CN104744613A

CN104744613A - Half-metallocene catalyst containing fluorobenzene amidine, preparation method and application thereof

Info

Publication number: CN104744613A
Application number: CN201310738100.XA
Authority: CN
Inventors: 魏东初; 周辉; 方岳亮
Original assignee: SUZHOU APAC PHARMACEUTICAL TECHNOLOGY Co Ltd
Current assignee: YAPEIXI TECHNOLOGY (JIAXING) CO., LTD.
Priority date: 2013-12-27
Filing date: 2013-12-27
Publication date: 2015-07-01

Abstract

The invention relates to a half-metallocene catalyst containing fluorobenzene amidine, a preparation method and an application thereof. The disclosed half-metallocene catalyst containing fluorobenzene amidine contains electron-withdrawing fluorine-containing groups, a space structure and an electronic structure of the half-metallocene catalyst containing fluorobenzene amidine are different from those of the existing metallocene catalyst. A result of an experiment shows that the half-metallocene catalyst containing fluorobenzene amidine is used in olefin polymerization so that a novel polymer having commercial values and a controllable structure is obtained. In the invention, a fluorobenzene amidine-containing half-metallocene catalyst intermediate produced in the reaction process is a novel compound; the reaction process has the advantages of intelligible route and easy operation, mild reaction condition and easy control.

Description

Fluorine-containing benzene carbon amidine single metallocene catalyst, preparation method and application thereof

Technical field

The invention belongs to the field of chemical synthesis, relate to a kind of fluorine-containing benzene carbon amidine single metallocene catalyst, its preparation method and application thereof.Be applicable to catalyze and synthesize high-molecular weight atactic polyolefine.

Background technology

Many different catalyzer and technique is there is in field of olefin polymerisation.In a large amount of production process, there is the polyolefine normally target product of higher molecular weight and narrower molecular weight distribution, because this kind of polyolefine has better physical strength.Although traditional Ziegler-Natta catalyst can prepare the polyolefine of high molecular, its molecular weight distribution is wider.

The olefin polymerization catalysis that metallocene catalyst is made up of metallocene and organic ligand.Compared with conventional olefin polymerizing catalyst, metallocene catalyst has more excellent polymerization behavior, can give the stuctures and properties of polyolefine material uniqueness, as good impact strength and toughness, and good melting characteristic etc.Many polar monomers and tradition are thought can synthesize new polymeric material with it by the monomer that can not be polymerized.Metallocene catalyst drops into industrial applications in June, 1991 first in the U.S..Along with productive life is to the improve of material requirements, to the research of metallocene catalyst, there are wide application and market outlook.

At present, metallocene catalyst researchist thinks that part is the key of design novel polymerization catalyst jointly.The stereoeffect of part, electronic effect and the catalyst configuration caused thereof have material impact to catalytic performance.Therefore, find new metallocene catalyst part and optimize part synthesis technique, not only can reduce production and research cost, and the space of adjustment metallocene catalyst that can be simple and quick and electronic structure, thus control the process of polymerization.

WO2005090418A1 and WO2007031295A1 reports the preparation of fluorine-containing benzene carbon amidine single metallocene-titanium catalyst, but the preparation of fluorine-containing benzene carbon amidine list zirconocene catalyst there is not yet bibliographical information.

WO2008148499A1, WO2008151776A1 and WO2009063084A2 reports dimerization fluorine-containing benzene carbon amidine list cyclopentadienyl catalyst and is catalyzing and synthesizing the application on supramolecular polypropylene, dimerization fluorine-containing benzene carbon amidine list cyclopentadienyl catalyst, compared with other catalyzer existing, has amazing catalytic activity.

Summary of the invention

The object of this invention is to provide fluorine-containing benzene carbon amidine single metallocene catalyst of series of new and preparation method thereof.

The technical scheme realizing the object of the invention is:

Fluorine-containing benzene carbon amidine single metallocene catalyst, its general formula as shown in the formula (I):

Wherein,

R1 fat tertiary amine, is selected from structure below;

R2 is the saturated fatty alkyl of the straight or branched of C1-C8;

Ar is fluorine-containing aromatic ring and fluorine-containing heterocycle; Ar is selected from

N is 2 ~ 5.

R is structure as shown in the formula (II):

X is chlorine or methyl, and M is titanium or zirconium.

Above-mentioned catalyzer name is called 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-di-isopropyl-2, 4, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-di-isopropyl-2, 3, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-di-isopropyl-3, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-di-isopropyl-2, 3, 4-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-di-isopropyl-2, 3, 6-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-di-isopropyl-2, 4, 5-trifluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium dichloride etc., do not enumerate herein.

Fluorine-containing benzene carbon amidine single metallocene catalyst of the present invention, space structure and electronic structure all differ from existing metallocene catalyst, and experiment proof is applied to olefin polymerization process, can the controlled new polymeric materials with commercial value of generating structure.

Present invention also offers the preparation method of above-mentioned fluorine-containing benzene carbon amidine single metallocene catalyst.

The preparation method of fluorine-containing benzene carbon amidine single metallocene catalyst as shown in the formula (I), comprises the following steps:

A () reacts to obtain aryl amidine with the aryl compound of saturated fatty secondary amine, methyl-magnesium-bromide and cyano group;

(b) with triethylamine reaction reagent, and above-mentioned fragrant amidine and 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination (titanium or zirconium) reaction, obtain 1,2,3,4,5-pentamethylcyclopentadiene base-aryl amidine-dichloride (titanium or zirconium);

C () 1,2,3,4,5-pentamethylcyclopentadiene base-aryl amidine-titanium dichloride and methyl bromide reactive magnesium, obtains product 1,2,3,4,5-pentamethylcyclopentadiene base-aryl amidine-dimethyl (titanium or zirconium).

Preparation method of the present invention is obtained by reacting amidine with secondary amine by cyanophenyl under methyl-magnesium-bromide condition, gained intermediate amidine is with 1 at triethylamine under the condition of alkali, 2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination (titanium or zirconium) is reacted, then with methyl-magnesium-bromide reagent react, two chlorine is replaced into methyl and obtains required catalyzer.Its reaction equation is as follows.

Preparation method's concrete steps of the present invention are:

A () reacts to obtain aryl amidine as shown in figure (III) with the aryl compound of fatty primary secondary amine, methyl-magnesium-bromide and cyano group;

Wherein, R1 fat tertiary amine, is selected from structure below;

R2 is the saturated fatty alkyl of the straight or branched of C1-C8;

N is 2 ~ 5.

(b) with triethylamine reaction reagent, and above-mentioned fragrant amidine and as figure (IV) shown in structure 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination (titanium or zirconium) is reacted, must as schemed structure 1,2 shown in (V), 3,4,5-pentamethylcyclopentadiene base-aryl amidine-dichloride (titanium or zirconium);

Wherein, R1 fat tertiary amine, is selected from structure below;

R2 is the saturated fatty alkyl of the straight or branched of C1-C8;

N is 2 ~ 5.

Wherein, R1 fat tertiary amine, is selected from structure below;

R2 is the saturated fatty alkyl of the straight or branched of C1-C8;

N is 2 ~ 5.

（II）

M is titanium or zirconium.

The fluorine-containing benzene carbon amidine single metallocene catalyst intermediate produced in preparation process of the present invention, its chemical name is N, N-dimethyl-2, 4, 6-trifluoro benzene carbon amidine, N, N-dimethyl-2, 3, 5-trifluoro benzene carbon amidine, N, N-dimethyl-2, 3, 4-trifluoro benzene carbon amidine, N, N-dimethyl-2, 3, 6-trifluoro benzene carbon amidine, N, N-dimethyl-2, 4, 5-trifluoro benzene carbon amidine, N, N-dipropyl-2, 4, 6-trifluoro benzene carbon amidine, N, N-dipropyl-2, 3, 5-trifluoro benzene carbon amidine, N, N-dipropyl-3, 4, 5-trifluoro benzene carbon amidine, N, N-dipropyl-2, 3, 4-trifluoro benzene carbon amidine, N, N-dipropyl-2, 3, 6-trifluoro benzene carbon amidine, N, N-dipropyl-2, 4, 5-trifluoro benzene carbon amidine, N, N-diethyl-2, 4, 6-trifluoro benzene carbon amidine, N, N-diethyl-2, 3, 5-trifluoro benzene carbon amidine, N, N-diethyl-2, 3, 4-trifluoro benzene carbon amidine, N, N-diethyl-2, 3, 6-trifluoro benzene carbon amidine, N, N-diethyl-2, 4, 5-trifluoro benzene carbon amidine etc., do not enumerate herein.

The present invention has positive effect: (1) the invention discloses the fluorine-containing benzene carbon amidine single metallocene catalyst of series of new, is applied to olefin polymerization process, can the controlled new polymeric materials with commercial value of generating structure; (2) the fluorine-containing benzene carbon amidine single metallocene catalyst intermediate produced in reaction process of the present invention is new compound; (3) reaction process clear route of the present invention is easy to operate, and reaction conditions gentleness is easy to control.

Embodiment

(embodiment 1)

(1): the synthesis of preparation N, N-di-isopropyl 2,3-difluoro benzene carbon amidine

Diisopropylamine (16.17g, 0.16mol) is dissolved in 250mL toluene solution, is warming up to 50 DEG C, drip the diethyl ether solution (50mL, 3.0M, 0.15mol) of methyl-magnesium-bromide, after dripping, react after 1.5 hours, white solid is separated out, reaction solution is cooled to 0 DEG C, add the aryl compound (0.15mol) containing cyano group, reaction solution is warming up to room temperature naturally, react after 16 hours, reaction solution adds water (100mL), and extraction is gone out, after organic phase is separated, and aqueous phase extracted with diethyl ether twice (50mL).Organic phase merged, dried over sodium sulfate, filtering sodium sulfate, underpressure distillation concentrates to obtain product (yield 50%).

(2): 1,2,3,4,5-pentamethylcyclopentadiene base-titanous chloride obtains according to the method synthesis in patent CN101077879A.

(3): preparation 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-di-isopropyl 2,3-difluoro benzene carbon amidine)-titanium dichloride.

Triethylamine (2.5mL, 1.83g, 18.1mmol) is added 1,2,3,4,5-pentamethylcyclopentadiene base-titanous chloride (1.03g, 4.7mmol) and N, N-di-isopropyl 2, in toluene (50mL) solution of 3-difluorophenyl amidine (4.7mmol), reaction was at room temperature stirred after 64 hours, after being leached by solid, with toluene (60mL) drip washing filter residue, obtain crude product after filtrate reduced in volume, obtain product (yield 45%) with normal hexane making beating washing.

(4): preparation 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-di-isopropyl 2,3-difluoro benzene carbon amidine)-dimethyl titanium.

1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-di-isopropyl 2,3-difluorophenyl amidine) the adding in toluene (100mL) solution of-titanium dichloride (12.18g, 24.7mmol), be cooled to-78 DEG C, drip methyl-magnesium-bromide (16.5mL, 3.0M diethyl ether solution, 49.5mmol) solution, reaction solution at room temperature stirs 18 hours, reacting liquid filtering, filtrate is concentrated under vacuo obtains crude product, and in normal hexane, (100mL) making beating obtains product (yield 70%).

(embodiment 2)

(1): get N, N-di-isopropyl 2,3-difluoro benzene carbon amidine.

(2): get 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination zirconium.

(3): preparation 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-di-isopropyl 2,3-difluoro benzene carbon amidine)-zirconium dichloride.

Triethylamine (2.5mL, 1.83g, 18.1mmol) is added 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination zirconium (1.05g, 4.7mmol) and N, in toluene (50mL) solution of N-di-isopropyl 2,3-difluorophenyl amidine (4.7mmol), reaction was at room temperature stirred after 64 hours, after solid is leached, with toluene (60mL) drip washing filter residue, after filtrate reduced in volume, obtain crude product, obtain product 1 with normal hexane making beating washing, 2,3,4,5-pentamethylcyclopentadiene base-(N, N-di-isopropyl 2,3-difluoro benzene carbon amidine)-zirconium dichloride (yield 50%).(4) 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-di-isopropyl 2,3-difluoro benzene carbon amidine)-zirconium dimethyl is prepared.

1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-di-isopropyl 2,3-difluorophenyl amidine) the adding in toluene (100mL) solution of-zirconium dichloride (12.30g, 24.7mmol), be cooled to-78 DEG C, drip methyl-magnesium-bromide (16.5mL, 3.0M diethyl ether solution, 49.5mmol) solution, reaction solution at room temperature stirs 18 hours, reacting liquid filtering, and filtrate is concentrated under vacuo obtains crude product, in normal hexane, (100mL) making beating obtains product, yield 73%.

(embodiment 3)

(1): preparation N, N-diethyl-2,4,6-trifluoro benzene carbon amidine.

Diethylamide (11.70g, 0.16mol) is dissolved in 250mL toluene solution, is warming up to 50 DEG C, drip the diethyl ether solution (50mL, 3.0M, 0.15mol) of methyl-magnesium-bromide, after dripping, react after 1.5 hours, white solid is separated out, reaction solution is cooled to 0 DEG C, add the aryl compound (0.15mol) containing cyano group, reaction solution is warming up to room temperature naturally, react after 16 hours, reaction solution adds water (100mL), and extraction is gone out, after organic phase is separated, and aqueous phase extracted with diethyl ether twice (50mL).Organic phase merged, dried over sodium sulfate, filtering sodium sulfate, underpressure distillation concentrates to obtain product (yield 51%).

(2): get 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination zirconium.

(3): preparation 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-diethyl 2,4,6-trifluoro benzene carbon amidine)-zirconium dichloride.

Diethylamide (2.5mL, 1.83g, 18.1mmol) is added 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination zirconium (1.05g, 4.7mmol) and N, N-diethyl 2,4, in toluene (50mL) solution of 6-trifluorophenyl amidine (4.7mmol), reaction was at room temperature stirred after 64 hours, after being leached by solid, with toluene (60mL) drip washing filter residue, obtain crude product after filtrate reduced in volume, obtain product 1,2 with normal hexane making beating washing, 3,4,5-pentamethylcyclopentadiene base-(N, N-diethyl 2,4,6-trifluoro benzene carbon amidine)-zirconium dichloride (yield 50%).(4) 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-diethyl 2,4,6-trifluoro benzene carbon amidine)-zirconium dimethyl is prepared.

1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-diethyl 2,4,6-trifluorophenyl amidine) the adding in toluene (100mL) solution of-zirconium dichloride, be cooled to-78 DEG C, drip methyl-magnesium-bromide (16.5mL, 3.0M diethyl ether solution, 49.5mmol) solution, reaction solution at room temperature stirs 18 hours, reacting liquid filtering, and filtrate is concentrated under vacuo obtains crude product, in normal hexane, (100mL) making beating obtains product, yield 71%.

(embodiment 5)

(1): the synthesis of N, N-dibutyl 2,3,6-trifluoro benzene carbon amidine

Dibutylamine (20.64g, 0.16mol) is dissolved in 250mL toluene solution, is warming up to 50 DEG C, drip the diethyl ether solution (50mL, 3.0M, 0.15mol) of methyl-magnesium-bromide, after dripping, react after 1.5 hours, white solid is separated out, reaction solution is cooled to 0 DEG C, add the aryl compound (0.15mol) containing cyano group, reaction solution is warming up to room temperature naturally, react after 16 hours, reaction solution adds water (100mL), and extraction is gone out, after organic phase is separated, and aqueous phase extracted with diethyl ether twice (50mL).Organic phase merged, dried over sodium sulfate, filtering sodium sulfate, underpressure distillation concentrates to obtain product (yield 45%).

(2): get 1,2,3,4,5-pentamethylcyclopentadiene base-titanous chloride.

(3): preparation 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 2,3,6-trifluoro benzene carbon amidine)-titanium dichloride.

By dibutylamine (2.33g, 18.1mmol) add 1,2,3,4, in toluene (50mL) solution of 5-pentamethylcyclopentadiene base-titanous chloride (4.7mmol) and N, N-dibutyl 2,3-difluorophenyl amidine, reaction was at room temperature stirred after 64 hours, after being leached by solid, with toluene (60mL) drip washing filter residue, after filtrate reduced in volume, obtain crude product, product 1 is obtained with normal hexane making beating washing, 2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 2,3,6-trifluoro benzene carbon amidine)-titanium dichloride (yield 50%).

(4) 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 2,3,6-trifluoro benzene carbon amidine)-dimethyl titanium is prepared.

1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 2,3,6-trifluorophenyl amidine) the adding in toluene (100mL) solution of-titanium dichloride (24.7mmol), be cooled to-78 DEG C, drip methyl-magnesium-bromide (16.5mL, 3.0M diethyl ether solution, 49.5mmol) solution, reaction solution at room temperature stirs 18 hours, reacting liquid filtering, and filtrate is concentrated under vacuo obtains crude product, in normal hexane, (100mL) making beating obtains product, yield 73%.

(embodiment 6)

(1): preparation N, N-diethyl-1,2,3,4,5,6-penta fluoro benzene amidine.

Diethylamide (11.70g, 0.16mol) is dissolved in 250mL toluene solution, is warming up to 50 DEG C, drip the diethyl ether solution (50mL, 3.0M, 0.15mol) of methyl-magnesium-bromide, after dripping, react after 1.5 hours, white solid is separated out, reaction solution is cooled to 0 DEG C, add the aryl compound (0.15mol) containing cyano group, reaction solution is warming up to room temperature naturally, react after 16 hours, reaction solution adds water (100mL), and extraction is gone out, after organic phase is separated, and aqueous phase extracted with diethyl ether twice (50mL).Organic phase merged, dried over sodium sulfate, filtering sodium sulfate, underpressure distillation concentrates to obtain product (yield 47%).

(2): get 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination zirconium.

(3): preparation 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-diethyl 1,2,3,4,5,6-penta fluoro benzene amidine)-zirconium dichloride.

By diethylamide (2.5mL, 1.83g, 18.1mmol) add 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-tri-chlorination zirconium (1.05g, 4.7mmol) and N, N-diethyl 1, 2, 3, 4, 5, in toluene (50mL) solution of 6-pentafluorophenyl group amidine (4.7mmol), reaction was at room temperature stirred after 64 hours, after solid is leached, with toluene (60mL) drip washing filter residue, crude product is obtained after filtrate reduced in volume, product 1 is obtained with normal hexane making beating washing, 2, 3, 4, 5-pentamethylcyclopentadiene base-(N, N-diethyl-1, 2, 3, 4, 5, 6-penta fluoro benzene amidine)-zirconium dichloride (yield 48%).

(4) 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-diethyl 1,2,3,4,5,6-penta fluoro benzene amidine)-zirconium dimethyl is prepared.

1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-diethyl 1,2,3,4,5,6-pentafluorophenyl group amidine)-zirconium dichloride add in toluene (100mL) solution, be cooled to-78 DEG C, drip methyl-magnesium-bromide (16.5mL, 3.0M diethyl ether solution, 49.5mmol) solution, reaction solution at room temperature stirs 18 hours, reacting liquid filtering, filtrate is concentrated under vacuo obtains crude product, and in normal hexane, (100mL) making beating obtains product, yield 63%.

(embodiment 7)

(1): get N, N-dibutyl 1,2,3,4,5,6-trifluoro benzene carbon amidine.

(2): get 1,2,3,4,5-pentamethylcyclopentadiene base-titanous chloride.

(3): preparation 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 1,2,3,4,5,6-penta fluoro benzene amidine)-titanium dichloride.

Dibutylamine (2.33g, 18.1mmol) is added 1,2,3,4,5-pentamethylcyclopentadiene base-titanous chloride (4.7mmol) and N, in toluene (50mL) solution of N-dibutyl 2,3-difluorophenyl amidine, reaction was at room temperature stirred after 64 hours, after solid is leached, with toluene (60mL) drip washing filter residue, after filtrate reduced in volume, obtain crude product, obtain product 1 with normal hexane making beating washing, 2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 1,2,3,4,5,6-penta fluoro benzene amidine)-titanium dichloride (yield 50%).

(4) 1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 1,2,3,4,5,6-penta fluoro benzene amidine)-dimethyl titanium is prepared.

1,2,3,4,5-pentamethylcyclopentadiene base-(N, N-dibutyl 1,2,3,4,5,6-pentafluorophenyl group amidine)-titanium dichloride (24.7mmol) add in toluene (100mL) solution, be cooled to-78 DEG C, drip methyl-magnesium-bromide (16.5mL, 3.0M diethyl ether solution, 49.5mmol) solution, reaction solution at room temperature stirs 18 hours, reacting liquid filtering, filtrate is concentrated under vacuo obtains crude product, and in normal hexane, (100mL) making beating obtains product, yield 73%.

Claims

1. a fluorine-containing benzene carbon amidine single metallocene catalyst, is characterized in that, its general formula as shown in the formula (I):

Wherein:

R1 is fat tertiary amine, and its structure is one of following structure:

R2 is the saturated fatty alkyl of the straight or branched of C1-C8;

Ar is fluorine-containing aromatic ring or fluorine-containing heterocycle, and its structure is one of following structure:

N is 2 ~ 5;

R is structure as shown in the formula (II):

X is chlorine or methyl, and M is titanium or zirconium.

2. fluorine-containing benzene carbon amidine single metallocene catalyst according to claim 1, it is characterized in that: described catalyst is 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dimethyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diethyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dipropyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dibutyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diisopropyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dimethyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diethyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dipropyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dibutyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diisopropyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dimethyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diethyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dipropyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, 5 two fluoro-N, N-dibutyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diisopropyl-1-naphthalene amidine-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dimethyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4,The 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dimethyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dimethyl-3-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diethyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diethyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diethyl-3-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dipropyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dipropyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dipropyl-3-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dibutyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dibutyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dibutyl-3-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diisopropyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diisopropyl-2-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diisopropyl-3-carbonamidine-1-thiophene-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 6-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 6-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 6-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 6-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 6-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-pyrroles's-3,4,5-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,3,4-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,3,6-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,4,5-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,3,4,5-tetrafluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,3,4,6-tetrafluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,3,5,6-tetrafluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-3,5-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,5-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-3,4-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,3-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles-2,4 difluorobenzene amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,6-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-pyrroles's-2,3,4,5,6-phenyl-pentafluoride amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,4,6-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,3,5-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-3,4,5-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,3,4-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,3,6-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,4,5-trifluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,3,4,5-tetrafluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,3,4,6-tetrafluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,3,5,6-tetrafluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-3,5-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2,5-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-3,4-difluoro benzene carbon amidine-titanium chloride, 1,2,3,4,5-pentamethylcyclopentadiene base-piperidines-2, 3-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 6-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 6-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4, 5-trifluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 5-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 5, 6-tetrafluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 5-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 6-difluoro benzene carbon amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-titanium chloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dimethyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diethyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dipropyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dibutyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diisopropyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dimethyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diethyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dipropyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dibutyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diisopropyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dimethyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diethyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dipropyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, 5 two fluoro-N, N-dibutyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diisopropyl-1-naphthalene amidine-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dimethyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dimethyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dimethyl-3-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diethyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diethyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diethyl-3-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4,The 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dipropyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dipropyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dipropyl-3-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dibutyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dibutyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dibutyl-3-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diisopropyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diisopropyl-2-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diisopropyl-3-carbonamidine-1-thiophene-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2,3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 6-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4, 5-trifluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 5-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 5, 6-tetrafluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 5-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 6-difluoro benzene carbon amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-zirconium dichloride, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dimethyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diethyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dipropyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dibutyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diisopropyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dimethyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diethyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dipropyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dibutyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diisopropyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dimethyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diethyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dipropyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, 5 two fluoro-N, N-dibutyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diisopropyl-1-naphthalene amidine-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dimethyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dimethyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dimethyl-3-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diethyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diethyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diethyl-3-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dipropyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dipropyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dipropyl-3-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4,The 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dibutyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dibutyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dibutyl-3-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diisopropyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diisopropyl-2-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diisopropyl-3-carbonamidine-1-thiophene-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 6-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 6-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2,3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 6-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 6-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 6-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-pyrroles-3, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 6-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 6-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4, 5-trifluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 5-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 6-difluoro benzene carbon amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation titanium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dimethyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diethyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dipropyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-dibutyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 8-bis-, N-diisopropyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dimethyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diethyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dipropyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-dibutyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-5, the fluoro-N of 7-bis-, N-diisopropyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dimethyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diethyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-dipropyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, 5 two fluoro-N, N-dibutyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-4, the fluoro-N of 5-bis-, N-diisopropyl-1-naphthalene amidine-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dimethyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dimethyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dimethyl-3-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4,The 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diethyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diethyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diethyl-3-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dipropyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dipropyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dipropyl-3-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-dibutyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-dibutyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-dibutyl-3-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-4-, N-diisopropyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-3-, N-diisopropyl-2-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, the 5-pentamethylcyclopentadiene fluoro-N of base-5-, N-diisopropyl-3-carbonamidine-1-thiophene-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diisopropyl-2, 6-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dimethyl-2, 6-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-diethyl-2, 6-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dipropyl-2, 6-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N, N-dibutyl-2, 6-difluoro benzene carbon amidine-di-methylation zirconium 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4,5-pentamethylcyclopentadiene base-pyrroles-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 6-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-pyrroles-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 4-difluoro benzene carbon amidine-di-methylation zirconium,1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 6-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-piperidines-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 6-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4, 5-trifluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 5-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 5, 6-tetrafluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 5-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-3, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 4-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 6-difluoro benzene carbon amidine-di-methylation zirconium, 1, 2, 3, 4, 5-pentamethylcyclopentadiene base-N methyl piperazine-2, 3, 4, 5, 6-phenyl-pentafluoride amidine-di-methylation zirconium, middle one.

3. a fluorine-containing benzene carbon amidine single metallocene catalyst intermediate as claimed in claim 1, is characterized in that: the structure formula (I) as claimed in claim 1 of described intermediate, and in its Chinese style (I), R1, R2, Ar are as claimed in claim 1, and R is H.

4. fluorine-containing benzene carbon amidine single metallocene catalyst intermediate according to claim 3, is characterized in that: described intermediate is for being N, N-dimethyl-2,4,6-trifluoro benzene carbon amidine, N, N-dimethyl-2,3,5-trifluoro benzene carbon amidine, N, N-dimethyl-2,3,4-trifluoro benzene carbon amidine, N, N-dimethyl-2,3,6-trifluoro benzene carbon amidine, N, N-dimethyl-2,4,5-trifluoro benzene carbon amidine, N, N-dipropyl-2,4,6-trifluoro benzene carbon amidine, N, N-dipropyl-2,3,5-trifluoro benzene carbon amidine, N, N-dipropyl-3,4,5-trifluoro benzene carbon amidine, N, N-dipropyl-2,3,4-trifluoro benzene carbon amidine, N, N-dipropyl-2,3,6-trifluoro benzene carbon amidine, N, N-dipropyl-2,4,5-trifluoro benzene carbon amidine, N, N-diethyl-2,4,6-trifluoro benzene carbon amidine, N, N-diethyl-2,3,5-trifluoro benzene carbon amidine, N, N-diethyl-2,3,4-trifluoro benzene carbon amidine, N, N-diethyl-2,3,6-trifluoro benzene carbon amidine, N, N-diethyl-2,4,5-trifluoro benzene carbon amidine, N, N-dibutyl-2,4,6-trifluoro benzene carbon amidine, N, N-dibutyl-2,3,5-trifluoro benzene carbon amidine, N, N-dibutyl-3,4,5-trifluoro benzene carbon amidine, N, N-dibutyl-2,3,4-trifluoro benzene carbon amidine, N, N-dibutyl-2,3,6-trifluoro benzene carbon amidine, N, N-dibutyl-2,4,5-trifluoro benzene carbon amidine, N, N-di-isopropyl-2,4,6-trifluoro benzene carbon amidine, N, N-di-isopropyl-2,3,5-trifluoro benzene carbon amidine, N, N-di-isopropyl-3,4,5-trifluoro benzene carbon amidine, N, N-di-isopropyl-2,3,4-trifluoro benzene carbon amidine, N, N-di-isopropyl-2,3,6-trifluoro benzene carbon amidine, N, N-di-isopropyl-2,4,5-trifluoro benzene carbon amidine, N, N-dimethyl-2,3,4,5-tetrafluoro benzene carbon amidine, N, N-dimethyl-2,3,4,6-tetrafluoro benzene carbon amidine, N, N-dimethyl-2,3,5,6-tetrafluoro benzene carbon amidine, N, N-dipropyl-2,3,4,5-tetrafluoro benzene carbon amidine, N, N-dipropyl-2,3,4,6-tetrafluoro benzene carbon amidine, N, N-dipropyl-2,3,5,6-tetrafluoro benzene carbon amidine, N, N-diethyl-2,3,4,5-tetrafluoro benzene carbon amidine, N, N-diethyl-2,3,4,6-tetrafluoro benzene carbon amidine, N, N-diethyl-2,3,5,6-tetrafluoro benzene carbon amidine, N, N-dibutyl-2,3,4,5-tetrafluoro benzene carbon amidine, N, N-dibutyl-2,3,4,6-tetrafluoro benzene carbon amidine, N, N-dibutyl-2,3,5,6-tetrafluoro benzene carbon amidine, N, N-di-isopropyl-2,3,4,5-tetrafluoro benzene carbon amidine, N, N-di-isopropyl-2,3,4,6-tetrafluoro benzene carbon amidine, N, N-di-isopropyl-2,3,5,6-tetrafluoro benzene carbon amidine, N, N-dimethyl-2,3,4,5,6-penta fluoro benzene amidine, N, N-diethyl-2,3,4,5,6-penta fluoro benzene amidine, N, N-dipropyl-2,3,4,5,6-penta fluoro benzene amidine, N, N-dibutyl-2,3,4,5,6-penta fluoro benzene, N, N-di-isopropyl-2,3,4,5,6-penta fluoro benzene amidine, fluoro-N, the N-dimethyl of 5,8-bis--1-naphthalene amidine, fluoro-N, the N-diethyl of 5,8-bis--1-naphthalene amidine, fluoro-N, the N-dipropyl of 5,8-bis--1-naphthalene amidine, fluoro-N, the N-dibutyl of 5,8-bis--1-naphthalene amidine, fluoro-N, the N-di-isopropyl of 5,8-bis--1-naphthalene amidine, fluoro-N, the N-dimethyl of 5,7-bis--1-naphthalene amidine, fluoro-N, the N-diethyl of 5,7-bis--1-naphthalene amidine, fluoro-N, the N-dipropyl of 5,7-bis--1-naphthalene amidine, fluoro-N, the N-dibutyl of 5,7-bis--1-naphthalene amidine, fluoro-N, the N-di-isopropyl of 5,7-bis--1-naphthalene amidine, fluoro-N, the N-dimethyl of 4,5-bis--1-naphthalene amidine, fluoro-N, the N-diethyl of 4,5-bis--1-naphthalene amidine, fluoro-N, the N-dipropyl of 4,5-bis--1-naphthalene amidine, 4,5 two fluoro-N, N-dibutyl-1-naphthalene amidines, fluoro-N, the N-di-isopropyl of 4,5-bis--1-naphthalene amidine, fluoro-N, the N-dimethyl of 4--2-carbonamidine-1-thiophene, fluoro-N, the N-dimethyl of 3--2-carbonamidine-1-thiophene, fluoro-N, the N-dimethyl of 5--3-carbonamidine-1-thiophene, fluoro-N, the N-diethyl of 4--2-carbonamidine-1-thiophene, fluoro-N, the N-diethyl of 3--2-carbonamidine-1-thiophene, fluoro-N, the N-diethyl of 5--3-carbonamidine-1-thiophene, fluoro-N, the N-dipropyl of 4--2-carbonamidine-1-thiophene, fluoro-N, the N-dipropyl of 3--2-carbonamidine-1-thiophene, fluoro-N, the N-dipropyl of 5--3-carbonamidine-1-thiophene, fluoro-N, the N-dibutyl of 4--2-carbonamidine-1-thiophene, fluoro-N, the N-dibutyl of 3--2-carbonamidine-1-thiophene, fluoro-N, the N-dibutyl of 5--3-carbonamidine-1-thiophene, fluoro-N, the N-di-isopropyl of 4--2-carbonamidine-1-thiophene, fluoro-N, the N-di-isopropyl of 3--2-carbonamidine-1-thiophene, fluoro-N, the N-di-isopropyl of 5--3-carbonamidine-1-thiophene, N, N-di-isopropyl-3,5-difluoro benzene carbon amidine, N, N-di-isopropyl-2,5-difluoro benzene carbon amidine, N, N-di-isopropyl-3,4-difluoro benzene carbon amidine, N, N-di-isopropyl-2,3-difluoro benzene carbon amidine, N, N-di-isopropyl-2,4 difluorobenzene amidine, N, N-di-isopropyl-2,6-difluoro benzene carbon amidine, N, N-dimethyl-2,5-difluoro benzene carbon amidine, N, N-dimethyl-3,4-difluoro benzene carbon amidine, N, N-dimethyl-2,3-difluoro benzene carbon amidine, N, N-diethyl-2,5-difluoro benzene carbon amidine, N, N-diethyl-3,4-difluoro benzene carbon amidine, N, N-diethyl-2,3-difluoro benzene carbon amidine, N, N-diethyl-2,6-difluoro benzene carbon amidine, N, N-dipropyl-3,5-difluoro benzene carbon amidine, N, N-dipropyl-2,5-difluoro benzene carbon amidine, N, N-dipropyl-3,4-difluoro benzene carbon amidine, N, N-dipropyl-2,3-difluoro benzene carbon amidine, N, N-dipropyl-2,4 difluorobenzene amidine, N, N-dipropyl-2,6-difluoro benzene carbon amidine, N, N-dibutyl-3,5-difluoro benzene carbon amidine, N, N-dibutyl-2,5-difluoro benzene carbon amidine, N, N-dibutyl-3,4-difluoro benzene carbon amidine, N, N-dibutyl-2,3-difluoro benzene carbon amidine, N, N-dibutyl-2,4 difluorobenzene amidine, N, N-dibutyl-2,6-difluoro benzene carbon amidine, pyrroles-2,4,6-trifluoro benzene carbon amidine, pyrroles-2,3,5-trifluoro benzene carbon amidine, pyrroles-3,4,5-trifluoro benzene carbon amidine, pyrroles-2,3,4-trifluoro benzene carbon amidine, pyrroles-2,3,6-trifluoro benzene carbon amidine, pyrroles-2,4,5-trifluoro benzene carbon amidine, pyrroles-2,3,4,5-tetrafluoro benzene carbon amidine, pyrroles-2,3,4,6-tetrafluoro benzene carbon amidine, pyrroles-2,3,5,6-tetrafluoro benzene carbon amidine, pyrroles-3,5-difluoro benzene carbon amidine, pyrroles-2,5-difluoro benzene carbon amidine, pyrroles-3,4-difluoro benzene carbon amidine, pyrroles-2,3-difluoro benzene carbon amidine, pyrroles-2,4 difluorobenzene amidine, pyrroles-2,6-difluoro benzene carbon amidine, pyrroles-2,3,4,5,6-penta fluoro benzene amidine, piperidines-2,4,6-trifluoro benzene carbon amidine, piperidines-2,3,5-trifluoro benzene carbon amidine, piperidines-3,4,5-trifluoro benzene carbon amidine, piperidines-2,3,4-trifluoro benzene carbon amidine, piperidines-2,3,6-trifluoro benzene carbon amidine, piperidines-2,4,5-trifluoro benzene carbon amidine, piperidines-2,3,4,5-tetrafluoro benzene carbon amidine, piperidines-2,3,4,6-tetrafluoro benzene carbon amidine, piperidines-2,3,5,6-tetrafluoro benzene carbon amidine, piperidines-3,5-difluoro benzene carbon amidine, piperidines-2,5-difluoro benzene carbon amidine, piperidines-3,4-difluoro benzene carbon amidine, piperidines-2,3-difluoro benzene carbon amidine, piperidines-2,4 difluorobenzene amidine, piperidines-2,6-difluoro benzene carbon amidine, piperidines-2,3,4,5,6-penta fluoro benzene amidine, N methyl piperazine-2,4,6-trifluoro benzene carbon amidine, N methyl piperazine-2,3,5-trifluoro benzene carbon amidine, N methyl piperazine-3,4,5-trifluoro benzene carbon amidine, N methyl piperazine-2,3,4-trifluoro benzene carbon amidine, N methyl piperazine-2,3,6-trifluoro benzene carbon amidine, N methyl piperazine-2,4,5-trifluoro benzene carbon amidine, N methyl piperazine-2,3,4,5-tetrafluoro benzene carbon amidine, N methyl piperazine-2,3,4,6-tetrafluoro benzene carbon amidine, N methyl piperazine-2,3,5,6-tetrafluoro benzene carbon amidine, N methyl piperazine-3,5-difluoro benzene carbon amidine, N methyl piperazine-2,5-difluoro benzene carbon amidine, N methyl piperazine-3,4-difluoro benzene carbon amidine, N methyl piperazine-2,3-difluoro benzene carbon amidine, N methyl piperazine-2,4 difluorobenzene amidine, N methyl piperazine-2,6-difluoro benzene carbon amidine, N methyl piperazine-2,3, a kind of in 4,5,6-penta fluoro benzene amidine.

5. an application for fluorine-containing benzene carbon amidine single metallocene catalyst as claimed in claim 1 or 2, is characterized in that: its application and olefin polymerization process.

6. a preparation method for fluorine-containing benzene carbon amidine single metallocene catalyst as claimed in claim 1 or 2, comprises the steps:

A () is obtained by reacting aryl amidine with saturated fatty secondary amine, methyl-magnesium-bromide and the aryl compound with cyano group;

(b) with triethylamine reaction reagent, and above-mentioned aryl amidine and 1,2,3,4,5-pentamethylcyclopentadiene base-tri-chlorination (titanium or zirconium) reaction, obtain 1,2,3,4,5-pentamethylcyclopentadiene base-aryl amidine-dichloride (titanium or zirconium);

C () 1,2,3,4,5-pentamethylcyclopentadiene base-aryl amidine-dichloride (titanium or zirconium) and methyl bromide reactive magnesium, obtains product 1,2,3,4,5-pentamethylcyclopentadiene base-aryl amidine-dimethyl (titanium or zirconium).