vacuum chamber, above support makes separately or directly formed on vacuum chamber inwall or on central layer.
2. the composite vacuum insulating plate of glass solder as claimed in claim 1, is characterized in that the composite vacuum insulating plate of described glass solder comprises surface plate, curved slab, bending plate and sketch plate.
3. the composite vacuum insulating plate of glass solder as claimed in claim 1, is characterized in that described panel or described central layer are metal sheet, ceramic wafer, glass plate, plastic plate or composite plate.
4. the composite vacuum insulating plate of glass solder as claimed in claim 1, is characterized in that the surface of described central layer can be coated with low-radiation film.
5. the composite vacuum insulating plate of glass solder as claimed in claim 1, it is characterized in that described vacuum chamber has one to several, when described vacuum chamber is two, upper and lower two vacuum chambers stack bonding along the diagonal dislocation of lower upper surface, it is made to form overlap edge, to reduce edge cold bridge impact during installation.
6. the composite vacuum insulating plate of glass solder as claimed in claim 1, is characterized in that the inwall of described vacuum chamber can have coating that is heat insulation, sound insulation.
7. the composite vacuum insulating plate of glass solder as claimed in claim 1, is characterized in that described glass solder is pressure welding.
8. the composite vacuum insulating plate of glass solder as claimed in claim 1, is characterized in that above support has one to several layers.
9. the composite vacuum insulating plate of glass solder as claimed in claim 1, is characterized in that there is getter in described vacuum chamber.
10. the preparation method of the composite vacuum insulating plate of the glass solder described in any one of claim 1 to 9, is characterized in that comprising the following steps:
The first step, make one piece of panel, one piece of central layer and two pieces of low carbon steel plates for the formation of vacuum chamber respectively according to the shape of the composite vacuum insulating plate of the glass solder of required making and size, two pieces of low carbon steel plates for the formation of vacuum chamber are carried out flanging shaping and on one piece of low carbon steel plate or and central layer on make supporter and extract opening;
Second step, first by the weld coated glass solder of the lower low carbon steel plate in two pieces of low carbon steel plates, again central layer is placed on consistency from top to bottom between two pieces of low carbon steel plates to be combined, then send in edge sealing heating furnace, by the heat fused of glass solder, cooling solidification, the edge of two pieces of low carbon steel plates is hermetic welded together; Vacuum chamber after edge sealing is joined together to form composite plate by welding or bonding mode and panel; In extract opening, place solder, composite plate is sent in vacuum drying oven, once can send into one to several piece;
3rd step, first vacuum drying oven is warming up to the temperature of bleeding, again vacuum drying oven is evacuated to below 0.1Pa, then vacuum drying oven is warming up to the temperature of sealing, solder fusing is by extract opening self-closed, with stove cooling, solder solidify rear to vacuum chamber realize tightness welding, open the composite vacuum insulating plate that vacuum drying oven obtains glass solder.
CN201310721491.4A 2013-12-25 2013-12-25 Glass welded composite vacuum insulation board and production method thereof Pending CN104746675A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310721491.4A CN104746675A (en) 2013-12-25 2013-12-25 Glass welded composite vacuum insulation board and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310721491.4A CN104746675A (en) 2013-12-25 2013-12-25 Glass welded composite vacuum insulation board and production method thereof

Publications (1)

Publication Number Publication Date
CN104746675A true CN104746675A (en) 2015-07-01

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Application Number Title Priority Date Filing Date
CN201310721491.4A Pending CN104746675A (en) 2013-12-25 2013-12-25 Glass welded composite vacuum insulation board and production method thereof

Country Status (1)

Country Link
CN (1) CN104746675A (en)

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